• Title/Summary/Keyword: 수분 안정성

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Preparation and Properties of Modified Polyethylenes: 1. Preparation and Properties of Dispersions in Water (변성 폴리에틸렌의 제조 및 물성 : 1. 제조 및 수분산 특성)

  • Lee, Jae Heung;Lee, Sang-Hun
    • Journal of Adhesion and Interface
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    • v.3 no.3
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    • pp.7-14
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    • 2002
  • Modified polyethylenes with polar side groups of -COOK, $-CONH_2$, and -COOH were prepared at a dispersion state in water by reacting poly(ethylene-co-methylacrylate) (PEMA) with aqueous solution of KOH and ammonia. Types and their contents of side groups were investigated by infrared spectroscopy, elemental analysis and atomic absorption analysis. Solution viscosity and surface tension were also measured as a function of solid contents. Stability and transparency of the dispersions were greatly affected by the content of COOK in the side groups. The stable dispersion could be prepared at a composition of COOK of 20 mole% at least. The transparency was increased with increasing the COOK contents, but decreased with increasing the amide content at a constant composition of COOK. Solution viscosities increased abruptly at a lower solid content when the COOK contents were increased, implying higher entanglement between the chains in dispersions with higher content of hydrophilic COOK group. The dispersions of higher COOK content revealed lower surface tension values.

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Effects of Water Activity on Microbial Growth in Herb Extract (생약제 농축액에서 미생물 성장에 대한 수분활성도의 영향)

  • 곽이성;신현주;주종재
    • Journal of Food Hygiene and Safety
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    • v.13 no.2
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    • pp.77-82
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    • 1998
  • As a fundermental research for quality stailization of herb extract, the effects of water activity on microbial growth in herb extract were investigated. Herbs-Panax ginseng, Cinnamomum cassia, Lycium chinense, Zyzyphus jujuba, Lindera obtusilobum-were mixed and extracted with water at $80^{\circ}C$ and concentrated at $75^{\circ}C$. Water activity of the herb extract was adjusted to 0.86, 0.80 and 0.69, using water activity analyzer. The extracts were incubated for 180 days at $40^{\circ}C$ and then examined microbial cell counts and some physicochemical properties. In the extract of $a_{w}$ 0.86, 18 CFU/g of initial viable cell was increased to 80 CFU/g with 90 days of incubation and to 190 CFU/g 180 days of incubation. In the extract of $a_{w}$ 0.80, 24 CFU/g of initial viable cell was also increased to 83 CFU/g during the 90 days of incubation and to 170 CFU/ g for the 180 days of incubation. However, in the extract of $a_{w}$ 0.69, viable cell after 180 days of incubation was remained at almost the same level as initial viable cell. pH of herb extract was reduced in proportion to the decrease in water activity. The TLC (thin layer chromatography) patterns of ginseng saponins of herb extract did not show any significant changes after 180 days of incubation. Growth of pathogenic microorganisms was inhibited more with lower water activity of the herb extracts. In the herb extract inoculated with Candida albicans and Aspergillus niger, initial viable cells of 150 and 140 CFU/g were decreased to 30 and 20 CFU/g, repectively, after 30 days of incubation at $28^{\circ}C$. In the case of herb extract inoculated with Escherichia coli, Staphylococcus aureus, and Pseudomonas aeruginosa, growth of the bacteria was totally inhibited even after 30 days of incubation at $37^{\circ}C$.

