• Title/Summary/Keyword: 수치확산

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Effect of Current Density on Ion Conductivity of Membrane in Proton Exchange Membrane (고분자전해질 연료전지에서 고분자막의 이온전도도에 미치는 전류밀도의 영향)

  • Hwang, Byungchan;Oh, Sohyung;Lee, Daewoong;Chung, Hoi-Bum;You, Seung-Eul;Ku, Young-Mo;Na, Il-Chae;Lee, Jung-Hoon;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.1-5
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    • 2018
  • In this work, we study the ion conductivity by analyzing the impedance to the high current density range that the PEMFC (Proton Exchange Membrane Fuel Cell) is actually operated. The effect of GDL (Gas Diffusion Layer)presence on impedance was investigated indirectly by measuring hydrogen permeability. When the RH (Relative Humidity)was higher than 60% in the low current range (< $80mA/cm^2$), the moisture content of the polymer membrane was sufficient and the ion conductivity of the membrane was not influenced by the current change. However, when RH was low, ion conductivity increased due to water production as current density increased. The ion conductivity of the membrane obtained by HFR (High Frequency Resistance) in the high current region ($100{\sim}800mA/cm^2$)was compared with the measured value and simulated value. At RH 100%, both experimental and simulated values showed constant ion conductivity without being influenced by current change. At 30~70% of RH, the ionic conductivity increased with increasing current density and tended to be constant.

Reservoir Modeling for Carbon Dioxide Sequestration and Enhanced Oil Recovery (이산화탄소 지중저장과 원유 회수증진 공정을 위한 저류층 모델링)

  • Kim, Seung-Hyok;Lee, Jong-Min;Yoon, En-Sup
    • Journal of the Korean Institute of Gas
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    • v.16 no.3
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    • pp.35-41
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    • 2012
  • Manifold researches for carbon capture and storage (CCS) have been developed and large scale-carbon capture system can be performed recently. Hence, the technologies for $CO_2$ sequestration or storage become necessary to handle the captured $CO_2$. Among them, enhanced oil recovery using $CO_2$ can be a solution since it guarantees both oil recovery and $CO_2$ sequestration. In this study, the miscible flow of oil and $CO_2$ in porous media is modeled to analyze the effect of enhanced oil recovery and $CO_2$ sequestration. Based on Darcy-Muskat law, the equation is modified to consider miscibility of oil and $CO_2$ and the change of viscosity. Finite volume method is used for numerical modeling. As results, the pressure and oil saturation changes with time can be predicted when oil, water, and $CO_2$ are injected, respectively, and $CO_2$ injection is more efficient than water injection for oil recovery.

Optimization Method for the Design of LCD Back-Light Unit (LCD Back-Light Unit 설계를 위한 최적화 기법)

  • Seo Heekyung;Ryu Yangseon;Choi Joonsoo;Hahn Kwang-Soo;Kim Seongcheol
    • Journal of KIISE:Computer Systems and Theory
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    • v.32 no.3
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    • pp.133-147
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    • 2005
  • Various types of ray-tracing methods are used to predict the quantity measures of radiation illumination, the uniformity of illumination, radiation performance of LCD BLU(Hack-Light Unit). The uniformity of radiation illumination is one of the most important design factor of BLU and is usually controlled by the diffusive-ink pattern printed on the bottom of light-guide panel of BLU. Therefore it is desirable to produce an improved (ideally, the optimal) ink pattern to achieve the best uniformity of radiation illumination. In this paper, we applied the Welder-Mead simplex-search method among various direct search method to compute the optimal ink pattern. Direct search methods are widely used to optimize the functions which are often highly nonlinear, unpredictably discontinuous, and nondifferentiable, The ink-pattern controlling the uniformity of radiation illumination is one type of these functions. In this paper, we found that simplex search methods are well suited to computing the optimal diffusive-ink pattern. In extensive numerical testing, we have found the simplex search method to be reasonably efficient and reliable at computing the optimal diffusive-ink pattern. The result also suggests that optimization can improve the functionality of simulation tools which are used to design LCD BLU.

A Three-Dimensional Galerkin-FEM Model with Density Variation (밀도 변화를 포함하는 3차원 연직함수 전개모형)

  • 이호진;정경태;소재귀;강관수;정종율
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.8 no.2
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    • pp.123-136
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    • 1996
  • A three-dimensional Galerkin-FEM model which can handle the temporal and spatial variation of density is presented. The hydrostatic approximation is used and density effects are included by means of conservation equation of heat and the equation of state. The finite difference grids are used in the horizontal plane and a set of linear-shape functions is used for the vertical expansion. The similarity transform is introduced to solve resultant matrix equations. The proposed model was first applied to the density-driven circulation in an idealized basin in the presence of the heat exchange between the air and the sea. The advection terms in the momentum equation were ignored, while the convection terms were retained in the heat equation. Coefficients of the vertical eddy viscosity and diffusivity were fixed to be constant. Calculation in a non-rotating idealized basin shows that the difference in heat capacity with depth gives rise to the horizontal gradient of temperature. Consequently, there is a steady new in the upper layer in the direction of increasing depth with compensatory counter flow .in the lower layer. With Coriolis force, geostrophic flow was predominant due to the balance between the pressure gradient and the Coriolis force. As a test in region of irregular topography, the model is applied to the Yellow Sea. Although the resultant flow was very complex, the character of the flow Showed to be geostrophic on the whole.

