• 제목/요약/키워드: 수소자동차

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고분자전해질 연료전지에서 고분자막을 통한 물의 이동 (Transport of Water through Polymer Membrane in Proton Exchange Membrane Fuel Cells)

  • 이대웅;황병찬;임대현;정회범;유승을;구영모;박권필
    • Korean Chemical Engineering Research
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    • 제57권3호
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    • pp.338-343
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    • 2019
  • 고분자전해질 연료전지에서 전해질막의 물이동과 함수율은 고분자막의 성능에 많은 영향을 미친다. 본 연구에서는 간단한 방법에 의해 물이동에 관한 고분자막의 물성(전기삼투계수, 물 확산계수)을 측정하고 이들을 이용해 막을 통한 물의 이동량과 이온전도도를 모델식에 의해 모사한 후 실험값과 비교하였다. 물이동의 구동력은 전기삼투와 확산만이 라고 본 1차원 정상상태 지배방정식을 매트랩으로 수치해석하였다. $144{\mu}m$ 두께의 고분자막의 전기삼투계수를 수소펌핑셀에서 구한 결과 1.11을 얻었다. 물확산계수를 상대습도의 함수로 나타냈고 물확산에 대한 활성화에너지는 $2,889kJ/mol{\cdot}K$였다. 이들 계수를 적용해 모사한 물이동량과 이온전도도 결과는 실험값과 잘 일치함을 보였다.

조건부가치측정법을 이용한 수소버스 연료장치 안전성 평가 및 검사기술에 대한 투자 편익 분석 (Investment Benefit Analysis of Safety Assessment and Inspection Technologies of Hydrogen Bus Fuel System Using Contingent Valuation Methods)

  • 임서현;장정아
    • 자동차안전학회지
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    • 제14권4호
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    • pp.43-52
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    • 2022
  • Recently, the government has been expanding the supply of hydrogen vehicles according to the roadmap for vitalizing the hydrogen economy, but is developing safety assessment and inspection technology for the relevant vehicles. This study analyzed the prevention of hydrogen bus accidents' economic effect that arises from the application and development of large-capacity CHSS oil pressure repetition-test assessment technology, hydrogen bus internal chamber pressure transmission and emission volume inspection technology, among various technologies capable of assessing the safety of a hydrogen bus fuel system. To this end, the contingent valuation method (CVM), one of the value evaluation methods of non-market goods, was applied to investigate users' willingness to pay for each inspection technology. The survey for users' willingness to pay was conducted by attaching posters to promote surveys on the internet and within buses to the entire public. As a result of the analysis, the average WTP of the hydrogen bus internal chamber pressure transmission volume inspection technology was 25.3 KRW, the average WTP of the hydrogen bus internal chamber pressure emission volume inspection technology was 18.6 KRW, and the average WTP of the large-capacity CHSS oil pressure repetition-test assessment technology was measured at 16.7 KRW. In addition, the costs and benefits of the introduction of the relevant inspection technology were defined through the interviewing of experts at related research institutions and businesses. As a result of conducting an economic analysis (4.5% discount rate) according to the development of each inspection technology, economic feasibility was seen in all assessment and inspection technologies. As much as the technology is indispensable for the safe use of hydrogen buses, it shows that investment in related technology is very necessary in the future. However, because it was decided that the relevant analysis will differ according to the distribution rate of hydrogen buses, further analysis following this future distribution rate of hydrogen buses is needed, and future users should be made clearly aware of the safety and environmental nature of the technology.

마그네슘 제련(製鍊) 기술현황(技術現況)과 리싸이클링 관련(關聯) 대상분야(對象分野) (Current Status of Magnesium Smelting and the Related Recycling Topics)

  • 박형규
    • 자원리싸이클링
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    • 제16권2호
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    • pp.3-11
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    • 2007
  • 최근 국내에서 자동차 부품산업 및 전자기기 산업에서 마그네슘 금속의 수요가 증가하고 있다. 본 고에서는 마그네슘 금속 제련에 관하여 원료 광석, 세계 생산량과 상용화 조업중인 기술들을 요약 정리하였으며, 국내 마그네슘 관련 시장현황과 기술동향들을 조사하였다. 마그네슘 제련은 크게 용융염 제련법과 열환원법 두가지로 대별할 수 있으며 이들 기술의 일반적인 현황을 살펴보았다. 또한, 국내에서 수행중인 마그네슘의 용융염 제련 연구에 대하여 간략히 기술하고, 용융염 제련시 발생되는 염소나 염화수소의 회수 및 처리 등 재활용 분야와 관련기술을 소개하고자 한다.

