• Title/Summary/Keyword: 수용면적

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Silicon/Carbon Composites Having Bimodal Mesopores for High Capacity and Stable Li-Ion Battery Anodes (고용량 고안정성 리튬 이차전지 음극소재를 위한 이중 중공을 갖는 실리콘/탄소 복합체의 설계)

  • Park, Hongyeol;Lee, Jung Kyoo
    • Clean Technology
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    • v.27 no.3
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    • pp.223-231
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    • 2021
  • In order to address many issues associated with large volume changes of silicon, which has very low electrical conductivity but offers about 10 times higher theoretical capacity than graphite (Gr), a silicon nanoparticles/hollow carbon (SiNP/HC) composite having bimodal-mesopores was prepared using silica nanoparticles as a template. A control SiNP/C composite without a hollow structure was also prepared for comparison. The physico-chemical and electrochemical properties of SiNP/HC were analyzed by X-ray diffractometry, X-ray photoelectron spectroscopy, nitrogen adsorption/desorption measurements for surface area and pore size distribution, scanning electron microscopy, transmission electron microscopy, galvanostatic cycling, and cyclic voltammetry tests to compare them with those of the SiNP/C composite. The SiNP/HC composite showed significantly better cycle life and efficiency than the SiNP/C, with minimal increase in electrode thickness after long cycles. A hybrid composite, SiNP/HC@Gr, prepared by physical mixing of the SiNP/HC and Gr at a 50:50 weight ratio, exhibited even better cycle life and efficiency than the SiNP/HC at low capacity. Thus, silicon/carbon composites designed to have hollow spaces capable of accommodating volume expansion were found to be highly effective for long cycle life of silicon-based composites. However, further study is required to improve the low initial coulombic efficiency of SiNP/HC and SiNP/HC@Gr, which is possibly because of their high surface area causing excessive electrolyte decomposition for the formation of solid-electrolyte-interface layers.

Analysis of Evacuation Time According to Variation of Evacuation Stairs' Width in Large-Scale Goshiwons (대규모 고시원의 피난계단 폭의 변화에 따른 피난소요시간 분석)

  • Oh, Su-cheol;Kong, Ha-Sung
    • The Journal of the Convergence on Culture Technology
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    • v.8 no.5
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    • pp.641-651
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    • 2022
  • This research compares and analyzes evacuation time depending on the change in stair width in case of fire at Goshiwons. For this, a simulation has been conducted based on possible evacuation time according to the calculation method for the number of people admittable to a specific target for fire fighting equipped with accommodation. Currently, Gosiwon, which is classified as an accommodation facility (a total floor area of 500 m2 or more), uses blind spots prescribed by the Fire Services Act, Building Act, and Parking Act to build a high-rise building on a small area of land, and most Gosiwon is transformed into a modified accommodation. This is in line with the owner's operating profit, so it is expected to show a continuous increase. Securing the golden time of Gosiwon evacuation time is the last bastion of Gosiwon residents who belong to the economically disadvantaged in our society, and we hope this study will serve as a starting point for discussions on revising related laws and regulations to establish a social safety net As a result of the evacuation simulation analysis, the evacuation time was the least when the width of the group and the evacuation stairs were expanded to 200cm, and the evacuation time of the existing building was reduced by up to 166.3 seconds by comparing 648.4 seconds and scenario 6. This analysis can be meaningful, in that the width of the evacuation stairs revision of related laws and regulations for the safety of multiplex available premises.

Analyzing the Impact of Species on Urban Development Using Meta Population Model (메타개체군 이론을 활용한 도시개발에 따른 생물 종 영향 평가 활용 가능성 분석)

  • Eun Sub Kim;Young Won Mo;Tae Yoon Park;Yoonho Jeon;Jiyoung Choi;Dong Kun Lee
    • Journal of Environmental Impact Assessment
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    • v.32 no.2
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    • pp.61-71
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    • 2023
  • As differences in the impact of each species on a spatial scale occur, analysis at the landscape scale is necessary to evaluate the impact of a development project. In previous studies, the Incidence Function Model (IFM) based on meta population theory was used to analyze the impact of species on the environment that changes according to urban development. However, since the model was required at least 10 occupied areas, it is difficult to use it for species that are difficult to monitor such as endangered species. Therefore, we proposed the Incidence Function Model (IFM) using species distribution model to fill the species data. In addition, we reviewed whether the developed model can be used in environmental impact assessment. As a result of the analysis, the minimum occupancy of Prionailurus bengalensis on urban development decreased to 56.5% and the possibility of survival to 28.7%. We confirmed that It rapidly decreased from the reference points of 230 and 70habitats through analysis of the meta-population capacity according to the decrease in the number of habitats. These results can be assessing the environment impact of each species on habitat loss. And it can support decision-making on the minimum number and area of habitat for species protection. This study is expected to be used as basic data for environment impact assessment on before and after development projects and mitigation measures plans, thereby increasing the effectiveness of reduction plans.