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Kinetic Behavior of Immobilized Tyrosinase on Carbon in a Simulated Packed-Bed Reactor (충전층에서 탄소에 고정시킨 Tyrosinase의 반응속도에 관한 연구)

  • Shin, Sun Kyoung;Kim, Kyeo-Keun
    • Analytical Science and Technology
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    • v.10 no.1
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    • pp.66-74
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    • 1997
  • Influence of the axial dispersion on immobilized enzyme catalytic bed was investigated in order to examine the kinetic behavior of the biocatalysis. The enzyme employed in this study was the tyrosinase(EC 1.14.18.1) immobilized on carbon support : this system requires two substrates of phenol and oxygen. This enzyme has potential application for phenol degradation in waste water. A simulated reactor was a packed-bed reactor of 2.54cm in diameter and 10cm long, loaded with the immobilized carbon particle with an average diameter of $550{\mu}m$. A phenol feed in the strength of 55.5mM(5220ppm) was used to observe the behavior of the immobilized enzyme column at three different dissolved oxygen levels of 0.08445mM(2.7ppm), 0.1689mM(5.4ppm) and 0.3378mM(9.5ppm) with the flow rates in the range of 60(1mL/s) to 180mL/min(3mL/s). Examination of the Biot number and Damkolher numbers of the immobilized system enables us to eliminate the contribution of external mass transfer to set of differential equations derived from the dispersion model. Solution of the equation was finally obtained numerically with the application of the Danckwert boundary conditions and the assumed zero-and first order rates on the non-linear two substrate enzyme kinetics. Higher conversion of phenol was observed at the low flow rates and at the higher oxygen concentration. Comparison of axial dispersion and plug flow model showed that no detectable difference was observed in the column outlet conversion between the axial and the plug flow models which was in complete agreement with the previous studies.

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Heat of Combustion Experiment Based on the Ratio of Moisture Content of Infected and Non-Infected Bursaphelenchus Xylophilus (재선충 감염 소나무와 비 감염 소나무의 수분함유율에 따른 연소열 실험)

  • Kwon, Hyuk;Kong, Ha-Sung
    • The Journal of the Convergence on Culture Technology
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    • v.7 no.2
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    • pp.443-451
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    • 2021
  • This study compared and analyzed the thermal characteristics based on the ratio of moisture content of infected and non-infected Bursaphelenchus Xylophilus by heat of combustion experiment. The experiment results are as follows. The analysisresult of the ratio of water content shows that 19.92% on average for infected Bursaphelenchus Xylophilus and 26.27% for non-infected which decreases water content as the size of conduction, convection, and radiant heat increases in case of fire. As the vaporization of the moisture content accelerates, the average moisture content is reached, and the result is contrary to the thermal characteristics of the wood that the moisture content is not ignited by a heat source when the moisture content is under 15%. The combustion heat analysis result showed that infected and non-infected Bursaphelenchus Xylophilus had no significant difference in combustion heat at about 3%. However, it shows that combustion heat is higher than other species. In conclusion, decreasing in moisture content based on the increasing conduction, convection, and radiant heat is one of the direct causes of ignition, and the lower the moisture content, the faster the fire spreads.

Numerical Modeling for Effect on Bund Overtopping Caused by a Catastrophic Failure of Chemical Storage Tanks (저장시설의 순간 전량 방출 시 방류벽의 월파 효과에 대한 수치모델링)

  • Min, Dong Seok;Phark, Chuntak;Jung, Seungho
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.42-50
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    • 2019
  • As the industry develops in Korea, the use of hazardous chemicals is increasing rapidly and chemical accidents are increasing accordingly. Most of the chemical accidents are caused by leaks of hazardous chemicals, but there are also accidents in which all the substances are released instantaneously due to sudden high temperature/pressure or defection of the storage tanks. This is called catastrophic failure and its frequency is very low, but consequence is very huge when it occurs. In Korea, there were 15 casualties including three deaths due to catastrophic rupture of water tank in 2013, and 64 instances of failures from 1919 to 2004 worldwide. In case of catastrophic failure, it would be able to overflow outside the bund that reduces the evaporation rate and following consequence. This incident is called overtopping. Overseas, some researchers have been studying the amount of external overflow depending on bund conditions in the event of such an accident. Based on the previous research, this study identified overtopping fraction by condition of bund in accordance with Korea Chemicals Controls Act Using CFD simulation. As a result, as the height increases and the distance to the facility decreases while meeting the minimum standard of the bund capacity, the overtopping effect has decreased. In addition, by identifying the effects of overtopping according to atmospheric conditions, types of materials and shapes of bunds, this study proposes the design of the bund considering the effect of overtopping caused by catastrophic failure with different bund conditions.

