• 제목/요약/키워드: 성장 곡선

검색결과 517건 처리시간 0.028초

Growth of Zn0.4Fe2.6O4 Thin Films using Pulsed Laser Deposition and their Crystal Structural and Magnetic Properties (Pulsed Laser Deposition을 이용한 Zn0.4Fe2.6O4 박막의 합성과 그 결정성 및 자기적 특성의 연구)

  • Jang, A.N.;Song, J.H.;Park, C.Y.
    • Journal of the Korean Magnetics Society
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    • 제21권3호
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    • pp.88-92
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    • 2011
  • We grew $Zn_{0.4}Fe_{2.6}O_4$ thin films using Pulsed Laser Deposition and studied their crystal structure and magnetical characteristics as a function of growth temperature ($T_g$). For the film with $T_g=300^{\circ}C$, X-ray reflections from ${\alpha}-Fe_2O_3$ and ZnO were observed. However, when $T_g$ was increased from 300 to $500^{\circ}C$, crystal structure of inverse spinel was stabilized with the crystal orientation of $Zn_{0.4}Fe_{2.6}O_4(111)/Al_2O_3(0001)$ without any detection of ${\alpha}-Fe_2O_3$ and ZnO phases. The surface morphology shows flattening behavior with increasing $T_g$ from 300 to $500^{\circ}C$. These observations indicate that Zn is substituted into tetrahedron A-site of the inverse-spinel $Fe_3O_4$. M-H curves exhibit clear ferromagnetism for the sample with $T_g=500^{\circ}C$ whereas no ferromagnetism is observed for the film with $T_g=300^{\circ}C$.

Effect of CH3COOH Concentration on Characteristics of Fe2O3Supported δ-alumina Catalyst by Hydrothermal Method (CH3COOH 농도가 수열법으로 제조된 Fe2O3 담지 감마알루미나 촉매의 특성에 미치는 영향)

  • 박병기;이정민;서동수
    • Journal of the Korean Ceramic Society
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    • 제40권8호
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    • pp.758-764
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    • 2003
  • The cylindrical ${\gamma}$-alumina pellets were prepared by forming, hydration, drying and calcination after mixing amorphous alumina and pore generating agent with water. Concentration of Fe(NO$_3$)$_3$ㆍ9$H_2O$ that was catalyst precursor was fixed and made mixing solution that changed concentration of $CH_3$COOH in range of 2.5~20%, and here ${\gamma}$-alumina pellets were immerged and were hydrothermaly treated for 3 h at $200^{\circ}C$. And then we investigated creation and change of crystal, pore characteristics, $N_2$ adsorption and desorption isotherms, changes of acid site and mechanical strengths etc. According to the concentration of $CH_3$COOH, the crystals grew to acicular shape of 0.5~2${\mu}m$ length, and crystal structure showed the pseudo-boehmite structure. When hydrothermaly treated in 10% $CH_3$COOH solution, pore volume between 100~1000 $\AA$ was highest by 0.86 cc/g, and width of hysteresis curved line due to $N_2$ adsorption/desorption appeared as was smallest. When concentration of $CH_3$COOH was in range of 5~15%, new C-H functional groups were formed. Mechanical strength of pellets was highest by 1.35 MPa when $CH_3$COOH concentration was 2.5%.

Analysis of the Maximum Heat Release Rate in Accordance with the Test Method of the Flame Retardant Performance for Pipe Insulation (배관용 보온재의 난연 성능 시험방법에 따른 최대 발열량 분석)

  • You, Woo Jun;Park, Jung Wook;Sin, Yeon Je;Park, Hyeong Gyu;Lim, Ohk Kun
    • Fire Science and Engineering
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    • 제34권1호
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    • pp.18-25
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    • 2020
  • In this study, the heat release rate of pipe insulation is analyzed by considering the installation status in accordance with the standards ISO 20632 and NFPA 274. The flame retardation rate was evaluated for six types of test samples: polyethylene foam covered with beaten silver (PE(S)), PE foam tapped (PE(N)), elastomeric closed cell thermal insulation (rubber), Japanese PE foam (PE(J)), Japanese polyurethane foam (PU(J)), and Japanese styro form (ST(J)) by EN 13501-1 and fire growth curve. The results show that PU(J), PE(J), and PE(N) were Class E and ultra-fast, NFPA 274 test standards for Class D and Fast, and PE(S) by ISO 20632 were Class C and Slow, and Rubber and ST(J) were Classes and Low. However, the changes in the time-averaged maximum heat release rate for each test standard (ISO 20632 and NFPA 274) to evaluate the flame retardation rate differed among identical materials. This means that the fundamental study is necessary to analyze the more accurate reasons.

