• Proceedings of the Korea Water Resources Association Conference
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• 2008.05a
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• pp.1713-1716
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• 2008

최근 배출되는 미량유해물질로 1991년 페놀, 2004년 1,4-다이옥산, 2006년 퍼클로레이트 검출 등 빈번하게 원수수질 오염사고가 발생하고 새로운 미량유해 화학물질의 배출이 우려됨에 따라, 일부 시민단체, 시의회, 언론 등에서 깨끗하고 안전한 상수원수 확보를 위한 근본적인 대책을 요구하는 목소리가 커지고 있다. 이에 대한 대책의 일환으로 취수원 이전에 대한 타당성 등이 검토되고 있다. 이러한 요구를 바탕으로 본 연구에서는 K-WEAP 모형을 이용하여 낙동강수계 물수지 분석을 실시하였다. 관련된 기존자료를 이용하여 용수수요량을 산정하였으며, 갈수량시 물수지 분석을 실시하였다. 연구에 사용된 K-WEAP 모형은 SEI-B(Srockholm Environment Institute, Boston Center)에서 개발된 WEAP에 기반을 두고 우리나라에 특성에 맞게 모의형태를 개선하고 한글화한 모형으로 분석대상 지역으로서 도시지역과 농업지역, 단일 소유역이나 복잡한 하천유역의 물 수요-공급 시스템에 적용할 수 있다. 또한 K-WEAP 모형은 용수목적별 수요량 분석, 물 절약, 수리권과 배분 우선순위, 지하수와 하천유량 모의, 저수지 운영, 수력발전, 오염물질 추적, 생태계 필요수량 분석과 같은 광범위한 부문의 문제들까지 다룰 수 있다. 본 연구에서 물수지 분석에 사용된 대상구간은 낙동지점에서 고령교지점까지 약 120km이며, 낙동강에 유입되는 지류로는 감천과 금호강을 대상에 포함하였다. 대상구간에 대해서는 3가지의 시나리오를 바탕으로 모의를 진행하였다. 선정된 3가지 시나리오는 현재의 대구 인근지역의 취수와 방류를 고려하는 상태와 현실가능성이 있는 2가지의 대안에 대해서 분석을 실시해 보았다. 대안들은 각각의 대구 취수시설을 구미 상류로 이전하여 취수하는 상황과 구미지역 및 칠곡지역의 방류구 시설을 하류로 이전하여 방류하는 상황으로 가정하여 분석을 실시하였다. 분석결과 현재 상태의 시나리오에서만 갈수기시 만족할 만한 결과를 보여주었고 나머지 2가지의 시나리오에서는 유량이 부족함을 나타났다. 현재의 상태를 모의한 시나리오를 제외한 시나리오의 분석에서는 갈수기 시에 물 부족을 겪게 된다. 이는 낙동강 상류에서 추가방류가 없으면 해결되지 못하는 상황으로 다른 대안들(신규 댐 방류 등)에 대한 추가적인 시나리오 분석이 필요할 것으로 판단된다.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.8 no.4
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• pp.59-67
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• 1988

Anaerobic digestion at the temperature of $35-55^{\circ}C$ was conducted using an artificial sludge of uniform composition. The hydraulic retention time of 5 days was chosen because the temperature effect was effectively shown at a high loading. Inhibition of the methane fermentation decreased as the temperature increased. Acid fermentation was prevalent at the mesophilic and intermediate temperatures, while active methane fermentation took place at $55^{\circ}C$. Temperature not only affects activity of the microorganisms, but also affects physical and chemical properties of the sludge, Digestion inhibition was much reduced when the feed sludge was diluted, and active methane fermentation was possible at all temperatures. The digestion efficiency was governed by the organic loading rate as well as the hydraulic 10ading rate. No reduction of the digestion efficiency at $40-45^{\circ}C$, which had been referred to a critical temperature range, was observed. The digestion efficiency increased monotonically from mesophilic to thermophilic range. Improved settling properties of digested sludge was also recorded at higher temperatures.

• Journal of Soil and Groundwater Environment
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• v.7 no.3
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• pp.19-32
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• 2002

This study is objected to identify the relations between surface- and shallow ground-water and the seasonal variation of their qualities in watersheds near Muju area. The water type shows mainly Ca-$HCO_3$type. Heavy-metal contamination of surface water is locally detected, due to the mixing with mine drainage. In October nitrate concentration is especially high in densely populated area. Cluster Analysis and Principal Component Analysis are implemented to interpret the complexity of the chemical variation of surface- and ground-water with large amount of chemical data. Based on the cluster analysis, surface-water was divided into five groups and ground-water into three groups. Principal Component Analysis efficiently supports the result of cluster analysis, allowing the identification of three main factors controlling the water quality. There are (1) hydrogeochemical factor, (2) anthropogenic factor and (3) heavy metal contaminated by mine drainage.