Weights for Evaluation items of Conformity index of Bird breeding sites on the West and South coasts of Korea (서·남해 연안성 조류번식지 적합성지수 평가항목 가중치 설정)

  • Kim, Chang-Hyeon;Kim, Won-Bin;Kim, Kyou-Sub;Lee, Chang-Hun
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.41 no.4
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    • pp.40-48
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    • 2023
  • This study is part of a foundational research effort aimed at developing a suitability index for breeding grounds related to avian activities along the domestic South and West coasts, including islands. Focus Group Interviews (FGI) and Analytic Hierarchy Process (AHP) analyses were conducted. The results are as follows. First, as a result of determining the value of the suitability of coastal bird breeding sites, the 'Natural Value(0.763)' was higher than the 'Artificial Value(0.237)'. Other artificial values were identified as sub-ranked except for 'Protected Areas' to ensure continuous integrity of breeding spaces. Second, as a result of re-establishing the 25 evaluation items classified in the two-time FGI as higher concepts, nine natural values and five artificial values were finally selected as a total of 14. Third, the results of the mid-classification evaluation of the importance of the suitability of coastal bird breeding sites were identified in the order of 'Ecological Value(0.392)', 'Topographic Value(0.251)', 'Passive Interference(0.124)', 'Geological Value(0.120)', and 'Active Interference(0.113)'. Fourth, the results of the priority of evaluation items of coastal bird breeding sites were in the order of 'Vegetation Distribution (0.187)', 'Area of Mudflats(0.118)', 'Presence or Absence of Mudflats(0.092)', 'Appearance of Natural Enemies(0.087)', 'Protected Areas(0.08)', 'Island Area (0.069)', 'Over-Breeding devastation(0.064)', 'Soil Composition Ratio(0.056)', 'Distance from Land(0.054)', 'Ocean farm area (0.045)', 'Cultivated land area(0.041)', 'Cultivation behavior(0.038)', 'Angle of the Surface(0.036)', and 'Land Use(0.033)'. It is judged that the weighting result value of the evaluation items derived in this study can be used for priority evaluation focusing on the coastal bird breeding area space. However, it seems that the correlation with the unique habitat suitability of bird individuals needs to be supplemented, and spatial analysis research incorporating species-specific characteristics will be left as a future task.

Transport behavior of a surfactant tracer(CPC) with Langmuir type adsorption isotherm on NAPL-water interface in a homogeneous porous medium (NAPL-물 계면에서 Langmuir형 흡착특성을 보이는 계면추적자(CPC)의 다공성 균질매질내 유동특성)

  • 김헌기;문희수;이상훈
    • Journal of Soil and Groundwater Environment
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    • v.6 no.2
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    • pp.3-13
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    • 2001
  • It has been known that nonlinear characteristics of sorption affect the transport behavior of water soluble pollutants in soils. However detailed experimental studies have not been performed to verify the effect of non-linearity of adsorption isotherm on transport of chemicals in porous media. In this research, the distortion of breakthrough curves of a cationic surfactant (cetylpyridinium chloride, CPC) in a engineered stainless steel column packed with glass beads were investigated. Glass beads with about 110 $\mu\textrm{m}$diameter coated with a thin n-decane film were used as the media providing the sorption surface for CPC. The CPC adsorption isotherm on the surface of n-decane from aqueous solution was a typical Langmuir type. The breakthrough curve of CPC using step Input showed a late breakthrough on the front side and early breakthrough on the back side accordance to the shape of the isotherm. The retardation factor of CPC was found to be a strong function of the input concentration, which also a manifestation of the non-linearity of the isotherm. The retardation factors for the CPC with step input agreed with those of pulse input that the maximum concentrations are controlled to be the same as the step input concentrations. This results support the validity of the unproven field practices of using hydrogeotracers with non-linear adsorption isotherms to determine the hydrogeological parameters, e.g., NAPL saturation, air-water or NAPL-water interfacial areas.

