• Polymer(Korea)
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• 제30권5호
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• pp.373-379
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• 2006

Polymerizable discotic liquid crystals containing diacetylene and acryloyl groups were formed through hydrogen bonding between phloroglucinol core and polymerizable pyridine derivatives, and their photopolymerization behavior was investigated. The discotic complexes exhibited discotic columnar and rectangular columnar mesophases depending on the number of aromatic rings. Photopolymerization of the discotic complexes was carried out by UV irradiation in the liquid crystalline state. IR and UV-Vis spectroscopy affirmed that diacetylene and acryloyl groups were selectively Polymerized, and that crosslinked polymers containing short conjugated diacetylene oligomers were produced by 1,4-addition. X-ray diffraction experiment showed that the columnar order in the discotic complex containing phenyl-pyridine moiety was maintained after photopolymerization, and that the rectangular columnar order in he discotic Complex with biphenyl units was changed to the lamellar order.

• Proceedings of the Korean Vacuum Society Conference
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.181-181
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• 2013

최근에 형광체 결정 입자의 크기와 적당한 활성제 이온의 종류를 선택하여 우수한 발광 특성을 갖는 세라믹 형광체를 합성하고자 많은 노력을 경주하고 있다. 본 연구에서는 비교적 간단한 장비로 구성되며, 볼밀을 통하여 초기 물질들을 혼합하고 분쇄하여 최적의 형광 특성을 갖는 형광체 분말을 비교적 용이하게 합성하기에 적합한 고상반응법을 사용하여 적색, 황색, 녹색 형광체 La2WO6:RE3+ (RE=Eu, Dy, Tb)를 제조하고자 한다. 사용한 초기 물질은 (99.99% 순도), (99.99%), (99.9%), (99.9%) (99.9%)을 화학 정량으로 준비하였고, 활성제 이온의 함량비를 0, 0.01, 0.05, 0.10, 0.20 mol로 각각 변화시켜 형광체를 제조하여 그것의 발광과 흡광, 결정 입자의 크기와 형상을 조사하였다. 이온이 도핑된 형광체의 경우에, 발광 스펙트럼은 이온의 함량비에 관계없이 모든 시료에서 전형적인 이온의 (j=1-4) 전이에 의한 발광 스펙트럼을 나타내었고, 가장 강한 적색 발광 파장은 611 nm에서 관측되었으며, 이온의 함량비가 0.15 mol에서 발광 피크가 장파장 쪽으로 10 nm 이동하였으며, 세 종류의 발광 스펙트럼의 세기는 최대를 나타내었다. 이온의 함량비가 더욱 증가함에 따라 모든 발광 스펙트럼의 세기는 순차적으로 감소하였다. 이 현상은 농도 소광 현상으로 해석 할 수 있다. 이온이 도핑된 형광체의 경우에, 이온의 함량비에 관계없이 모든 시료에서 이온의 전형적인 전이에 의한 발광 스펙트럼이 관측되었으며, j=13/2에서 가장 강한 황색 발광이 피크 581 nm에서 관측 되었다. 상대적으로 발광 세기가 약한 484 nm에 정점을 갖는 청색 발광스펙트럼은 전이 신호이다. 이온의 함량비가 0.10 mol 일 때 세 영역의 발광 스펙트럼의 세기는 최대를 나타내었다. 이온의 함량비가 증가함에 따라 모든 발광 스펙트럼의 세기는 순차적으로 감소하였다. 주 흡광 스펙트럼은 이온의 함량비에 관계없이 모든 시료에서 파장 250 nm에서 관측되었다. 이온이 도핑된 형광체의 경우에, 이온의 함량비에 관계없이 모든 형광체 분말은 발광 세기가 제일 강한 550 nm의 피크를 갖는 녹색 발광과 상대적으로 발광 세기가 약한 495와 590 nm에 피크를 갖는 청색과 주황색 발광 스펙트럼들이 각각 관측되었다. 이 발광 신호들은 Tb3+ 이온의 5D47Fj (j=4, 5, 6) 전이에 의해 발광된 신호임을 확인하였다.

• The Journal of the Acoustical Society of Korea
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• 제29권2호
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• pp.118-124
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• 2010

In this paper, design parameters of dynamic vibration absorber, which is used to reduce bending vibrations of a vehicle drive line, is optimized. For obtaining the correct dynamic response characteristics, a flexible-body drive line is made by applying the flexibility data extracted from vibration analysis of propeller shafts to the drive line dynamic model. Inner tube mass, rubber stiffness and rubber damping coefficient of the dynamic vibration absorber are taken as design parameters for optimization. To minimize the vertical acceleration of the drive line, a second-order regression equation of the objective function is generated by performing the central composite experimental design with 3 factors, 2 levels and 15 test runs. And the design parameters of the dynamic vibration absorber are determined by using optimization program. The vehicle model with optimized dynamic vibration absorber reduces the vertical acceleration peak of the drive line by 17.1 % in compared with the initial model.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• 제13권3호
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• pp.103-109
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• 2013

