• Title/Summary/Keyword: 셀전압

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Influence of Water-Cement Ratios and Curing Conditions on the Diffusion Characteristics of Chloride Ion in Concrete (콘크리트의 염소이온 확산특성에 미치는 물-시멘트비 및 양생조건의 영향)

  • Bae, Su-Ho;Lee, Kwang-Myong;Kim, Jee-Sang;Jung, Sang-Hwa
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4A
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    • pp.753-759
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    • 2006
  • To predict service life of concrete structures exposed to chloride attack, surface chloride concentration, diffusion coefficient of chloride ion, and chloride corrosion threshold value in concrete, are used as important factors. Of these, as the diffusion coefficient of chloride ion for concrete is strongly influenced by concrete quality and environmental conditions of structures and may significantly change the service life of structures, it is considered as the most important factor for service life prediction. The qualitative factors affecting the penetration and diffusion of chloride ion into concrete are water-cement (W/C) ratio, age, curing conditions, chloride ion concentration of given environment, wet and dry conditions, etc. In this paper the influence of W/C ratio and curing conditions on the diffusion characteristics of chloride ion in concrete was investigated through the chloride ion diffusion test. In the test, the voltages passing through the diffusion cell were measured by accelerated test method using potential difference, and then with the consideration of IR drop ratio the diffusion coefficient of chloride ion for concrete with different W/C ratios were estimated by Andrade's model. Furthermore, under different curing conditions formulas for the estimation of the diffusion coefficient of chloride ion have been proposed by the regression analysis considering the effect of W/C ratio and age.

Gain Enhancement of Double Dipole Quasi-Yagi Antenna Using Meanderline Array Structure (미앤더라인 배열 구조를 이용한 이중 다이폴 준-야기 안테나의 이득 향상)

  • Junho Yeo;Jong-Ig Lee
    • Journal of Advanced Navigation Technology
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    • v.27 no.4
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    • pp.447-452
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    • 2023
  • In this paper, gain enhancement of a double dipole quasi-Yagi antenna using a meanderline array structure was studied. A 4×1 meanderline array structure consisting of a meanderline conductor- shaped unit cell is located above the second dipole of the double dipole quasi-Yagi antenna. It was designed to have gain over 7 dBi in the frequency range between 1.70 and 2.70 GHz in order to compare the performance with the case using a conventional strip director. As a result of comparison, the average gain of the double dipole quasi-yagi antenna with the proposed meander line array structure was larger compared to the case with the conventional strip director. A double dipole quasi-Yagi antenna using the proposed meanderline array structure was fabricated on an FR4 substrate and its characteristics were compared with the simulation results. Experiment results show that the frequency band for a VSWR less than 2 was 1.55-2.82 GHz, and the frequency band for gain over 7 dBi was measured to be 1.54-2.83 GHz. The frequency bandwidth with gain over 7 dBi increased, and average gain also slightly increased, compared to the conventional case using a strip director.

Effect of Compensation for Thickness Reduction by Chemical Degradation of PEMFC Membrane on Performance and Durability (PEMFC 고분자막의 화학적인 열화에 의한 두께 감소 보정이 성능 및 내구성에 미치는 영향)

  • Sohyeong Oh;Yoojin Kim;Seungtae Lee;Donggeun Yoo;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.62 no.1
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    • pp.1-6
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    • 2024
  • As the demand for hydrogen electric vehicles for commercial vehicles increases, the durability of PEMFCs must increase more than five times that of passenger cars, so research and development to improve durability is urgent. When the PEMFC membrane electrode assembly (MEA) undergoes chemical degradation, the MEA thickness decreases and pinholes occur. In this study, changes in the performance and durability of the MEA were measured while increasing the clamping pressure of the unit cell after open circuit voltage (OCV) holding, an accelerated chemical degradation experiment. As the clamping pressure increased, the resistance of the polymer membrane and the membrane/electrode contact resistance decreased, improving the I-V performance and reducing the hydrogen permeability. As the hydrogen permeability decreased, the OCV increased. When the pinhole area was removed and the MEA clamping pressure was increased, the hydrogen permeability decreased sharply, confirming that the local degradation has a large effect on the performance and durability of the entire cell. When the pinhole was removed and re-clamping and OCV holding was evaluated, it was confirmed that the durability improved according to the decrease in membrane resistance and hydrogen permeability.

