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Experimental Analysis on Filtration-Permeation: Influence of the Type and Sheets of Filter Media, and Filtration Pressure (여과-투과에 대한 실험적 분석: 여과매체의 종류, 여과매체의 매수, 여과압력의 영향)

  • Yim, Sung-Sam;Song, Yun-Min
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.317-327
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    • 2012
  • The average specific cake resistance, the most important indicator for cake filtration and solid-liquid separation, is measured by filtration experiment. But the exact value is difficult to measure because of the other influences such as sedimentation during filtration. This study, a little more stable method named filtration-permeation is proposed for measuring average specific cake resistance. The filtration-permeation is composed of permeation of particle eliminated water through pre-formed cake by filtration. Using 1 wt% calcium carbonate suspension, the filtration-permeation experiments were performed for 8 kinds of filter media at the conditions of 0.5 atm and 0.2 atm, 1 and 3 sheets of filter media. At each specific condition, three to five times filtration-permeation were accomplished. As a result, stable permeation speed is measured. According to this experimental result, the characteristics of permeation and the effect of sedimentation are analyzed with Ruth's equation. The one way analysis of variance (one way ANOVA) is applied to the average specific cake resistances of filtration and permeation obtained with the selected three kinds of filter media. The average specific cake resistances between 0.5 atm and 0.2 atm by filtration do not distinguished, but those by permeation is perfectly distinguished. The experimental results during permeation have a very narrow distribution than that measured during filtration. The analysis of filtration experiments, it was verified that the resistance of filter medium by traditional method is of no significance. Finally, the migration of small particles through the medium composed of fiber glass at low pressure was studied.

Study on the Pyrolysis Kinetics of Deasphalted Oil Using Thermogravimetric Analysis (열중량 분석법을 이용한 Deasphalted Oil의 열분해 특성 분석)

  • Shin, Sang Cheol;Lee, Jung Moo;Lee, Ki Bong;Jeon, Sang Goo;Na, Jeong Geol;Nho, Nam Sun
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.391-397
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    • 2012
  • The depletion of conventional oil reserves and the increasing energy need in developing countries such as China and India result in exceeding oil demand over supply. As a solution of the problem, the efficient utilization of heavy oil has been receiving more and more interest. In order to utilize heavy oil, upgrading processes are required. Among the upgrading processes, thermal decomposition is thought to be relatively simple and economical. In this study, to understand basic characteristics of thermal decomposition of heavy oil, we conducted pyrolysis experiments of deasphalted oil (DAO) produced by a solvent deasphalting process. DAO is a mixture of many components and consists mainly of materials of carbon number 20~40. For the comparison with results of DAO pyrolysis, additional pyrolysis experiments with single materials of carbon number 30 ($C_{30}H_{62}$, $C_{30}H_{58}O_4S$, $C_{30}H_{63}O_3P$) were conducted. Pyrolysis experiments were carried out non-isothermally with variation of heating rate (10, 50, $100^{\circ}C$/min) in a thermogravimetric analyzer. Average pyrolysis activation energy determined by using Arrhenius method, Ingraham and Marrier method, and Coats and Redfern method was 72~99 kJ/mol. In the activation energy calculated by Ozawa-Flynn-Wall method, DAO had wider variation than other single materials.

Adsorption Equilibrium, Kinetics and Thermodynamics Studies of Malachite Green Using Zeolite (제올라이트를 이용한 말라카이트 그린의 흡착평형, 동력학 및 열역학 연구)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.18 no.1
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    • pp.76-82
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    • 2012
  • The paper includes utlization of zeolite as potential adsorbent to remove a hazardous malachite green from waste water. The adsorption studies were carried out at 298, 308 and 318 K and effects of temperature, contact time, initial concentration on the adsorption were measured. On the basis of adsorption data Langmuir and Freundlich adsorption isotherm model were also confirmed. The equilibrium process was described well by Freundlich isotherm model, showing a selective adsorption by irregular energy of zeolite surface. From determined isotherm constants, zeolite could be employed as effective treatment for removal of malachite green. From kinetic experiments, the adsorption process followed the pseudo second order model, and the adsorption rate constant ($k_2$) decreased with increasing initial concentration of malachite green. Thermodynamic parameters like activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption. The activation energy calculated from Arrhenius equation indicated that the adsorption of malachite green on the zeolite was physical process. The negative free energy change (${\Delta}G^{\circ}$ =-6.47~-9.07 kJ/mol) and the positive enthalpy change (${\Delta}H^{\circ}$ = +32.414 kJ/mol) indicated the spontaneous and endothermic nature of the adsorption in the temperature range 298~318 K.

UA Tree-based Reduction of Speech DB in a Large Corpus-based Korean TTS (대용량 한국어 TTS의 결정트리기반 음성 DB 감축 방안)

  • Lee, Jung-Chul
    • Journal of the Korea Society of Computer and Information
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    • v.15 no.7
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    • pp.91-98
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    • 2010
  • Large corpus-based concatenating Text-to-Speech (TTS) systems can generate natural synthetic speech without additional signal processing. Because the improvements in the natualness, personality, speaking style, emotions of synthetic speech need the increase of the size of speech DB, it is necessary to prune the redundant speech segments in a large speech segment DB. In this paper, we propose a new method to construct a segmental speech DB for the Korean TTS system based on a clustering algorithm to downsize the segmental speech DB. For the performance test, the synthetic speech was generated using the Korean TTS system which consists of the language processing module, prosody processing module, segment selection module, speech concatenation module, and segmental speech DB. And MOS test was executed with the a set of synthetic speech generated with 4 different segmental speech DBs. We constructed 4 different segmental speech DB by combining CM1(or CM2) tree clustering method and full DB (or reduced DB). Experimental results show that the proposed method can reduce the size of speech DB by 23% and get high MOS in the perception test. Therefore the proposed method can be applied to make a small sized TTS.