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형태안정성 레이온 복합소재 염색가공 연구

  • Kim, Myeong-Sun;Park, Seong-Min;Gwon, Il-Jun;Seo, Mal-Yong;Kim, Hye-Jeong
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.103-103
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    • 2011
  • 비스코스레이온(Viscose Rayon)소재는 목재 펄프를 원료로 한 재생섬유(습식방사)로서 Drape성과 반발성은 탁월하나, 습식방사에 따른 분자구조적 불안정성으로 건 습열처리시 형태불안정(치수변화율이 큼)으로 제직(준비) 및 후공정상 여러 가지 Trouble 유발과 완제품 세탁시 수축발생으로 종종 Dry Creanning 해야 하는 문제점들이 내재되어 있다. 또한 수분흡수시 강도저하, 수축과 구김, 염색 불균염 등의 문제점과 섬유공정상 생활취급상에 많은 애로를 가지고 있으며, 구성고분자가 수소결합에 의해 강고하여 "신축문제", 수분흡수시 팽윤(Swelling)에 의한 형태불안, 즉 "수축문제"가 개선해야 할 고질적 문제로 남아있다. 따라서 본 연구에서는 레이온 소재의 형태안정화 제품을 개발하기 위하여 복합사고공 및 염색가공 기술을 개발하고자한다. 신축 및 복합기술에 의한 Rayon DTY, N/R 신축 및 복합기술에 의한 Rayon DTY, N/R 복합가공사를 개발, 제편직 요소기술과 염가공기술을 연구하므로서 형태안정성 레이온 복합소재 제품을 개발하고자 한다. Rayon 소재의 후공정 용이성과 형태안정성을 부여하기 위하여, 레이온 DTY가공사, Rayon-합섬 장(長)-장(長) 복합사를 개발하여 CoolBiz용 냉감소재 및 스포츠 웨어 소재 등으로 활용하고자 한다. 사가공기술에 의한 신도 16%, 수축률 1.6%인 형태안정 Rayon DTY 소재를 개발하였으며, 선연후가공기술에 의하여 N/R 복합가공사를 개발, 신도 18%, 수축률 1.2%인 차별화 레이온 소재를 개발하였다. 이에 기존 Rayon 후가공 및 염색공정과 상이한 개발된 선연후 가연 Rayon DTY가공사 및 T/R혼방사를 활용한 직물에 대하여 최적 전처리, 염색 후가공 공정의 최적 조건을 알아보았다.

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Characteristics of Rice Flours Prepared by Moisture-Heat Treatment (수분-열처리에 의해 제조한 멥쌀가루의 특성)

  • Lee Mi-Kyung;Shin Mal-Shick
    • Korean journal of food and cookery science
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    • v.22 no.2 s.92
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    • pp.147-157
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    • 2006
  • To improve the properties of non-waxy rice flours for baking, soaked-wet milled rice flour (SWRF) was adjusted moisture content (MC) to 30 and 50 % and heated at 50 and $70^{\circ}C$ in a shaking water bath for 6 and 18 hrs, respectively. Moisture-heat treated rice flours were investigated with regard to particle size distribution, and morphological, physicochemical and pasting properties for comparing dry and wet milled flours. The particle size of rice flour treated with 30% MC was distributed between $4-20{\mu}m\;and\;100-200{\mu}m$, like SWRF. The particles above $200{\mu}m$ in the flour were produced at higher heating temperature. By SEM, starch granules were found in the rice flours treated with 30% MC, who whereas aggregated starch granules were shown in the flours treated with 50% MC. Moisture-heat treatment using higher MC and heating temperature decreased the lightness and increased the yellowness of non-waxy rice flours. Water binding capacity of 30% moisture treated rice flour was similar to that of SWRF. In the same moisture treated rice flour, swelling power was higher, but solubility was lower at $50^{\circ}C$ than at $70^{\circ}C$. The initial pasting temperature by RVA increased after moisture-heat treatment. The peak viscosity of moisture-heat treated rice flour was higher for 30% moisture than that of the others. The rice flour treated with 30% MC and heated at $50^{\circ}C$ showed low setback and increased stability for retrogradation.

Characterization of Biomass-Based Foam Structures for Home-Meal-Replacement Containers (가정간편식 용기용 바이오매스 기반 발포구조체의 특성에 관한 연구)

