• Journal of the Korea Concrete Institute
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• v.19 no.5
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• pp.613-621
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• 2007

Due to the increasing significance of durability, much researches on carbonation, one of the major deterioration phenomena are carried out. However, conventional researches based on fully hardened concrete are focused on prediction of carbonation depth and they sometimes cause errors. In contrast with steel members, behaviors in early-aged concrete such as porosity and hydrates (calcium hydroxide) are very important and may be changed under carbonation process. Because transportation of deteriorating factors is mainly dependent on porosity and saturation, it is desirable to consider these changes in behaviors in early-aged concrete under carbonation for reasonable analysis of durability in long term exposure or combined deterioration. As for porosity, unless the decrease in $CO_2$ diffusion due to change in porosity is considered, the results from the prediction is overestimated. The carbonation depth and characteristics of pore water are mainly determined by amount of calcium hydroxide, and bound chloride content in carbonated concrete is also affected. So Analysis based on test for hydration and porosity is recently carried out for evaluation of carbonation characteristics. In this study, changes in porosity and hydrate $(Ca(OH)_2)$ under carbonation process are performed through the tests. Mercury Intrusion Porosimetry (MIP) for changed porosity, Thermogravimetric Analysis (TGA) for amount of $(Ca(OH)_2)$ are carried out respectively and analysis technique for porosity and hydrates under carbonation is developed utilizing modeling for behavior in early-aged concrete such as multi component hydration heat model (MCHHM) and micro pore structure formation model (MPSFM). The results from developed technique is in reasonable agreement with experimental data, respectively and they are evaluated to be used for analysis of chloride behavior in carbonated concrete.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.6
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• pp.9-17
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• 2019

Cement hydrates and the related characteristics change with ages, and the behaviors are much related with chloride diffusion. In this work, 30% replacement ratio with FA(Fly Ash) and GGBFS(Ground Granulated Blast Furnace Slag) are considered for concrete with three levels of W/B (Water to Binder ratio) and 2 years of curing period. Chloride diffusion coefficients from accelerated condition are obtained at 5 measurement period (28days, 56days, 180days, 365days, and 730days), and the results are compared with porosity, binding capacity, and permeability from program-DUCOM. The similar changing pattern between chloride diffusion and permeability is observed since permeability is proportional to the square of porosity. Curing period is grouped into 4 periods and the changing ratios are investigated. Cement hydrate characteristics such as porosity, permeability, and diffusion coefficient are dominantly changed at the early ages (28~56 days), and diffusion coefficient in OPC concrete with low W/B continuously changes to 180days.

• Resources Recycling
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• v.24 no.1
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• pp.12-20
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• 2015

In this study, change of hydration property with contents and type of gypsum in ternary natural hydraulic lime containing blast furnace slag and gypsum was investigated. Anhydrite, hemihydrate and dihydrate were added 3 % and 10 %, respectively in natural hydraulic lime adding blast furnace slag 20 %. Hydration and physical behavior due to solubility and reactivity of different types of gypsum were analyzed in early hydration. As a result of analysis of hydration properties, in all samples, hydrates such as ettringite and C-S-H were produced in early hydration, and amount of hydrates with increase of hydration time was increased. In the case of compressive strength, when contents of gypsum are 3 %, it was higher compressive strength than other specimens. At hydration 28 days, for addition of anhydrite and hemihydrate, compressive strength was more than adding dihydrate.

• Cement Symposium
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• s.38
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• pp.124-132
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• 2011

• Cement Symposium
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• no.23
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• pp.165-169
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• 1995

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.132-133
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• 2018

The In this study, the change of composition of the hydrates according to the recovery age of concrete in the case of fire damage was confirmed through microscopic analysis. In 28 days of age, the production of ettringite was higher than that of day 1, and the calcium hydroxide was increased in the 91 day. It has been recovered through the generation of major hydrates which affect the strength.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.1
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• pp.1-12
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• 2021

The present study proposes the modified-stoichiometric model for describing hydration of sodium silicate-based alkaliactivated slag(AAS), and compares the results with the thermodynamic modelling-based calculations. The proposed model is based on Chen and Brouwers(2007a) model with updated database as reported in recent studies. In addition, the calculated results for AAS are compared to those for hydrated portland cement. The maximum difference between the proposed model and the thermodynamic calculation for AAS was at most 20%, and the effects of water-to-binder ratio and activator dosages were identically described by both approaches. In particular, the amount of non-evaporable water was within 10% difference, and was in excellent agreement with the experimental results. Nevertheless, notable deviation was observed for the chemical shrinkage, which is largely dependent on the volume of hydrates and pores.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2010.04a
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• pp.758-761
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• 2010

본 연구에서는 원전격납구조물과 같이 고품질의 대형 매스콘크리트의 설계, 시공, 품질예측 및 관리에 필요한 구조물 건전성 평가시스템 구축의 일환으로 수화열 예측 프로그램을 개발하였다. 개발된 수화열 예측 프로그램은 국내에서 생산된 시멘트 및 결합재의 화학조성성분, 분말도와 같은 기초정보 및 배합정보를 입력하여 경시변화에 따른 수화발열량을 계산하는 방식으로서 기존의 연구결과를 바탕으로 개발되었다. 개발된 프로그램은 배합환경조건을 고려하여 초기배합온도 3종류(10, 20, $30^{\circ}C$)로 실험한 단열온도상승 실험 결과와 비교해 보았으며, 좋은 상관성을 나타냄을 확인할 수 있었다.

• Solar Energy
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• v.10 no.2
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• pp.38-43
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• 1990

The present study was to investigate the use of a phase change material for hydronic radiant floor heating. Two identical unit test cells sized $1.8m^L{\times}1.8m^W{\times}1.8m^H$ were built and installed with specially designed $1.6cm^T{\times}9cm^W{\times}80cm^H$ aluminum Ondol-panels holding 1.25kg of calcium chloride hexahydrate(CCH) each. It was found that the Ondol-panel with CCH reduced the room temperature fluctuations and maintains the phase changing temperature for considerably long duration, $2{\sim}4$ times of heating hour, over no-CCH one.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.741-744
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• 2008

Quality control of early age concrete significantly influences the long term performance. Primary factors for early age concrete quality control should include the relative humidity and temperature variation, and these are more important as structures become massive and huge. Temperature raise due to cement hydration causes stress, which can develop to cracking with internal and/or external restraints. Exposure conditions including ambient temperature, humidity and wind also significantly affect the cracking behavior of early age concrete. Among many of studies on the early age concrete behavior, investigation on the variation of temperature and relative humidity internal of concrete is not common. That is in part because the difficulties in measuring the relative humidity and temperature inside the concrete. This study used a digital sensor with an appropriate logger to measure internal temperature and relative humidity. This direct measuring method is expected to provide more reliable and comprehensive data acquisition on the early age behavior of concrete.