• Journal of Conservation Science
• /
• v.25 no.2
• /
• pp.147-154
• /
• 2009

The change of strength and water vapour diffusion resistant by soluble salts was investigated in the tuff and granite used in many stone monuments of Gyeongju area. With $Na_2SO_4$ and $CaSO_4{\cdot}2H_2O$ were treated the rock samples to understand the difference of solubility. The densities of the tested rocks were increased by the impregnation of $CaSO_4{\cdot}2H_2O$ and $Na_2SO_4$. The flexural strength was increased in the tuff samples but decreased in the granite as the salts increased in the pore. In the tuff, the uniaxial compressive strength was increased by $CaSO_4{\cdot}2H_2O$, but decreased by $Na_2SO_4$. In the granite, it was decreased slightly by $CaSO_4{\cdot}2H_2O$, but increased by $Na_2SO_4$. The water vapour diffusion resistant was increased by the salts in both rocks. As results, it was cleared that the mechanical strength colud be increased in early stage of weathering by the accumulation of salt and water vapour diffusion resistant.

• Nuclear Engineering and Technology
• /
• v.16 no.2
• /
• pp.80-88
• /
• 1984

The removal mechanism of air borne methyl iodide by triethylenediamine (TEDA) impregnated charcoal bed was investigated. The analysis of experimental data indicates that pore diffusion is the rate controlling step when the air velocity is over 20cm/sec, and both fore diffusion resistance and external mass transfer resistance are contributed to the overall resistance when the air velocity is 10cm/sec. The adsorption model to describe the performance of impregnated charcoal bed under dry condition where water vapors do not exist in air, is proposed. The calculated values and experimental results are well matched.

• Transactions of the Korean hydrogen and new energy society
• /
• v.13 no.3
• /
• pp.214-223
• /
• 2002

Kinetic and effectiveness factors for methanol steam reforming using commercial copper-containing catalysts in a plug flow reactor were investigated over the temperature ranges of $180-250^{\circ}C$ at atmospheric pressure. The selectivity of $CO_2$/$H_2$ was almost 100%, and CO products were not observed under reaction conditions employed in this work. It was indicated that $CO_2$ was directly produced and CO was formed via the reverse water gas shift reaction after methanol steam reforming. The intrinsic kinetics for such reactions were well described by the Langmuir-Hinshelwood model based on the dual-site mechanism. The six parameters in this model, including the activation energy of 103kJ/mol, were estimated from diffusion-free data. The significant effect of internal diffusion was observed for temperature higher than $230^{\circ}C$ or particle sizes larger than 0.36mm. In the diflusion-limited case, this model combined with internal effectiveness factors was also found to be good agreement with experimental data.

• Journal of Bio-Environment Control
• /
• v.6 no.3
• /
• pp.205-215
• /
• 1997

An accurate transpiration model for greenhouse tomato crop, which is liable to transpiration depression and yield loss because of low solar radiation and high humidity, could be an efficient tool for the optimum control of greenhouse climate and for the optimization of Irrigation scheduling. The purpose of this study was to develop transpiration model of greenhouse tomato and to carry out the experimental verification. The formulas to calculate the canopy transpiration and temperature simultaneously were derived from the energy balance of canopy. Transpiration and microclimate variables such as net radiation, solar radiation, humidity, canopy and air temperature, etc. were simultaneously measured to estimate parameters of model equations and to verify the suggested model. Leaf boundary layer resistance was calculated as a function of Nusselt number and stomatal diffusive resistance was parameterized by solar radiation and leaf-air vapor pressure deficit. The equation for stomatal diffusive resistance could explain more than 80％ of its variation and the calculated stomatal diffusive resistance showed good agreements with the measured values in situations independent of which the constants of the equation were estimated. The canopy net radiation calculated by Stanghellini's model with slight modification agreed well with the measured values. The present transpiration model, into which afore-mentioned component equations were assembled, was found to predict the canopy temperature, instantaneous and daily transpiration with considerable accuracy in greenhouse climates.