Estimation of Strain for Large Deformation in SMA-textile Actuator Using Nonlinear Geometry Analysis (비선형 기하해석을 이용한 SMA 섬유 액츄에이터의 대변형에 대한 변형률 추정)

  • Muhammad Umar Elahi;Jaehyun Jung;Salman Khalid;Heung Soo Kim
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.37 no.4
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    • pp.259-265
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    • 2024
  • Shape memory alloy (SMA)-textile actuators have attracted significant attention across various fields, including soft robotics and wearable technology. These smooth actuators are developed by combining SMA and simple textile fibers and then knitting them into two loop patterns known as the knit (K-loop) and plain (P-loop) patterns. Both loops are distinguished by opposite bending characteristics owing to loop head geometry. However, the knitting processes for these actuator sheets require expertise and time, resulting in high production costs for knitted loop actuation sheets. This study introduces a novel method by which to assess the strain in SMA textile-based actuators, which experience large deformations when subjected to voltage. Owing to the highly nonlinear constitutive equations of the SMA material, developing an analytical model for numerical analysis is challenging. Therefore, this study employs a novel approach that utilizes a linear constitutive equation to analyze large deformations in SMA material with nonlinear geometry considerations. The user-defined material (UMAT) subroutine integrates the linear constitutive equation into the ABAQUS software suite. This equivalent unit cell (EUC) model is validated by comparing the experimental bending actuation results of K-loops and P-loops.

Study on LiFePO4 Composite Cathode Materials to Enhance Thermal Stability of Hybrid Capacitor (하이브리드 커패시터의 열안정성 개선을 위한 LiFePO4 복합양극 소재에 관한 연구)

  • Kwon, Tae-Soon;Park, Ji-Hyun;Kang, Seok-Won;Jeong, Rag-Gyo;Han, Sang-Jin
    • Korean Chemical Engineering Research
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    • v.55 no.2
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    • pp.242-246
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    • 2017
  • The application of composite cathode materials including $LiFePO_4$ (lithium iron phosphate) of olivine crystal structure, which has high thermal stability, were investigated as alternatives for hybrid battery-capacitors with a $LiMn_2O_4$ (spinel crystal structure) cathode, which exhibits decreased performance at high temperatures due to Mn-dissolution. However, these composite cathode materials have been shown to have a reduction in capacity by conducting life cycle experiments in which a $LiFePO_4$/activated carbon cell was charged and discharged between 1.0 V and 2.3 V at two temperatures, $25^{\circ}C$ and $60^{\circ}C$, which caused a degradation of the anode due to the lowered voltage in the anode. To avoid the degradation of the anode, composite cathodes of $LiFePO_4/LiMn_2O_4$ (50:50 wt%), $LiFePO_4$/activated carbon (50:50 wt%) and $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ (50:50 wt%) were prepared and the life cycle experiments were conducted on these cells. The composite cathode including $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ of layered crystal structure showed stable voltage behavior. The discharge capacity retention ratio of $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ was about twice as high as that of a $LiFePO_4/LiMn_2O_4$ cell at thermal stability experiment for a duration of 1,000 hours charged at 2.3 V and a temperature of $80^{\circ}C$.

Low price type inspection and monitoring system of lithium ion batteries for hybrid vessels (하이브리드 선박용 리튬 배터리의 저가형 감시시스템 구현)

  • Kwon, Hyuk-joo;Kim, Min-kwon;Lee, Sung-geun
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.1
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    • pp.28-33
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    • 2016
  • Batteries are used for main power engine in the fields such as mobiles, electric vehicles and unmanned submarines, for starter and lamp driver in general automotive, for emergency electric source in ship. These days, lead-acid and the lithium ion batteries are increasingly used in the fields of the secondary battery, and the lead-acid battery has a low price and safety comparatively, The lithium ion battery has a high energy density, excellent output characteristics and long life, whereas it has the risk of explosion by reacting with moisture in the air. But Recently, due to the development of waterproof, fireproof, dustproof technology, lithium batteries are widely used, particularly, because their usages are getting wider enough to be used as a power source for hybrid ship and electric propulsion ship, it is necessary to manage more strictly. Hybrid ship has power supply units connected to the packets to produce more than 500kWh large power source, and therefore, A number of the communication modules and wires need to implement the wire inspection and monitor system(WIIMS) that allows monitoring server to transmit detecting voltage, current and temperature data, which is required for the management of the batteries. This paper implements a low price type wireless inspection and monitoring system(WILIMS) of the lithium ion battery for hybrid vessels using BLE wireless communication modules and power line modem( PLM), which have the advantages of low price, no electric lines compared to serial communication inspection systems(SCIS). There are state of charge(SOC), state of health(SOH) in inspection parts of batteries, and proposed system will be able to prevent safety accidents because it allows us to predict life time and make a preventive maintenance by checking them at regular intervals.