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Application of Electrocoagulation for Printing Wastewater Treatment: From Laboratory to Pilot Scale

  • Thuy, Nguyen Thi;Hoan, Nguyen Xuan;Thanh, Dang Van;Khoa, Pham Minh;Tai, Nguyen Thanh;Hoang, Quang Huy;Huy, Nguyen Nhat
    • Journal of Electrochemical Science and Technology
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    • v.12 no.1
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    • pp.21-32
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    • 2021
  • This study reports for the first time the application of electrocoagulation (EC) from laboratory to pilot scales for the treatment of printing wastewater, a hazardous waste whose treatment and disposal are strictly regulated. The wastewater was taken from three real printing companies with strongly varying characteristics. The treatment process was performed in the laboratory for operational optimization and then applied in the pilot scale. The weight loss of the electrode and the generation of sludge at both scales were compared. The results show that the raw wastewater should be diluted before EC treatment if its COD is higher than about 10,000 mg/L. Pilot scale removal efficiencies of COD and color were slightly lower compared to those obtained from the laboratory scale. At pilot scale, the effluent CODs removal efficiency was 81.9 - 88.9% (final concentration of 448 - 992 mg/L) and color removal efficiency was 95.8 - 98.6% (final level of 89 - 202 Pt-Co) which proved the feasibility of EC treatment as an effective pre-treatment method for printing wastewater as well as other high colored and hard-biodegradable wastewaters.

Effect of Perforated PVC Underdrainage Pipe on Desalting of Plastic Film House Soils (시설재배지 유공관 암거배수에 의한 염류집적 경감효과)

  • Kim, Dae-Su;Yang, Jae E.;Ok, Yong-Sik;Yoo, Kyung-Yoal
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.2
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    • pp.65-72
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    • 2006
  • Objective of this research was to remove the accumulated salts in the plastic film house soils by installing the perforated PVC (${\phi}10cm$) underdrainage pipes at 50 cm depth of soils with cultivating vegetables. Efficiency of the underdrainage pipes was assessed based on the changes of soil chemical properties such as pH, EC, and cations, and growth and yield parameters of the vegetables between the two treatments; the control and the underdrainage pipe treatments. The EC of the underdrainage pipes installed soils after two growing seasons were in the ranges of $1.42-2.88dS\;m^{-1}$ but those of the control were in the ranges of $3.86-4.53dS\;m^{-1}$, indication the underdrainage pipes effectively removed the accumulated salts in soils. The pHs of the control soils and the underdrainage pipe installed soil were in the ranges of 7.2-7.5 and 6.9-7.3, respectively. There was a significant correlation between pH and cation exchange capacity (CEC) of the soils ($CEC=17.107{\times}pH-106.2$, $r^2=0.759$, P < 0.05). The ECs of the soils at different depths were compared between the two treatments after cultivating vegetables with lettuce-lettuce-garland chrysanthemum rotation systems. The ECs of the control soils at depths of 0-10, 10-20, 20-30, 30-40, and 40-50 cm were 3.45, 3.47, 3.03, 2.03, and $2.28dS\;m^{-1}$, respectively, with decreasing with soil depths. On the other hand, the respective ECs of the underdrainage pipes installed soils were 2.43, 2.52, 2.28, 4.00, and $4.23dS\;m^{-1}$ with increasing with soil depths. This might be derived from the salts moved downward with the draining water into the subsoil. The order of cations moved downward was Mg > Ca > K, based on the ratios of cations at specific depth over those at the surface soil. The survival rates of lettuce after 15 days of transplanting in the underdrainage pipe installed soils were 98.2% as compared to 86.6% of the control. The underdrainage pipe treatment also increased the diameter of the lettuce stalk from 12.9mm of the control to 13.7mm. Overall results demonstrated that the installment of the underdrainage pipes in the subsoils of the salt accumulated plastic film house soil effectively removed the salts by leaching downward,resulting in lowering soil EC and enhancing the growth and yield of vegetables.

