• Transactions of the Korean hydrogen and new energy society
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• v.16 no.2
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• pp.180-190
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• 2005

The PSA cycle was performed for the separation of binary gas mixture $H_2/Ar$ (80%/20%) using the six-step two-bed process. Adsorption equilibrium contains a LRC model for equilibrium adsorption isotherms and a LDF model for mass transfer. Aspen ADSIM, simulator was applied to predict the separation performance. The effect of cycle parameters such as feed rate, adsorption pressure and P/F ratio on the separation of hydrogen has been studied in experiment and simulation. In the results, maximize the recovery of hydrogen as a high purity was 13LPM feed flowrate, 120sec adsorption time, 11atm adsorption pressure and 0.1 P/F ratio in a cyclic steady-state come out since 10th cycle.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.3
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• pp.315-324
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• 2000

R-410A, R-407C, and four refrigerant mixtures composed of R-32, R-l34a, R-l43a, R-l52a, R-600(butane), and R-600a(isobutane) were tested in an attempt to replace R-22 used in most of the residential air conditioners. The performance evaluation was carried out in a psychrometric calorimeter test facility using a residential spilt type air conditioner under the KS rating conditions. Except for the lubricant and hand-operated expansion valve, the other parts of the air conditioner were the same with the commercial system. Performance characteristics were measured; COP, capacity, compressor power, and VCR. R-410A was shown to have 5.5% higher COP and 3.5% lower capacity than R-22. R-32/134a/600a (42.8/ 46.0/11.2 wt%) mixture have the best performance among the four refrigerant mixtures composed of hydrofluorocarbon and hydrocarbon. This inixture have 3.0% lower COP and 1.6% lower capacity than R-22.

• Journal of the Korean Society of Propulsion Engineers
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• v.7 no.4
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• pp.27-32
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• 2003

The Performance of micro combustor in various condition was exploited experimentally. Various geometric conditions of combustor were considered to figure out the performance of micro combustor. The micro combustor studied in this study was constant volume with cylindrical shape. Geometric parameters of combustor were defined to be combustor height and diameter. The effect of height was exploited parametrically with the size of 1mm, 2mm and 3mm. The effect of diameter was observed parameterized with 7.5mm and 15mm. Three different combustibles or Stoichiometric mixture of methane/air, hydrogen/air were used. Pressure transition during combustion process was recorded. The maximum pressure by combustion responded favorably with the change of height of combustor and the initial pressure. The flame propagation was visulized using Schlieren method. The flame propagation within combustor was observed when specific conditions such as combustor height and initial pressure over critical value was satisfied.

• Journal of the Korean Chemical Society
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• v.24 no.5
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• pp.347-355
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• 1980

The rate constants for the reaction of ${\alpha}$-naphthalene carbonyl chloride and ${\beta}$-naphthalene carbonyl chloride have been determined in methanol-acetonitrile and methanol-acetone. The rate constant of ${\alpha}$-naphtalene carbonyl chloride is higher than that of ${\beta}$-naphthalene carbonyl chloride. This behavior is consistent with Dewar's number, Nr and also Streitwieser's value ${\sigma}^+$. Since in the transition state carbonyl carbon is transformed to$sp^3$, no peri-hydrogen effect was observed.

• Elastomers and Composites
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• v.14 no.4
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• pp.260-263
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• 1979

티오디에탄올을 기본(基本)으로 하는 신합성(新合成)고무의 사용온도범위(使用溫度範圍)는 $-65^{\circ}C$에서 $150^{\circ}C$이며 표준연료(標準燃料) C와 gasohol을 포함(包含)한 각종(各種) 자동차용(自動車用) 오일에 대하여 우수(優秀)한 내유성(耐油性)을 보였고, 이 외(外)에 자연(自然)에서 널리 발생(發生)되는 황화수소(黃化水素)가스에 대(對)하여서도 우수(優秀)한 내(耐)가스성(性)을 보였다. 이 TDE 탄성체(彈性體)의 배합(配合)은 종래(從來)의 2본(本) 로울러 또는 밀폐식(密閉式) 혼합기(混合機)로 혼연(混練)할 수 있으며, compression, 사출(射出), 프레스 등으로 가황(加黃) 또는 유출(押出)이 가능하다. American Cyanamid Co에서는 TDE탄성체(彈性體)를 이용(利用)한 응용개발(應用開發)에 있으며 파일롯규모(親模)의 생산체제(生産體制)를 시도(試圖)할 것으로 알려져 있다. 이것이 시판(市販)되면 상품명(商品名)으로 Cymax라 명명(命名)될 것이며, 아민계(系곤) 가황제(加黃劑)인 DPP의 상품명(商品名)도 Cymax Curative P로 시판(市販)하게 될 것이다.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2008.04a
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• pp.100-103
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• 2008

