• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.291-300
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• 2008

Catalytic cracking of n-octane was carried out over H-ZSM-5 zeolite catalysts after calcination with air and steaming with 100% steam in the temperature range of $550-750^{\circ}C$ for 24 h and compared with the results of thermal cracking. The increase of calcination and steaming temperature resulted in the decrease of surface area, pore volume, and strong acid sites, which was mainly caused by the dealumination of H-ZSM-5 framework. It was found by $^{27}Al$ and $^{29}Si$ MAS NMR that the dealumination was proceeded through the transformation process of tetrahedral framework Al${\rightarrow}$penta-cordinated Al ${\rightarrow}$ octahedral framework Al and the phenomena was much more severe in steaming conditions than that of calcination. In the catalytic cracking of n-octane, as the temperatures of calcination and steaming were increased, the conversion of n-octane, the selectivity of light olefins and ethylene to propylene ratio were decreased due to the dealumination of framework aluminum resulting the loss of acidic strengths. The conversion, selectivity of light olefins and ethylene to propylene ratio reached almost to the level of thermal cracking after steaming at $750^{\circ}C$ for 24 h.

• Transactions of the Korean Society of Mechanical Engineers
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• v.10 no.3
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• pp.427-431
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• 1986

3점 굽힘 시험편, 중앙균열 인장 시험편, 콤팩트 인장 시험편에 대한 J적분식을 하나의 일반화된 형태로 유도한다. 이 일반식은 Eftis와 Liebowitz에 의해 제안된 하중과 하중점 변위 사이의 관계와 Sumpter에 의한 탄성과 소성성분 J적분의 중첩개념을 이용함으로써 유도된다. 일반식에 포함된 .eta.계수를 위 3가지 시험편에 대해서 결정한다. 위 3가지 시험편에 대한 J적분의 최종식은 하중과 하중점 변위곡선 아래의 면적을 측정하지 않아도 되는 형태로 나타난다. 본 연구의 결과식은 Landes등에 의한 실험치와 비교하여 매우 잘 일치함을 보인다.

• Journal of the Korean Society for Precision Engineering
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• v.16 no.4 s.97
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• pp.178-188
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• 1999

충격하중을 받는 시험편 높이의 1/4 길이의 notch를 가진 3점 굽힘시험편들의 기계적 거동에 관한 컴퓨터 시뮬레이션을 하고 이 시뮬레이션에 대한 실험적 검증도 하여 그 타당성을 입증하였다. 시험편들의 양쪽 가장자리(지지점)에서 작용되어지는 여러 가지의 하중속도에 대한 경우들과 탄소성 von Mises 재질인 모델들을 시뮬레이션에 포함시켰으며 이들에 대한 결과들을 간극 개구 변위, 반력, 크랙선단 개구 변위 및 변형률등이 속도에 의존되는 재질(점소성 재질)에 대한 시뮬레이션 결과와 비교하였다. 또한 여러가지의 동적 하중을 받는 상황하에서의 안정성이 본 연구의 시뮬레이션을 통하여 비교되었으며 그 차이점들이 규명되었다.

• Korean Journal of Food Science and Technology
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• v.21 no.6
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• pp.815-819
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• 1989

Rheological properties of chestnut starch suspensions (3 and 4%, db) and gelatinized starch (4%, db) were investigated with a capillary and rotational viscometer, respectively. Starch suspensions had no yield stress and showed dilatant flow behavior in the temperature ranges of $30-65^{\circ}C$. However, starch suspension showed pseudoplastic flow behavior at $70^{\circ}C\; and\;above\; 65^{\circ}C$ for 3 and 4% concentration, respectively Flow activation energy below $50^{\circ}C$ was 0.56 kcal/mole but increased to 51.9-80.8 kcal/mole at $60-70^{\circ}C$. The behavior of gelatinized starch (4%) was pseudoplastic regardless of heating temperature $(65-80^{\circ}C)$ and time (15-60 min). The apparent viscosity of the starch remained constant after heating at $80^{\circ}C$ for 45 min. The swelling power and log apparent viscosity showed similar pattern. The activation energy of the apparent viscosity of the geletinized starch at $70-80^{\circ}C$ was 13.09kcal/mole. The apparent viscosity of thermal-gelatinized $(90^{\circ}C)$ starch was lower than that of 15 psi-gelatinized starch.