Fabrecation and Characterization of $SrBi_2TaNbO_9$ Ferroelectric Thin Film Prepared by Sol-Gel Method (SOL-GEL법을 이용한 $SrBi_2TaNbO_9$ 강유전성 박막 제조 및 특성 평가)

  • 이진한;박상준;장건익
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.94-98
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    • 2000
  • Polycrystalline SBTN ferroelectric thin films were prepared by sol-gel method with various Nb mole ratios on Pt/ $SiO_2$/Si (100) substrates. The films were annealed at different temperatures and characterized in terms of phase and microstructure. Relatively a well saturated hysteresis pattern was obtained at x =0.2 in S $r_{0.8}$B $i_{2.3}$(T $a_{1-x}$ N $b_{x}$)$_2$ $O_{9+}$$\alpha$/ thin films. At an applied voltage of 5V, the dielectric constant ($\varepsilon$$_{r}$) and dissipation factor (tan $\delta$) of typical S $r_{0.8}$B $i_{2.3}$(T $a_{1-x}$ N $b_{x}$)$_2$ $O_{9+}$$\alpha$/ thin film (x=0.2) were about 236.2 and 0.034. Measured remanent polarization (2Pr) and coercive field (Ec) were 4.28C/c $m_2$, and 38.88kv/cm respectively. No fatigue was observed up to 6$\times$10$_{10}$ switching cycles at 5V and the normalized polarization reduced by a factor of only 4%.%. 4%.%. 4%.%.%.%.%.

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Acaricidal Activity of A Newly Synthesized K16776 against Honeybee Mite, Varroa destructor (Acari: Varroidae) (꿀벌응애에 대한 신규화합물 K16776의 살비효과)

  • Oh, Man-Gyun;Ahn, Hee-Geun;Kim, Hyun-Kyung;Yoon, Chang-Mann;Kim, Jin-Ju;Kim, Tae-Joon;Lee, Dong-Guk;Chung, Geun-Hoe;Kim, Gil-Hah
    • The Korean Journal of Pesticide Science
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    • v.12 no.2
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    • pp.192-196
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    • 2008
  • This study examined the acaricidal activity of a new compound, K16776 against honeybee mite, Varroa destructor which is ecto-parasite of Apis mellifera. Acaricidal activity was performed using six acaricides, two Chinese commercial acaricides and one newly synthesized K16776 against V. destructor in the small container and in the bee hive. K16776 and amitraz exhibited 100% acaricidal activity against V. destructor without insecticidal toxicity to A. mellifera in the small container. The other acaricide was not activity. Applied to the bee hives, K16776 showed acaricidal activity as 98.7% ($250{\times}$) and 88.6% ($500{\times}$) and amitraz showed as 100% ($500{\times}$) and 90% ($1,000{\times}$), respectively. Made in China, Cao Suan Sha Man Pian and Wangs showed acaricidal activity as 56.9% and 66.7%, respectively. The result indicates that K16776 can be potentially useful control agent against honeybee mite, V. destructor.

Losses of Chemical Components by Infiltration Water during the Rice Cultivation at Silt Loam Paddy soil (영농기간 지하침투수에 의한 미사질양토 논의 화학성분 손실량)

