• Title/Summary/Keyword: 수지상

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Synthesis of O/W Emulsion of Alkyd Resin for Reducing of VOC (VOC 절감을 위한 알키드 수지의 O/W 에멀젼 제조)

  • Lee, Young Sang;Lee, Euy Soo;Ha, Jin Kuk
    • Journal of Adhesion and Interface
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    • v.11 no.1
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    • pp.9-14
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    • 2010
  • O/W emulsions were prepared with the phase inversion emulsification methods. The emulsifiers were used the UNIQ-1 (isopropylamine alkyl aryl sulphonate) and UNIQ-2 (alkoxylated glycol ether). Investigated effect that HLB value, agitator velocity and manufacture temperature get in mean particle size of emulsions. Mean particle size receives much effect of HLB value. Also, estimated stability about storage temperature and light. Emulsion's mean particle size was 193 nm lastly, reduced VOC amount used 90% than existing alkyd resin.

Toughness Improvement of Tetrafunctional Epoxy Resin with Thermoplastic Polymer (열가소성 고분자를 이용한 사관능성 에폭시 수지의 강인성 향상에 관한 연구)

  • Shim, Jyong-Sup;Jung, Ho-Soon;Jang, Jyong-Sik
    • Applied Chemistry for Engineering
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    • v.1 no.2
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    • pp.124-132
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    • 1990
  • In order to improve the mechanical properties and fracture toughness of HPT 1071/DDS system, poly(aryl etherimide) (PEI) was incorporated in the resin system. In HPT 1071/DDS system, mechanical properties of cured epoxy resins were not strongly dependent on the concentration of DDS curing agent strongly. In the case of HPT 1071/DDS/PEI system, the fracture toughness and flexural properties of epoxy resins increased with increasing the concentration of PEI. SEM micrographs of cured epoxy resin indicated that the phase separation occured at the low concentration of PEI in this system. In addition, investigation of the relationship between mechanical properties and the morphology of modified epoxy resin was undertaken in HPT 1071/DDS/PEI system.

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Degradation Assessment of Thermoplastic Synthetic Resin Using Propagation Characteristics of Ultrasound (초음파 전파특성을 이용한 열가소성 합성수지의 열화 평가)

  • Jeon, Woo-Sang;Kim, Gi-Jin;Kwon, Sung-Duk
    • Journal of the Korean Society for Nondestructive Testing
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    • v.34 no.2
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    • pp.141-147
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    • 2014
  • A nondestructive ultrasonic technique was applied to evaluate the thermal characteristics and degradation of synthetic polymer resin (plastics) with better cost-effectiveness and functionality than glass and metal. Thermoplastic and transparent acrylic resin (PMMA) specimens were annealed at below the glass transition temperature ($T_g$), and the propagation characteristics (attenuation and velocity) were measured. The attenuation increased and the velocity decreased with thermal degradation. The results showed that the thermal aging of the specimens could be evaluated quantitatively and that the Tg could be evaluated qualitatively.

Synergistic Anti-Tumor Effect by the Combination of Cyclophosphamide and Dendritic Cell Vaccination in Murine Tumor Model that CEA Expressing (CEA 발현 마우스 종양모델에서 Cyclophosphamide와 수지상세포 백신의 병합치료에 의한 상승적인 항종양 효과)

  • Park, Mi-Young
    • Korean Journal of Clinical Laboratory Science
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    • v.54 no.1
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    • pp.38-48
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    • 2022
  • Carcinoembryonic antigen (CEA) is an oncofetal antigen primarily detected in the peripheral blood of cancer patients, particularly in those with colorectal cancer. CEA is considered a valuable target for antigen-specific immunotherapy. In this study, we induced the anti-tumor immunity for CEA through the administration of a dendritic cell (DC) vaccine. However, there was a limitation in inducing tumor regression in the DC vaccinated mice. To enhance the efficacy of anti-tumor immunity in MC38/CEA2 tumor-bearing mice, we evaluated the effects of DC vaccine in combination with cyclophosphamide (CYP). Administration of CYP 100 mg/kg in mice resulted in significant inhibition of tumor growth in the 2-day tumor model, whereas a lower inhibition of tumor growth was seen in the 10-day tumor model. Therefore, the 10-day tumor model was selected for testing chemo-immunotherapy. The combined CYP and DC vaccine not only increased tumor antigen-specific immune responses but also induced synergistic anti-tumor immunity. Furthermore, the adverse effects of CYP such as weight loss and immunosuppression by regulatory T cells and myeloid-derived suppressor cells showed a significant reduction in the combined chemo-immunotherapy treatment compared with CYP alone. Our data suggest that chemoimmunotherapy with the DC vaccine may offer a new therapeutic strategy to induce a potent anti-tumor effect and reduce the adverse effects of chemotherapy.