Miller-Rabin method is the most prevalently used primality test. However, this method mistakenly reports a Carmichael number or semi-prime number as prime (strong lier) although they are composite numbers. To eradicate this problem, it selects k number of m, whose value satisfies the following : m=[2,n-1], (m,n)=1. The Miller-Rabin method determines that a given number is prime, given that after the computation of $n-1=2^sd$, $0{\leq}r{\leq}s-1$, the outcome satisfies $m^d{\equiv}1$(mod n) or $m^{2^rd}{\equiv}-1$(mod n). This paper proposes a step-by-step primality testing algorithm that restricts m=2, hence achieving 98.8% probability. The proposed method, as a first step, rejects composite numbers that do not satisfy the equation, $n=6k{\pm}1$, $n_1{\neq}5$. Next, it determines prime by computing $2^{2^{s-1}d}{\equiv}{\beta}_{s-1}$(mod n) and $2^d{\equiv}{\beta}_0$(mod n). In the third step, it tests ${\beta}_r{\equiv}-1$ in the range of $1{\leq}r{\leq}s-2$ for ${\beta}_0$ > 1. In the case of ${\beta}_0$ = 1, it retests m=3,5,7,11,13,17 sequentially. When applied to n=[101,1000], the proposed algorithm determined 96.55% of prime in the initial stage. The remaining 3% was performed for ${\beta}_0$ >1 and 0.55% for ${\beta}_0$ = 1.

• Applied Chemistry for Engineering
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• 제1권2호
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• pp.140-146
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• 1990

Polydimethylsiloxane(PDMS) containing [N, N'-bis (3- (salicylidene amino) propyl) amine Co(II)] (Co(saldpt)) as a fixed oxygen carrier was synthesized. UV-visible spectra of the membrane demonstrated that Co(saldpt) binded molecular oxygen specificaaly and reversibly. From time lag method experiment, it was found that both oxygen permeability and diffusibity increase with decreasing upstream pressure, while solubility maintain nearly constant. The maximum oxygen permeability and oxygen selectivity over nitrogen obtained was 18.6 barrer and 4, respectively, at 25 mmHg and $40^{\circ}C$ from the the PDMS membrane containing 1 wt% of Co(saldpt). Facilitation behavior was explained in terms of the dual sorption model.

• Membrane Journal
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• 제25권3호
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• pp.248-255
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• 2015

Aminated polyetherimide membrane synthesized in the laboratory according to amine ratio was used for measurement of gas permeability, diffusivity, and solubility about carbon dioxide, nitrogen, methane, oxygen, and sulfur dioxide with Time-lag method at room temperature. Generally, gas permeability is totally decreased because the more amination rate reacted to the main chain of amine groups, the more intermolecular space became narrow. However, gas permeability of sulfur dioxide was increased due to combination of sulfur dioxide and amine groups have acid and base properties respectively. Diffusivity and solubility of dry gas are totally decreased excluding sulfur dioxide as increasing amination rate. In case of sulfur dioxide, however, diffusivity as well as solubility was increased as increasing amination rate. Selectivity of carbon dioxide/nitrogen showed 60 when amination rate was 3. In case of humid gas, gas permeability of carbon dioxide was 70 barrer when relative humidity showed 100, and selectivity with nitrogen approximately showed 18.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• 제27권1호
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• pp.69-75
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• 2016

In this paper, we propose a inverse synthetic aperture radar(ISAR) rotational motion compensation(RMC) method to remove residual blurring caused by non-uniform rotational motion of a target. First, a range bin having an isolated scatterer is selected. Next, polynomial phase signal in the selected range bin is estimated by using both Fourier transform(FT) and polynomial-phase transform(PPT). Finally, a new slow time variable that uniformly samples radar signal along the aspect angle directions is defined by using the estimated phase signal, and we interpolate radar signal in terms of the new time variable. As a result, rotational motion to blurr ISAR images is removed, and focused ISAR images are obtained. Simulation results using battleship model validate the robustness and effectiveness of our proposed RMC method.

• Journal of the Korean Electrochemical Society
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• 제3권2호
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• pp.69-71
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• 2000

Redox-active calix[4]arenes with carboxylic acid and disulfide groups were prepared and spontaneous deposition on silver and gold surfaces was observed. Owing to their unusual structure, the calix[4]arenes exhibit selective affinity fur alkaline earth metal ions in aqueous media. When annular ionophores are immobilized on the surface, voltammetric and spectroscopic studies show the entrapment of metal ions. Furthermore, it was possible to reversibly capture and remove the ions using strong chelating agents such as ethylenediaminetetraacetic acid (EDTA).

• Journal of Korean Society of Steel Construction
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• 제11권3호통권40호
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• pp.311-318
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• 1999

Concrete filled tubular(CFT) members have many structural and constructional advantages. The prefabrication of CFT members can be thought an idea for the good qualify control of concrete. The objective of this study is to suggest the construction method of prefab CFT beam-columns. Tests are performed to understand their structural behaviors. The opening space between prefab CFT members and the size of tubular members are the parameters of this study. The results of this study will be based on the suggestion of prefab CFT.

• The Journal of Korean Institute of Communications and Information Sciences
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• 제37A권12호
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• pp.1031-1037
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• 2012

We study an algorithm that can efficiently find square roots and cube roots by modifying Tonelli-Shanks algorithm, which has an application in Number Field Sieve (NFS). The Number Field Sieve, the fastest known factoring algorithm, is a powerful tool for factoring very large integer. NFS first chooses two polynomials having common root modulo N, and it consists of the following four major steps; 1. Polynomial Selection 2. Sieving 3. Matrix 4. Square Root. The last step of NFS needs the process of square root computation in Number Field, which can be computed via square root algorithm over finite field.