• Journal of Conservation Science
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• v.37 no.5
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• pp.567-578
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• 2021

In this study, the physicochemical properties of 21 wall fragments and rooftile pieces excavated from Jeseoksa Dump-site were analyzed, and the possibility of heat exposure, such as the fire reported in the literature, was investigated by estimating the firing temperature. From the results, it was estimated that the rooftiles were composed of refined materials, and the walls were composed of materials having different particle sizes depending on the layer. Unlike ordinary rooftiles and walls, they exhibited an uneven surface with traces of bloating phenomenon in the cross section. It was estimated from the blackening of some portions that firing was not performed in a controlled state in a constant firing environment. In addition, the estimated firing temperature showed that the non-overfired rooftiles had endured a firing temperature of 900℃ or less, but the over-fired samples were subjected to a temperature of 1,000℃ or higher and were fired at a temperature higher than the manufacturing temperature at that time. Additionally, the rooftiles probably became defective during firing or molding at the time of production, but the non-overfired rooftiles exhibited an intact shape and showed the possibility of heat exposure due to fire. Therefore, the analytical results of this study confirm that the defective architectural components damaged by the fire, as reported in the literature, were discarded in the Jeseoksa dump-site.

• Korean Journal of Food Science and Technology
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• v.24 no.1
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• pp.54-58
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• 1992

The reological properties of commercial corn starch solutions at various concentrations($4{\sim}9%$) and temperatures($30{\sim}60^{\circ}C$) were investigated. The rheological behavior of corn starch solutions was illustrated by Herschel-Bulkley equation and exhibited pseudoplastic behavior with yield stress. The degree of pseudoplasticity of starch solution increased as the starch concentration increased but was independent on temperature. Apparent viscosity and yield stress of starch solutions were exponentially dependent on concentration and temperature. The critical concentrations for sol-gel transition and for the onset of close-packing of the starch granules were $6.22{\sim}6.52%\;and\;2.68{\sim}2.78%$ respectively.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 1997.06a
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• pp.5-15
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• 1997

It is the objective of this study that by conducting the serni-solid extrusion using A12024, the effect of various process variables on the quality of extruded product and extrusion force is understood. The results of experiment are compared with those of finite element simulation in order to verify the effectiveness of the developed FE-simulation code. In order to simulate densification in the deformation of serni-solid material, the semi-solid material is assumed to be composed of solid region as porous skeleton following compressible visco-plastic model and liquid region following Darcy's equation for the liquid flow saturated in the interstitial space. Then the flow and deformation of the semi-solid alloy are analyzed by coupling the deformation of the porous skeleton and the flow of the eutectic liquid. It is assumed that initial solid fraction is homogeneous. Yield and plastic potential function presented by Kuhn and constitutive model developed by Gunasekera are used for solid skeleton.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 1996.03b
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• pp.93-100
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• 1996

In this paper, a computer simulationtechnique for the forging process having a spring-attached die was presented . The penalty rigid-thermoviscoplastic finite element method was empolyed together with an interatively force-balancing method, in which the convergence was achieved when the forming load and the spring reaction force are in equilibrium within the user-specified allowable accuracy. The force balance was controled by adjusting the velocity of the spring-attched die. th minimize the number of internations, a velocity estimating schemewas proposed. Two application examples found in the related company were given. In the first application example, the predicted metal folw lines were compared with the acturally forged ones. in the second example, a hot forging process with a spring-attached die was simulated and the analyzed results were discussed in order to investigated the effects of spring-attached dies on the metal flow lines and the forming loads.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.5 no.4
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• pp.282-285
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• 2004

Kinetics of H-spillover over $Pt/MoO_3$ was greatly affected by the amount of residual chlorine differing by calcination temperature. Multifacetted techniques for characterization were dedicated to elucidate the faster reduction of chlorine in the isothermal reduction (ITR) at $50^circ{C}$ after calcination. Reduction of residual chlorine over Platinum resulted in opening the more channel of hydrogen pathway into more $MoO_3$ particles and controlling the kinetics of hydrogen uptake.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.4A
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• pp.767-774
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• 2006

This study has focused on the possibility for recycling of tailings from the sangdong tungsten mine as powder (TA) of self-compacting concrete (SCC). The experimental tests for entrapped water ratio were carried out in accordance with the specified method by Okamura. The rheological measurements of cement paste were conducted by using a commercially digital Brookfield viscometer (Model LVDV-II+) equipped with cylindrical spindles, also tests for slump-flow, time required to reach 500 mm of slump flow (sec), time required to flow through V-funnel (sec) and filling height of U-box test (mm) were carried out in accordance with the specified by the Japanese Society of Civil Engineering (JSCE). The results of this study, entrapped water ratio was decreased with increasing replacement of TA. Thickness of pseudo water film was increased, and mean plastic viscosity was decreased with increasing replacement of TA. And slump-flow of SCC was decreased with increasing replacement of TA. But time required to reach 500 mm of slump flow (sec), time required to flow through V-funnel (sec) and filling height of U-box test (mm) were satisfied a prescribed range. The mechanical properties including compressive strength, splitting tensile strength and elastic modulus were checked with the requirements specified by Korean Industrial Standard (KS). The compressive strength of SCC was decreased with increasing replacement of TA, splitting tensile strength and elastic modulus were similar to those of normal concrete.