• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2001.04a
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• pp.89-89
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• 2001

종이는 목재섬유와 물의 현탁액을 스크련을 통해 균일하게 분산시킨 판상섬유 제품 으로서 가격이 저렴하고, 열, 전기절연성, 필터기능, 난연성 및 폐기성이 우수하여 다양한 분 야에서 활용되고 있다. 특히 최근에는 종이의 고부가가치화, 차별화를 위하여 내열성, 전기 절연성, 내수성, 기계적 특성, 내약품성, 생체적응성을 지닌 다양한 기능지가 개발되어 식품, 전기, 전자, 건축, 화학, 의료 관련 산업에 있어서 주요 재료로 이용되고 있다. 특히 전기, 전 자산업 발전과 더불어 전기절연성이 우수한 종이의 역할과 수요는 크게 증대되고 있으며 산 업발전의 핵심적인 제품으로서 자리매김을 하고 있다. 하지만 국내의 경우 전기절연지와 관 련된 제품 및 생산기술 부족으로 전량을 수입에 의존하고 있는 실정이며, 그 수입량은 앞으 로 전기 및 전자 산업의 발전으로 인해 더욱 증가할 것으로 예상된다. 이러한 수입의존성을 극복하기 위해서는 전기절연지와 관련된 제품개발 및 생산기술에 관한 연구가 시급히 요청 되고 있다. 이러한 기술의 국산화는 수입 대체 효과 뿐만 아니라 관련 산업의 발전에도 기 여할 수 있을 것으로 예상되며 수출산업으로 성장할 수 있을 것으로 예상된다. 종이의 전기적 성질은 유전상수, 유전손실율과 같은 유전적 특성과 전기저항, 절연 파괴강도의 기계적 특성으로 구분할 수 있다. 종이의 전기적 성질 가운데 유전율은 전기장 에 대한 종이의 물리화학적인 반응으로 일반적으로 종이의 밀도와 종이를 구성하는 성분의 쌍극자 모멘트에 비례하며 온도에 따라서도 변화한다. 일반적으로 온도가 상승하면 열에너 지를 얻게된 쌍극자가 전기장에 배열됨으로써 유전율이 상승하지만 온도가 유리전이점 이상 으로 높아질 경우 열적 교란에 의해서 분극 능력이 감소하게 되어 유전완화 현상이 나타난 다. 전기절연지로 사용될 종이의 절연특성을 이해하기 위해서는 사용환경에 따른 유전적 특 성 및 tan$\delta$에 관한 연구가 펼요하다. 본 연구에서는 종이의 유전특성을 개선하기 위해서 펼름형성능력이 우수한 polyvinyl alcoholCPV A)과 aery lonitrile을 이용하여 시아노에틸화한 P PYA의 표면처리에 따른 종이의 유전적 특성의 변화를 검토하였다. 그 결과 PYA에 도입된 시아노에틸기에 의해 유전율을 증가시킬 수 있음을 확인하였다. 또 본 연구에 적용된 시험 범위에서는 온도상승에 따라 유전율이 상승하였다.

• Korean Chemical Engineering Research
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• v.48 no.6
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• pp.673-678
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• 2010

In the present study, mixed carbon-supported platinum(Pt) nanoparticles were prepared by a chemical reduction method of Pt precursor solution on two types of carbon materials such as activated carbons(ACs) and graphite nanofibers(GNFs). Average crystalline sizes and loading levels of Pt metal particles could be controlled by changing a content of GNFs. The highest electroactivity for methanol oxidation was obtained by preparing the carbon supports having 15 wt% GNFs. Furthermore, with an increase of GNFs content from 0% to 15%, an electrical conductivity was changed from $10^{-4}S/cm$ to $10^{-1}S/cm$. By an introduction of 10 wt% GNFs additive, the electroactivity of platinum particles was enhanced, but was saturated in the case of 15 wt% GNFs contents. This was related with the fact that the electroactivity change was dependent on the electrical conductivity of mixed carbon supports and Pt particle deposition content or deposition morphology.

