• Title/Summary/Keyword: 수요와 분포

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a-SiGe:H 박막의 고상결정화에 따른 주요 결험 스핀밀도의 변화

  • 노옥환;윤원주;이정근
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.78-78
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    • 2000
  • 다결정 실리콘-게르마늄 (poly-SiGe)은 태양전지 개발에 있어서 중요한 물질이다. 우리는 소량의 Ge(x=0.05)으로부터 다량의 Ge(x=0.67)을 함유한 수소화된 비정질 실리콘-게르마늄 (a-SiGe:H) 박막의 고상결정화 과정을 ESR (electron spin resonance)방법으로 조사해보았다. 먼저 PECVD 방법으로 Corning 1737 glass 위에 a-Si1-xGex:H 박막을 증착시켰다. 증착가스는 SiH4, GeH4 가스를 썼으며, 기판온도는 20$0^{\circ}C$, r.f. 전력은 3W, 증착시 가스압력은 0.6 Torr 정도이었다. 증착된 a-SiGe:H 박막은 $600^{\circ}C$ N2 분위기에서 다시 가열되어 고상결정화 되었고, 결정화 정도는 XRD (111) peak의 세기로부터 구해졌다. ESR 측정은 상온 x-band 영역에서 수행되었다. 측정된 ESR스팩트럼은 두 개의 Gaussian 함수로써 Si dangling-bond와 Ge dangling-bond 신호로 분리되었다. 가열 초기의 a-SiGe:H 박막 결함들의 스핀밀도의 증가는 수소 이탈에 기인하고, 또 고상결정화 과정에서 결정화된 정도와 Ge-db 스핀밀도의 변화는 서로 깊은 상관관계가 있음을 알 수 있었다. 특히 Ge 함유량이 큰 박막 (x=0.21, 0.67)에서 뿐만 아니라 소량의 Ge이 함유된 박막(x=0.05)에서도 Ge dangling-bond가 Si dangliong-bond 보다 고상결정화 과정에서 더 중요한 역할을 한다는 것을 알수 있었다. 또한 초기 열처리시 Si-H, Ge-H 결합에서 H의 이탈로 인하여 나타나는 Si-dangling bond, Ge-dangling bond 스핀밀도의 최대 증가 시간은 x 값에 의존하였는데 이러한 결과는 x값에 의존하는 Si-H, Ge-H 해리에너리지로 설명되어 질 수 있다. 층의 두께가 500 미만인 커패시터의 경우에 TiN과 Si3N4 의 계면에서 형성되는 슬릿형 공동(slit-like void)에 의해 커패시터의 유전특성이 파괴된다는 사실을 알게 되었으며, 이러한 슬릿형 공동은 제조 공정 중 재료에 따른 열팽창 계수와 탄성 계수 등의 차이에 의해 형성된 잔류응력 상태가 유전막을 기준으로 압축응력에서 인장 응력으로 바뀌는 분포에 기인하였다는 사실을 확인하였다.SiO2 막을 약화시켜 절연막의 두께가 두꺼워졌음에도 기존의 SiO2 절연막의 절연 파괴 전압 및 누설 전류오 비교되는 특성을 가졌다. 이중막을 구성하고 있는 안티퓨즈의 ON-저항이 단일막과 비교해 비슷한 것을 볼 수 잇는데, 그 이유는 TiO2에 포함된 Ti가 필라멘트에 포함되어 있어 필라멘트의 저항을 감소시켰기 때문으로 사료된다. 결국 이중막을 구성시 ON-저항 증가에 의한 속도 저하 요인은 없다고 할 수 있다. 5V의 절연파괴 시간을 측정한느 TDDB 테스트 결과 1.1$\times$103 year로 기대수치인 수십 년보다 높아 제안된 안티퓨즈의 신뢰성을 확보 할 수 있었다. 제안된 안티퓨즈의 이중 절연막의 두께는 250 이고 프로그래밍 전압은 9.0V이고, 약 65$\Omega$의 on 저항을 얻을수 있었다.보았다.다.다양한 기능을 가진 신소재 제조에 있다. 또한 경제적인 측면에서도 고부가 가치의 제품 개발에 따른 새로운 수요 창출과 수익률 향상, 기존의 기능성 안료를 나노(nano)화하여 나노 입자를 제조, 기존의 기능성 안료에 대한 비용 절감 효과등을 유도 할 수 있다. 역시 기술적인 측면에서도 특수소재 개발에 있어 최적의 나노 입자 제어기술 개발 및 나노입자를 기능성 소재로 사용하여 새로운 제품의 제조와 고압 기상 분사기술의 최적화에 의한 기능성 나노 입자 제조 기술을 확립하고 2차 오염 발생원인 유기계 항균제를 무기계 항균제로 대체할 수 있다. 이와 더불