Processing - Interlaminar Shear Strength Relationship of Carbon Fiber Composites Reinforced with Carbon Nanotubes (탄소나노튜브로 보강된 탄소섬유복합재의 제조공정과 층간전단강도)

  • Kim, Han-Sang
    • Composites Research
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    • v.24 no.5
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    • pp.34-38
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    • 2011
  • Carbon nanotubes (CNTs) have been widely investigated as reinforcements of CNT/polymer nanocomposites to enhance mechanical and electrical properties of polymer matrices since their discovery in the early 90's. Furthermore, the number of studies about incorporating CNTs into carbon fiber reinforced plastics (CFRP) to reinforce their polymer matrices is increasing recently. In this study, single-walled carbon nanotubes (SWNT) were dispersed in epoxy with 0.2 wt.% and 0.5 wt.%. Then, the SWNT/epoxy mixtures were processed to carbon fiber composites by a vacuum assisted resin transfer molding (VARTM) and a wet lay up method. The processed composite samples were tested for the interlaminar shear strength (ILSS). The relationship between the interlaminar shear strengths and processing, and the reinforcement mechanism of carbon nanotubes were investigated. CNT/epoxy nanocomposite specimens showed the increased tensile properties. However, the ILSS of carbon fiber composites was not enhanced by reinforcing the matrix with CNTs because of processing issues caused by increased viscosity of the matrix due to addition of CNTs particularly for a VARTM method.

The Properties of Different Polyols for Paint to Polyisocyanate (도료용 폴리올 종류에 따른 폴리이소시아네이트와의 물성)

  • Seo, Seok-Hwan;Suh, Cha-Soo;Park, Jin-Hwan
    • Applied Chemistry for Engineering
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    • v.19 no.5
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    • pp.547-553
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    • 2008
  • To achieve the ideal performances of paint film, resins and hardeners have to be chosen and designed in a proper way depending on the exposure circumstance of substrate and the requested physical properties. Six different kinds of clear paints were made in this experiment using alkyd polyol, polyester polyol, polyester modified acrylic polyol and another 3 acrylic polyol resins whose $T_g$ and OH value were partially modified. Then the tests for chemical, physical, and mechanical properties were measured after forming the paint films using aliphatic and aromatic polyisocyanate. The viscosity and elasticity of paint film were then measured in terms of gel point and $tan{\delta}$ using Rheometer and DMA. Through this viscoelastic characteristic test of polyurethane resin, we were able to choose the adequate resins and hardeners which are the most important in the top and primer painting system of urethane paint and, as a result of observing the physical, mechanical, and chemical properties of paint film by urethane, we have finally reached the conclusion that we could apply the proper polyol to top and primer paint for developing the polyurethane paint system.

Evaluation for the application of WRF meteorological data on grid-based soil moisture model in upland (WRF 기상자료의 밭 토양 물수지 모형 적용 및 효과 분석)

  • Hong, Min Ki;Lee, Sung Hack;Choi, Jin Yong;Lee, Seung-Jae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.213-213
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    • 2015
  • 밭에서의 점적 관개를 이용한 노지 재배의 경우 적정 관개 계획 수립을 위해서는 작물 및 토양의 수분 정보에 대한 정확한 파악이 필요하다. 본 연구에서는 밭 토양을 GIS(Geographic Information System)를 통해 격자 형태로 분할하여 작물의 증발산량 및 토양의 수분함량을 모의할 수 있는 격자 기반 토양 물수지 모형을 개발하였다. 본 모형을 통해 작물의 소비수량 및 필요 수량을 파악함으로써 작부기간 중 필요한 관개수량을 제시하는 것이 가능하다. 고도화 기상자료로는 국가농림기상센터에서 운영 중인 고해상도 WRF(Weather Research and Forecasting) 모형에서 생산된 격자 형태의 복사, 온도, 바람, 강수 자료를 사용하였고 고도화 기상자료의 격자 해상도 별로 모의되는 작물 및 토양의 수분 정보 간 비교 및 분석을 실시하였다. 토양 물수지 모형에 입력되는 격자형태의 자료로는 기상, 토성 및 토지이용 자료가 있으며 기상자료의 경우 가로 및 세로의 크기가 각 270, 810, 2430m로 동일한 3가지 경우로 나누어 적용했으며 토성 및 토지이용 자료의 경우 기상 격자의 최소 크기에 맞춰 가로 및 세로의 크기가 각 270m인 격자로 분할하였다. 이와 같은 과정에 의한 모의 결과 각 격자별 작물 증발산량, 토양수분함량 및 관개수량의 일 연별 시계열 자료를 얻을 수 있으며 동시간대 격자별 수문인자 값을 산정하고 위치에 따른 공간적 상호 상관성을 분석하였다. 결과적으로, 고도화 기상자료의 격자 크기에 따른 밭 토양 물수지 분석 결과를 통해 고도화 기상 격자의 규모별 밭 토양 물수지 분석 효용성을 파악하고자 하였다. 더불어, 시험 지역(Test Bed) 선정을 통해 토양수분 및 증발산량을 실측하고 본 모형의 모의 결과와 비교함으로써 검정하는 것을 향후 연구 계획으로 한다.