• Elastomers and Composites
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• v.44 no.1
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• pp.22-33
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• 2009

Recently, elastomer-nanocomposites reinforced with low volume fraction of nanofillers have attracted great interest due to their fascinating properties. The incorporation of nanofillers, such as, layered silicate clays, carbon nanotubes, nanofibers, calcium carbonate, metal oxides or silica nanoparticles into elastomers improves significantly their mechanical, thermal, dynamic mechanical, barrier properties, flame retardancy, etc. The properties of nanocomposites depend greatly on the chemistry of polymer matrices, nature of nanofillers, and the method in which they are prepared. The uniform dispersion of nanofillers in elastomer matrices is a general prerequisite for achieving desired mechanical and physical characteristics. In this paper, current developments in the field of elastomer nanocomposites reinforced with layered silicates, silica, carbon nanotubes, nanofibers and various other nanoparticles have been addressed.

• Textile Coloration and Finishing
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• v.31 no.3
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• pp.135-146
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• 2019

A series of azo based disperse dyes were synthesized and applied to polyester(PET) fiber in supercritical carbon dioxide($ScCO_2$). Various aniline derivatives were used as diazo component and coupled with glycine ethylester or carbonic acid ethylester derivatives to give azo based disperse dyes. Depending on the various diazo substituents, absorption maxima varied from 415 to 529nm in acetone. Dyeing in $ScCO_2$ was carried out at $120^{\circ}C$ and 250bar pressure for 2hrs with 0.5% o.w.f. of dye concentration. Dyed PET fiber had excellent brightness and good light, washing and perspiration(acid/alkali) fastness properties.

• Membrane Journal
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• v.29 no.1
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• pp.30-36
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• 2019

In this study, we reported a solid-state supercapacitor consisting of titanium nitride (TiN) nanofiber and poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS) conducting polymer electrode and poly(vinyl alcohol) (PVA)-based polymer electrolyte membrane. The TiN nanofiber was selected as electrode materials due to high electron conductivity and 2-dimensional structure which is beneficial for scaffold effect. PEDOT-PSS is suitable for organic/inorganic composites due to good redox reaction with hydrogen ions in electrolyte and good dispersion in solution. By synergetic effect of TiN nanofiber and PEDOT-PSS, the PEDOT-PSS/TiN electrode showed higher surface area than the flat Ti foil substrate. The PVA-based polymer electrolyte membrane could prevent leakage and explosion problem of conventional liquid electrolyte and possess high specific capacitance due to the fast ion diffusion of small $H^+$ ions. The specific capacitance of PEDOT-PSS/TiN supercapacitor reached 75 F/g, which was much higher than that of conventional carbon-based supercapacitors.

• Composites Research
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• v.19 no.2
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• pp.20-27
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• 2006

The hybrid composite materials with non-woven tissue (NWT) was developed to improve the mechanical properties of conventional FRP composite materials. The hybrid prepreg with NWT consists of FRP prepreg and NWT prepreg. The NWT prepreg consists of NWT and polymer resin. The NWT has short fibers, discretely distributed with in-plane random orientation fibers. The purposes of this study of hybrid prepreg with NWT are (i) to increase the interlaminar properties(the fracture toughness and strength), (ii) to improve the mechanical properties and reliability, while maintaining a low cost, (iii) to introduce a tough and strong interlayer at critical positions to be required of strength in the laminate. To accomplish the above purposes, a production technique to decrease voids in NWT layers was proposed in this paper. The interlaminar failure characteristics of laminated composite materials was tremendously improved by hybrid concept with NWT.

• Applied Microscopy
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• v.36 no.2
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• pp.109-118
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• 2006

The physicochemical properties of damaged hair by irradiation of ultraviolet-B (UV-B) have been investigated by using transmission electron microscope and scanning electron microscope. The range of irradiation of hair irradiated for expectative 6 hours, 12 hours, 24 hours and 48 hours with stimulated ultraviolet ray. The treated hairs showed characteristic morphological damage pattern in the cornified cell of matrix and the cuticle following time past. The various sized vacuoles in the endocuticle of the cuticular cells was formed. The statistically significant differences in diameter of cuticular cell were observed in terms of tranverse swelling by formation of vacuoles. The hair cortex and matrix undergo long term exposure to UV-B radiation. The macrofibrils of cortex appeared to be affected most by UV-B, although the morphology and volume of melanin granule was not changed. The physicochemical destruction of hair matrix and cuticular cells is largely accelerated by long term irradiation of UV-B.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2012.03a
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• pp.49-49
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• 2012