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An Analysis of Price Competition between Two Ports using Game Model (게임모형을 이용한 두 항만간 가격경쟁에 관한 연구)

  • Kim, Tae-Gi;Park, Gyei-Kark
    • Journal of Korea Port Economic Association
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    • v.25 no.3
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    • pp.251-268
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    • 2009
  • This study analyzes price competition between two ports theoretically using a game model. We considered two cases: in Case I, consignors are located in a given position, and in Case II, consignors are distributed uniformally between two ports. The results are as follows. In Case I, the higher consignors' preferences for quality are, the more two ports' prices increase. As the locations of consignors are closer to Port H, the price of Port H increases and that of the low quality port(Port L) decreases. In addition, when transportation cost increases, the price of Port L decreases and the price of Port H tends to increase. If the quality of Port H improves, the price of the port H increases but the price of Port L is not clearly determined. In Case II, the higher consignors' preferences for quality are, the more two ports' prices increase. As transportation cost increases, the prices of both ports decrease but the price of Port L decreases twice as fast as that of Port H. In addition, if the quality of Port H improves, the price of Port H increases but the price of Port L decreases when transportation cost is high.

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Comparison of Liquefaction Probability Map Regarding with Geotechnical Information and Spatial Interpolation Target (공간보간 대상 및 지반정보에 따른 액상화 확률지도 비교)

  • Song, Seongwan;Hwang, Bumsik;Cho, Wanjei
    • Journal of the Korean GEO-environmental Society
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    • v.22 no.11
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    • pp.5-13
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    • 2021
  • The interest of expecting the liquefaction damage is increasing due to the liquefaction in Pohang in 2017. Liquefaction is defined as a phenomenon that the ground can not support the superstructure due to loss of the strength of the ground. As an alternative against this, many studies are being conducted to increase the precision and to compose a liquefaction hazard map for the purpose of identifying the scale of liquefaction damage using the liquefaction potential index (LPI). In this research, in order to analyze the degree of precision with regard to spatial interpolation objects such as LPI value and geotechnical information for LPI determination, liquefaction hazard map were made for the target area. Furthermore, based on the trend of precision, probability value was analyzed using probability maps prepared through qualitative characteristics. Based on the analysis results, the precision of the liquefaction hazard map setting the spatial interpolation object as geotechnical information is higher than that as LPI value. Furthermore, the precision of the liquefaction hazard map does not affect the distribution of the probability value.

Comparison and discussion of water supply and demand forecasts considering spatial resolution in the Han-river basin (분석단위 세분화에 따른 한강권역의 물수급 분석 비교 및 고찰)

  • Oh, Ji-Hwan;Kim, Yeon-Su;Ryu, Kyong Sik;Bae, Yeong Dae
    • Journal of Korea Water Resources Association
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    • v.52 no.7
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    • pp.505-514
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    • 2019
  • Our country is making efforts to manage water resources efficiently. In the future, It is necessary to develop a plan after subdividing the basin considering regional problems and water use, topographical and climatic characteristics. This study constructed water supply and demand system based on the standard watershed unit for water shortage evaluation considering spatial resolution. In addition, water shortage were calculated and compared using the MODSIM model in the Han-river basin. As a result, the average water shortage occurring during the 49 years (1967-2015) was 129.98 million $m^3$ for the middle watershed unit and 222.24 million $m^3$ for the standard watershed unit, resulting in a difference of about 2.1 billion m3. However, the trends and distribution of water shortage occurrence were very similar. The reason for this is that, in the case of the Middle watershed unit analysis, water shortages are calculated for the demand for living, industrial, and agricultural water for the representative natural flow value, assuming that all the water can be used in basin. The standard basin unit analysis showed that the difference between the fractionated supply and demand resulted in a large water shortage due to the relatively small amount of available water, and that the main stream did not show water shortage due to the ripple effect of the return flow. If the actual water use system is considered in the model as well as the subdivision of the spatial unit, it will be possible to evaluate the water supply and demand reflecting the regional characteristics.