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Microstructural Change by Hot Forging Process of Korean Traditional Forged High Tin Bronze (전통기술로 제작된 방짜유기의 열간 단조 과정별 미세조직 변화)

  • Lee, Jae-sung;Jeon, Ik-hwan;Park, Jang-sik
    • Journal of Conservation Science
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    • v.34 no.6
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    • pp.493-502
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    • 2018
  • Currently, the fabrication of a high-tin bronze spoon by traditional manufacturing techniques involves 10 steps in the bronze ware workshop. Hot forging has a major influence on manufacturing and involves two to three steps. The dendritic ${\alpha}$-phase in the microstructure of the high-tin bronze spoon is refined and finely dispersed through hot forging. In addition, twinning is observed in the ${\alpha}$-phase of the hammered part, and the ${\alpha}$-phase microstructure gradually transform from a polygon to a circular shape due to hammering. In this process, the adjacent ${\alpha}$-phases overlap with each other and remain combined after quenching. The microstructure with the overlapping is also observed in bronze artifacts, and this shows the correlation with technical system. The results of the experimental hot forging of Cu-22%Sn alloys show that the decrease in in the amount of the dendritic microstructure, which forms during casting, is in proportion to the number of processing steps and that the refined grain obtained by hammering contributes to the improvement in the strength of the material. From the hammering marks, which are observed on both the bronze artifact excavated from archaeological sites and on the high-tin bronze spoon produced in the traditional workshop, it is presumed that the knowledge regarding the unrecorded manufacturing system of bronze ware in ancient times has been passed down in a traditional way up to the system used currently.

Fixation of Sericin of Silk Fabric by Epoxy Resin (Epoxy수지에 의한 견직물의 Sericin정착)

  • 문영배;남중희
    • Journal of Sericultural and Entomological Science
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    • v.26 no.2
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    • pp.16-25
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    • 1984
  • The sericin fixation of silk fabrics by epoxy resins was studied in the presence of aqueous salt solution in different solvents at the indicated temperature for the desired time. Heavy weight gains were obtained in the reaction with glycerol diglycidyl ether (EX-313) and ethylene glycol diglycidyl ether (EX-810) catalyzed by potassium thiocyanate in such solvents as carbon tetrachloride and p-chloroethylene. The obtained results were summarized as follows; 1) The tested resins were found similar in reaction behavior to silk fabric. The effect of fixation and weight gains was higher in EX-810 than EX-313. 2) The weight gains were increased with reaction time and temperature, and degumming ratio reached a constant value in 90 min at 70$^{\circ}C$. 3) The weight gains and the degumming ratio reached an equilibrium at 3-5% of epoxy concentration. 4) The weight gains were remarkably influenced and increased by the concentration of salt solution. The degumming ratio reached an equilibrium over 0.5N concentration of salt. 5) The weight gains were increased with the dipping time in gently-sloping. The degumming ratio reached an equilibrium over 15 min dipping. 6) The effect of sericin fixation of hydrophobic solvents, such as Carbon Tetrachloride, p-Chloroeth-ylene, Cyclohexane, Xylene and Toluene, was found suitable. 7) The effect of drying temperature was not remarkable on the weight gains and the degumming ratio. 8) There was a slight decrease in the moisture regain of sericin-fixed silk and it may be possible to maintain the moisture regain in the sericin-fixed silk by the epoxy resins. 9) The results on testing physical properties of sericin-fixed silk fabric were as follows; The crease recovery was almost not different from undegummed fabric, but inferior to degummed fabric. The tensile strength was improving in accordance with the effect of sericin fixation, either the elongation did.

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An Experimental Study on the Effect of Capillary Pressure on the Void Formation in Resin Transfer Molding Process (수지이동 성형공정에서 기공형성에 미치는 모세관압의 영향에 관한 실험적 연구)

  • 이종훈;김세훈;김성우;이기준
    • The Korean Journal of Rheology
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    • v.10 no.4
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    • pp.185-194
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    • 1998
  • Flow-induced voids during resin impregnation and poor fiber wetting give serious effects on the mechanical properties of composites in resin transfer molding process. In order to better understand the characteristics of resin flow and to investigate the mechanism of void formation, flow visualization experiment for the resin impregnation was carried out on plain weaving glass fiber mats using silicon oils with various viscosity values. The permeability and the capillary pressure for the fiber mats of different porosities were obtained by measuring the penetration length of the resin with time and with various injection pressure. At low porosity and low operating pressure, the capillary pressure played a significant role in impregnation process. Video-assisted microscopy was used in taking the magnified photograph of the flow front of the resin to investigate the effect of the capillary pressure on the void formation. The results showed that the voids were formed easily when the capillary pressure was relatively high. No voids were detected above the critical capillary number of 2.75$\times$$10^{-3}, and below the critical number the void content increased exponentially with decrease of the capillary number. The content of void formed was independent of the viscosity of the resin. For a given capillary number, the void content reduced with the lower porosity of the fiber mat.

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