• Title/Summary/Keyword: 섬유활성탄

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Removal of Hydrogen Sulfide by Using Sodium Carbonate Impregnated Activated Carbon Fiber (탄산나트륨 첨착섬유활성탄을 이용한 황화수소의 제거)

  • Jung, Hun-Suck;Won, Yong Sun;Siregar, Devi Marietta;Mission, Sophie Kavugho;Lim, Jun-Heok
    • Clean Technology
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    • v.23 no.1
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    • pp.113-117
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    • 2017
  • We prepared sodium carbonate impregnated activated carbon fiber and evaluated its availability for hydrogen sulfide removal by the comparison with the counterpart, sodium carbonate granular impregnated activated carbon. The sodium carbonate impregnated concentration and immersion duration were chosen as two primary parameters. First, the hydrogen sulfide adsorption capacity increased in proportion to the impregnated concentration up to 3 wt%, above which the sodium carbonate impregnated amount rarely showed an increase due to the pore filling effect for both cases. The optimal impregnated concentration was thus set to 3 wt%. Meanwhile, impregnated activated carbon fiber required only half of the immersion duration compared with granular impregnated activated carbon, while showing a 30% increase on the hydrogen sulfide removal capacity. The greater specific area of impregnated activated carbon fiber explained it. In conclusion, we evaluated advantage of preparation time and improved hydrogen sulfide adsorption capacity by impregnate sodium carbonate, which is capable of reacting with hydrogen sulfide chemically, onto the activated carbon fiber with improved specific area.

Evaluation of Dispersion of Activated Carbon Fiber in Mortar Using Electrical Resistivity Method (전기저항 측정을 통한 모르타르 내의 섬유활성탄의 분산성 평가)

  • Lee, Bo Yeon;Lee, Jae Seoung
    • Journal of the Korea Concrete Institute
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    • v.29 no.3
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    • pp.283-290
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    • 2017
  • Various types of fibers are utilized in cementitious materials in order to improve their performances. Here, the extent of fiber dispersion is of key importance regardless of the purpose of using fiber. In this study, activated carbon fiber dispersion in mortar samples was evaluated using electrical resistivity method. In particular, the extent of fiber dispersion was compared per mixing methods and surface treatments. The results suggest that the surface resistivity method is capable of evaluating dispersion of activated carbon fiber and that ultrasound dispersion method is superior to mortar mixer and hand mixer method. The use of superplasticizer improved dispersion but acid treatment was not effective.

Removal of Ammonia in Water using Acid-impregnated Activated Carbon and Dynamic Membrane System (산 첨착활성탄과 동적막 공정을 이용한 수중 암모니아 제거)

  • Choi, Won Kyung;Shin, Dong-Ho;Lee, Yong Taek
    • Applied Chemistry for Engineering
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    • v.17 no.3
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    • pp.310-316
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    • 2006
  • In this study, activated carbon in a powder form was used to remove dissolved ammonia which causes a fouling smell in water. Since the adsorption capacity of common powder activated carbon is not high enough, we prepared powder activated carbon deposited on an acid solution to enhance the adsorption capacity. The acid-impregnated activated carbon was applied on the surface of porous fibril support ($10{\sim}50{\mu}m$) by which adsorption and separation processes take place simultaneously by varying effective pressure. As the result, the ammonia removal efficiency is above 60% in the mixing process which is 10~15% higher than general powder activated carbon. From the result of an experiment on the pure permeable test of a dynamic membrane, its transmittance is 400~700 LMH (liter per hour), indicating that the prepared membrane works as a microfiltration membrane. Therefore, it is expected that the membrane prepared in this way would improve the efficiency of water treatment than conventional membranes.

Effective Absorption Capacity of Highly Absorptive Materials using Isothermal Calorimetry, Considering the Effect of Specific Surface Area (등온열량계를 사용한 고흡수성 재료의 유효흡수율 측정: 비표면적의 영향)

  • Lee, Bo Yeon
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.2
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    • pp.49-56
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    • 2018
  • The use of highly absorptive materials in cement-based materials is increasing for internal curing purpose. However, calculation of correct absorption capacity of such materials is not easy, which leads to change in the effective water-to-cement ratio of cement paste by either absorbing or releasing water. In this study, effective absorption capacity of a highly absorptive material was found using isothermal calorimetry. Moreover, the effect of specific surface area was investigated. It was found that the method was capable of finding effective water absorption capacity of activated carbon fiber. For the activated carbon fiber used in this research, the effect of specific surface area was negligible because the high BET surface area was due to micropores less than 1nm, which does not affect the rate of hydration curve. Thus, the effective absorption capacity of such materials can be found successfully using this method.