  • Han, Kang-Wan;Cho, Jae-Young;Son, Jae-Gwon
    • Korean Journal of Environmental Agriculture
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    • v.17 no.3
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    • pp.268-273
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    • 1998
  • Changes of chemical component and losses of chemical fertilizer by infiltration water from 0.5ha of paddy field in Chinan area of Chonbuk province during the rice cultivation were investigated. The infiltration water samples were collected in a ceramic porous cup which was a buried at the 30, 50, 70, 90㎝ of soil depth. pH of infiltration water ranged $6.64{\sim}7.90$ and EC showed $324{\sim}647{\mu}$S/cm. The content of total-N, $NH_4-N$ and $NO_3-N$ were $0.58{\sim}14.59$, $0.05{\sim}4.25$, and $0.15{\sim}7.71mg/L$ respectively. The content of total-P and ortho-P were $0.009{\sim}0.077mg/L$ and $0{\sim}0.029mg/L$ The content of $Ca^{++}$, $Mg^{++}$, $Na^{+}$ and $K^{+}$ showed $0.88{\sim}4.78$, $0.22{\sim}1.04$, $0.17{\sim}0.98$, and $0.84{\sim}3.19㎎/L$. These all at the first transplanting are higher than that of other periods. The content of $SO_4^{2-}$ showed $3.92{\sim}18.72mg/L$ and decreased with a soil depth. However $Cl^-$ of infiltration water ranged $9.03{\sim}19.97mg/L$ and no difference with a soil depth. When infiltrated $2,416.5m^{3}$ of an infiltration water from 0.5ha of paddy field during the rice cultivation, losses of chemical components were 20.34㎏/㏊ of total-N, 3.54㎏/㏊ of $NH_4-N$, 10.44㎏/㏊ of $NO_3-N$, 0.16㎏/㏊ of total-P and 0.028㎏/㏊ of ortho-P. Also $Ca^{++}$, $Mg^{++}$, $Na^+$, $K^+$, $SO_4^{2-}$ and $Cl^-$ were lost 10.24, 2.84, 2.84, 7.22, 50.04 and 62.20㎏/㏊ respectively. There were lost by infiltration water 9.35% of nitrogen, 0.59% of phosphorous and 22.79% of potassium in applied chemical fertilizer.

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Purification and Characterization of Lactate Dehydrogenase Isozymes in Channa argus (가물치(Channa argus) 젖산탈수소효소 동위효소들의 정제 및 특성)

  • Park, Eun-Mi;Yum, Jung-Joo
    • Journal of Life Science
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    • v.20 no.2
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    • pp.260-268
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    • 2010
  • The lactate dehydrogenase (EC 1.1.1.27, LDH) isozymes in tissues from Channa argus were purified and characterized by biochemical, immunochemical and kinetic methods. The activity of LDH in skeletal muscle was the highest at 380.4 units and those in heart, eye and brain tissues were 13.4, 3,5 and 5.4 units, respectively. Citrate synthase (EC 4.1.3.7, CS) activity in heart tissue was the highest at 20.7 units. LDH/CS in skeletal muscle, heart, eye and brain tissues were 172.9, 0.6, 0.32 and 0.47. Protein concentration in skeletal muscle tissue was 14.7 mg/g and specific activities of LDH in skeletal muscle, heart, eye and brain tissues were 25.88, 0.79, 0.31 and 1.38 units/mg, respectively. Therefore, skeletal muscle tissue was anaerobic and heart tissue was aerobic. The LDH isozymes in tissues were identified by polyacrylamide gel electrophoresis, immunoprecipitation and Western blot with antiserum against $A_4$, $B_4$, and eye-specific $C_4$. LDH $A_4$, $A_3B$, $A_2B_2$. $AB_3$ and $B_4$ isozymes were detected in every tissue, $C_4$, $AC_3$, $A_2C_2$ and $A_3C$ were detected in eye tissue, and $A_3C$ was found in brain tissue. LDH $A_4$, $A_3B$, $A_2B_2$, $AB_3$, $B_4$, eye-specific $C_4$ isozymes were purified by affinity chromatography and Preparative PAGE Cells. The LDH $A_4$ isozyme was purified in the fraction from elution with $NAD^+$ containing buffer of affinity chromatography. Eye-specific $C_4$ isozyme was eluted right after $A_4$, after which $B_4$ isozyme was eluted with plain buffer. As a result, one part of molecular structures in $A_4$, $B_4$ and eye-specific $C_4$ were similar, but were different from each other in $B_4$ and $C_4$. Therefore the subunit A may be conservative in evolution, and the evolution of subunit B seems to be faster than that of subunit A. The activity of LDH $A_4$, $A_2B_2$, $B_4$, and eye-specific $C_4$ isozymes remained at 39.98, 21.28, 19.67 and 16.87% as a result of the inhibition by 10 mM of pyruvate, so the degree of inhibition was very high. The $Km^{PYR}$ values were 0.17, 0.27 and 0.133 mM in $A_4$, $B_4$ and eye-specific $C_4$ isozymes, respectively. The optimum pH of LDH $A_4$, $B_4$, eye-specific $C_4$, $A_2B_2$, $A_3B$, and $AB_3$ were pH 6.5, pH 8.5, pH 5.5, pH 6.0-6.5, pH 5.0 and pH 7.5. The $A_4$ and heterotetramer isozymes stabilized a broad range of pH. Especially, LDH activities in skeletal muscle tissue were high, resulting in a high degree of muscle activity.LDH metabolism in eye tissue seems to be converted faster from pyruvate to lactate by eye-specific $C_4$ isozyme as eye-specific $C_4$ have the highest affinity for pyruvate, and right after the conversion, oxidation of lactate was induced by $A_4$ isozyme. It was found that expression of Ldh-C, affinity to substrate and reaction time of $C_4$ isozyme were different according to the ecological environmental and feeding capturing patterns.

