• Title/Summary/Keyword: 수소의 확산

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Characteristics of Autoignited Laminar Lifted Flames in Heated Coflow Jets of Carbon Monoxide/Hydrogen Mixtures (일산화탄소/수소 혼합기의 가열된 동축류 제트에서 자발화된 층류 부상화염의 특성)

  • Choi, Byung-Chul;Chung, Suk-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.6
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    • pp.639-646
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    • 2012
  • The characteristics of autoignited lifted flames in laminar jets of carbon monoxide/hydrogen fuels have been investigated experimentally in heated coflow air. In result, as the jet velocity increased, the blowoff was directly occurred from the nozzle-attached flame without experiencing a stabilized lifted flame, in the non-autoignited regime. In the autoignited regime, the autoignited lifted flame of carbon monoxide diluted by nitrogen was affected by the water vapor content in the compressed air oxidizer, as evidenced by the variation of the ignition delay time estimated by numerical calculation. In particular, in the autoignition regime at low temperatures with added hydrogen, the liftoff height of the autoignited lifted flames decreased and then increased as the jet velocity increased. Based on the mechanism in which the autoignited laminar lifted flame is stabilized by ignition delay time, the liftoff height can be influenced not only by the heat loss, but also by the preferential diffusion between momentum and mass diffusion in fuel jets during the autoignition process.

Ventilation Performance Study on Hydrogen Leakage Characteristics of Container Packaged Water Electrolysis Production System (컨테이너 패키지형 그린수소 수전해 생산 시스템의 수소 누출 특성에 관한 환기 성능 연구)

  • SOOIN KWON;BYUNGSEOK JIN;CHEEWOO LEE;SEONGYONG EOM;GYUNGMIN CHOI
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.3
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    • pp.324-335
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    • 2024
  • The container package type sealed water electrolysis production system installs mechanical balance of plant and electrical balance of plant as an integrated unit to enable independent operation within the package module. The auxiliary equipment required to operate the water electrolysis system must be integrated to reduce the installation area and shorten the installation time. At this time, as leak risk factors are placed in a dense space, when a hydrogen gas leak accident occurs, it can have a mutual influence on other adjacent facilities, so it contains various risk factors. In this study, when a gas leak occurs in a container packaged water electrolysis system, possible sources of leakage in the system according to the KS C IEC 60079-10-1:2015 and KGS GC101 standards were identified, and the leak rate and leak characteristics were calculated. did. The hazardous area and its range were calculated according to ventilation and dilution characteristics. In order to optimize ventilation characteristics, design of experiment was used to analyze the influence to evaluate the adequacy of ventilation, and overseas ventilation standards were analyzed and compared. In addition, the optimal ventilation structure and characteristics of the container packaged water electrolysis system were presented according to the results of the experimental design method.

Study on the Improvement of Electrochemical Performance by Controlling the Surface Characteristics of the Oxygen Electrode Porous Transport Layer for Proton Exchange Membrane Water Electrolysis (양이온 교환막 수전해용 산화전극 확산층의 표면 특성 제어를 통한 전기화학적 성능 개선 연구)

  • Lee, Han Eol;Linh, Doan Tuan;Lee, Woo-kum;Kim, Taekeun
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.332-339
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    • 2021
  • Recently, due to concerns about the depletion of fossil fuels and the emission of greenhouse gases, the importance of hydrogen energy technology, which is a clean energy source that does not emit greenhouse gases, is being emphasized. Water electrolysis technology is a green hydrogen technology that obtains hydrogen by electrolyzing water and is attracting attention as one of the ultimate clean future energy resources. In this study, the surface properties of the porous transport layer (PTL), one of the cell components of the proton exchange membrane water electrolysis (PEMWE), were controlled using a sandpaper to reduce overvoltage and increase performance and stability. The surfaces of PTL were sanded using sandpapers of 400, 180, and 100 grit, and then all samples were finally treated with the sandpaper of 1000 grit. The prepared PTL was analyzed for the degree of hydrophilicity by measuring the water contact angle, and the surface shape was observed through SEM analysis. In order to analyze the electrochemical characteristics, I-V performance curves and impedance measurements were conducted.

