• Title/Summary/Keyword: 수소 산업

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Preparation and characterization of poly(dimethylsiloxane) foam prepared by hydrogen condensation reaction (수소 축합 반응에 의한 폴리디메틸실록산 미세 발포체의 제조 및 물성분석 연구)

  • Lee, Soo;Moon, Sung Jin
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.4
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    • pp.802-812
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    • 2016
  • Silicone foam is very useful as flame resistant material for many industrial areas such as high performance gasketing, thermal shielding, vibration mounts, and press pads. A silicone foam was prepared through simultaneous crosslinking and foaming by hydrogen condensation reaction of a vinyl-containing polysiloxane (V-silicone) and a hydroxyl-containing polysiloxane (OH-silicone) with hydride containing polysiloxane (H-silicone) in the presence of platinum catalyst and imorganic filler at room temperature. This is more convenient process for silicone foam manufacturing than the conventional separated crosslinking and foaming systems. Funtionalized silicones we used in this experiment were consisted with a V-silicone containing 1,0 meq/g of vinyl groups and a viscosity of 20 Pa-s, an OH-silicone with 0.4 meq/g of hydroxyl groups and a viscosity from 50 Pa-s, and an H-silicone containing 7.5 meq/g of hydride groups and a viscosity of 0.06 Pa.s. The effects of compositions of functionalized silicones and additives, such as catalyst and filler on the structure and mechanical properties of silicone foam were studied. 0.5 wt% of Pt catalyst was enough to accelerate the foaming rate of silicone resins. The addition of OH-silicone with lower viscosity accelerates the initial foaming rate and decreases the foam density, but the addition of V-silicone with lower viscosity reduces the tensile strength as well as the elongation. The final foam density, tensile strength, and elogation of silicone foam prepared under the SF-3 condition increase maximum to $0.58g/cm^3$, $3,51kg_f/cm^2$, and 176 %, repectively. We found out the filler alumina also played an important role to improve the mechanical properties of silicone foams in our foaming system.

Mineralogical Properties and Paragenesis of H-smectite (H-스멕타이트의 광물학적 특성과 생성관계)

  • Noh, Jin-Hwan;Hong, Jin-Sung
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.4
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    • pp.377-393
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    • 2010
  • Pumiceous tuffs occurring in the Beomgockri Group are examined applied-mineralogical characteristics and their controling factors to evaluate their potentials as the adsorption-functional mineral resources. The pumiceous tuffs are diagenetically altered to low-grade zeolitcs and bentonites in the Janggi area. Compositional specialty due to the presence of pumice fragments induces the altered tuffs to exhibit the characteristic adsorption property combined with cation exchange capacity, specific surface area, and acidic pH. Unusual lower pH in the adsorption-functional mineral substances is turned out to be originated from the presence of H-smectite having $H^+$ in the interlayer site of the sheet structure. On account of disordered crystallinity resulting from the exchanged $H^+$ in the interlayer site, the smectite commonly forms crenulated edges in the planar crystal form and exhibits characteristic X-ray diffraction patterns showing comparatively lower intensities of basal spacings including (001) peak than conventional Ca-smectite. Based on the interpretation of paragenetic relations and precursor of the H-smectite, a genetic model of the peculiar clay mineral was proposed. The smectite formation may be facilitated resulting from the precipitation of opal-CT at decreasing pH condition caused by the release of H+ during diagenetic alteration of pumice fragments. Because of the acidic smectite, the low-grade mineral resources from the Beomgockri Group may be applicable to the adsorption industry as the raw materials of acid clays and bed-soil.