Autoignition suppression of hydrogen/air premixed mixtures by $CF_3CHFCF_3$(HFP) was investigated computationally. Numerical simulation was performed in isobaric and homogeneous system to evaluate the induction times. The detailed chemistry of 93 species and 817 reaction mechanism was introduced for hydrogen/air/HFP mixtures. The results shows the similar concentrations for the major reactants such as hydrogen and oxygen during autoignition while water vapor produced at the ignition temperature was decomposed later, which leaded to the shoulder on the concentration of H, OH and O radical with time. The fluorine included from HFP was converted mainly to stable HF and the carbon was formed to various species, CF2, CF2O, CO etc. More details of chemical effects of HFP addition will be investigate with sensitivity analysis in the near future.

• Journal of the Korean Institute of Gas
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• v.1 no.1
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• pp.49-55
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• 1997

Destruction phenomena of structure by gas explosion is due to the explosion pressure and heat. Explosion pressure is a kind of energy converted from the gas mixture explosion. In this paper, we tried to find the relationship between explosion characteristics and combustion heat of the hydrocarbon-oxygen mixtures. Experiment were carried out with the volume of $5916cm^3$ cylindrical explosion vessel. Hydrocarbon gases which used in this study were methane, ethylene, propane, and buthane Experimental parameter was the concentration of the gas mixtures. Explosion characteristics were measured with strain type pressure transducer through the digital storage oscilloscope. From the experimental result, it was found that explosion pressure depend upon the combustion heat.

• Journal of the Korean Institute of Gas
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• v.25 no.5
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• pp.11-18
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• 2021

Since hydrogen has the lower minimum ignition energy than that of gasoline, hydrogen could be also appropriate for the IC engine systems. However, due to the low ignition energy, there might be a 'back-fire' and 'pre-ignition' problems with hydrogen SI(Spark-ignition) combustion. In this research, cooling effects of intake gas mixture on the improvement of the maximum power output were evaluated in a 2.4 L SI engine. There were two ways to cool intake gas mixtures. The first one was cooling intake fresh air by adjusting inter-cooler system after turbocharger. The other one was cooling hydrogen fuel before supplying by using heat ex-changer. Cooling hydrogen was performed under natural aspired condition. The result showed that cooling fresh air from 40 ℃ to 20~30 ℃ improved the maximum brake power up to 6.5~8.6 % and cooling hydrogen fuel as -6 ℃ enhanced the maximum brake power likewise.

• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.209-213
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• 2008

The fixed bed gasification reactor with 1 m hight and 10.2 cm diameter was utilized for the hydrogen production from biomass wastes. Lauan sawdust was used for non-catalytic and catalytic gasification reaction as a sample in the fixed bed reactor. The fixed bed temperature and catalyst are the major variables affecting the process operation. Thus, the effect of fixed bed temperature and the catalysts on gas composition were studied at the temperature range from $400^{\circ}C$ to $700^{\circ}C$. The yield of hydrogen was increased at higher temperature in the fixed bed reaction. Fractions of hydrogen, carbon monoxide and methane gas in the product gas increased when sodium carbonate ($Na_2CO_3$) and potassium carbonate ($K_2CO_3$) catalysts were used. Furthermore, sodium carbonate catalyst was more effective to obtain higher hydrogen yield compared to potassium carbonate catalyst.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.3 no.5
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• pp.337-349
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• 1991

Heat and mass transfer rates to spray water droplets for spray transients in a high pressure vessel have been predicted by two different droplet models: the complete mixing model and the non-mixing model. In this process, the ambient fluid surrounding the droplets is a real-gas mixture composed of saturated steam and noncondensable hydrogen gas at high pressure. The physical properties of the mixture are estimated by applying the concept of compressibility factor and using appropriate correlations. A computer program, DROPHMT, to calculate the heat and mass transfer rates for two different droplet models has been developed. As an illustrative application of the computer program to engineering practices, heat and mass transfer rates to spray water droplets for spray transients in a Pressurized Water Reactor (PWR) pressurizer have been calculated, and the typical results have been provided.