바닥재 자카드직물에 사용이 예상되는 LMP(low meltig polyester) 복합사는 사염 시 높은 수축율 및 열융착의 가능성 때문에 일반적인 폴리에스테르의 염색조건에서는 염색이 불가하다. 따라서 적정의 수축율 내에서 가능한 염색조건에 대해 고찰하였다. LMP 복합사는 웅진케미컬에서 생산된 Regular PET/LMP(75:25) 260d/48f 원사를 사용하였다. 수축율은 KS K 0215에 준하여 측정하였다. 염색은 E-type 및 S-type(Foron Dark Blue S-WF) 분산염료를 사용하였으며, E-type 중에서는 아조계(Lumacron Blue SERL 200%) 와 안트라퀴논계(Foron Blue E-BL 150)의 2 종류를 사용하였다. 염색된 시료는 현미경 단면사진을 이용하여 염료의 내부확산을 확인하였으며, 환원세정 전후의 K/S 값을 측정하였다. LMP원사의 수축율을 시험한 결과 $90^{\circ}C$에서 9% 정도의 수축율을 나타내어, $90^{\circ}C$ 이상에서는 사염이 어려운 것으로 나타났다. 따라서 염색온도는 $80^{\circ}C$와 $90^{\circ}C$로 하였다. S-type의 염료를 이용한 경우 $90^{\circ}C$에서 4일 이상 염색해도 염착이 이루어지지 않아 대상 염료에서 제외하였다. E-type 염료인 경우 아조계는 흡진율은 높았으나 내부 regular PET에의 확산이 매우 느리고, 안트라퀴논계는 상대적으로 확산이 빠른 것으로 나타났다. 안트라퀴논계 분산염료는 $80^{\circ}C$에서 내부로의 확산에 4일 이상이 소요되며, $90^{\circ}C$에서는 2일 이상이 소요되었다. 이 후 환원세정에 의한 K/S 값의 변화 및 마찰견뢰도를 시험하였으며, 환원세정 후의 섬유단면 사진을 통해 염료의 migration성을 평가하였다.

• Journal of Adhesion and Interface
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• v.14 no.2
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• pp.75-81
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• 2013

Epoxy matrix based composites were fabricated by adding SiC nano fillers. The interfacial properties of composites were varied with different shapes of SiC nano fillers. To investigate the shape effects on the interfacial properties, beta and whisker type SiC nano fillers were used for this evaluation. The dispersion states of nano SiC-epoxy nanocomposites were evaluated by capacitance measurements. FE-SEM was used to observe the fracture surface of different structures of SiC-epoxy nanocomposites and to investigate for reinforcement effect. Interfacial properties between carbon fiber and SiC-epoxy nanocomposites were also evaluated by ILSS (interlaminar shear strength) and IFSS (interfacial shear strength) tests. The interfacial adhesion of beta type nanocomposites was better than whisker type.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.3
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• pp.581-593
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• 1990

A semi-solid alloy in which solid and liquid phase are co-existing is obtained by strirring of Al7075 molten metal. A semi-solid alloy is dependent on the corresponding temperature within the solid-liquid range, and the process parameters should be controlled accurately to obtain the homogeneous semi-solid alloy. The possibility o homogeneous fiber-reinforce aluminum alloy by addition of $Al_{2}$O$_{3}$ short fibers with vigorous agitation was investigated. The billet of composite materials was fabricated by squeeze casting, and homogeneous dipersion state of fibers in billet of fabricated metal matrix composites was observed. A slurry of semi-solid short fiber metal matrix composites is used in the direct rolling process, and this process showed the fabrication possibility of metal matrix composite sheets. The fabricated sheet was tested regarding vickers hardness, elongation and micro-structure. It has become clear that mashy state processing and working are very useful to obtain parts of composites material closed to near net shape.