Application of Granulated Coal Ash for Remediation of Coastal Sediment (연안 저질 개선을 위한 석탄회 조립물의 활용)

  • Kim, Kyunghoi;Lee, In-Cheol;Ryu, Sung-Hoon;Saito, Tadashi;Hibino, Tadashi
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.17 no.1
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    • pp.1-7
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    • 2014
  • This paper aims to explain the safety assessment and remediation mechanism of Granulated Coal Ash (GCA) as a material for the remediation of coastal sediments and to evaluate the improvement of the sediment in Kaita Bay, where GCA was applied. The concentrations of heavy metal contained in GCA and the dissolved amounts of heavy metal from GCA satisfied the criteria for soil and water pollution in Japan. The mechanisms on the remediation of coastal sediments using GCA is summarized as follows; (1) removal of phosphate and hydrogen sulfide (2) neutralization of acidic sediment (3) oxidation of reductive sediment (4) increase of water permeability (5) increase of soil strength (6) material for a base of seagrass. From the results obtained from the field experiment carried out in Kaita Bay, it was clarified that GCA is a promizing material for remediation of coastal sediment. This remediation technology can contribute to promote waste reduction in society and to decrease cost of coastal sediment remediation by applying GCA in other polluted coastal areas.

A Distributed Intelligent System for Multidisciplinary Design Optimization (다분야통합최적설계를 위한 지능형 분산 시스템)

  • 이재호;홍은지
    • Proceedings of the Korea Inteligent Information System Society Conference
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    • 2000.11a
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    • pp.257-266
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    • 2000
  • 산업 및 가정용 기기들이 점차 복잡해짐에 따라 다양한 공학 분야의 해석 기술을 동시에 고려하면서 이들 원리를 적용한 최적의 설계를 결정하는 방법론의 필요성이 대두되고 있다. 다분야통합최적설계 또는 MDO(Multidisciplinary Design Optimization)라 일컫는 새로운 기술은 이러한 필요에 대응하는 기술로서 국내외적으로 활발한 연구가 진행되고 있다. 이러한 MDO 기술을 구현하는 소프트웨어와 하드웨어 복합 체계를 MDO 프레임웍(framework)이라 한다. 일반적으로 프레임웍이란 실제 응용프로그램의 용도에 맞는 주문제작(customization)이 가능한 일종의 전단계 프로그램이라 할 수 있다 MDO 프레임웍은 설계 및 해석 도구들간의 인터페이스를 제공하고, 이들 도구들이 사용하는 설계 데이터를 효율적으로 공유할 수 있도록 지원하여, 설계 작업을 정의, 실행, 관리하는 역할을 한다. 이러한 MDO 프레임웍은 설계 작업을 통합적으로 관리하고 자동화하여 설계 도구간의 데이터 전달과 변환에 소묘되는 설계자의 부담을 경감시키며 다분야 전문가가 참여하는 공통 작업 환경을 제공함으로써 설계 효율성을 증진시킨다. 본 논문에서는 이러한 효용을 달성하기 위한 MDO 프레임웍(framework)을 제시하고 프레임웍 설계의 논리적 근저와 타당성을 밝힌다. 본 논문에서 제안하는 다분야 통합 최적화를 위한 분산형 지능 시스템인 DisMDO는 사용자가 GUI를 동해서 편리하게 다분야통합최적화 문제를 해결할 수 있도록 지원하며, 제공되는 스크립트 언어를 동해서도 이를 정의할 수 있도록 지원하여 일괄처리도 가능하도록 한다. 또한, 집중화된 데이터베이스를 관리하여 다분야 전문가들이 공통의 데이터를 안전하게 공유할 수 있도록 지원하며, 외부에서 제공되는 해석 도구나 최적화 모듈을 손쉽게 프레임웍에 통합시킬 수 있도록 하는 인터페이스 제작기(factory) 기능을 제공한다.ackscattering spectroscopy, X-ray diffraction, secondary electron microscopy, atomic force microscoy, $\alpha$-step, Raman scattering spectroscopu, Fourier transform infrared spectroscopy 및 micro hardness tester를 이용하여 기판 bias 전압이 DLC 박막의 특성에 미치는 영향을 조사하였다. 분석결과 본 연구에서 제작된 DLC 박막은 탄소와 수소만으로 구성되어 있으며, 비정질 상태임을 알 수 있었다. 기판 bias 전압의 증가에 따라 박막의 두께가 감소됨을 알 수 있었고, -150V에서는 박막이 거의 만들어지지 않았으며, -200V에서는 기판 표면이 식각되었다. 이것은 기판 bias 전압과 ECR 플라즈마에 의한 이온충돌 효과 때문으로 판단되며, 150V 이하에서는 증착되는 양보다 re-sputtering 되는 양이 더 많을 것으로 생각된다. 기판 bias 전압을 증가시킬수록 플라즈마에 의한 이온충돌 현상이 두드러져 탄소와 결합하고 있던 수소원자들이 떨어져 나가는 탈수소화 (dehydrogenation) 현상을 확인할 수 있었으며, 이것은 C-H 결합에너지가 C-C 결합이나 C=C 결합보다 약하여 수소 원자가 비교적 해리가 잘되므로 이러한 현상이 일어난다고 판단된다. 결합이 끊어진 탄소 원자들은 다른 탄소원자들과 결합하여 3차원적 cross-link를 형성시켜 나가면서 내부 압축응력을 증가시키는 것으로 알려져 있으며, hardness 시험 결과로 이것을 확인할 수 있었다. 그리고 표면거칠기는 기판 bias 전압을 증가시킬수록 더 smooth 해짐을 확인하였다.인하였다.을 알 수 있었다. 즉 계면에서의 반응에 의해 편석되는 Ga에 의해 박막의 strain이 이완되면, pinhole 등의 박막결함