Tritium Distribution in Some Environmental Samples-Rices, Chinese Cabbages and Pine Needles in Korea (국내 환경시료(쌀, 채소, 솔잎) 중 삼중수소의 분포)

  • Kim, Chang-Kyu;Cho, Yong-Woo;Han, Man-Jung;Pak, Chan-Kirl
    • Journal of Radiation Protection and Research
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    • v.17 no.2
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    • pp.25-35
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    • 1992
  • To evaluate tritium level in some environmental samples, tissue-free water tritium (TFWT) and tissue-bound tritium (TBT) were analyzed in rices, chinese cabbages and pine needles collected at 12 locations in Korea. The TFWT was recovered by freeze-drying of the samples and the TBT was obtained in the form of water by combustion of the dried samples. Tritium was measured by liquid scintillation counter. The concentrations of TFWT were in the range of $0.96{\sim}3.96 Bq/1,\; 0.83{\sim}3.40 Bq/1\;and\;1.02{\sim}3.01 Bq/1$ in rices, chinese cabbages and pine needles, respectively. The mean specific activity ratios (TBT/TFWT) were 0.94, 1.71 and 1.39 in rices, chinese cabbages and pine needles, respectiviely. This excess TBT in the samples may be attributed to the fact that the residence time of TBT in the plant is longer than that of TFWT. The specific activity ratio depends on the plant species, the exposed time to tritiated atmosphere, atmospheric moisture, temperature and diffusion factor.

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Liftoff mechanisms in hydrogen turbulent non-premixed jet flames (수소 난류확산화염에서의 부상 메커니즘에 대한 연구)

  • Oh, Jeong-Seog;Kim, Mun-ki;Choi, Yeong-Il;Yoon, Young-Bin
    • 한국연소학회:학술대회논문집
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    • 2007.05a
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    • pp.7-12
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    • 2007
  • To reveal the newly found liftoff height behavior of hydrogen jet, we have experimentally studied the stabilization mechanism of turbulent, lifted jet flames in a non-premixed condition. The objectives of the present research are to report the phenomenon of a liftoff height decreasing as increasing fuel velocity, to analyse the flame structure and behavior of the lifted jet, and to explain the mechanisms of flame stability in hydrogen turbulent non-premixed jet flames. The velocity of hydrogen was varied from 100 to 300m/s and a coaxial air velocity was fixed at 16m/s with a coflow air less than 0.1m/s. For the simultaneous measurement of velocity field and reaction zone. PIV and OH PLIF technique was used with two Nd:Yag lasers and CCD cameras. As results, it has been found that the stabilization of lifted hydrogen diffusion flames is related with a turbulent intensity, which means that combustion occurs where the local flow velocity is valanced with the turbulent flame propagation velocity.

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A Numerical Study of Diffusion Flames in Supersonic Flow (초음속 유동장 내의 확산 화염에 관한 수치 연구)

  • 김지호;윤영빈;정인석
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1997.11a
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    • pp.17-17
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    • 1997
  • 극초음속 여객기와 군사용 항공기에 대한 수요가 증가함에 따라서 새로운 개념의 다양한 추진기관이 연구가 진행되고 개발되어 왔다. 초음속 항공기의 속도 영역은 마하 10-20 정도가 되는데 이 속도 한계를 극복하기 위하여 초음속 연소 램제트 엔진(SCRamjet; Supersonic Combustion Ramjet)이 제안되었다. 스크램 제트를 개발하기 위해서는 연료와 산화제의 혼합 효율 문제, 화염의 안정화 문제, 벽면의 냉각에 관한 문제 등 몇 가지 기본적인 문제들을 해결해야 한다. Univ of Michigan에서 실험한 연소기를 모델로 본 연구에서는 연료와 공기의 혼합에 관한 수치 연구를 수행하였다. 다원 혼합기체에 관한 축대칭 Navier-Stokes 방정식을 지배 방정식을 이용하였고 비평형 화학반응식을 고려하였다. 공간 차분에는 유한 체적법을 이용하였다. 대류 플럭스 항은 Roe의 Upwind FDS 기법을 사용하여 차분하였고 점성항에는 중심 차분법을 이용하였다. 시간 적분법으로는 근사 자코비안과 LU분할 기법을 이용한 완전 내재적 방법이 쓰였다. 난류 모델로는 Mentor에 의해 제안된 2 방정식 k-$\varepsilon$/k-$\omega$ 혼합모델을 사용하였다. 유동장이 실험에서의 찍은 사진과 유사한 모습의 충격파 간섭을 수치 모사하였고 수소가 확산되는 모습과 함께 노즐 lip 주위의 재순환 영역에 대해서 살펴볼 수 있었다.