Analysis of CO2 Emission Depending on Hydrogen Production Methods in Korea (국내 수소 생산에 따른 CO2 발생량 분석)

  • Han, Ja-Ryoung;Park, Jinmo;Kim, Yohan;Lee, Young Chul;Kim, Hyoung Sik
    • Journal of the Korean Institute of Gas
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    • v.23 no.2
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    • pp.1-8
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    • 2019
  • Because of environmental pollution problem, interests in hydrogen energy has been concentrating sharply. Especially in Korea, the market related with fuel cell vehicles and hydrogen refueling stations is increasing actively under the government-led. However, the actual contributions to environmental improvement effect of hydrogen energy is required to be evaluated with representing reality. In this sense, lots of conventional analyzing tools have some limitations to adapt in Korea's situation directly. It is caused by the differences of raw energy market between the US and Korea. That is, most of analytic tools are developed by representing energy market of the US, where can produce variety of raw feed energy sources. Therefore, in this paper, we propose mass balance based numerical analyzing method, which is suitable for the actual hydrogen production process in Korea for exact evaluation of $CO_2$ emission amount in this country. Using proposed method, we has demonstrated reformed hydrogen from natural gas, LPG and naphtha, electrolysis-based hydrogen, and COG-based hydrogen. Furthermore, with the comparison of GREET program analysis results, robustness of numerical analysis method is demonstrated.

The Development of VR based Application for Realistic Disaster Prevention Training (현실감 있는 재난재해 예방 교육을 위한 VR 기반 앱 개발)

  • Kim, Taehoon;Youn, Junhee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.12
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    • pp.287-293
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    • 2018
  • The Korean peninsula has been known as an area that is free of volcanic disasters. However, recent observations and research results of volcanoes in Far East Asia, including Baedu Mountain and Japanese volcanoes, show that the Korean peninsula is no longer a safe area from volcanic disasters. Since 2012, the Korean government has been developing an IT-based construction technology, VDRS (Volcanic Disaster Response System), for effective volcanic disaster response system. The main users of VDRS are public officers in central or local governments. However, most of them have little experience and knowledge about volcanic disasters. Therefore, it is essential to develop education contents and implement training on volcanic disaster response for effective response in a real disaster situation. In this paper, we deal with the development of a mobile application based on virtual reality (VR) for realistic volcanic disaster response training. The objectives of training are the delivery of knowledge and experience for volcanic disasters. First, VR contents were generated based on spatial information. A 3D model was constructed based on a Digital Elevation Model (DEM), and visualization models for meterological effects and various volcanic disaster diffusion effects were implemented for the VR contents. Second, the mobile application for the volcanic disaster response training was implemented. A 12-step story board is proposed for volcanic disaster experience. The application was developed with the Unity3D engine based on the proposed story board to deliver knowledge of various volcanic disasters (volcanic ash, pyroclastic flows, volcanic mudflow etc.). The results of this paper will be used for volcanic disaster response and prevention training and for more realistic training linked with augmented reality technology in the future.

Effect of Intersecting Angles of Rock Fractures on Solute Mixing at Fracture Junction (암반단열의 교차각이 교차점에서의 용질의 혼합에 미치는 영향)

  • Kim, Dahye;Yeo, In Wook
    • Economic and Environmental Geology
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    • v.54 no.4
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    • pp.465-473
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    • 2021
  • This numerical study aims at analyzing the effect of flow characteristics, caused by geometrical features such as intersecting angles, on solute mixing at fracture junctions. It showed that not only Pe, the ratio of advection to diffusion, but also the intersecting angles played an important role in solute mixing at the junction. For the intersection angles less than 90°, the fluid flowed to the outlet in the same direction as the injected flow direction, which increased the contact at the junction with the streamlines coming from the different inlets. On the other hand, for the intersecting angles greater than 90°, the fluid flowed out to the outlet opposite to the flow direction in the inlet, leading to minimizing the contact at the junction. Therefore, in the former case, solute mixing occurred even at high Pe, and in the latter case, solutes transport along the streamlines even at low Pe. For Pe < 1, the complete mixing model was known to occur, but for the intersecting angle greater than 150°, no complete solute mixing occurred. Overall, the transition from the complete mixing model to the streamline-routing model occurred for Pe = 0.1 - 100, but it highly depended on the intersecting angles. Specifically, the transition occurred at Pe = 0.1 - 10 for intersecting angles ≧ 150° and at Pe = 10 - 100 for intersecting angles ≦ 30°. For Pe > 100, the streamline-routing model was dominant regardless of intersecting angles. For Pe > 1,000, the complete streamline-routing model appeared only for the intersecting angles greater than 150°. For the intersecting angles less than 150°, the streamline-routing model dominated over the complete solute mixing, but solute mixing still occurred at the fracture junction.