• Title/Summary/Keyword: 수분평형

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Diacylglycerol Production by Enzymatic Glycerolysis of Soybean Oil. (대두유에서 글리세롤리시스 반응을 이용한 디글리세리드의 효소적 생산)

  • 박경준;안은영;권기석;김강성;강성태
    • Microbiology and Biotechnology Letters
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    • v.32 no.1
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    • pp.84-90
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    • 2004
  • Diglyceride (DG) was prepared by reaction of soybean oil and glycerol in the presence of lipase. The initial rate of DG production was greatly affected by the amount of lipase. However the DG content at equilibrium was hardly affected by the amount of lipase added to the reaction mixture. The initial rate of FFA formation was highly affected by the moisture content between 0.5 and 2.3%, but at higher water content (3.3-5.2%), there was a small increase in the rate. And DG content at equilibrium slowly increased with the increase of the water content in glycerol up to 4.4%. However, there was a sharp decrease in DG content at higher water content (5.2-6.4%) due to higher free fatty acid production. The highest yield of DC was obtained at the temperature ranges of 30-5$0^{\circ}C$. The final yield of DG was not dependent on the glycerol (GL) to triglyceride (TG) molar ratio. However, at the molar ratio of 0.75:1 (GL/TG), the enzyme-catalyzed reaction was highly efficient and utilized all the glycerol. In optimized conditions for glycerolysis a yield of approximately 45% DG was obtained. 66% of total DG was 1,3-DG.

Effects of Water Content and Temperature on Equilibrium Distribution of Organic Pollutants in Unsaturated Soil (토양내 유기독성물질의 평형분포에 미치는 토양수분과 온도의 영향)

  • Koo, Ja Kong;Shin, Hang Sik;Kim, Dong Ha
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.8 no.3
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    • pp.119-128
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    • 1988
  • The purpose of this research is to quantify the effects of water content(0.3~1.255%) and temperature ($4{\sim}40^{\circ}C$) on the equilibrium distribution of toxic organic pollutant in unsaturated soil. The priority pollutants, Dichloromethane and 1, 1, 1-Trichloroethane were selected as toxic organic pollutants and the Korean decomposed granite soil as the experimental soil media. Two models were developed on the basis of shapes of soil water distribution in unsaturated soil and compared; complete surface coating(model I) vs. spot clustering (model II). From the experiment, a large decrease in the values of effective partition coefficient ($K_{eff}$) was observed as the water content increased. As the temperature increased, the $K_{eff}$ values decreased, and this effect was magnified at lower water contents. The values of $K_{eff}$ were correlated better with the estimated values using model II. Thus it was experimentally proved that the soil water tends to enclose the soil grain partly at lower water contents.

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Browning and Sorption Characteristics of Dried Garlic Flakes with Relative Humidity and Storage Temperature (상대습도와 저장온도에 따른 건조마늘 플레이크의 갈변 및 흡습특성)

  • Kim, Hyun-Ku;Jo, Kil-Suk;Kang, Tong-Sam;Shin, Hyo-Sun
    • Korean Journal of Food Science and Technology
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    • v.19 no.2
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    • pp.176-180
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    • 1987
  • The sorption characteristics of dried garlic flakes stored at various relative humidity and storage temperature were studied. At low relative humidity below RH 51%, the sorption equilibrium was easily attained, whereas at higher relative humidity above RH 67%, the flakes were browned by higher equilibrium moisture content. The flakes were browned at relative humidity above 67% at $20^{\circ}C$ and $35^{\circ}C$, above 84% at $5^{\circ}C$, respectively. The moisture contents of monolayer value for the flakes were ranging from 5.80% to 6.20% (DB) with varying temperatures. And the necessity of moisture-proof packaging material suggested for the long term storage of the flakes because the lower moisture content and storage temperature, the higher driving force of wetting. Regression equation for browning rate prediction with relative humidity and storage temperature of the flakes was determined.