  • Kim, Inae;Kim, Sumin;Kambiz, Sadeghi;Han, Jeonggu;Hwang, Kiseop;Kwon, Hyukjoon;Kim, Yongsu;Yoo, Seung Ran;Seo, Jongchul
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.26 no.2
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    • pp.77-83
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    • 2020
  • A series of foamed plastic sheets containing biomass (as HMR container) were developed via different foaming process temperatures, and their density, porosity, WVTR, and pore morphology were evaluated. Thermal stability of samples during re-heating the food in oven, change in morphology, density, porosity, and WVTR were investigated using a simulated thermal shock process according to MIL-STD-883E assay. As such, the pore size of samples was generally increased with increasing temperature of the foaming process. It can be explained that as foaming temperature increased, the viscosity of molten resins and the repulsive force against pore expansion decreased. In addition, an increase in the thermal shock cycle reduced the pore size and WVTR, while density increased because high temperature treatment that softened the sheet matrix was followed by a low temperature incubation, which contracted the matrix, thereby changing the physical and morphological properties of samples. However, an insignificant change in density was observed and WVTR tended to be decreased, indicating that as-prepared foamed plastic sheets could be used as a high thermal stable container for HMR application. Therefore, it found that the properties of newly developed HMR containers containing biomass were dependent on the foaming process temperature. Moreover, to better understanding of these newly developed containers, further investigations dealing with foaming process temperature based on various food items and cooking conditions are needed.

The Study of Water Stability of MDF Cement Composite by Addition of Silane Coupling Agent (Silane Coupling Agent 첨가에 의한 MDF Cement Composite의 수분안정성 연구)

  • 노준석;김진태;박춘근;오복진;최상홀
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.421-428
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    • 1998
  • The effect of silane coupling agents on the water stability of HAC/PVA based MDF cement composites which were modified with urethane and epoxy resin were studied as a function of the functional groups and addition amount of silane coupling agent. According to the composition of polymer matrix the silanes with different functional groups showed the different effectiveness. In case of the only PVA matrix the silane with vinyl functional group was more effective than other silanes. When the epoxy resin was added the silane of epoxy-methodxy group enhanced the flexural strength of dry and wet state more than other. In case of urethane-added MDF cement the silane of diamine group was effective and enhanced the water sta-bility fo MDF cement composite more and more as the addition amount of silane increased, Especially in case of warm-presed composite the effect of silane was enhanced By addition of 2wt% of silane with 야-amine group the flexural strength of urethane-added composites were enhanced by 20% more in dry state 40-70% in wet state in accord with the porosity analysis. The flexural strength of the poxy resin-added MDF cement composite was increased by addition of 1wt% and 2wt% silane of epoxy-methoxy group However the addition of 4wt% of silane decreased the flexural strength of dry and wet state by formation of closed pore in the polymer matrix.

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A Study for establishment of soil moisture station in mountain terrain (1): the representative analysis of soil moisture for construction of Cosmic-ray verification system (산악 지형에서의 토양수분 관측소 구축을 위한 연구(1): Cosmic-ray 검증시스템 구축을 위한 토양수분량 대표성 분석 연구)

  • Kim, Kiyoung;Jung, Sungwon;Lee, Yeongil
    • Journal of Korea Water Resources Association
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    • v.52 no.1
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    • pp.51-60
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    • 2019
  • The major purpose of this study is to construct an in-situ soil moisture verification network employing Frequency Domain Reflectometry (FDR) sensors for Cosmic-ray soil moisture observation system operation as well as long-term field-scale soil moisture monitoring. The test bed of Cosmic-ray and FDR verification network system was established at the Sulma Catchment, in connection with the existing instrumentations for integrated data provision of various hydrologic variables. This test bed includes one Cosmic-ray Neutron Probe (CRNP) and ten FDR stations with four different measurement depths (10 cm, 20 cm, 30 cm, and 40 cm) at each station, and has been operating since July 2018. Furthermore, to assess the reliability of the in-situ verification network, the volumetric water content data measured by FDR sensors were compared to those calculated through the core sampling method. The evaluation results of FDR sensors- measured soil moisture against sampling method during the study period indicated a reasonable agreement, with average values of $bias=-0.03m^3/m^3$ and RMSE $0.03m^3/m^3$, revealing that this FDR network is adequate to provide long-term reliable field-scale soil moisture monitoring at Sulmacheon basin. In addition, soil moisture time series observed at all FDR stations during the study period generally respond well to the rainfall events; and at some locations, the characteristics of rainfall water intercepted by canopy were also identified. The Temporal Stability Analysis (TSA) was performed for all FDR stations located within the CRNP footprint at each measurement depth to determine the representative locations for field-average soil moisture at different soil profiles of the verification network. The TSA results showed that superior performances were obtained at FDR 5 for 10 cm depth, FDR 8 for 20 cm depth, FDR2 for 30 cm depth, and FDR1 for 40 cm depth, respectively; demonstrating that those aforementioned stations can be regarded as temporal stable locations to represent field mean soil moisture measurements at their corresponding measurement depths. Although the limit on study duration has been presented, the analysis results of this study can provide useful knowledge on soil moisture variability and stability at the test bed, as well as supporting the utilization of the Cosmic-ray observation system for long-term field-scale soil moisture monitoring.