Liquid Phase Adsorption of Activated Carbon Fibers (활성탄소섬유의 액상흡착)

  • Moon, Dong Cheul;Kim, Chang Soo;Park, Il Yeong;Kim, Mi Ran;Hong, Seung Soo;Lee, Kwang Ho;Lee, Chang Gi
    • Analytical Science and Technology
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    • v.13 no.5
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    • pp.573-583
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    • 2000
  • Activated carbon fibers (ACFs) were prepared from various precursors of plantic, synthetic, and mixed fabrics of viscous rayon and cotton. Their adsorption performances of phenol and methylene blue in aqueous phase were evaluated through their adsorption isotherms, adsorption rates and breakthrough curves. The two adsorbates showed type I adsorption isotherm on ACFs. Adsorption rates to ACFs were 100 fold faster than to GAC. The effective diffusion coefficients of the adsorbates in ACFs were twenty fold greater than in GAC. The ACFs removed completely ten organic pollutants from a prepared water specimens through the 2nd column of a natural filtration method where 50 L of the water samples were treated.

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Influence of Textural Structure by Heat-treatment on Electrochemical Properties of Pitch-based Activated Carbon Fiber (열처리 온도에 의한 피치계 활성탄소섬유의 기공구조 변화가 전기화학적 특성에 미치는 영향)

  • Kim, Kyung Hoon;Park, Mi-Seon;Jung, Min-Jung;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.26 no.5
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    • pp.598-603
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    • 2015
  • In this study, electrochemical properties of pitch-based activated carbon fibers (ACFs) were investigated by different heat-treatment temperature of the pitch-based ACFs in order to improve the specific capacitance of electric double-layer capacitor (EDLC). The ACFs were prepared by different heat-treatment temperatures of 1050 and $1450^{\circ}C$, after activation with 4 M KOH at $800^{\circ}C$ using stabilized pitch fiber. The specific surface area of prepared ACFs increased from $828m^2/g$ to $987m^2/g$, also the micropore and mesopore volumes of prepared ACFs were increased. These results because pore was produced by desorbing oxygen and hydrogen elements within the ACFs, and pore size was increased by contraction ACFs by heat-treatment process. Because of the porous properties, the specific capacitance was increased from 73 F/g to 119 F/g using cyclic voltammetry with 1 M $H_2SO_4$ at scan rates of 5 mV/s.

Development of Carbonization Technology and Application of Unutilized Wood Wastes(II) - Carbonization and it's properties of wood-based materials - (미이용 목질폐잔재의 탄화 이용개발(II) - 수종의 목질재료 탄화와 탄화물의 특성 -)

  • Kong, Seog-Woo;Kim, Byung-Ro
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.2
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    • pp.57-65
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    • 2000
  • Objective of research is obtain fundamental data of carbonized wood wastes for soil condition, de-ordorization, absorption of water, carrier for microbial activity, and purifying agent for water quality of river. The carbonization technique and the properties of carbonized wood wastes(wood-based materials) were analyzed. Proximate analysis showed the wood-based materials contains 0.37~2.27% ash, 70~74% volatile matter, and 17~20% fixed carbon. As carbonization temperature was increased, the charcoal yield was decreased. However, no difference in charcoal yield was found due to time increase. The specific gravity after the carbonization decreased about 30~40% comparing to green wood. The charcoal had 1.08~4.18% ash, 5.88~13.79% volatile matter, and 80.15~90.94% fixed carbon. The pH of plywood and particleboard(pH 9 at $400^{\circ}C$, pH 10 at $600^{\circ}C$ and $800^{\circ}C$) made charcoals was higher than that of fiberboard. The water-retention capacity was not affected by the carbonization temperature and time. The water-retention capacity within 24h was about 2~2.5 times of sample weight, and the Equilibrium moisture content(EMC) became 2~10% after 24h. EMC of charcoal from the thinned trees were 9.40~11.82%($20^{\circ}C$, RH 90%), 6.87~7.61%($20^{\circ}C$, RH 65%), and 1.69~2.81%($20^{\circ}C$, RH 25%). EMC of charcoal from the wood-based materials under $20^{\circ}C$, relative humidity(RH) 90% was similar to EMC of charcoal from the thinned trees(9~11 %). However, under $20^{\circ}C$, RH 25.65%, EMC of charcoal from the wood-based materials were higher(2~3%) than EMC of charcoal from the thinned trees. Every charcoal from the wood-based materials fulfilled the criteria in JWWA K 113-1947.

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