Experimental and Analytical Evaluation of the Seismic performance of a Concrete Box Structure Strengthened with Pre-flexed Members (프리플렉스 부재를 이용한 콘크리트 박스 구조물 내진보강에 관한 실험 및 해석적 평가)

  • Ann, Ho-June;Song, Sang-Geun;Min, Dae-Hong;An, Sang-Mi;Kong, Jung-Sik
    • Journal of the Computational Structural Engineering Institute of Korea
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    • 제29권5호
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    • pp.397-403
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    • 2016
  • During the rapid economic growth in Korea since the 1970s, many underground facilities were constructed such as under passes and railways. Seismic design has been mandated in 1988, but the structures built before 1988 were not reflected on the seismic design. Accordingly, these underground structures require effective seismic reinforcing methods to ensure safety when the earthquake happens. By these reasons, in this study, using the proposed pre-flexed members, RC box structure was analyzed for seismic reinforcement of the corner. This method is based on a principle that enlarging the resistance against the external force by installing the pre-flexed member to the box structure corner. To evaluate validity, a newly developed member with CornerSafe was compared with traditional type reinforcement using experiments and finite element analysis. In finite element mode, nonlinearity of steel was modeled based on J2 plasticity model and concrete was based on CEB FIP MODEL CODE 1990. Also, composite ratios of box and pre-flexed member were computed for design application. The reinforcement and box structure were analyzed under the bond condition completely attached by the tie, and the results of experiment and finite element analysis were same in the force-displacement curve.

Influence of the thermal preheating for the GaAs(100) substrate exerted on ZnTe epilayer (GaAs(100) 기판에 대한 열에칭이 ZnTe 에피층에 미치는 영향)

  • 남성운;유영문;오병성;이기선;최용대;정호용
    • Journal of the Korean Vacuum Society
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    • 제7권4호
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    • pp.348-354
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    • 1998
  • To investigate an influence of the thermal preheating for the substrates exerted on the heteroepilayers, the ZnTe epilayers are grown on the GaAs (100) at the substrate temperature of 450~$630^{\circ}C$ by hot wall epitaxy (HWE). For this purpose, double crystal rocking curve (DCRC) and photoluminescence (PL) are measured. The full width at half maximum of DCRC are the smallest in the ZnTe epilayers grown on the GaAs thermally etched at around both $510^{\circ}C$ and $590^{\circ}C$. However, at around $550^{\circ}C$ they increase due to the reconstruction of the atoms in the surface. And they increase due to the oxide layer at below $490^{\circ}C$ and due to the surface defects at above $610^{\circ}C$. From PL analysis, the full width at half maximum of the light hole exciton $X_{1s,th}$ and of the second-order Raman line increase at around $550^{\circ}C$. With the increasing preheating temperature, the intensities of Y-bands and of the oxygen bound exciton (OBE) peak related to an oxide layer on the GaAs surface generally decrease. From these experimental results, it's confirmed that the GaAs substrate thermally etched influences the ZnTe pilayers.

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Population Dynamics of Mabled sole Limanda yokohamae($G{\"{U}}NTHER$) in Tokyo Bay, Japan (동경만산 문치가자미Limanda yokohamae($G{\"{U}}NTHER$)의 자원양 변동의 해석)

  • PARK Jong-Soo;SIMIZU Mako-to
    • Korean Journal of Fisheries and Aquatic Sciences
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    • 제24권1호
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    • pp.1-8
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    • 1991
  • Population dynamics of Matted sole Limanda yokohamae($G{\"{U}}NTHER$) in Tokyo bay, Japan has been studied by virtual population analysis (VPA) for multi cohort and experimental fishing. Based on the biological data, the present parameters of the Limanda yekohamae stock at the Tokyo bay, Japan were estimated as follows: natural mortality coefficient(M) were 0.313 for male and 0.250 for female, terminal fishing mortality coefficient(F) were 2.190 for male, and 0.798 for female, rate of exploitation(E) was $30\%\;to\;50\%$. From the result of virtual population analysis for multi cohort, the population size were estimated from 3,5000,000 to 9,200,000 fishes, according to the result of experimental fishing, estimated stock size were 2,400,000 to 8,700,000 fishes. Stock size difference of the two methods were about two times in 1987, however, other years has been showed from 0.8 to 1.5 times. Both method has been showed same increase and decrease tendency of the c. p. u. e. and catches. From the isopleth diagram plot by Beverton and Holt's yield per recruit, the catches could be increase two times for female, 1.3 times for male than present aspects by the fishing management. And further, as reducing fishing effort, extension of mesh size and rising the length at first caputre, are reasonable in order to manage the stock at the optimum level.

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Regional frequency analysis using spatial data extension method : I. An empirical investigation of regional flood frequency analysis (공간확장자료를 이용한 지역빈도분석 : I. 지역홍수빈도분석의 실증적 검토)

  • Kim, Nam Won;Lee, Jeong Eun;Lee, Jeongwoo;Jung, Yong
    • Journal of Korea Water Resources Association
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    • 제49권5호
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    • pp.439-450
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    • 2016
  • For the design of infrastructures controlling the flood events at ungauged basins, this study tries to find the regional flood frequencies using peak flow data generated by the spatial extension of flood records. The Chungju Dam watershed is selected to validate the possibility of regional flood frequency analysis using the spatially extended flood data. Firstly, based on the index flood method, the flood event data from the spatial extension method is evaluated for 22 mid/smaller sub-basins at the Chungju Dam watershed. The homogeneity of the Chungju dam watershed was assessed in terms of the different size of watershed conditions such as accumulated and individual sub-basins. Based on the result of homogeneity analysis, this watershed is heterogeneous with respect to individual sub-basins because of the heterogeneity of rainfall distribution. To decide the regional probability distribution, goodness-of fit measure and weighted moving averages method from flood frequency analysis were adopted. Finally, GEV distribution was selected as a representative distribution and regional quantile were estimated. This research is one step further method to estimate regional flood frequency for ungauged basins.

