• 한국염색가공학회지
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• 제13권3호
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• pp.188-196
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• 2001

1, 1-diamino-3, 3, 5, 5-tetrachlorocyclotriphosphazene, 1, 1-diami-no3, 3, 5, 5-tetra-(p-bromophenoxy)cyclotriphosphazene, and 1, 1-diamino-3, 3, 5, 5-tetra-(p-chlorophenoxy) cyclotri-phosphazene(ACPP) was prepared from hexachlorocyclotriphosphazene and used for the curing agent of bisphenol A type epoxy resin and phenol novolak. The resistance to chemicals and water of the cured epoxy resins were examined by DMTA and compared with those of the epoxy rosins cured with phosphazene derivatives and 4, 4'-diaminodiphenylmethane. The effect of the curing agent on resistance to chemicals and water of the cured epoxy resins were investigated. The epoxy resins cured with 1, 1-diamino-3, 3, 5, 5-tetrachlorocyclotriphosphazene and 1, 1- diamino-3, 3, 5, 5-tetra- (p-bromophenoxy)cyclotriphosphazene showed superior resistance to chemicals and water to those of 1, 1-diamino-3, 3, 5, 5-tetra- (p-chlorophenoxy)cyclotriphosphazene and 4, 4'-diaminodiphenylmethane. It is an effective curing agent for epoxy resins to enhance the resistance to chemicals, water and tome proofing.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2003년도 춘계학술대회논문집
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• pp.363-370
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• 2003

Shrinkage of injection molded parts is different form operational conditions of injection molding such as injection temperature, injection pressure and mold temperature, and mold design such as gate size. It is also various for different resins which have crystalline structure or not. In this study part shrinkage was investigated for various operational condition and resins; PBT for crystalline polymer, and PC and PMMA for amorphous polymer was used in experiment. Crystalline polymer shows higher part shrinkage by about three times than amorphous polymer. Part shrinkage increased as injection temperature and mold temperature increased and injection pressure decreased. Part shrinkage decreased as gate size increased since the pressure delivery is mush easier for large gate size. Part shrinkage according to the gate location was that the position in the part with close to the gate showed large shrinkage and this phenomenon might be occurred by residual stress.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2003년도 춘계학술대회 논문집
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• pp.151-156
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• 2003

방사선을 이용한 그라프트 공중합은 고분자막이나 부직포, 합성수지 등 각 소재의 기본 성질은 손상되지 않으며 금속이온이나 유해가스 등의 흡착능을 갖는 기능성기의 도입이 가능한 방법으로 널리 사용되고 있다. 방사선을 이용한 섬유상 흡착포의 제조는 단량체와 섬유에 방사선을 동시에 조사하는 동시조사법과 진공상태 또는 질소 분위기 하에서 방사선을 조사하여 라디칼을 형성한 후 단량체와 접촉시켜 반응을 진행시키는 방법 그리고 공기 중에서 방사선을 조사하여 섬유상에 peroxide group 또는 hydroperoxide group을 생성시킨 후 이를 높은 온도에서 열분해 시켜 단량체와 그라프트 반을을 진행시키는 방법이 사용되고 있다. (중략)

• 한국기계가공학회지
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• 제16권2호
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• pp.94-101
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• 2017

Recently, the small quantity batch production method has come into the spotlight as there are more plastic processing methods. At the same time, the 3D printer market has become globally widespread due to expired 3D printer patents. In particular, the FDM method is widely used for cheap products and materials. However, the FDM scheme is not as good as the injection molding method for quality and strength. This study investigated the effect of the internal filling and strength according to layer thickness to search for the optimum printing of the factors (infill and layer thickness) that determine the strength of the model.

• 소성∙가공
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• 제15권9호
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• pp.641-647
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• 2006

During the injection molding process an excessive packing can occur in the smaller volume cavity because of volumetric difference of the family-mold. It causes warpage by increased residual stress in the product and flesh by over packing. In this study, we used a variable-runner system for the filling balance of the cavities by changing the cross-sectional area of a runner, and confirmed the filling imbalance by temperature and pressure sensors. We carried out experiments to examine the influence of types of resins such as LDPE/ABS/PA6,6 on the filling balancing of the system, in order to help mold designers, who can easily adopt the variable-runner system to their design. We also examined filling imbalance in the system with CAE analysis.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1997년도 춘계학술대회 논문집
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• pp.827-831
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• 1997

Conductive veramic matrix composite(CMC) workpiece of TiC 33%/Al /sab 2/O /sab 3/ 66% Y /sab 2/ O /sab 3/ was machined by die sinking electrical discharge machining(EDM) according to different pulse duration and suty factor for reverse polarity of electrode. Material removal rate(MRR) was examined by process under various operating conditions. The surface morphology was evaluated by surface roughness values and scanning electron microscopy(SEM) research. The more MRR was obtained according to increase pulse duration and duty factor. Also the maximum surface roughness(Rmax) of EDMed surface was slightly changed with increased pulse duration and duty factor. The SEM photographs of EDMed surface showed wide recast wide recast distribution region of melting materials in purse duration 0.130(ms) than 0.048(ms).

• 한국기계가공학회지
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• 제6권3호
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• pp.92-97
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• 2007

The overlay welding the automobile where the durability is demanded, it is used in the vessel engine valve, plant valve and pump parts. Cause of damage public opinion one what is thought is the fatigue load due to the opening and shutting operation right time repetition of the engine valve. The damage cause of the engine valve or explanation of destruction mechanism is very difficult. The research which it sees to make clear a overlay welding of Co-alloy by Plasma Transferred Arc Weld Surfacing Process reconsideration fatigue crack initiation and fatigue crack growth mechanism at high temperature.

• 소성∙가공
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• 제16권1호
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• pp.31-35
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• 2007

Automotive weather strip should have good weather ability, sealability, durability, etc. to perform its duty as body sealing for vehicles under different harsh environments. Due to its comprehensive properties, thermoplastic vulcanizate(TPV) is widely employed in weather strip as alternative for ethylene propylene diene rubber(EPDM). In this study, the influences of the recycled TPV on the tensile strength and hardness were investigated. As results of the injection molding experiment, the recycled TPV's tensile strength and hardness were higher than the virgin TPV and recycled TPV's extension was improve. The morphology showed that recycled TPV's rubber particles became smaller than virgin TPV's rubber particles.

• 한국기계가공학회지
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• 제3권3호
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• pp.46-51
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• 2004

Nowadays, plastic industry has needed to produce parts that require high precision and quality. To make a high precision and quality part, before injection molding, plastic material in investigated about their properties such as shrinkage, warpage, etc. In this study, experiments were conducted with PP(polypiopylene) to figure out shrinkage behavior according to three type aspect ratio of samples. The injection speed that affects on shear late, molecular orientation within plastic part was determined as main variable of experiment. As a result of experimental study, part shrinkage had a tendency to be decreased by increasing injection speed and aspect ratio of samples.

• 한국염색가공학회지
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• 제20권4호
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• pp.21-30
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• 2008

To understand the complex hydrogen bonding structure, several phenolic derivatives and benzoxazine model compounds are synthesized and characterized by Fourier transform infrared spectroscopy (FT-IR). The estimation of molar extinction coefficients for various types of hydrogen bonding species is systematically carried out by the curve-resolving of FT-IR spectra. The distribution of hydrogen bonding species in benzoxazine model dimers is quantitatively analyzed. It is revealed that benzoxazine dimers and BA-a polybenzoxazine are mainly composed of intramolecular interaction rather than intermolecular interaction.