A Study on the Users' Recognition of the ISA Based Specialized Library Operation (ISA 기반 특화도서관 운영에 대한 이용자의 인식조사 연구)

  • Noh, Younghee;Shin, Youngji;Kwak, Woojung
    • Journal of the Korean Society for information Management
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    • v.36 no.2
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    • pp.7-29
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    • 2019
  • The purpose of this study is to investigate the status of specialized services, user experience, and the overall satisfaction for the specialized library users, and based on the ISA method, compare the specialized theme data, specialized service place, specialized program, specialized theme area facilities and environment, and derive issues of the specialized library operation and improvement measures. Consequently, first, when selecting the theme of the specialized library, the theme ought to be selected to reflect the regional characteristics, history and demographics of the library, and the demand survey of the local residents and library users would need to be considered. Second, when planning the specialized program, the specialized library ought to consider operating differentiated programs based on the program operator who has the expertise to improve the quality of the program. Furthermore, sufficient theme related books and space must be secured, and moreover, the program must be planned in connection with the book collection. Third, the specialized library should be so structured as to ensure that the space may serve specialized themes provided by the library in order to provide specialized collections, services, and information services for the users. In addition, reflecting the needs of the users in designing the space must be considered.

Study on Electrochemical Performances of PEO-based Composite Electrolyte by Contents of Oxide Solid Electrolyte (산화물계 고체전해질 함량에 따른 PEO 기반 복합전해질 전기화학 성능 연구)

  • Lee, Myeong Ju;Kim, Ju Young;Oh, Jimin;Kim, Ju Mi;Kim, Kwang Man;Lee, Young-Gi;Shin, Dong Ok
    • Journal of the Korean Electrochemical Society
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    • v.21 no.4
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    • pp.80-87
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    • 2018
  • Safety issues in Li-ion battery system have been prime concerns, as demands for power supply device applicable to wearable device, electrical vehicles and energy storage system have increased. To solve safety problems, promising strategy is to replace organic liquid electrolyte with non-flammable solid electrolyte, leading to the development of all-solid-state battery. However, relative low conductivity and high resistance from rigid solid-solid interface hinder a wide application of solid electrolyte. Composite electrolytes composed of organic and inorganic parts could be alternative solution, which in turn bring about the increase of conductivity and conformal contact at physically rough interfaces. In our study, composite electrolytes were prepared by combining poly(ethylene oxide)(PEO) and $Li_7La_3Zr_2O_{12}$ (LLZO). The crystallinity, morphology and electrochemical performances were investigated with the control of LLZO contents from 0 wt% to 50 wt%. From the results, it is concluded that optimum content and uniform dispersion of LLZO in polymer matrix are significant to improve overall conductivity of composite electrolyte.

Evaluation of Rededge-M Camera for Water Color Observation after Image Preprocessing (영상 전처리 수행을 통한 Rededge-M 카메라의 수색 관측에의 활용성 검토)

  • Kim, Wonkook;Roh, Sang-Hyun;Moon, Yongseon;Jung, Sunghun
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.37 no.3
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    • pp.167-175
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    • 2019
  • Water color analysis allows non-destructive estimation of abundance of optically active water constituents in the water body. Recently, there have been increasing needs for light-weighted multispectral cameras that can be integrated with low altitude unmanned platforms such as drones, autonomous vehicles, and heli-kites, for the water color analysis by spectroradiometers. This study performs the preprocessing of the Micasense Rededge-M camera which recently receives a growing attention from the earth observation community for its handiness and applicability for local environment monitoring, and investigates the applicability of Rededge-M data for water color analysis. The Vignette correction and the band alignment were conducted for the radiometric image data from Rededge-M, and the sky, water, and solar radiation essential for the water color analysis, and the resultant remote sensing reflectance were validated with an independent hyperspectral instrument, TriOS RAMSES. The experiment shows that Rededge-M generally satisfies the basic performance criteria for water color analysis, although noticeable differences are observed in the blue (475 nm) and the near-infrared (840 nm) band compared with RAMSES.