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Investigation of liftoff mechanisms in hydrogen turbulent non-premixed jet flames (수소 난류확산화염에서의 부상 메커니즘에 대한 연구)

  • Oh, Jeong-Seog;Kim, Mun-Ki;Choi, Yeong-Il;Yoon, Young-Bin
    • 한국가시화정보학회:학술대회논문집
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    • 2006.12a
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    • pp.135-140
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    • 2006
  • The stabilization mechanism of turbulent, lifted jet flames in a non-premixed condition has been studied experimentally. The objectives are to explain the phenomenon of a liftoff height decreasing as increasing fuel velocity and to reveal the mechanisms of flame stability Hydrogen was varied from 100 to 300 m/s and a coaxial air was fixed at 16 m/s with a coflow air less than 0.1 m/s. The technique of PIV and OH PLIF was used simultaneously with CCD and ICCD cameras. It was found that the liftoff height of the jet decreased with an increased fuel jet exit velocity. The leading edge at the flame base was moving along the stoichiometric line. Finally we confirmed that the stabilization of lifted hydrogen diffusion flames is related with a turbulent intensity, which means combustion is occurred where the local flow velocity is equal to the turbulent flame propagation velocity.

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Near-Extinction Structure of Counterflow Nonpremixed Hydrogen-Air Flames (소염상태 근방에서의 대향류 수소확산화염의 구조)

  • Kim, H.J.;Kim, Y.M.
    • 한국연소학회:학술대회논문집
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    • 1997.06a
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    • pp.77-87
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    • 1997
  • The axisymmetric Navier-Stokes model together with detailed chemical kinetics and variable transport properties has been applied to analyze the effects of the multidimensional flow on the flame characteristics in the nitrogen-diluted hydrogen counterflow nonpremixed flame. Computations are performed for two nozzle exit area-averaged velocities. Effects of multidimensional flow and strain rate on the near-extinction structure of the highly diluted hydrogen flames are discussed in detail.

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The Characteristics and Stability of Ion Exchange Membrane in All-Vanadium Redox Flow Battery (전바나듐계 레독스-흐름 2차전지에서 이온교환막의 특성 및 안정성)

  • 신석재;강안수
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.10a
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    • pp.63-64
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    • 1993
  • 레독스-흐름 2차전지는 발전소의 잉여전력, 태양전지 및 전기자동차 등 응용 분야가 넓은 유망한 에너지 저장 방법의 하나이다[1,2]. Fe-Cr계 2차전지와 비교하여 수소 가스의 발생이 없고 양쪽 액의 확산에의한 혼합으로 전지의 용량이 떨어지지 않고 rebalance의 필요가 없는 등 많은 장점을 가지고 있으며 조작이 간단하며 기전력 (1,4 V)과 에너지 밀도가 높기 때문에 compact화가 가능하다[1].

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Properties of the gate dielectrics by thermal oxidation in ${N_2}O$ gas (${N_2}O$ 가스로 열산화된 게이트 유전체의 특성)

  • 김창일;장의구
    • Electrical & Electronic Materials
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    • v.6 no.1
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    • pp.55-62
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    • 1993
  • 수소 관련된 species를 포함하지 않고 자기제한특성으로 초박막 성장을 용이하게 제어할 수 있는 N$_{2}$O 가스 분위기에서 실리콘의 산화는 질화된 산화막의 재산화공정 보다 훨씬 간단한 공정이다. N$_{2}$O산화로 형성된 Si-SiO$_{2}$ 계면에서 nitrogen-rich층은 산화막 구조를 강화할 뿐만 아니라 게이트 유전체의 질을 개선하고 산화율을 감소시키는 산화제의 확산 장벽으로 작용한다. 초박막 oxynitride 게이트 유전체가 종래의 열산화 방법으로 제작되었고 oxynitride막의 특성이 AES와 I-V 특성 측정의 결과를 분석하여 연구하였다.

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