• Journal of the Korean Chemical Society
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• v.43 no.5
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• pp.596-600
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• 1999

• Journal of the Korean Chemical Society
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• v.52 no.4
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• pp.350-355
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• 2008

• Journal of the Korean Chemical Society
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• v.62 no.6
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• pp.453-457
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• 2018

• Journal of the Korean Chemical Society
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• v.40 no.7
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• pp.531-534
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• 1996

• Journal of the Korean Chemical Society
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• v.36 no.3
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• pp.466-467
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• 1992

• Journal of the Korean Chemical Society
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• v.13 no.3
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• pp.209-214
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• 1969

The experiment have been carried out for the determination of aggregation state of isopolytantalate anion in aqueous solution by using "Ultracentrifuge Method". The molecular weight of this anion at pH 10.7 could be determined as a heptatantalate anion $Ta_7O_{22}^{9-}$.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.10a
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• pp.29.2-29.2
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• 2011

수용액 상에서 유기물이나 무기물의 전해산화에는 높은 산소과전압과 그 화학종에 대한 화학적, 물리적 안정성이 요구되며, 이러한 요구 조건을 만족하는 소재로써 백금족의 원소가 통상 사용되고 있으나, 가격이 매우 비싸다는 단점을 가지고 있다. 특히 고전류밀도 폐수처리 불용성 전극은 수용액을 전기분해할 때 높은 전류밀도를 낼 수 있으며, 폐수에 혼합되어 있는 각종 화학적 성분에 대한 화학적, 물리적 내구성이 있는 전극으로서, 현재 기존의 수처리용 전극은 금속 Ti을 기판으로 하여 그 위에 불용성 촉매로써 전도성 금속염을 도포, 열처리를 반복하여 산화물의 형태로 수 ${\mu}m$의 두께로 코팅하는 이른바, DSA (Dimensionally Stable Anodes) 전극을 사용하고 있는데, 이는 제조 단가의 상승과 금속 Ti 기판 상에 코팅된 전도성 금속산화물의 미약한 접착력으로 인한 탈리로 전극 전체의 성능 저하 및 수명 단축을 초래하는 문제점이 있다. 본 연구에서는 상기의 문제점을 개선하고자 대표적 불용성 촉매 물질인 백금을 RF magnetron 스퍼터링방식으로 100~300 nm 두께로 성막하여 Ti 기판에 대한 불용성 촉매 물질의 부착력과 내구성 및 모의 해수에 대한 해수전해 특성 등을 평가하였다.

• Journal of the Korean Applied Science and Technology
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• v.37 no.5
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• pp.1100-1105
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• 2020

We investigated the driving force and the required charges for spontaneous reduction of metal nanoparticles (NPs) on a scotch tape induced by mechanochemical activation. The charges were analyzed based on anodic stripping voltammetry (ASV) of silver, which is proportional to the number of charge identities on the tape. The results supported that the driving force is mechanochemical radicals rather than ions in the light of the high charge density on the tape.

• Membrane Journal
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• v.19 no.4
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• pp.324-332
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• 2009

This study aimed to measure chemical resistance properties of the microfiltration flat-sheet membrane made by Chlorinated Polyvinyl Chloride (CPVC) with respect to the immersed time. The solutions of effective chlorine 0.5 wt% NaClO, HCl 1 wt% and pH 4 buffer under acidic condition, NaOH 4 wt% and pH 10 buffer under alkine condition were used as widely applied chemicals for membrane washing. The CPVC membrane samples were immersed in the above chemical solutions during 1, 3, 5 and 10 days at 5, 25 and $50^{\circ}C$, respectively. After then, the tensile strength and elongation at break as the chemical durability for the samples were measured and evaluated. The tensile strength decreased within 5% at $5^{\circ}C$, but decreased up to 17% at 25 and $50^{\circ}C$ for 0.5 wt% NaClO solution mainly used for membrane cleaning. The chemical resistance of CPVC membrane was good enough for HCl 1 wt% and pH 4 buffer acid solutions, but the most vulnerable for NaOH 4 wt% solution.

• Journal of the Korean Chemical Society
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• v.53 no.4
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• pp.415-421
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• 2009

A convenient and practical synthesis of 1, 8-dioxo-octahydroxanthene derivatives using various aldehydes, 5, 5-dimethyl-1, 3-cyclohexanedione in water was successfully carried out in the presence of polyethylene glycol (PEG) as a catalyst. Simple work-up, clean products, high yields and water as a green solvent are the attractive features of this methodology.