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Browning and Sorption Characteristics of Garlic Powder with Relative Humidity and Storage Temperature (상대습도와 저장온도에 따른 마늘가루의 갈변 및 흡습특성)

  • Kim, Hyun-Ku;Jo, Kil-Suk;S.Hawer, Woo-Derck;Shin, Dong-Hwa
    • Korean Journal of Food Science and Technology
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    • v.20 no.3
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    • pp.399-404
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    • 1988
  • The sorption characteristics of garlic powder stored at various relative humidities and storage temperatures were studied. At lower relative humidity below RH 51%, the sorption equilibrium was easily attained, whereas at higher relative humidity above RH 67%, the powders were browned by higher equilibrium moisture content. The powders were browned at relative humidity above 67% at $20^{\circ}C\;and\;35^{\circ}C,\;above\;84%\;at\;5^{\circ}C$, respectively. The moisture contents of monolayer value for the powder were ranged from 5.53%(DB) to 5.92% (DB) with varying temperatures. And the necessity of moistureproof packaging material suggested for the long term storage of the powder because the lower moisture content and storage temperature, the higher driving force of wetting.

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Comparison of Sorption Characteristics of Red Pepper Powders with Their Seeds Mixing Ratio (고추씨 혼합비율에 따른 고추가루의 흡습특성 비교)

  • Kim, Hyun-Ku;Jo, Kil-Suk;Park, Mu-Hyun;Chang, Young-Sang;Shin, Zae-Ik
    • Korean Journal of Food Science and Technology
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    • v.22 no.7
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    • pp.817-823
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    • 1990
  • The sorption characteristics of red pepper powders in terms of mixing ratio of seeds to red pepper powders were investigated at various relative humidities and temperatures as storage conditions. At lower relative humidity below 43% RH, the sorption equilibrium was easily reached regardless of mixing ratio, whereas at higher relative humidity above 75%, the powders gained moisture rapidly, resulting in the color change to brown. At extremely lower RH below 33%, decoloration occurred in red pepper powder. The moisture contents of monolayer value for red pepper powders without seeds were ranging from 5.88% to 7.35% inversely proportional to the temperature. The moisture contents of monolayer value decreased with increase of mixing ratio of seeds.

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Soaking and Drying Characteristics of Grains and Legumes (곡류와 두류의 침지 및 건조 특성)

  • Park Jong-Dae;Jeon Hyang-Mi;Kum Jun-Seok;Lee Hyun-Yu
    • Food Science and Preservation
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    • v.13 no.3
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    • pp.344-350
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    • 2006
  • Soaking and drying were studied for seven grains and legumes including glutinous rice, brown rice, glutinous brown rice, glutinous barley, Seoritae, Heuktae and red bean to improve taste of cooked mixed grams and make easy to cook then Seoritae and Heuktae showed the highest water absorption and the rest were in the order of glutinous barley, glutinous rice, milled rice, brown glutinous rice, brown rice, and red bean. In regards with water absorption index by soaking temperature, the higher the temperature showed, the more water absorption and the shorter time to reach the water absorption balance, the more grinding legumes. showed the more water absorption and the shorter time to reach to the water absorption balance. The soaked samples were dried at mom temperature $30^{\circ}\C,\;50^{\circ}\C$, and microwave 300 W, 700 W and 1000 W power. As a result 700 W drying method br microwave can dry samples in the shortest time without damage to the samples. Therefore, it was considered as the best pretreatment conditions for mixed stains to dry with 700 W microwave after one-hour soaking at $30^{\circ}C$.

