• Title/Summary/Keyword: 수평 성장

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수평배향 SWNTs의 직경제어 합성에 관한 연구

  • Kim, Jin-Ju;Jeong, Gu-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.457-457
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    • 2011
  • 단일벽 탄소나노튜브(SWNTs)는 직경 및 키랄(chiral)특성에 따라 반도체성 튜브와 금속성 튜브로 구분되며, 작은 직경의 SWNTs는 큰 직경의 튜브에 비하여 일반적으로 기계적 특성이 뛰어나다고 알려져 있다. 따라서, 합성하는 단계에서 SWNTs의 직경 및 chiral 특성의 제어가 가능 하게 된다면 전자소자로의 응용을 한층 앞당길 수 있을 것으로 예상하고 있다. 이와 더불어 SWNTs의 수평배향성장은 SWNTs의 집적(integration)을 용이하게 할 수 있기 때문에 향후 나노전자소자 개발을 목표로 최근 많은 연구결과들이 보고되고 있다. 하지만 현재는 SWNTs가 고밀도로 합성되기 때문에, 우수한 개별 (individual) SWNT의 전기적 특성보다는 집단적(ensemble) 특성을 얻고 있다. 따라서, 합성기판 위에서 개별적인 SWNT를 낮은 밀도로 수평배향 성장하는 일은 향후 나노튜브기반의 고성능 전자소자 개발에 중요한 과제이다. 나아가, 수평배향 성장 된 개별 SWNT의 직경 및 키랄 특성까지 함께 제어할 수 있다면 곧바로 응용에 적용할 수 있는 획기적인 기술이 될 것이다. 본 연구에서는, SWNTs의 수평배향도 및 직경을 제어하여 성장시키는 것을 목표로 하였다. 합성기판은 퀄츠를 이용하였고, 합성촉매로는 나노입자의 밀도를 비교적 쉽게 제어할 수 있고, 균일한 크기를 갖는 페리틴 단백질을 이용하였다. 단분산(monodispersion) 된 촉매 나노입자를 얻기 위해서 스핀코팅 조건과 페리틴 용액농도를 조절하여 퀄츠기판 위에 분산시킨 후, 아르곤 분위기 하에 열처리를 통하여 촉매 나노입자의 크기 감소를 유도하였다. 그 결과 열처리 시간이 증가함에 따라 촉매 나노입자의 크기가 감소하는 것을 알 수 있었고, SWNTs의 직경 또한 감소하는 것을 확인하였다. 또한 퀄츠기판 위에 직경제어 합성 된 수평배향 SWNTs를 다른 기판으로 전사하는 기술을 확립함으로써, 향후 SWNTs기반의 소자 제작기술의 바탕을 마련하였다.

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A New Poly-Si TFT with Selectively Doped Channel Fabricated by Novel Excimer Laser Annealing (새로운 레이저 어닐링 방법을 이용한 다결정 실리콘 박막 트랜지스터)

  • Lee, Jae-Hoon;Lee, Min-Cheol;Jeon, Jae-Hong;Han, Min-Koo
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1448-1450
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    • 2001
  • 본 연구에서는 알루미늄 마스크를 이용하여 다결정 실리콘 결정립의 수평성장을 유도하는 새로운 엑시머 레이저 어닐링 방법을 제안한다. 제안된 방법은 비정질 실리콘 박막 위에 알루미늄 패턴을 형성하여 선택적으로 레이저 빔을 차단시키고, 액상 실리콘의 열을 금속박막을 통해 방출시킴으로써 다결정 실리콘 결정립의 수평성장을 유도할 수 있다. 제안된 레이저 결정화 방법을 이용하여 최대 1.6${\mu}m$의 수평성장 결정립을 형성하였고, 알루미늄 패턴의 경계로부터 결정립을 성장시킴으로써 결정립 경계의 위치를 제어하였다. 제안된 방법을 이용하여 제작한 다결정 실리콘 박막 트랜지스터는 기존의 다결정 실리콘 박막 트랜지스터에 비해 전계효과 이동도 및 온/오프 전류비 등의 전기적 특성이 우수하였다.

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Calculation of the amount of excess As charge for the GaAs single crystal growting with the horizontal Bridgman method of single temperature zone(1-T HB) (단일 온도대역 수평 Bridgman(1-T HB) 법에 의한 GaAs 단결정 성장시 As 원소의 초과 유입량 계산)

  • 오명환;주승기
    • Korean Journal of Crystallography
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    • v.7 no.1
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    • pp.64-72
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    • 1996
  • Calculation of the amount of excess arsenic charge has been carried out for the single crystal growth of GaAs with 1-T HB(single temperature zone horizontal Bridgman) method which has no low temperature arsenic zone. Based upon the investigation of the thermochemical properties of the Ga and As system, a general equation for the excess dimension of the ampoule and temperature gradient of the furnace. From this result, a theoretical background of the 1-T HB method has been constructed for the single crystal growth of GaAs.