Physical and Chemical Ingredients Components and Physiological Activity of Chungtaejeon and Green Tea Extracts (청태전과 녹차 추출물의 이화학적 성분과 생리 활성)

  • Park, Yong-Seo;Lee, Mi-Kyung;Ryu, Hyeun-Hee;Heo, Buk-Gu
    • Journal of the East Asian Society of Dietary Life
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    • v.18 no.3
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    • pp.391-396
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    • 2008
  • This study was carried out to help restore and spread broaden the consumption of Chungtaejeon, a our traditional tea, Chungtaejeon in Korea, and as well as to gather the basic data on Chutaejeon tea. We have also compared the various ingredients components and physiological activities of Chungtaejeon tea extracts with that of green tea extracts. According to the results, the total phenol contents in of the Chungtaejeon and green tea extracts were 90.56 and 98.70 mg/100 mL, respectively, and their tannin contents levels in Chungtaejeon and green tea extracts were 214.14 mg/100 mL and 259.60 mg/100 mL, respectively, showing a difference in content. The catechin contents of the Chetaejeon and green tea extracts were in the order of EGC($15.80{\sim}16.50\;mg/100mL$), EGCG($10.40{\sim}10.60\;mg/100 mL$), and ECG($9.55{\sim}9.88\;mg/100 mL$), however, with the exception of EC(7.86 mg/100 mL) in the green tea extracts, there were not significant differences between that in them Chetaejeon and green tea extracts. Quercetin was the main flavonoid ingredient component in those both the Chungtaejeon and green tea extracts was quercetin, at levels of 0.08 mg/100 mL and 0.06 mg/100 mL and its contents in Chungtaejeon and green tea extracts were 0.08 mg/100 mL and 0.06 mg/100 mL, respectively. The primary amino acid in both tea extracts was theanine main amino acid at levels of, theanine contents were most increased in 8.02 mg/100mL and 10.80 mg/100 mL, respectively, Chungtaejeon tea extracts by 8.02 mg/100 mL and green tea extracts by 10.80 mg/100 mL. And the arginine contents of the Chungtaejeon and green tea extracts in Chungtaejeon and green tea extracts were 1.78 mg/100 mL and 1.86 mg/100 mL, respectively. In terms of mineral composition, potassium content was highest contents in the Chungtaejeon and green tea extracts by 19.80 and 18.04 mg/100 mL, respectively. Finally, the Chungtaejeon tea extracts offered the greatest anti-oxidation and ACE inhibition activities were most increased in the Chungtaejeon tea extracts, and the green tea extracts showed the highest level of nitrite radical scavenging activity at 90% was extremely much increased in the green tea extracts by 90%.

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