• Journal of Environmental Science International
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• v.9 no.3
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• pp.241-252
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• 2000

Twenty-two water samples(fifteen groundwater and seven geothermal water samples) were collected to elucidate chemical characteristics of the ground and geothermal waters in the Haeundae hot spring area and its vicinity. Major and honor elements were analyzed for ground and geothermal water samples. The concentrations of $K^+$, Na+$, $Ca^{2+}$, $SO_4^{2-}$, $Cl^-$, ^F^-$ and $SiO_2$ were higher in the geothermal water samples than the groundwater samples except $HCO_3^- and Mg^{2+}$ ions. Based on the contents of Fe, Zn, Cu, Al, Mn and Pb, some of the ground and geothermal water samples are contaminated by anthropogenic sources. The ground waters shown on the Piper diagram belong to $Ca-HCO_3$ type, while the geothermal waters Na-Cl type. The graphs of $Cl^-$ versus $Na^+$, $Ca^{2+}, Mg^{2+}, K^+, SO_4^{2-} and HCO_3^-$ indicate that the groundwater is related partly with mineral-water reaction and partly with anthropogenic contamination, while the geothermal water is related with saline water. On the phase stability diagram, groundwater and thermal water mostly fall in the field of stability of kaolinite. This indicates that the ground and geothermal waters proceed with forming kaolinite. Factor and correlation analyses were carried out to simplify the physicochemical data into grouping some factors and to find interaction between them. Based on the Na-K, Na-K-Ca and Na-K-Ca-Mg geothermometers and silica geothermometers, the geothermal reservoir is estimated to have equilibrium temperature between 125${$\mid$circ}C$ and 160${$\mid$circ}C$.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.10 no.4
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• pp.305-311
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• 2012

Geology, hydrogeology, and geochemistry are the main technical siting factors of a geological repository for spent nuclear fuels. This paper focused on how rock's different geological conditions, such as topography, soils, rock types, structural geology, and geological events, influence the functions of the geological repository. In the context, the site selection criteria of various countries were analyzed with respect to the geological conditions. Each country established the criteria based on its important geological backgrounds. For example, it was necessary for Sweden to take into account the effect of ice age on the land uplift and sea level change, whereas Japan defined seismic activity and volcanism as the main siting factors of the geological repository. Therefore, the results of the paper seems to be helpful in preparing the siting criteria of geological repository in Korea.

• Tunnel and Underground Space
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• v.18 no.3
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• pp.165-174
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• 2008

Thermo-hydro-chemico-mechanical evolution of the radioactive waste repository and surrounding geological media is one of the key issues for the radioactive waste disposal. This article describes not only the basic context for the site selection but also a reasonable strategy for the repository related research based on the results of the French repository project carried out by ANDRA (National radioactive waste management agency). To have some alternatives for the determination of a preferable depth and geological media, it would be recommendable to establish a database system. The curing process of the fractures or microfissures in the EDZ (Excavation Disturbed Zone) during operation time has to be examined considering the evolution of the EDZ and the reversibility of the repository. It is prerequisite to carry out a feasibility study and to validate the design concept and design parameters in a properly constructed underground research laboratory (URL) in Korea.

• Journal of the Korean Society of Groundwater Environment
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• v.5 no.4
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• pp.203-209
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• 1998

The quality of groundwater used for natural mineral water should be strictly regulated on international level by hydrogeology experts and officials because groundwater is greatly subjected to contaminations and its aquifer system may be easily destroyed by external reasons. A total of 18 natural mineral water plants exist in Precambrian metamorphic terrains of the Gyunggi massif and Yeungam massif. The g개undwater quality for the natural mineral water investigated in hydrochemical aspects shows that pH ranges from 6.85 to 8.02 with an average of 7.52. The electric conductivity (EC) and hardness average 134.1 $\mu$S/cm and 43.5, respectively, which are relatively low to the total average (151.4 $\mu$S/cm and 57.9). The contents of major cations and anions are in the order of $Ca^{2＋}$＞$Na^{＋}$＞Mg$^{2＋}$＞K$^{＋}$ and HCO$_3$$^{-}$ ＞SO$_4$$^{2－}$ ＞Cl$^{-}$ ＞F$^{-}$ , respectively. The dominant water types determined by Piper diagram are $Ca^{2＋}$－$Na^{＋}$－HCO$^{-}$ $_3$and $Ca^{2＋}$-HCO$^{-}$ $_3$, mainly due to the dissolution of plagioclase in the host rocks. Representative correlation coefficients between chemical species are $Ca^{2＋}$－HCO$^{-}$ $_3$(0.92), $Ca^{2＋}$－Cl$^{-}$ (0.63), $Na^{＋}$－F$^{-}$ (0.67), HCO$^{-}$ $_3$－Cl$^{-}$ (0.66), and $Na^{＋}$－HCO$^{-}$ $_3$(0.63). The determinative. coefficients between $Ca^{2＋}$ and HCO$^{-}$ $_3$, and (Ca$^{2＋}$＋$Na^{＋}$＋K$^{＋}$ and EC art highest among the elements. According to the saturation index, most chemical species are undersaturated with respect to major minerals, except for some silica phases. In viewpoint of phase equilibrium, the chemical evolution of the groundwater may continue to proceed with increasing pH because the groundwater is undersaturated with respect to feldspars.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.101-104
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• 2005