Hydrophobic property of surface glaze of ceramic tiles by copper powder addition (구리 분말 첨가를 통한 도자타일 표면유약의 소수화 특성)

  • Choi, Cheong-Soo;Han, Kyu-Sung;Hwang, Kwang-Taek;Kim, Jin-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.5
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    • pp.215-221
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    • 2019
  • Ceramic tiles, which are widely used as interior and exterior materials for construction, have recently been required to have pollution prevention function. In order to remove contaminants, many researches of ceramic tiles with hydrophilic surface property through $TiO_2$ coating and hydrophobic surface property by improving the flow of water droplets have been proceeded. Expecially, it is very important to develop a surface glaze having hydrophobicity through a sintering process above $1000^{\circ}C$ without an additional coating process and the degradation of mechanical properties. In this study, surface glaze with copper powder was applied to manufacture of ceramic tile. Contact angle of ceramic tile according to thickness of surface glaze layer was investigated after the conventional sintering process. The contact angle of the ceramic tile surface without the copper powder was shown to be $25.3^{\circ}$, which is close to hydrophilic surface. However, the contact angle was increased up to $109.8^{\circ}$ when the thickness of surface glaze with the copper powder was $150{\mu}m$. The excellent hydrophobic property of the surface glaze with copper powder was resulted from the cellular structure of copper particles on the glaze surface. In addition, the mechanical properties of the developed hydrophobic ceramic tiles such as bending strength, chemical resistance, abrasion resistance, and frost resistance were well maintained and meet the criteria of 'KS L 1001 Ceramic tile'.

Crack Propagation Analysis for IMO Type-B Independent Tank with Liquefied Natural Gas Carrier (LNG 운반선에 적용된 독립형 탱크의 균열 진전 해석에 관한 연구)

  • Kim, Beom-il;Shafiqul, Islam MD
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.4
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    • pp.529-537
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    • 2021
  • Membrane-type hull and cargo holds have been designed and built for large ship. However, there is a growing interest in applying the same technology to small and medium-sized Liquefied natural gas(LNG) carriers to meet the recent increase in demand for LNG as an ecofriendly fuel and for expanding LNG bunkering infrastructure. The purpose of this study is to apply the IMO Type-B tank to small and medium-sized LNG carriers and verify the safety and suitability of the design. Fatigue crack propagation analysis was performed to install a partial second drip tray installed at the lower part of the LNG cargo tank by calculating the amount of leaked gas in the support structure supporting the cargo tank. First, a program for fatigue crack propagation analysis was developed, in which Paris' law and British Standard 7910 (BS 79110) were applied based on the International Code for the Construction of Equipment and Ships Carrying Liquefied Gases in Bulk, an international standard for LNG carriers. In addition, a surface crack propagation analysis was performed. Next, a methodology for assuming the initial through-crack size was developed to determine the size of the partial second barrier. The analysis was performed for 15 days, which is a possible return time after cracks are detected. Finally, the safety and suitability of the IMO Type-B for LNG cargo tanks required by international regulations were verified. For the accurate analysis of fatigue crack propagation, it is necessary to develop and verify the analysis procedure based on direct analysis and international regulations.

MLP-based 3D Geotechnical Layer Mapping Using Borehole Database in Seoul, South Korea (MLP 기반의 서울시 3차원 지반공간모델링 연구)

  • Ji, Yoonsoo;Kim, Han-Saem;Lee, Moon-Gyo;Cho, Hyung-Ik;Sun, Chang-Guk
    • Journal of the Korean Geotechnical Society
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    • v.37 no.5
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    • pp.47-63
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    • 2021
  • Recently, the demand for three-dimensional (3D) underground maps from the perspective of digital twins and the demand for linkage utilization are increasing. However, the vastness of national geotechnical survey data and the uncertainty in applying geostatistical techniques pose challenges in modeling underground regional geotechnical characteristics. In this study, an optimal learning model based on multi-layer perceptron (MLP) was constructed for 3D subsurface lithological and geotechnical classification in Seoul, South Korea. First, the geotechnical layer and 3D spatial coordinates of each borehole dataset in the Seoul area were constructed as a geotechnical database according to a standardized format, and data pre-processing such as correction and normalization of missing values for machine learning was performed. An optimal fitting model was designed through hyperparameter optimization of the MLP model and model performance evaluation, such as precision and accuracy tests. Then, a 3D grid network locally assigning geotechnical layer classification was constructed by applying an MLP-based bet-fitting model for each unit lattice. The constructed 3D geotechnical layer map was evaluated by comparing the results of a geostatistical interpolation technique and the topsoil properties of the geological map.