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Production of Single-Cell Protein on Petroleum Hydrocarbon Part 7. Growth Conditions of Mixed Cultures in Pilot Plant (석유탄화수소를 이용한 단세포단백질의 생산에 관한 연구 제 7 보 시험공장에서 혼합배양균주의 생육조건)

  • Pyun, Yu-Ryang;Mheen, Tae-Ick;Kwon, Tai-Wan
    • Korean Journal of Food Science and Technology
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    • v.6 no.4
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    • pp.231-240
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    • 1974
  • The growth of a mixed yeast culture consisting of Canda tropicalis var. KIST 76 and Tricosporon cutaneum KIST 76-H was compared with that of pure cultures under pilot plant conditions. The mixed culture was judged stable based on the nearly constant ratio of the two organisms at the completion of fermentation. We obtained higher cell yields, protein content and productivity in the mixed culture on n-paraffin than the pure culture of C. tropicalis var. KIST 76. T. cutaneum KIST 76-H did not grow on n-paraffin medium. With the batch cultivation of mixed organisms on n-paraffin, the specific growth rates during the exponential growth phase were 0.24-0.33 $hr^{-1};$ cell yields were 96-106% and productivities were 2.9-3.6g/l. hr. The cells obtained contained 55-58% crude protein and 5.5-6.3% lipid. The critical value of dissolved oxygen concentration Ccrit. and saturation constant, km, are approximately 1.5 ppm and 0.228 ppm respectively. Also we established the optimal conditions for the mixed culture in batch fermentation.

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Effect of Sex on Quality Grade Factors, Physicochemical and Sensory Traits of Longissimus Dorsi in Hanwoo (성별이 한우 등심의 육질등급요인, 이화학적 및 관능특성에 미치는 영향)

