• Title/Summary/Keyword: 수전해

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A Study on the Analysis of Hazardous Risk Factors for Component in Hydrogen Station with Water Electrolysis Device (수전해 수소충전소 부품별 유해위험요인 분석)

  • Seo, Doo-Hyoun;Rhie, Kwang-Won;Kim, Tae-Hun
    • Journal of the Korean Institute of Gas
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    • v.23 no.6
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    • pp.33-38
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    • 2019
  • In order to invigoration the hydrogen economy, production of hydrogen needed for hydrogen charging stations and hydrogen fuel cells is needed. Generally, it is reforming used to coal fuel or natural gas. Other technologies include water electrolysis using pure water. Among these water electrolysis technologies, development is mainly carried out using PEM(Polymer Electrolyte Membrane electrolysis). In this study, the company aims to identify potential harmful hazards to PEM electrolysis hydrogen stations in the development stage among hydrogen charging stations. In order to find the hazardous factors in the facilities of the electrolysis and hydrogen charging stations, we were analyzed by Failure Mode & Effect Analysis(FMEA).

Technology Trends in Stainless Steel for Water Splitting Application (스테인레스 강의 수전해 전극 응용기술 동향)

  • Kim, Moonsu;Ha, Jaeyun;Kim, Yong-Tae;Choi, Jinsub
    • Journal of the Korean Electrochemical Society
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    • v.24 no.2
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    • pp.13-27
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    • 2021
  • Stainless steel, which includes Ni and Cr with Fe balance, is most often applied for a wide range of applications such as structure and equipment material. It is not only suitable for use in these applications due to its good corrosion resistance, but also can be applied to catalyst, supporting material, and current collector due to intrinsic properties of Ni and Fe contained in stainless steel. Therefore, in recent years, a lots of surface treatment methods have been studied to activate stainless steel, developing application of water splitting system. In this review paper, the research on the surface treatment technology of stainless steel for water splitting is summarized. It is expected to be able to propose the diverse surface treatment approaches of stainless steel for application to low-cost and highly efficient water splitting electrode.

Research Trend in Electrocatalysts for Anion Exchange Membrane Water Electrolysis (음이온교환막 수전해 촉매기술 동향)

  • Kim, Jiyoung;Lee, Kiyoung
    • Journal of the Korean Electrochemical Society
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    • v.25 no.2
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    • pp.69-80
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    • 2022
  • The anion exchange membrane (AEM) water electrolysis for high purity hydrogen production is attracting attention as a next-generation green hydrogen production technology by using inexpensive non-noble metal-based catalysts instead of conventional precious metal catalysts used in proton exchange membrane (PEM) water electrolysis systems. However, since AEM water electrolysis technology is in the early stages of development, it is necessary to develop research on AEM, ionomers, electrode supports and catalysts, which are key elements of AEM water electrolysis. Among them, current research in the field of catalysts is being studied to apply a previously developed half-cell catalyst for alkali to the AEM system, and the applied catalyst has disadvantages of low activity and durability. Therefore, this review presented a catalyst synthesis technique that promoted oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) using a non-noble metal-based catalyst in an alkaline medium.

Effect of Operation Temperature on the Durability of Membrane and Electrodes in PEM Water Electrolysis (PEM 수전해에서 막과 전극의 내구성에 미치는 구동 온도의 영향)

  • Donggeun Yoo;Seongmin Kim;Byungchan Hwang;Sohyeong Oh;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.19-25
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    • 2023
  • Although a lot of research and development has been conducted on the performance improvement of PEM (Proton Exchange Membrane) water electrolysis, the research on durability is still in early stage. This study investigated effect of temperature on the water electrolysis durability when driving temperature of the PEM water electrolysis was increased to improve performance. Voltage change, I-V, CV (Cyclic Voltammetry), LSV (Linear Sweep Voltammetry), Impedance, and FER (Fluoride Emission Rate) were measured while driving under a constant current condition in a temperature range of 50~80 ℃. As the operating temperature increased, the degradation rate increased. At 50~65 ℃, the degradation of the IrO2 electrocatalyst mainly affected the durability of the PEM water electrolysis cell. At 80 ℃, the polymer membrane and electrode degradation proceeded similarly, and the short resistance decreased to 1.0 kΩ·cm2 or less, and the performance decreased to about 1/3 of the initial stage after 144 hours of operation due to the shorting phenomenon.

Understanding Thermodynamics of Operating Voltage and Efficiency in PEM Water Electrolysis System for Carbon Neutrality and Green Hydrogen Energy Transition (탄소중립과 그린 수소에너지 전환을 위한 PEM 수전해 시스템에서 작동 전압 및 효율의 열역학적 이해)

  • HyungKuk Ju;Sungyool Bong;Seungyoung Park;Chang Hyun Lee
    • Journal of the Korean Electrochemical Society
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    • v.26 no.4
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    • pp.56-63
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    • 2023
  • The development of renewable energy technologies, such as solar, wave, and wind power, has led to the diversification of water electrolysis technologies, which can be easily coupled with renewable energy sources in terms of economics and scale. Water electrolysis technologies can be classified into three types based on operating temperature: low-temperature (<100 ℃), medium-temperature (300-700 ℃), and high-temperature (>700 ℃). It can also be classified by the type of electrolyte membrane used in the system. However, the concepts of thermodynamic and thermo-neutral voltages calculations and are very important factors in the evaluation of energy consumption and efficiency of water electrolysis technologies, are often confused. This review aims to contribute to a better understanding of the calculation of operating voltage and efficiency of PEM water electrolysis technologies and to clarify the differences between thermodynamic voltage and thermo-neutral voltage.

