• Title/Summary/Keyword: 수소 수율

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A Study on Characteristics of Wood Pellet Gasification in Two Stage Gasifier (Two Stage Gasifier에서의 우드펠릿 가스화 특성 연구)

  • Lee, Moon-Won;Choi, Sun-Yong;Kim, Lae-Hyun
    • Journal of Energy Engineering
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    • v.19 no.4
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    • pp.240-245
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    • 2010
  • In this study, characteristics of wood pellet gasification was studied using a Two Stage Gasifier which is consisted of pyrolysis reactor and ultra high temperature reformer. The average yields of $H_2$, $CH_4$, CO, $CO_2$ were 16.7, 11.3, 37.2, 26.6 L/mim, conversion rate from biomass to gas was 65% in pyrolysis reactor and gas yields in reformer were 55.4, 0.8, 120.8, 56.8 L/mim, respectively. The hydrogen flow rate from reformer is obtained 360.1 L/hr. The most of $CH_4$ was decomposed from 12.3 to 0.3 vol.% while $H_2$ is from 18.2 to 23.7 vol.% in reformer by methane dry reforming, Boudouard reaction, oxidation and/or steam reforming. The amount of $H_2O$ generated by hydration reaction from reformer was 1111.8 g, its accelerated conversion of $CH_4$ to other products. The conversion rate from $CH_4$ to other Compounds was 97.2%. Cold gas efficiency was 53.2%.

Antioxidant Activity of Ethanol Extract from $D\breve{o}d\breve{o}k$(Codonopsis lanceolata) (더덕 에탄올추출물의 항산화효과)

  • Maeng, Young-Sun;Park, Hye-Kyung
    • Korean Journal of Food Science and Technology
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    • v.23 no.3
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    • pp.311-316
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    • 1991
  • This study was carried out to investigate the antioxidant activity of the ethanol extract from $d\bar{o}d\bar{o}k$ compared with that from ginseng. The peroxide values and thiobarbituric acid values were examined in order to estimate the antioxidant activity of the extract in soybean oil and lard. The antioxidant activity of the extract in soybean oil increased in the order of BHA$d\bar{o}d\bar{o}k$ cold extract(WDCE)$d\bar{o}d\bar{o}k$ reflux extract(WDRE)$d\bar{o}d\bar{o}k$ cold extract(CDCE)$d\bar{o}d\bar{o}k$ reflux extract(CDRE) $d\bar{o}d\bar{o}k$ showed significantly stronger antioxidant activity than that from ginseng.

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Enzymatic Hydrolysis of Pre-treated Ulva pertusa with Alkaline Peroxide (구멍갈파래의 알칼리 과산화수소 전처리 및 효소 가수분해 특성)

  • Yoon, Byung-Tae;Kim, Young-Wun;Chung, Keun-Wo;Kim, Jin-Seog
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.336-339
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    • 2011
  • Algae is an abundant and potential fermentation substrate. The enzymatic hydrolysis of algae was investigated by pre-treating an alkaline hydrogen peroxide with commercial cellulase and viscozyme. Algae used in this study was the Ulva pertusa. The evaluated response was the yield of released glucose after the enzymatic hydrolysis. Alkaline hydrogen peroxide containing mixtures of 1 wt% hydrogen peroxide and 1~1.75 wt% sodium hydroxide was also used. The results show that the highest glucose conversion was obtained for Ulva pertusa using 5 wt% hydrogen peroxide at $60^{\circ}C$ for 3 h. The required amount of enzymes after the pre-treatment with alkaline hydrogen peroxide were reduced by far compared to that of untreated Ulva pertusa. Also, the amount of glucose that is released during the enzymatic hydrolysis was increased.

Enhancement of High-Temperature Catalytic Reactions Using Membranes (분리막을 이용한 고온 촉매 반응 효율 향상)

  • Eun-Young Kim;Myeong-Hun Hyeon;Su-Young Moon
    • Membrane Journal
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    • v.33 no.6
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    • pp.305-314
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    • 2023
  • Various methods for removing by-products from chemical reactions are being studied to improve yield of catalytic reaction. Since the water is predominantly generated as a by-product in industrially significant reactions, it is necessary to develop the technology that can reliably remove water over a wide range of temperatures. Although several strategies using absorbents and additional dehydration reactions, have been proposed, they have limitations due to the issues such as additional energy and time consuming steps and sustainability of conversion. Membrane technology, which offers advantages such as easy operation, installation, and low maintenance costs, proves to be a promising approach for enhancing the efficiency of catalysts in various catalytic reactions. Therefore, this review discusses the removal of by-products using membranes and the associated benefits in this context.