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Morphological Changes of Accessory Genital Organs Induced by Treatment with Different Concentration of Estrogen Receptor Agonist in the Male Mouse (수컷 생쥐에서 에스트로겐 수용체 촉진제의 농도별 투여에 의한 부속 생식샘의 형태학적 변화)

  • Cho, Young-Kuk;Han, Ji-Yeon;Cho, Hyun-Wook
    • Applied Microscopy
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    • v.41 no.4
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    • pp.265-276
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    • 2011
  • The aim of the present study is to validate the effects of treatment with different concentration of estrogen receptor alpha agonist, propyl pyrazole triol (PPT) on the weight and histological structure in the accessory reproductive organs (ventral prostate, seminal vesicle and preputial gland) of male mouse. Treated groups received different doses of PPT 0.01 mg, 0.1 mg and 1.0 mg per week respectively, for 3, 5, and 8 weeks. In general, the weight of reproductive organs was increased in PPT 0.01 mg and 0.1 mg treatment, however decreased in PPT 1.0 mg treatment. Epithelial tissues in the ventral prostate were changed from simple columnar epithelium to squamous or cuboidal epithelium in the treated groups. On week 3, PPT groups caused decrease of epithelial cell height in the ventral prostate. Lumen of the seminal vesicle was narrowed in the treated group. Epithelial cell height of seminal vesicle was reduced in the PPT treatment. Acinus tissue of preputial gland in PPT 1.0 mg treatment was dramatically atrophied than that of control group. These results are useful as a reference to determine the administration concentration of PPT in experiments for understanding the physiological functions of estrogen in the male.

Studies on Cheese Ripening Part V. Degradation of Nitrogenous Compounds During the Ripening of Gouda-type Cheese (치이즈 숙성(熟成)에 관(關)한 연구(硏究) 제5보(第5報) Gouda-type 치이즈의 질소화합물(窒素化合物)의 변화(變化))

  • Kim, Yong-Kyo;Kim, Jong-Shik
    • Korean Journal of Food Science and Technology
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    • v.8 no.2
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    • pp.107-112
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    • 1976
  • This experiment has been carried out to study the changes of caseins is Gouda-type cheese during ripening by the use of DEAE-cellulose column and polyacrylamide gel electrophoresis. The results obtained were as follow: 1. The amount of water soluble nitrogenous compounds in the cheese ripened for 2 and 4 months was 19.03% and 30.61% for total nitrogen in the cheese, respectively. On the other hand, the amount of 5% NaCl soluble nitrogenous compounds in the cheese increased to 41.13% for 2 months ripening, but it decreased to 22.61% at 4th month. 2. By DEAE-cellulose column, various nitrogenous compounds of Gouda-type cheese were fractionated into 5 major and several minor peaks. The proportion of some fraction areas to the whole increased with the ripening period and the others decreased. 3. Electrophoretic patterns of various nitrogenous compounds in a 4-month-old cheese showed 5 and 8 bands, repectively. 4. Sixteen amino acids were identified in soluble and precipitable compounds at 12% TCA in a 4-month-old cheese.

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Numerical modeling of tidal discharge through a permeable dyke from varying surface gradients (내·외 수위차를 이용한 투수성 제체의 조류량 모델링)

  • Hong, Seong Soo;Kim, Tae In;Nguyen, Thao Thi Hoang;Gu, Jeong Bon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2021.06a
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    • pp.219-219
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    • 2021
  • 서해안 중부 아산만 안쪽에 위치하는 평택·당진항에서 장래 개발 예정인 면적 6.9km2의 내항2공구 수역은 내항2공구 외곽호안 - 내항가호안 - 내항2공구 중앙 분리호안으로 둘러싸여 있으며, 투수성 제체인 내항가호안 사석 공극을 통하여 해수가 유통되어 조석 현상이 나타나고 있다. 2020년 8~9월의 2개월간 내항2공구 외곽호안 내·외측에서 조석 관측 결과, 2공구 수역의 최대 조차는 1.97m로서 외측 해역 최대 조차 9.79m의 20.1%이고 내·외측의 순간 수위차는 최대 5.82m에 달한다. 내항가호안은 내항2공구 개발이 거의 완료되는 시기까지 유지될 예정이므로 2공구 개발에 따른 내측 조차와 내·외측 수위차의 변화를 정확하게 예측하는 것은 내항가호안 제체 안전에 매우 중요하다. 이 연구의 목적은 장래 개발단계별 변화 예측에 앞서, 관측이 이루어진 2개월간의 실시간 내측 조석과 내·외측 수위차 시계열을 Delft3D-Flow를 이용하여 기 구축된 아산만 수치모델에서 재현하는 것이다. 내항가호안 제체 통과 유량은 내·외측 수위차에 비례하는 것으로 가정하고, 수위차 - 유량 관계식을 도출하였다. 수위차는 평택 조위관측소와 내항2공구 수역의 1분 간격 관측 조위로부터 산출하였고, 제체 통과 유량은 내측 조위(z, 평택항 DL 기준, m) - 수용적(V, 106m3) 관계식으로 계산하였다. 내측 조위 - 수용적 관계식은 수심측량 성과로부터 V = 0.28z2 + 3.73z + 2.96 (r2=1.00)으로 얻어졌다. 다양한 함수식의 적합성을 검토한 결과, 다음과 같은 수위차(𝚫z, m) - 제체 통과 유량(Q, m3/s) 관계식을 도출하였다. [내항가호안 내측으로 유입시] $Q_{IN}=\{\begin{array}{lll}{\exp}\{0.54\;{\ln}({\Delta}z)+6.00\}&&\text{; }{\Delta}z{\leq}1.8\\219.82{\Delta}z+158.56&&\text{; }{\Delta}z>1.8\end{array}\;\;(r^2=0.86)$ [내항가호안 외측으로 유출시] QOUT = -exp{0.44 ln(-𝚫z) + 5.70} (r2=0.59) 매 𝚫t 마다 제체 통과 유량을 계산하는 알고리즘을 Delft3D 소스 코드에 추가하고, 8개 분조 합성조석(M2, S2, K1, O1, N2, K2, P1, Q1)을 외력조건으로 설정하여 2개월간 조석 수치모델링을 수행하였다. 내항2공구 수역의 매 시별 조위 관측치와 모델치를 비교한 결과, 오차는 -0.37~0.37m의 범위이고, 오차 평균은 0.02m, 절대오차 평균은 0.08m로 상당히 정확하게 실시간 조위 변동을 모의하였다. 보정·검정된 이 모델을 이용하여 향후 내항2공구 개발에 따른 내측 조석과 내·외측 수위차 변화에 대한 예측모의를 진행할 예정이다.