Gas Sensing Properties and Mechanism of the $\textrm{SnO}_2-\textrm{In}_2\textrm{O}_3$ System Prepared by Coprecipitation Method (공침법으로 제조된 $\textrm{SnO}_2-\textrm{In}_2\textrm{O}_3$ 계의 가스감응특성 및 감응기구)

  • Yun, Gi-Hyeon;Im, Ho-Yeon;Gwon, Cheol-Han;Yun, Dong-Hyeon;Kim, Seung-Ryeol;Hong, Hyeong-Gi;Lee, Gyu-Jeong
    • Korean Journal of Materials Research
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    • 제8권9호
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    • pp.813-818
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    • 1998
  • Ultrafine powders of $\textrm{In}_{2}\textrm{O}_{3}$-doped $\textrm{SnO}_{2}$ were synthesized by a coprecipitation method and the effects of pH value and the amount of In2Q addition on particle size were investigated. The influence of pH value on particle size could be negligible, whereas the amount of $\textrm{In}_{2}\textrm{O}_{3}$ has influenced on particle size and specific surface area. The gas sensitivity to hydrocarbOn($\textrm{C}_{3}\textrm{H}_{8}$, $\textrm{C}_{4}\textrm{H}_{10}$) increased with $\textrm{In}_{2}\textrm{O}_{3}$ addition and reached a maximum at 3wt.% addition. From the results of impedance analysis and I-V characteristics. it was showed that the agglomeration structure of particles and the boundaries between agglomerates were the important factors to determine the gas sensing mechanism.

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Morphology of La-Co substituted SrM ferrite (La-Co 치환량에 따른 스트론튬 페라이트의 미세구조)

  • Jang Se-Dong
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 한국자원리싸이클링학회 2004년도 13회 산화철워크샵
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    • pp.27-34
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    • 2004
  • This experiment was carried out to examine the effects of morphology on properties of La-Co substituted SrM ferrite. The magnetic properties of calcined and sintered materials varied with the substitutional amount of La and Co elements in Sr-ferrite. In the substituted SrM ferrite, the atomic fraction x of La is directly related to the mole ratio n of iron oxide and the atomic fraction y of Co by equation x=2ny. The HcJ values of the calcined powder were about 270 kA/m and 240 kA/m with x=0.3 and K=0.2, respectively at stoichiometriy, n=6.0. Crystallites of the sintered material were grown with a plate shape, and their size decreased with increasing mole ratios. Such a shape was caused by the initial state of crystallite formed after calcination. In case of x=0.3 and n=6.0, Br was 415 mT and HcJ was 355 kA/m, and in x=0.2 and n=6.0, Br was 410 mT and HcJ was 370kA/m. The squareness in 2nd quarter of BH curve with x=0.2 was smoothly improved compared with x=0.3

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Root Colonization and Quorum Sensing of the Antagonistic Bacterium Pseudomonas fluorescens 2112 involved in the Red-pepper Rhizosphere (생물방제균 Pseudomonas fluorescens 2112의 고추 근권정착능과 Quorum-sensing 기능)

  • Jung, Byung-Kwon;Kim, Yo-Hwan;Kim, Sang-Dal
    • Microbiology and Biotechnology Letters
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    • 제41권1호
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    • pp.105-111
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    • 2013
  • Biofilm formation of multifunctional plant growth promoting rhizobacterium (PGPR), Pseudomonas fluorescens 2112 is necessary for P. fluorescens 2112 to have a positive impact on the rhizosphere of red-pepper. This study investigated whether signal molecules of the quorum sensing AHLs are produced in order to confirm biofilm formative ability. Through the use of Petri dish bioassays a blue circle formed evidence of AHLs. It was confirmed that P. fluorescens 2112 produced six-carbon-chain-long AHLs by TLC bioassay. The bacterial density of P. fluorescens 2112 on the top and bottom of pepper plant roots was estimated as $3{\times}10^5$ and $8{\times}10^3$ CFU/g root, respectively. P. fluorescens 2112 exist more with high-density of $3.5{\times}10^6$ CFU/g soil at a depth of 1 cm but at a low-density of $1.1{\times}10$ CFU/g soil at a depth of 5 cm, from the surface of rhizosphere soil. In addition, biofilm formation of P. fluorescens 2112 on the epidermises and the tips of the red-pepper roots were confirmed visually by SEM. Thus, the production of AHLs by P. fluorescens 2112 brings about quorum sensing signaling and the formation of biofilm on the roots which has a positive effect on economically important crops such as red-pepper by additionally producing a variety of antifungal substances and auxin.