• Title/Summary/Keyword: 수소분포비율

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Regional Distribution of Hydrocarbon Degrading Bacteria in the Sediment of South Sea, Korea (남해해역 퇴적토의 탄화수소 분해세균 분포)

  • 김상진;최성찬
    • Korean Journal of Microbiology
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    • v.30 no.5
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    • pp.366-370
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    • 1992
  • Sediment samples were collected from the stations 0101-0921 located between N $32^{\circ}$30'~$34^{\circ}$30' and E $123^{\circ}$30'-$128^{\circ}$30' during July 31-August lO. 1988. The distributions of total heterotrophic bacteria, freshwater bacteria and hydrocarbon degrading bacteria were studied. Each bacterial distribution was in the range of $3{\times}10^{5}~9.2{\times}10^{6}CFU/cm^{3}$sediment, $3{\times}10^{3}~2.1{\times}10^{6}CFU/cm^{3}$ sediment and $2{\times}10^{4}~6.2{\times}10^{6}CFU/cm^{3}$ sediment. respectively. The percent of hydrocarbon degrading bacteria against total heterotrophic bacteria was 0.7-73,2 % which was much higher than other marine sediments reported. These values were statistically analyzed with the percent of freshwater bacteria against total heterotrophic bacteria. These two parameters were well correlated with the correlation coefficient r= 0.60058 (n=34) and P=0.OOO2. This means that the distributions of hydrocarbon degrading bacteria and freshwater bacteria in the research area were affected together by the fresh water discharge into the sea environment. Therefore it can be concluded that the distribution of hydrocarbon degrading bacteria in the sediment of South Sea was affected by petroleum hydrocarbon input from terrestrial region through rivers.

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Continuous Bio-hydrogen Production from Food Waste and Waste Activated Sludge (음식물 쓰레기와 폐활성 슬러지를 이용한 생물학적 수소생산 및 수소생산 미생물 군집분석)

  • Kim, Dong-Kun;Lee, Yun-Jie;Kim, Dong-Im;Kim, Ji-Seong;Yu, Myong-Jin;Pak, Dae-Won;Kim, Mi-Sun;Sang, Byoung-In
    • KSBB Journal
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    • v.20 no.6
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    • pp.438-442
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    • 2005
  • Batch experiments were performed to investigate the effects of volumetric mixing ratio(v/v) of two substrates, food wastes(FW) and waste activated sludge(WAS). In batch experiments, optimum mixing ratio for hydrogen production was found at $10{\sim}20$ v/v % addition of WAS. CSTR(Continuous Stirred tank reactor) was operated to investigate the hydrogen productivity and the microbial community under various HRTs and volumetric mixing ratio(v/v) of two substrates. The maximum yield of specific hydrogen production, 140 mL/g VSS, was found at HRT of 2 day and the volumetric mixing ratio of 20:80(WAS:FW). The spatial distribution of hydrogen producing bacteria was observed in anaerobic fermentative reactor using fluorescent in situ hybridization(FISH) method.

A numerical analysis study on the flammable volume by leakage of hydrogen fuel vehicles in parking lot (지하주차장 내 수소연료차의 수소 방출시 가연체적에 관한 수치해석적 연구)

  • Lee, Ho-Hyung;Kim, Hyo-Gyu;Yoo, Ji-Oh;Kim, Doo-Young
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.23 no.6
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    • pp.439-449
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    • 2021
  • The recent reduction in greenhouse gases, interest in environmental pollution such as low-carbon emission policies is increasing. Accordingly, the penetration rate of eco-friendly vehicles, including hydrogen battery vehicles capable of reducing carbon emission, is increasing, and thus it is required for disaster prevention and safety-related measures. In this study, the degree of risk for the concentration distribution of hydrogen when leaking hydrogen fuel vehicles according to ventilation conditions was analyzed through numerical analysis, limited to places in parking lots. As a result, when only one hydrogen tank was released, the combustible volume ratio of hydrogen in the underground parking lot was up to 8.6%, and as ventilation continued, the volume ratio of combustible hydrogen decreased to less than 1% after 150 seconds, indicating that mechanical ventilation is essential. In the case of simultaneous release or stage release of three hydrogen tanks, the final combustible volume ratio of hydrogen is similar, but the increase in the combustible volume ratio of hydrogen in the early stage of release is low, and further research is expected.