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GaN epitaxial growths on chemically and mechanically polished sapphire wafers grown by Bridgeman method (수평 Bridgeman법으로 성장된 사파이어기판 가공 및 GaN 박막성장)

  • 김근주;고재천
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.5
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    • pp.350-355
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    • 2000
  • The fabrication of sapphire wafer in C plane has been developed by horizontal Bridgeman method and GaN based semiconductor epitaxial growth has been carried out in metal organic chemical vapour deposition. The single crystalline ingot of sapphire has been utilized for 2 inch sapphire wafers and wafer slicing and lapping machines were designed. These several steps of lapping processes provided the mirror-like surface of sapphire wafer. The measurements of the surface flatness and the roughness were carried out by the atomic force microscope. The GaN thin film growth on the developed wafer was confirmed the wafer quality and applicability to blue light emitting devices.

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Utilization of Egg Type Male Chicks From Hatchery to Produce Yeast Culture for Animal Feed. (부화부산물 수평아리 사체를 이용한 사료용 효모 배양에 관한 연구)

  • 심관섭;박강희;김정학
    • Journal of Animal Environmental Science
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    • v.6 no.3
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    • pp.201-209
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    • 2000
  • Optimal conditions to utilize egg type male chicks from hatchery for cultivating yeast(Saccharomyces cerevisiae) and the effects of the yeast culture on growth of broiler chicks were investigated. The protein concentration of the spent cockerel extracts was the highest when extracted for 72 hours. Optimal water volume added to the spent cockerel chicks for the extraction was 1.5 times to the cockerel chicks weight (v/w ratio). Lipid in the extracts from the spent cockerel chicks did not affect on the yeast growth. The number of yeast cultured in the SCELP2 medium containing spent cockerel extracts and 4 % sugarcane molasses was higher by 26 % than that in the YEPD medium containing 1 % yeast extract, 2 % bacto pepton and 2 % glucose. Also the number of yeast cultured in the SBYW2 medium containing SCEP2 medium containing SCELP2 and 4 % brewer's yeast waste was increased by 8 %, compared to that in the SCELP2 medium. Body weight gain of chicks fed 4 % yeast culture supplementations cultivated in the SBYW2 medium was increased at 5 weeks by 9 %, relative to no supplementation(P<0.05). The results from this study suggest that the spent cockerel chicks can be utilized as nitrogen sources to produce yeast culture for animal feed.

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Cephalometric study of the effect of cervical pull headgear based on facial growth patterns (안모의 성장유형에 따른 경부견인 헤드기어의 효과에 대한 두부방사선계측학적 연구)

  • Kang, Eun-Ha;Chang, Chongon
    • The korean journal of orthodontics
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    • v.29 no.4 s.75
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    • pp.503-510
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    • 1999
  • The purpose of this study is to investigate the negative effects of cervical pull headgear and to compare the differences between the two groups of growers-vertical grower and horizontal grower group-which are classified by the posterior-anterior facial height ratio. Initial and final lateral cephalograms were taken for 26 patients including 15 vertical growers and 11 horizontal growers ; also, 3 angular measurements and 4 linear measurements were evaluated. The following results were found. 1. The palatal plane was tipped anteroinferiorly in the vertical grower group. 2. The posterior facial height/anterior facial height ratio was increased in the horizontal grower group. 3. The Mandibular plane angle remained stable on both groups. 4. There was no significant difference between the two groups in the amount of maxillary molar extrusion.

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Melt-solid interface and segregation in horizontal bridgman growth using 2 - and 3 - dimensional pseudo - steady - state model (2차원 및 3차원 정상상태 모델에 의한 수평브릿지만 결정성장에서의 고 - 액 계면과 편석)

  • 민병수;김도현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.4
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    • pp.306-317
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    • 1995
  • Abstract Gallium arsenide crystal is usually grown from the melt by the horizontal Bridgman method. We constructed pseudo - steady - state model for crystal growth of GaAs which inclue melt, crystal and the free interface. Mathematical equations of the model were solved for flow, temperature, and concentration field in the melt and temperature field in the crystal. The location and shape of the interface were also solved simultaneously. In 2 - dimensional model, the shape of the interface is flat with adiabatic thermal boundary condition, but it becomes curved with completely conducting thermal boundary condition. In 3 - dimensional model, the interface is less curved than 2 - dimensional case and the flow intensity is similar to that of 2 - dimensional case. With the increase of flow intensity vertical segregation shows maximum value in both 2 - and 3 - D model. However, the maximum value occurs in lower flow intensity in 2 - D model because the interface is more curved for the same flow intensity.