Effects of Water Activity and Light on the Oxidation of Carrot Carotenoids (당근 카로티노이드의 자동산화에 미치는 수분활성도 및 광선의 영향)

  • Song, Eun-Seung;Kim, Hae-Gyoung;Song, Yeong-Ok;Jeon, Yeong-Soo;Cheieh, Hong-Sik
    • Korean Journal of Food Science and Technology
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    • v.25 no.6
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    • pp.775-779
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    • 1993
  • The effects of water activity and light on the oxidation of carotenoid were studied using both the model systems of carrot lipids and freeze dried carrot. Autoxidation of crude lipids from the freeze dried carrot and the stability of carotenoids in controlled systems varing water activities and/or lights were examined. The degree of autoxidation of crude lipid stored at $30^{\circ}C$ for 16 days was significant(p< 0.05) and 71.8% destruction of carotenoid in the crude lipids were observed. When the powdered solid models of freeze dried carrot were stored at $30^{\circ}C$ for 35 days under various water activities and the presence of light, the maximum stability of carotenoid was found at $a_{w}$ 0.42 and the damaging effect of lights on the stability of carotenoid was significant (p<0.05). The absoprtion spectra of carotenoids changed according to the degree of oxidation, but shifts of the maximum wavelength was not observed.

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A Study on the BOS control of a small PEM fuel cell stack (소형 PEM 연료전지 스택의 BOS 제어에 관한 연구)

  • Kim, Tae-Hoon;Choi, Woo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.274-277
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    • 2009
  • 본 논문에서는 소형 PEM(Proton Exchange Membrane) 연료전지 스택의 BOS(Balance of Stack) 제어에 관하여 논의한다. 별도의 가습 장치가 필요치 않고 BOS의 구성이 비교적 간단한 소형 PEM 연료전지 시스템에서는 팬과 퍼지밸브만의 제어를 통해 스택 내부 수분의 조절과 열 관리가 수행된다. 따라서 본 논문에서는 부하에 따른 최적의 공기유량을 계산하고 요구되는 유량의 공급을 위해 팬을 제어하는 알고리즘을 통해 소형 연료전지 시스템의 과도응답 특성과 안정성을 향상시키는 방법에 관하여 제안한다. 150W급 소형 연료전지 시스템을 꾸미고, 마이크로컨트롤러를 이용한 제어회로를 구현하여 실험함으로써 제안된 알고리즘의 유용함을 검증하였다.

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Effect of MMT on Anti-Water Absorption of Polyamide/MMT Nanocomposites (MMT 첨가에 따른 Polyamide/MMT 나노복합체의 흡습 특성)

  • Park, Sang-Cheol;Kim, Ho-Gyum;Min, Kyung-Eun
    • Polymer(Korea)
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    • v.37 no.1
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    • pp.113-120
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    • 2013
  • The melt intercalation to commercialize nanocomposites in a pilot scale was applied and the water absorption characteristics for polyamide/MMT nanocomposites manufactured by twin screw extruder was studied. As a result, water absorption decreased with the introduction of MMT and dimensional stability was improved. However, as water absorption increased, flexural strength and modulus were reduced. Therefore, the effect of MMT introduction on mechanical properties of nanocomposites was clearly observed, which may increase the level of strength by maintaining anti-water absorption property of nanocomposite.