  • Lee, Jong-Moon;Choe, Ju-Hui;Oh, Mi-Hwa;Kim, Yong-Su;Cheon, Dong-Won;Seo, Sang-Chul;Hwang, Kyu-Seok;Jang, Ae-Ra
    • Food Science of Animal Resources
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    • v.30 no.2
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    • pp.321-327
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    • 2010
  • The effect of cattle sex (cow, bull, and steer) on carcass traits of quality grade factors, physicochemical, and sensory traits of Longissimus Dorsi in Hanwoo was evaluated. Carcass traits of 42,113 heads were collected nation-wide and 257 heads were slaughtered to analyze beef quality. Sex affected significantly marbling score, meat color, fat color, texture, maturity, and quality grade of Hanwoo (p<0.05). Hanwoo steer carcasses had the highest marbling score (5.02), maturity (2.17), and texture (1.31) than those of cows and heifers. Crude fat of steers was higher than that of other cows and bulls. Steers showed the highest $L^*$(39.01), Warner-Bratzler shear force (4.03 kg), and water holding capacity (57.08%), however, there was no significant differences between those of cows and bulls. Ultimate$pH_{24}$ was shown difference among sex (5.58-5.69), however, the values remained within normal range. In sensory evaluation analyses, sex affected significantly tenderness, juiciness, and flavor (p<0.05). Also, the over all acceptability of steer beef was significantly higher than that of cow and bull beef. These results could be used as fundamental data set for further research activities to elevate Hanwoo beef qualities (p<0.05).

Investment Benefit Analysis of Safety Assessment and Inspection Technologies of Hydrogen Bus Fuel System Using Contingent Valuation Methods (조건부가치측정법을 이용한 수소버스 연료장치 안전성 평가 및 검사기술에 대한 투자 편익 분석)

  • Seohyun, Lim;Jeong Ah, Jang
    • Journal of Auto-vehicle Safety Association
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    • v.14 no.4
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    • pp.43-52
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    • 2022
  • Recently, the government has been expanding the supply of hydrogen vehicles according to the roadmap for vitalizing the hydrogen economy, but is developing safety assessment and inspection technology for the relevant vehicles. This study analyzed the prevention of hydrogen bus accidents' economic effect that arises from the application and development of large-capacity CHSS oil pressure repetition-test assessment technology, hydrogen bus internal chamber pressure transmission and emission volume inspection technology, among various technologies capable of assessing the safety of a hydrogen bus fuel system. To this end, the contingent valuation method (CVM), one of the value evaluation methods of non-market goods, was applied to investigate users' willingness to pay for each inspection technology. The survey for users' willingness to pay was conducted by attaching posters to promote surveys on the internet and within buses to the entire public. As a result of the analysis, the average WTP of the hydrogen bus internal chamber pressure transmission volume inspection technology was 25.3 KRW, the average WTP of the hydrogen bus internal chamber pressure emission volume inspection technology was 18.6 KRW, and the average WTP of the large-capacity CHSS oil pressure repetition-test assessment technology was measured at 16.7 KRW. In addition, the costs and benefits of the introduction of the relevant inspection technology were defined through the interviewing of experts at related research institutions and businesses. As a result of conducting an economic analysis (4.5% discount rate) according to the development of each inspection technology, economic feasibility was seen in all assessment and inspection technologies. As much as the technology is indispensable for the safe use of hydrogen buses, it shows that investment in related technology is very necessary in the future. However, because it was decided that the relevant analysis will differ according to the distribution rate of hydrogen buses, further analysis following this future distribution rate of hydrogen buses is needed, and future users should be made clearly aware of the safety and environmental nature of the technology.

A Study on the Applicability of $C_5$ Hydrofluoroether-based Formulated Cleaning Agents as CFC-Alternatives ($C_5$계 수소불화에테르를 기반으로 하는 배합 세정제의 CFC 대체세정제 적용 연구)