To understand the geologic and hydrogeochemical controls on the occurrence of high fluoride concentrations in bedrock groundwaters in South Korea, we examined a total of 367 hydrochemistry data obtained from deep groundwater wells (avg, depth = 600 m) that were drilled for exploitation of hot springs. The fluoride concentrations were generally very high (avg. 5.65 mg/L) and exceeded the Drinking Water Standard (1.5 mg/L) in 72% of the samples, A significant geologic control of fluoride concentrations was observed: the highest concentrations occur in the areas of granitoids and granitic gneiss, while the lowest concentrations in the areas of volcanic and sedimentary rocks. In relation to the hydrochemical facies, alkaline $Na-HCO_3$ type waters had remarkably higher F concentrations than circum-neutral to slightly alkaline $Ca-HCO_3$ type waters. The Prolonged water-rock interaction occurring during the deep circulation of groundwater in the areas of granitoids and granitic gneiss is considered most important for the generation of high F concentrations. Under such condition, fluoride-rich groundwaters are likely formed through hydrogeochemical processes consisting of the removal of Ca from groundwater via calcite precipitation and/or cation exchange and the successive dissolution of plagioclase and F-bearing hydroxyl minerals (esp. biotite). Thus, groundwaters with high pH and very high Na/Ca ratio within granitoids and granitic gneiss are likely most vulnerable to the water supply problem in relation to the enriched fluorine.

• Journal of Soil and Groundwater Environment
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• v.16 no.6
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• pp.133-142
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• 2011

A total of 247 samples were collected from groundwater being used for drinking-water supply, and hydrogeochemistry and radionuclide analysis were performed. In-situ analysis of groundwaters resulted in ranges of $13.7{\sim}25.1^{\circ}C$ for temperature, 5.9~8.5 for pH, 33~591 mV for Eh, $66{\sim}820{\mu}S/cm$ for EC, and 0.2~9.4 mg/L for DO. Major cation and anion concentrations of groundwaters were in ranges of 0.5~227.6 for Na, 1.0~279.3 for Ca, 0.0~9.3 for K, 0.1~100.1 for Mg, 0.0~3.3 for F, 0.9~779.1 for Cl, 0.3~120.4 for $SO_4$, 0.0~27.4 for $NO_3$-N, and 6~372 mg/L for $HCO_3$. Uranium-238 and radon-222 concentrations were detected in ranges of N.D-$131.1{\mu}g/L$ and 18-15,953 pCi/L, respectively. In case of some groundwaters exceeding USEPA MCL level ($30{\mu}g/L$) for uranium concentration, their pH ranged from 6.8 to 8.0 and Eh showed a relatively low value(86~199 mV) compared to other areas. Most groundwaters belonged to Ca-(Na)-$HCO_3$ type, and groundwaters of metamorphic rock exhibited the highest concentration of Na, Mg, Ca, Cl, $NO_3$-N, U, and those of plutonic rock showed the highest concentration of $HCO_3$, and Rn. Uranium and fluoride from granite areas did not show any correlation. However, uranium and bicarbonate displayed a positive relation of some areas in plutonic rocks($R^2$=0.3896).

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.14 no.2
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• pp.135-147
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• 2016

The buffer in geological disposal system is one of the major elements to restrain the release of radionuclide and to protect the container from the inflow of groundwater. The buffer material requires long-term stability, low hydraulic conductivity, low organic content, high retardation of radionuclide, high swelling pressure, and high thermal conductivity. These requirements could be determined by the quantitative analysis results. In case of South Korea, the bentonites produced in Gyeongju area have been regarded as candidate buffer/backfill materials at KAERI (Korea Atomic Energy Research Institute) since 1997. According to the study on several physical and chemical characteristics of domestic bentonite in the same district, this is the Ca-type bentonite with about 65% of montmorillonite content. Through this study, we present the criteria for the performance evaluation items and methods when collecting new buffer/backfill materials.