차동 증폭회로를 적용한 축전지 잔존용량산정 (State of Charge Calculation Using a Differential Amplifier On the Batteries)

  • 조규판;문채주;김태곤;채성열;정문선;이경성
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2011년도 전력전자학술대회
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    • pp.557-558
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    • 2011
  • 전기자동차의 축전지 관리 시스템(BMS : Battery Management System)의 잔존용량(SOC : State Of Charge)산정에는 Ah 측정법, 비중측정법, 전압측정법 등이 있다. 기존 전압 측정법의 경우 측정 전압을 프로세서에서 직접 처리하기 때문에 축전지의 미세한 전압 변화를 측정하지 못하여 잔존 용량 산정시 세밀한 계산에 어려움이 따른다. 본 논문에서는 축전지의 전압 측정 시 프로세서 전단에 전압의 부분 증폭회로를 추가하여 축전지의 미세한 전압변화를 증폭하여 측정하는 방법을 제안 하였다. 니켈수소전지를 대상으로 실험한 결과 충전 중 기존 전압측정법은 1.431V, 1.436V, 1.441V가 측정 되었을 때의 잔존 용량은 84%로 일정하였다. 같은 전압변화에서 부분증폭회로를 적용한 충전전압은 1.4297V, 1.4303V ~ 1.4352V, 1.4358V로 측정 되었으며, 그에 따른 잔존용량은 84% ~ 85%로 기존 전압 측정법 보다 약 9 ~ 10배 정도 세밀하게 측정 되었다. 제안한 방법을 통한 실험으로 제안된 방법이 기존 전압 측정법보다 세밀한 전압 측정 및 SOC산정이 가능함을 확인 하였다.

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HFCV의 감전보호를 위한 전기안전 평가기법에 관한 연구 (Research on evaluation technique concerning electrical safety for electrical shock protection of HFCV(Hydrogen Fuel Cell Vehicle))

  • 이기연;김향곤;길형준;김동욱;유병열;박용선
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2009년도 춘계학술대회 논문집 전기설비전문위원
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    • pp.200-202
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    • 2009
  • 본 논문에서는 수소연료전지자동차의 고전압 시스템에서 직 간접접촉에 의한 인체 감전사고를 방지하기 위한 전기안전 평가기법인 절연저항과 전기적연속성 등에 대하여 분석하였다. ISO, UNECE, Japan Attachment 등의 외국 규격에서는 감전보호를 위한 평가 기준을 제시하고 있지만 세부적인 평가방법에 대해서는 명확하게 규정하고 있지 않기 때문에 전기안전 평가를 위한 측정방법 및 측정장비에 대한 최소한의 기준 정립이 필요한 실정이다. 따라서 본 연구에서는 전기안전 평가기법에 대한 HFCV 실차 상태의 실험을 통하여 나타난 문제점 분석을 통하여 감전보호를 위한 전기안전 평가기법 중 전기적 연속성 및 절연저항에 대한 측정방법과 측정장비의 사양에 대하여 제시하고자 한다.

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대형자동차 디젤엔진용 산화촉매의 성능평가에 관한 연구 (A Study on Evaluation of Diesel Oxidation Catalyst for Automotive Heavy-Duty Diesel Engine)

  • 최병철;정필수;명광재;김복석;박광수;박찬국;이진호
    • 동력기계공학회지
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    • 제5권2호
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    • pp.13-21
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    • 2001
  • Diesel emission control is being addressed worldwide to help preserve the global environment. This paper mainly deals with the effects of oxidation catalysts to reduce emissions from the automotive heavy-duty diesel engine. Two types of the oxidation catalyst with different kinds of precious material were used. An 11 litter displacement diesel engine with turbocharger was operated to evaluate DOC with various engine speed, load conditions under D-13 mode cycle. We could propose the detail emission data of an automotive heavy-duty diesel engine and the characteristics of the conversion efficiency of the DOC under the D-13 mode. It was found that the mean conversion efficiencies of CO and THC were 49.7% and 61% under the D-13 mode test, respectively.