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Microstructures of Horizontally Grown Multicrystalline Silicon Ribbon Molten Silcon (용융 실리콘으로부터 수평 성장 된 다결정 실리콘 리본의 미세구조)

  • Ko, Seung-Jin;Jang, Bo-Yun;Kim, Joon-Soo;Ahn, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.222-222
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    • 2010
  • 수평성장 방식을 이용하여 다결정 실리콘 리본을 제조하였으며, 제조된 리본의 미세구조 및 결함을 분석하였다. 기존 잉곳 성장 및 절단 공정을 통해 제조된 실리콘 웨이퍼는 절단 중 실리콘의 손살 때문에 단가를 상승 시킨다. 따라서 실리콘 용탕으로부터 직접 웨이퍼를 제조하는 리본 기술이 활발히 연구되고 있다. 본 연구에서는 수명 성장 법을 이용하여 용융 실리콘으로부터 다결정 실리콘 리본을 제조 하였다. 제조 된 리본의 크기$50{\times}50$ mm였으며 두께는 $375{\pm}50{\mu}m$ 이었다. 또한, 미세구조 분석 결과 결정들의 형상이 불규칙적 이었으며, 바닥에서부터 윗부분까지 한 방향으로 성장되었다. 수직성장된 결정들의 평균 입경은 $50.2{\mu}m$ 이었다. 전위 (dislocations ), 이중(twins), 그리고 기공 (pores) 같은 구조적 결점들과 SiC, 탄소, 그러고 산소와 같은 불순물 결함 등이 관찰 되었다. 본 연구를 통해 제조된 다결정 실리콘 리본은 태양전지용 웨이퍼로 응용 가능 할 것으로 판단된다.

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Finite element analysis of transient growth of GaAs by horizontal Bridgman method (수평브릿지만법에 의한 갈륨비소 과도기 성장의 유한요소 해석)

  • 김도현;민병수
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.1
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    • pp.19-31
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    • 1996
  • To invetigate the impurity distribution in GaAs crystal grown by horizontal Bridgman method, we constructd the mathematical model describing heat transfer, mass transfer and fluid flow n transient growth of GaAs. Galerkin finite element method and implicit time integration were used to solve the equations and simulate the transient growth. The concentration distribution is similar to the case of diffusion controlled growth when Gr - 0. With the increase of Gr the concentration profile is distroted and the minimum solute concentration appears near the interface. As solidification prosceeds, interface deflection increases steadily and transverse segregation increases until mixing by flow becomes steady. The axial segregation increases with solidification. But, with high intensity of flow axial segregation becomes steady after short transient. At small and large Gr the result showed a good agreememt with the prediction Smith and Scheil.

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Effect of Environment Factors on Growth and Mortality of Cupped Oyster, Crassostrea gigas (양식장 환경이 갯벌양식 굴 (Crassostrea gigas)의 성장과 폐사에 미치는 영향)

  • Park, Sang-Woo;Kim, Yong;Kim, Ji-Hye;Chung, Su-Whan;Han, Kyung-Nam
    • The Korean Journal of Malacology
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    • v.29 no.4
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    • pp.273-281
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    • 2013
  • In order to evaluate how the effects of aquacultural environment, such as temperature, salinity, DO, SS, Chlorophyll-a, COD and nutritive salts on Cupped oysters, an investigational study was conducted between September to December of 2011. During the study, different intermediate cage farms on the surface of the sea were used to culture and compare the growth and survival rate of the Cupped oysters in different fishing environments. The different intermediate cage farms used were Wonsando-ri, Chang-ri, and Pado-ri. In January of 2012, these oysters were transplanted to a horizontal net farm in a mudflat until July of that year. The adaptation rates of the Cupped oysters were tested at differential exposure times at varying intertidal periods. Wonsando-ri showed the highest water temperature and Chlorophyll-a levels, while the salinity was found to be within range of stable conditions among all three intermediate cage farms. Once the Cupped oysters were at the horizontal net farm, the growth was measured at distinct tidal exposure time of 1, 3, and 5 hours, whereby the growth rate was highest at 3, 1, and 5 hours, respectively. In addition, the oysters cultivated in intermediate cage farms had longer shell lengths compared to shell heights, while oysters cultured in the horizontal net farm had larger shell heights than shell lengths.