Estimation of Inbreeding Coefficients and Effective Population Size in Breeding Bulls of Hanwoo (Korean Cattle) (한우 씨수소의 근교계수와 유효집단크기의 추정)

  • Dang, Chang-Gwon;Lee, Jung-Jae;Kim, Nae-Soo
    • Journal of Animal Science and Technology
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    • v.53 no.4
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    • pp.297-302
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    • 2011
  • This study was carried out to estimate average inbreeding coefficients, relatedness and effective population size of breeding bulls and to suggest optimal alternatives on problems of current Hanwoo improvement system. Data on proven and young bulls were obtained from 1,128 heads of Livestock Improvement Main Center from 1983 to 2008. Pedigree information on proven and young bulls was obtained from 3,760 heads of Korea Animal Improvement Association. Average inbreeding coefficients and average relatedness of proven and young bulls were estimated at the range of 0.04-0.07%, 0.10-6.82%, respectively. Effective population size was estimated for 220 heads from the average rate of inbreeding of last 26 years. Average inbreeding coefficient is rising rapidly for the last two years as well as average relatedness. Effective population size was estimated for 47 heads for the last five years. These results suggest that selection criteria of proven bulls should include not only genetic evaluation of carcass performance from progeny-test, but also inbreeding and relationship coefficients, in order to maintain genetic variability of Hanwoo. In addition, effective population size should be increased by increasing the number of proven bulls.

A Study on the VHCF Fatigue Behaviors of Hydrogen Attacked Inconel 718 Alloy (수소취화된 인코넬 718의 VHCF(Very High Cycle Fatigue) 피로특성에 관한 연구)

  • Suh, Chang-Min;Nahm, Seung-Hoon;Kim, Jun-Hyong;Pyun, Young-Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.7
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    • pp.637-646
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    • 2016
  • This study is to investigate the influence of hydrogen attack and UNSM on fatigue behaviors of the Inconel 718 alloy. The decrease of the fatigue life between the untreated and the hydrogen attacked material is 10-20%. The fatigue lives of hydrogen attacked specimen decreased without a fatigue limit, similar to those of nonferrous materials. Due to hydrogen embrittlement, about 80% of the surface cracks were smaller than the average grain size of $13{\mu}m$. Many small surface cracks caused by the embrittling effect of hydrogen attack were initiated at the grain boundaries and surface scratches. Cracks were irregularly distributed, grew, and then coalesced through tearing, leading to a reduction of fatigue life. Results revealed that the fatigue lives of UNSM-treated specimens were longer than those of the untreated specimens.

Effect of N2 Diluent on Soot Formation Characteristics in Ethylene Diffusion Flames (에틸렌 확산화염 내 질소 혼합이 매연 생성 특성에 미치는 영향)

  • Jun-Soo Kim
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.29 no.4
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    • pp.356-362
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    • 2023
  • The risk of climate change has been long acknowledged, and ongoing efforts to overcome this issue, within the shipping sector, with the international maritime organization playing a central role. Conducting research on characteristics of soot formation is crucial to control its occurrence within the combustion process. In this study, the laser extinction method and chemical reaction numerical analysis were employed to examine the alterations in the state of chemical species associated with flame temperature, flame visual, and soot formation by mixing nitrogen, an inert gas, in the counterflow diffusion flame based on ethylene gas. The findings of the study suggest that as the mixing ratio of nitrogen increased, both the flame temperature and soot volume fraction decreased. Additionally, the area in which soot particles were distributed also decreased, and the volume fraction decrease rate declined when the mixing ratio increased by more than 30%. The mole fraction of the chemical species involved in soot growth also decreased. the chemical species associated with the HACA reaction were affected by variations in the hydrocarbon fuel ratio, and the chemical species related to the odd carbon path were confirmed to be affected by the flame temperature as well as the hydrocarbon fuel ratio.