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Reduction of Perchlorate and Nitrate by Citrobacter Amalonaticus Strain JB101 : Kinetics and the Applicability of MBR (Citrobacter Amalonaticus Strain JB101에 의한 과염소산염과 질산염의 환원 : Kinetics 및 MBR을 이용한 처리 가능성)

  • Hong, Jae-Wha;Jang, Myung-Su;Lee, Il-Su;Bae, Jae-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.12
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    • pp.1298-1304
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    • 2005
  • This study was performed to evaluate the characteristics of the competition between two electron acceptors, perchlorate and nitrate, with Citrobacter Amalonaticus strain JB101. In addition, the applicability of membrane bioreactor(MBR) for perchlorate removal was evaluated. The maximum growth rate of strain JB101 on perchlorate and nitrate are 0.27 and 0.58 $hr^{-1}$, and maximum substrate utilization rates were 35.1 mg $ClO_4^-/g$ protein-day and 45.6 mg $NO_3^-/g$ protein-day, respectively. Nitrate was a competitive inhibitor for perchlorate, and strain JB101 prefer nitrate to perchlorate as electron acceptor. Complete removal of perchlorate could be achieved up to the surface leading rate of 4.6 g $ClO_4^-/m^2-day$ with the MBR fed with 20 mg $ClO_4^-/L$(HCMBR). When 5 mg/L of nitrate was added to the same influent, perchlorate removal efficiency decreased to 96.5%, while nitrate was completely removed. For the MBR fed with 0.7 mg/L of perchlorate (LCMBR), the maximum perchlorate removal efficiency was 100% up to the loading rate of 0.23 g $ClO_4^-/m^2-day$. Membrane fouling was found to be a problem at high leading rate for both MBRs. The acetate consumption ratio per perchlorate was $13.7{\sim}51.7\;e^-eq./e^-eq.$ in LCMBR, while the value was $2.5{\sim}3.6\;e^-eq./e^-eq.$ in HCMBR. This difference could be related to the acetate consumption with oxygen as electron acceptor. Therefore, the amount of acetate addition must be determined considering the concentrations of other electron acceptors in the influent.

Effect of Interference Mitigation Technique and Performance Analysis for Small Cell in Homogeneous Networks (동종네트워크 상에서 셀 소형화 간섭 완화 기법 및 성능 분석)

  • Jang, Ye-Ok;Cho, Eun-Hyung;Hong, Een-Kee
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.39C no.10
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    • pp.937-945
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    • 2014
  • As various services requiring high data rate are supported by introducing LTE/LTE-adv., mobile traffic increases rapidly. To cope with the continuous growth of traffic demand, small cell technology is considered as one of the most promising one. Small cell can increase system capacity by increasing the number of base stations with reduced cell radius. In this paper, we analyze the effect of cell densification with small cells in terms of SINR and average UE throughput considering cell split and the number of UE per unit area. As the cell becomes smaller, SINR degradation arises from high ICI(Inter Cell Interference) and we evaluate the effect of interference mitigation scheme in small cell environment where the proper interference mitigation technique is applied.