  • Min, Hye-Jin;Bae, Jae-Heum;Chang, Yoon-Sang
    • Clean Technology
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    • v.16 no.3
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    • pp.172-181
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    • 2010
  • Hydrofluoroethers (HFEs) with fluoride molecules in their structure which are evaluated as the third generation replacement alternatives to chlorofluorocarbons (CFCs) are known to be excellent for removal of nanoparticles and fluoride-type soils due to their low surface tension and high wetting index. In addition, HFEs have good physical properties with no flash point and excellent drying characteristics. But, HFEs also have shortcomings in that they are not effective for removal of organic soils due to their poor solubility in soil. In this study, $C_5$ HFE-based cleaning agents were formulated through addition of solvents such as isopropyl alcohol (IPA), ethyleneglycol monoether (EG), propyleneglycol monoethylether (PM) to HFE-7100 [$CF_3CF_2CF_2CF_2OCH_3$] or HFE-mec-f [$CF_3CHF=CF_2OCH_2CF_3$] with its maximum amount, respectively, in order to have no flash point for the safety in the working environment. These solvents are known to be excellent for dissolving organics in soil. Their physical properties and cleaning abilities for fluxes, water-insoluble cutting oils, and fluoride-type oils were evaluated and compared with those of other cleaning agents with single components. The experimental results show that the HFE-based formulated cleaning agents have various good physical properties which are almost similar to those of a single type of HFE cleaner. They show excellent cleaning ability for fluxes, water-insoluble cutting oils, and fluoride-type oils. These results indicate that the HFE-based formulated cleaning agents can be applicable to various industrial cleaning fields because of their good physical properties and cleaning abilities for various soils.

A Study on Metaverse Framework Design for Education and Training of Hydrogen Fuel Cell Engineers (수소 연료전지 엔지니어 양성을 위한 메타버스 교육훈련 플랫폼에 관한 연구)

  • Yang Zhen;Kyung Min Gwak;Young J. Rho
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.24 no.1
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    • pp.207-212
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    • 2024
  • The importance of hydrogen fuel cells continues to be emphasized, and there is a growing demand for education and training in this field. Among various educational environments, metaverse education is opening a new era of change in the global education industry, especially to adapt to remote learning. The most significant change that the metaverse has brought to education is the shift from one-way, instructor-centered, and static teaching approaches to multi-directional and dynamic ones. It is expected that the metaverse can be effectively utilized in hydrogen fuel cell engineer education, not only enhancing the effectiveness of education by enabling learning and training anytime, anywhere but also reducing costs associated with engineering education.In this research, inspired by these ideas, we are designing a fuel cell education platform. We have created a platform that combines theoretical and practical training using the metaverse. Key aspects of this research include the development of educational training content to increase learner engagement, the configuration of user interfaces for improved usability, the creation of environments for interacting with objects in the virtual world, and support for convergence services in the form of digital twins.

Development of Methanol Synthesis Process viaCatalytic Conversion of Simulated Steel Mill Gases for Optimal Productivity (제철 부생가스 모사가스를 활용한 메탄올 합성공정 개발)

  • Geunjae Kwak
    • Applied Chemistry for Engineering
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    • v.35 no.5
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    • pp.410-417
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    • 2024
  • Steel mill gases, including coke oven gas (COG), blast furnace gas (BFG), and Linz-Donawitz gas (LDG), are mainly used as fuels within steel plants, resulting in substantial CO2 emissions. This combustion process accounts for 10% of South Korea's total CO2 emissions. These off-gases, rich in CO, CH4, and hydrogen, have the potential to be converted into valuable chemicals through catalytic processes, thereby reducing CO2 emissions and increasing their economic value. This study investigates the conversion of steel mill gases into methanol, an important platform chemical and cleaner transportation fuel. By using COG and LDG as sources of CO and H2, respectively, a novel process was developed. In this process, H2-rich COG from a simple single-step membrane separation and raw LDG are converted into methanol with high selectivity using a Cu-Zn-Al catalyst. The study identified the optimal gas compositions for methanol production through experimental results, demonstrating efficient methanol synthesis from various compositions of LDG, COG, pure hydrogen, and H2-rich COG. This innovative approach not only aims to reduce specific CO2 emissions from steel plants but also enhances the economic value of the byproduct gases. Thus, the study provides a sustainable and economically advantageous solution for the steel industry.