용매 및 가교도에 따른 수소동위원소 교환반응용 촉매 담체의 물성 변화

  • 강희석;이한수;정흥석;안도희;백승우;이성호;김광락
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11a
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    • pp.151-156
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    • 1996
  • 수소동위원소 교환반응에 이용되는 스티렌-디비닐벤젠 고분자 촉매 담체를 제조하였다. 중합반응시 일정한 용매계에서 용매/모노머 함량비와 팽윤제/침전제 함량비를 변화시켜 담체의 표면특성에 미치는 영향을 확인하였다. 가교도가 33%일 경우 용매/모노머가 2.0 이하에서 팽윤제/침전제의 함량비가 증가할수록 10~30$\AA$의 반경을 갖는 기공의 분포가 증가하였다. 담체의 열적안정성을 확인하기 위한 열 중량 분석에서는 온도를 일정한 비율로 단시간에 증가시킬 경우에는 담체의 가교도에 관계없이 35$0^{\circ}C$ 근처에서 거의 유사한 degradation을 보였지만 온도를 매우 천천히 증가시켜 장시간 노출시킬 경우 가교도에 따라서 degradation의 정도와 경향이 다르게 나타남을 확인하였다.

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A Study on the Chamical and Physical Characteristics of Ultrasonic-Energy-Added Diesel Fuel (초음파 에너지 부가 지젤연료의 화학적, 물리적 특성에 관한 연구)

  • 최두석;윤면근;류정인
    • Transactions of the Korean Society of Automotive Engineers
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    • v.4 no.3
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    • pp.147-155
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    • 1996
  • This study investigated the characteristics of ultrasonic-energy-added diesel fuel. We compared the characteristics used H-NMR spectrum, FT-IR spectrum, viscosity and surface tension between conventional diesel fuel and ultrasonic-energy-added diesel fuel. The result are obtained as follow : We knew that ultrasonic energy result to reduce BI and weaken viscosity and surface tension. Also, the ultrasonic energy caused to reduce aromatics Ha and increase Alkanes Hγ. The effect of ultrasonic-energy-added dieselfuel was principally caused by change of chemical structures and a physical characteristics.

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The Effect of Hydrocarbon Content and Temperature Distribution on The Morphology of Diamond Film Synthesized by Combustion Flame Method (연소 화염법에 의해 합성된 다이아몬드형상에 미치는 탄화수소량과 온도분포의 영향)

  • Kim, Seong-Yeong;Go, Myeong-Wan;Lee, Jae-Seong
    • Korean Journal of Materials Research
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    • v.4 no.5
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    • pp.566-573
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    • 1994
  • The diamond synthesis by combustion flame method is considerably affected by the substrate surface temperature and its distribution which are mainly controlled by the ratio of mixed gas, $O_2/C_2H_2$. In order to elucidate the role of gas ratio in the diamond synthetic process by combustion flame, under various gas ratios (R=0.87~0.98; R=ratio of flow-rate of $O_2/C_2H_2$ gas) the substrate temperature was measured by using thermal video system and the morphological change of diamond crystals was analysed by using SEM, Raman spectroscope, and X-ray diffraction method. With increasing the gas ratio, i.e., decreasing the hydrocarbon content, the nucleation rate of diamond crystal was lowerd. It was also found that the morphology of diamond crystals changed from the cubo-octahedron type consisting of (100), (111) plane to the octahedron type of (111) plane. The increase of the substrate temperature consistently resulted in the increase of the nucleation rate as well as the growth rate of diamond crystals in which the surface of diamond crystal dominantly consisting of (100) plane.

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Isomer Formation in the Chlorination of Highmolecular Paraffinic Hydrocarbons by Various Halogenating Agents (여러 종류의 할로겐 화합물과 고분자량 파라핀계 탄화수소의 염소화에서 생기는 이성질화에 관한 연구)

  • Li-Hoan Kung
    • Journal of the Korean Chemical Society
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    • v.32 no.4
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    • pp.390-405
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    • 1988
  • The chlorination of $C_7H_16,\;C_8H_18,\;C_10H_22,\;and\;(Me_2CH)_2$ with N-Chlorosuccinimide, tert-BuOCl, $CCl_3SO_2Cl,\;CCl_4,\;CCl_3SCl,\; PCl_5,\;and\;Cl_2\;in\;C_6H_6\;or\;CS_2$ which both form loose complexes with $Cl_2$ atoms yielded mixtures of isomeric monochloroalkanes which were analyzed quantitatively. An isomer ratio differing from that known for the substitution of paraffinic hydrocarbons was observed. The isomer distribution observed is the result of the combined effects of the differing C-H dissociation energies of the different types of H atoms of the alkane and of the free energy of the attacking radical with polar effects of the attacking radical as well as of the hydrocarbon.

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