Research on Safety Measures for Design and Operation of Alkaline Water Electrolysis Facility (알칼라인 수전해 설비 설계 및 운영의 안전대책 연구)

  • Hyeon-Ki Kim;Doo-Hyoun Seo;Kwang-Won Rhie;Tae-Hun Kim;Seong-Chul Hong
    • Journal of the Korean Institute of Gas
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    • v.28 no.2
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    • pp.17-23
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    • 2024
  • As interest in sustainable and eco-friendly energy increases due to various problems in the carbon economy, a hydrogen economy that utilizes hydrogen as a main energy source is emerging. Among the methods of producing hydrogen, the water electrolysis method based on renewable energy produces environmentally friendly green hydrogen because it produces hydrogen from water. The water electrolysis facility currently under development produces hydrogen by receiving electricity directly from renewable energy and uses KOH(potassium hydroxide) as an electrolyte. In this study, HAZOP(Hazard and Operability Study), a qualitative risk assessment, was conducted on alkaline water electrolysis facilities to find problems and risk factors in the design and operation of water electrolysis facilities. Risks related to oxygen and KOH, an electrolyte, were identified as major risks, and it is believed that the safety of facilities and workers can be secured based on emergency action plans and safe operation procedures.

The Effect of the Photosynthetic Ability and the Nutritional Status on Dry matter Production and Yield Components of the Rice Plant at the Latter Half of the Growth Stage (수도 생육후기 광합성 능력과 영양환경이 건물생산과 수량구성요소에 미치는 영향)

  • Joo-Yul Lee
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.21 no.2
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    • pp.187-202
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    • 1976
  • Experiment were conducted to study the photosynthetic ability of several rice varieties and the influence of the drymatter production on the yield components of the rice plant, especially in ripening period. The photosynthetic ability at the ripening period, the varieties were classified into two groups as relatively high capacity and low capacity. With the earlier the transplanting date and the higher the N-content leaf blade, the greater the ratio of reserved assimilates befere heading time to the ear. This could be support the fact that the rate of full-ripened grains or grain yield of 'Tongil' variety may increased by the change of environment condition.condition.

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Experimental Study on the SPE Water Electrolysis in KIER (KIER 실험용 SPE 수전해장치의 실험결과 및 고찰)

  • 김정덕;심규성;명광식;김종원
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2002.05a
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    • pp.143-148
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    • 2002
  • SPE(solid polymer electrolyte) 수전해법은 고체고분자전해질 막(membrane)을 전해질로 사용하는 방법으로서 이 전해질 막은 알칼리 수전해에서의 KOH전해질과 격리막을 합쳐놓은 것과 같은 역할을 수행한다. SPE 수전해는 양극(anode)에서 촉매 전극에 의해 물로부터 산소기체(O$_2$)와 수소이온(H$^{+}$)이 발생되며 수소이온(H$^{+}$)은 다량의 물($H_2O$)분자와 함께 고체고분자전해질 막을 통하여 음극으로 이동하여 외부회로를 통해 도달한 전자(e)와 음극(cathode)에서 만나 수소기체(H$_2$)를 발생시키는 방법이다.(중략)

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Error Analysis for Temperature Big Data of Hydropower Collected by IoT sensors (IoT 센서로 수집한 수전 설비의 온도 데이터를 이용한 오류 빅데이터 분석)

  • Joo, Eun-Jin;Hong, Jang-Eui
    • Proceedings of the Korea Information Processing Society Conference
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    • 2017.04a
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    • pp.553-555
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    • 2017
  • 수전 설비 시스템은 전력 회사에서 3 상 전원을 받는 설비로, 전기를 공급받기 위한 설비이다. 정전이나 제품생산설비의 중단은 기업에 있어서는 경제적 손실이 매우 큰 사고일 수 밖에 없다. 요즘은 IoT 센서를 이용한 수전설비 관리 시스템의 활용이 늘어나고 있는 추세이다. IoT 센서를 이용한 수전 설비의 구축에서 정확한 상태 값의 센싱과 수집된 값의 전송, 그리고 정확성 판단에 대한 이슈들이 고려되어야 하며, 또한 기기간 통신을 통해 실시간 상호작용으로 수전설비의 고장을 어떻게 예방할 것인가에 대한 것이 중요하다. 본 연구에서는 수전 설비의 실시간 감지와 모니터링을 위한 목적으로 기존의 고장 및 오류 정보를 기반으로 하는 빅데이터 분석을 통해 발생 가능한 고장 및 오류를 사전 예측할 수 있도록 정보를 제공하는 것에 주안점을 두었다.

Electrochemical preparation of Blue TiO2 nanotube array and its application for oxygen evolution reaction (전기화학적 방법을 이용한 산소 발생용 Blue TiO2 전극제조 및 반응특성조사)

  • Han, Jun-Hyeok;Tak, Yong-Seok;Yun, Je-Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.46-46
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    • 2014
  • 알칼리 수전해는 신재생에너지를 이용하여 오염물질 없이 효율적으로 수소를 생산할 수 있는 방법 중의 하나이다. 알칼리 수전해 시스템의 산화전극으로 불용성전극이 많이 사용되고 있으나 높은 과전압과 제조 공정이 복잡한 문제점을 가지고 있다. 본 연구에서는 전기변색을 이용해 짙은 파란색의 $TiO_2$ 나노튜브를 알칼리 수전해 시스템의 산화전극으로 이용하고자 하였다. 양극산화법을 이용해 $TiO_2$ 나노튜브를 만드는 과정에서 양극산화 시간과 인가전압에 따라 Blue $TiO_2$의 산소발생반응(Oxygen evolution reaction, OER) 활성 변화를 측정하였고 나노튜브 길이가 길고 직경이 클수록 OER활성과 내구성이 향상되는 것을 확인하였다.

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