Effect of Cooking on Moisture Sorption Properties of Corn (삶은 옥수수의 수분흡습성질)

  • Mario, Carranza;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.22 no.5
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    • pp.530-532
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    • 1990
  • The moisture sorption behaviors of dry corn(DC). dry-corn (DCC) and soaked-rooked corn(SCC) at $25^{\circ}C$ were analyzed. The corn was soaked in water at $26^{\circ}C$ for 8hr. The cooking times for DCC and SCC were 30 and 20min. respectively, at $80^{\circ}C$. Desorption occurred for DC and DCC at RH below 23% and SCC at RH below 33% during storage. Moldiness was observed in all samples at RH 97%, after 192hr for DC and 288 hr for both DCC and SCC. At the same water activity. SCC sample had the highest moisture content, followed by DC. The SCC sample had the highest monolaver value and sorption heat. Stability isotherms indicated that DC and SCC had better storability than DCC.

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Numerical Study of Thermo-hydraulic Boundary Condition for Surface Energy Balance (지표면 열평형의 열-수리적 경계조건에 대한 수치해석)

  • Shin, Hosung;Jeoung, Jae-Hyeung
    • Journal of the Korean Geotechnical Society
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    • v.37 no.12
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    • pp.25-31
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    • 2021
  • Boundary conditions for thermal-hydraulic problems of soils play an essential role in the numerical accuracy. This study presents a boundary condition considering the thermo-hydraulic interaction between the ground and the atmosphere. Ground surface energy balance consists of solar radiation, ground radiation, wind convection, latent heat from water evaporation, and heat conduction to the ground. Equations for each heat flux are presented, and numerical analyses are performed in conjunction with the FEM program for the thermal-hydraulic phenomenon of unsaturated soils. Numerical results using the weather data at the Ulsan Meteorological Observatory are similar to the measured surface temperature. Latent heat caused by water evaporation during the daytime lowers the surface temperature of the bare soil, and a thermal equilibrium is reached at nighttime when the effect of the ground condition is significantly reduced. The temperature change of the surface ground is diminished at the deeper ground due to its thermal diffusion. Numerical analysis where the surface ground temperature is the primary concern requires considering the thermo-hydraulic interaction between the ground and the atmosphere.

A Moisture Diffusivity Model of Hardening Concrete (경화하는 콘크리트의 수분확산도 모형)

  • Jeong, Jin-Hoon
    • International Journal of Highway Engineering
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    • v.7 no.1 s.23
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    • pp.31-38
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    • 2005
  • Concrete has higher vapor pressure than its surrounding ambient air immediately after placement. Moisture at concrete surface evaporates to the ambient air to adjust equilibrium of the vapor pressure between them. The moisture inside the concrete moves to the surface because the evaporation at the surface causes gradient of vapor pressure inside the concrete. Plastic cracking, degree of hydration, strength development, and others caused by velocity of the moisture movement significantly influences quality of concrete. In this paper, the moisture diffusivity of early-age concrete was back-calculated using governing equation of the moisture diffusion, and temperature and relative humidity of concrete measured in a laboratory. The moisture diffusivity of the concrete was modeled using the back-calculated moisture diffusivity. The relative humidity of the concrete calculated by finite element method (FEM) using the modeled moisture diffusivity as Input data coincided with the measured relative humidity well.

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Comparison of Differential Scanning Calorimetry with Enzymatic Method for the Determination of Gelatinization Degree of Corn Starch (DSC에 의한 전분의 Endothermic peak와 효소분석법에 의한 호화도 비교)

  • Lee, Boo-Yong;Mok, Chul-Kyoon;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.25 no.4
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    • pp.400-403
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    • 1993
  • Gelatinization degrees of torn and waxy corn starches in the low-moisture environment were determined by DSC thermogram and enzymatic analysis, the results were compared each other As the moisture content increased from 20% to 70%, the enthalpy of endothermic peak of starch increased linearly in DSC thermograms. When the moisture content exceeded above 70%, the DSC enthalpy of starch remained constant in DSC thermogram. The enthalpies for gelatinization of corn and waxy corn starches were 3.23 cal/g and 4.2 cal/g, respectively. When gelatinization degrees of starches were measured by enzymatic analysis, the gelatinization degree increased linearly as the moisture content increased from 20% to 80%. A linear correlation between DSC and enzymatic analysis was obtained only when the moisture content was under 70%.

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