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정부정책에 대한 경험이 수소 연료전지 자동차의 수용에 미치는 영향 (Impact of experience on government policy toward acceptance of Hydrogen fuel cell vehicles)

  • 강민정;박희준
    • 한국품질경영학회:학술대회논문집
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    • 한국품질경영학회 2010년도 춘계학술대회
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    • pp.465-470
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    • 2010
  • Korea government declared that "low carbon, green growth" through green technologies and clean energy to be the new national vision for the next 60 years(President's Liberation Day speech on Aug. 15, 2008). And succeeding "Green New Deal" plan involves nine core projects including energy saving, recycling, clean energy development. It is because hydrogen fuel cell vehicles, using electricity from chemical reaction of hydrogen and oxygen, let out water which is a by-product of such chemical reaction instead of emitting harmful particulate and gases such as NOX, SOX and CO2 that hydrogen fuel cell vehicles and its technology are drawing public attention as one of the sensible solutions in accomplishing "low carbon, green growth" agenda. Nevertheless There are many chances that let the people have a practical experience of hydrogen fuel cell vehicles. Sometimes new products, including hydrogen fuel cell vehicles, made by advanced technology can not penetrate through the market when it faces public skepticism that is stimulated from lack of knowledge and experience. That is the reason why not only cost benefit analyses and scientific risk assessments but also public acceptance studies toward hydrogen fuel cell vehicles have to be performed [Schulte, 2004]. This research address a need for comprehensive study on factors influencing public acceptance of hydrogen fuel cell car, specifically focusing on impacts of personal experience related to governmental science and technology policy toward public acceptance.

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구조해석을 이용한 수소 연료전지 자동차 압력용기 밸브의 안전성 평가 (Safety Evaluation Based on Structural Analysis of Cylinder Valves for Fuel Cell Vehicles)

  • 이효렬;안중환;신진오;김화영
    • 한국생산제조학회지
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    • 제25권3호
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    • pp.189-197
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    • 2016
  • Green vehicles include electric vehicles, natural gas vehicles, and fuel cell vehicles (FCVs). In FCVs, pressure vessels have cylinder valves to control hydrogen flow. These valves should be of high quality in terms of safety because hydrogen is stored at ultra-high pressure in pressure vessels. Hence, safety evaluation of these valves is necessary to secure the safety of the FCV. A structural analysis of the cylinder valve was conducted in this study by using a commercial finite element analysis code. The results showed that the safety factor of valve component ranged 1.06-186.44. After categorizing, the stress components at critical points of the cylinder valve parts were evaluated using the corresponding allowable design criteria in the ASME code. The pressurization cycle test was performed as per the regulation to evaluate the safety of the valve.

수소 수율 증가를 위한 합성가스의 수성가스전환 반응 연구 (Water Gas Shift Reaction Research of the Synthesis Gas for a Hydrogen Yield Increase)

  • 김민경;김재호;김우현;이시훈
    • 신재생에너지
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    • 제5권2호
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    • pp.9-14
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    • 2009
  • Automobile Shredder Residue (ASR) is very appropriate in a gasification melting system. Gasification melting system, because of high reaction temperature over than $1,350^{\circ}C$, can reduce harmful materials. To use the gasification processes for hydrogen production, the high concentration of CO in syngas must be converted into hydrogen gas by using water gas shift reaction. In this study, the characteristics of shift reaction of the high temperature catalyst (KATALCO 71-5M) and the low temperature catalyst (KATALCO 83-3X) in the fixed - bed reactor has been determined by using simulation gas which is equal with the syngas composition of gasification melting process. The carbon monoxide composition has been decreased as the WGS reaction temperature has increased. And the occurrence quantity of the hydrogen and the carbon dioxide increased. When using the high temperature catalyst, the carbon monoxide conversion ratio ($1-CO_{out}/CO_{in}$) rose up to 95.8 from 55.6. Compared with average conversion ratio from the identical synthesis gas composition, the low temperature catalyst was better than the high temperature catalyst.

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자동차 강재의 수소취성 연구에 대한 고찰 (A Study on Hydrogen Embrittlement Research on Automotive Steel Sheets)

  • 양원석;서지원;안승호
    • Corrosion Science and Technology
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    • 제17권4호
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    • pp.193-201
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    • 2018
  • In order to suppress $CO_2$ emission and protect passengers in case of vehicle collision, continuous efforts are being made to increase the application ratio and tensile strength of advanced high strength steels used in the manufacturing of automotive body. Simultaneously, hydrogen embrittlement which was not a concern in the past has currently become a major issue due to microstructure that is sensitive to hydrogen uptake. The sensitivity increases with residual stress and hydrogen uptake content. Many automotive OEM companies and mill makers are setting specifications to control hydrogen embrittlement. The factors which lead to hydrogen embrittlement are material sensitivity, residual stress, and hydrogen concentration; researches are in progress to develop countermeasures. To reduce material sensitivity, mill makers add high energy trap elements or microstructure refinement elements. Automotive OEM companies design the car parts not to concentrate local stress. And they manage the levels to not to exceed critical hydrogen concentration. In this article, we have reviewed hydrogen embrittlement evaluation methods and corresponding solutions that are being studied in automobile manufacturing industries and mill makers.