II. 윤활기유 공정 및 제품소개

  • 이두원
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1986.06a
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    • pp.10-20
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    • 1986
  • I. 윤활기유 제조시설소개 개요 1) 고급 윤활기유(HVI)생산공장으로서 그간 수입에만 의존하던 최고급 품질의 기유를 국내 수요업체에 안정공급 2) 세계 최신 공정인 Gulf Lube Oil Hydrotreating Process Type III (수소첨가 개질공정)채택 3) 국내 최초일뿐 아니라, 세계에서도 일본, 카낟에 이어 3번째로 건설 1. 고품질 제품 생산-고점도 지수, 산화안정성 및 열안정성 우수, 잔류탄소분, 윤황분, 질소분 극소, 방향족 성분 및 회분 극소, 색상 양호 2. 첨가제(특히 산화방지제 및 점도 지수 향상제)사용효과 상승으로 완제품 생산시 생산비 감소 3. 동일 VI 제품 생산기준 수율이 높음 - Hydrocarbon Structure 변화로 원료 유중 부적합성분의 윤활기유화 4. Severity 조절로 Production Mode 변경 용이 5. 양질의 부산물 생산 - HDT Naphtha, Middle distillate 6. 용제 추출기유는 원유종류 및 성상에 따라 제품특성이 결정되나, 사용가능 원유가 다양 하면서도 제품특성 및 품질이 일정함.

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Effect of Productivity on the Hydrogen Content of Atmospheric gas in the BAF (BAF에서 분위기 가스의 수소 성분이 생산성에 미치는 영향)

  • 김순경;전언찬;김문경
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1996.11a
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    • pp.560-564
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    • 1996
  • In recently, annealing process of cold rolled sheet tend to change to continuous annealing process for improving qualify, saving yield. In the meantime as demand for various kind and small lot of products has been increasing, batch annealing has been appreciated for its small restriction for the operation. So, we tested on the effect for a hydrogen contents of atmospheric gas at annealing furnace. As a result of several investigation. We confirmed for the following characteristics ; improved productivity, uniform heating, improved surface quality, saving energy. Therefore, the use of hydrogen instead of nitrogen as the protective gas, combined with high convection in batch annealing furnaces, has shown that considerable increases in furnace output and material quality are attainable. Owing to the low density, high diffusion and reducing character of hydrogen, a better transfer resulting in uniform material temperatures and improved coil surfaces can be achieved.

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Catalase Production by Membrane Process for Treatment of Industrial Wastewater Containing Hydrogen Peroxide (막분리 공정을 이용한 과산화수소 함유 폐액처리용 카탈라제 생산)

  • 허병옥;이동철;신현재
    • KSBB Journal
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    • v.18 no.3
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    • pp.186-189
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    • 2003
  • This study aims to develop an economic process for the treatment of industrial wastewater containing hydrogen peroxide by using catalase. Core process is characterized by two membranes; microfiltration membrane and ultrafiltration membrane with different molecular cut-offs. Optimum dilution ratio of Aspergillus niger molds 개 buffer solution is 1:5. The final recovery yield of the enzyme is over 90% using the process. The enzyme solution shows the optimum temperature of 4$0^{\circ}C$ and pH range of 5-8.

The Syntheses of Organostannyl Compounds by Grignard Reaction Catalyzed by Ether in Non-ethereal Media (비에테르성 용매중에서 에테르촉매를 사용한 그리냐르반응에 의한 유기스탄닐화합물의 합성)

  • Bae Seok Seo;Il Kyu Lee
    • Journal of the Korean Chemical Society
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    • v.23 no.6
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    • pp.392-395
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    • 1979
  • Some alkyl or aryl halides, such as ethyl bromide, butyl chloride, phenyl bromide and benzyl chloride, were reacted by Grignard's method with anhydrous tin tetrachloride in hydrocarbon media. When small amounts of ether were added into the Grignard reaction step, the reaction proceeded rather smoothly and gave good yields of corresponding organotin compounds.

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Process Simulation and Economic Feasibility of Upgraded Biooil Production Plant from Sawdust (톱밥으로부터 생산되는 개질 바이오오일 생산공장의 공정모사 및 경제성 분석)

  • Oh, Chang-Ho;Lim, Young-Il
    • Korean Chemical Engineering Research
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    • v.56 no.4
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    • pp.496-523
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    • 2018
  • The objective of this study is to evaluate the economic feasibility of two fast pyrolysis and biooil upgrading (FPBU) plants including feed drying, fast pyrolysis by fluidized-bed, biooil recovery, hydro-processing for biooil upgrading, electricity generation, and wastewater treatment. The two FPBU plants are Case 1 of an FPBU plant with steam methane reforming (SMR) for $H_2$ generation (FPBU-HG, 20% yield), and Case 2 of an FPBU with external $H_2$ supply (FPBUEH, 25% yield). The process flow diagrams (PFDs) for the two plants were constructed, and the mass and energy balances were calculated, using a commercial process simulator (ASPEN Plus). A four-level economic potential approach (4-level EP) was used for techno-economic analysis (TEA) under the assumption of sawdust 100 t//d containing 40% water, 30% equity, capital expenditure equal to the equity, $H_2$ price of $1050/ton, and hydrocarbon yield from dried sawdust equal to 20 and 25 % for Case 1 and 2, respectively. TCI (total capital investment), TPC (total production cost), ASR (annual sales revenue), and MFSP (minimum fuel selling price) of Case 1 were $22.2 million, $3.98 million/yr, $4.64 million/yr, and $1.56/l, respectively. Those of Case 2 were $16.1 million, $5.20 million/yr, $5.55 million/yr, and $1.18/l, respectively. Both ROI (return on investment) and PBP (payback period) of Case 1(FPBU-HG) and Case 2(FPBU-EH) were the almost same. If the plant capacity increases into 1,500 t/d for Case 1 and Case 2, ROI would be improved into 15%/yr.