A Microstrip Bandpass Filters Using Dual-Behavior Resonators Integrated with EBG Structures to Improve Stopband Response (저지대역 개선을 위해 EBG구조를 집적한 DBR 마이크로스트립 대역통과 여파기)

  • Seok Chang-Heon;Jang Jae-Sam;Lim Jung-Sup;Hwang Ho-Soon;Jung Young-Ho;Lee Dong-Cheol;Lee Min-Soo
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.43 no.7 s.349
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    • pp.162-169
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    • 2006
  • A Micorstrip Bandpass Filter Using DBRs for WLAN ($2.3{\sim}2.4GHz$) applications is designed and an EBG structure is employed in the ground plane of the filter to suppress the stopband responses of the filter. The number of DBRs is chosen as two in consideration of low insertion loss and small size of two filter. The center frequency of the filter to be designed is 2.35GHz and its bandwidth is 140MHz. The responses of two kinds of DBR filters (one with EBG and the other without EBG) are calculated and compared with the measurements. The experimental results are in good agreement with the calculations: The bandwidth and insertion loss of the filter with EBG structure are 3.8% and 1.7dB respectively, while those of the filter without EBG structure are 7% and 1.23dB. It is shown that the insertion loss of the filter is increased and its bandwidth is deceased due to the EBG structure. Also the stopband responses of the filters with EBG structures are shown to be much improved compared with those without EBG.

Low Complexity Video Encoding Using Turbo Decoding Error Concealments for Sensor Network Application (센서네트워크상의 응용을 위한 터보 복호화 오류정정 기법을 이용한 경량화 비디오 부호화 방법)

  • Ko, Bong-Hyuck;Shim, Hyuk-Jae;Jeon, Byeung-Woo
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.45 no.1
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    • pp.11-21
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    • 2008
  • In conventional video coding, the complexity of encoder is much higher than that of decoder. However, as more needs arises for extremely simple encoder in environments having constrained energy such as sensor network, much investigation has been carried out for eliminating motion prediction/compensation claiming most complexity and energy in encoder. The Wyner-Ziv coding, one of the representative schemes for the problem, reconstructs video at decoder by correcting noise on side information using channel coding technique such as turbo code. Since the encoder generates only parity bits without performing any type of processes extracting correlation information between frames, it has an extremely simple structure. However, turbo decoding errors occur in noisy side information. When there are high-motion or occlusion between frames, more turbo decoding errors appear in reconstructed frame and look like Salt & Pepper noise. This severely deteriorates subjective video quality even though such noise rarely occurs. In this paper, we propose a computationally extremely light encoder based on symbol-level Wyner-Ziv coding technique and a new corresponding decoder which, based on a decision whether a pixel has error or not, applies median filter selectively in order to minimize loss of texture detail from filtering. The proposed method claims extremely low encoder complexity and shows improvements both in subjective quality and PSNR. Our experiments have verified average PSNR gain of up to 0.8dB.

A 12b 1kS/s 65uA 0.35um CMOS Algorithmic ADC for Sensor Interface in Ubiquitous Environments (유비쿼터스 환경에서의 센서 인터페이스를 위한 12비트 1kS/s 65uA 0.35um CMOS 알고리즈믹 A/D 변환기)

  • Lee, Myung-Hwan;Kim, Yong-Woo;Lee, Seung-Hoon
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.45 no.3
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    • pp.69-76
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    • 2008
  • This work proposes a 12b 1kS/s 65uA 0.35um CMOS algorithmic ADC for sensor interface applications such as accelerometers and gyro sensors requiring high resolution, ultra-low power, and small size simultaneously. The proposed ADC is based on an algorithmic architecture with recycling techniques to optimize sampling rate, resolution, chip area, and power consumption. Two versions of ADCs are fabricated with a conventional open-loop sampling scheme and a closed-loop sampling scheme to investigate the effects of offset and 1/f noise during dynamic operation. Switched bias power-reduction techniques and bias circuit sharing reduce the power consumption of amplifiers in the SHA and MDAC. The current and voltage references are implemented on chip with optional of-chip voltage references for low-power SoC applications. The prototype ADC in a 0.35um 2P4M CMOS technology demonstrates a measured DNL and INL within 0.78LSB and 2.24LSB, and shows a maximum SNDR and SFDR of 60dB and 70dB in versionl, and 63dB and 75dB in version2 at 1kS/s. The versionl and version2 ADCs with an active die area of $0.78mm^2$ and $0.81mm^2$ consume 0.163mW and 0.176mW at 1kS/s and 2.5V, respectively.

I/Q Imbalance Compensation Method for the Direct Conversion Receiver with Low Pass Filter Mismatch (저역 통과 필터 불일치를 포함한 직접 변환 수신기의 I/Q 불균형 보상 기법)

  • Yun, Seonhui;Ahn, Jaemin
    • Journal of the Institute of Electronics and Information Engineers
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    • v.51 no.11
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    • pp.3-10
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    • 2014
  • Direct conversion receiver(DCR) gets noticed for integration and cost reduction of wireless communication systems instead of the heterodyne receiver which uses complex filter. But DCR has several factors in performance degradation. One of them is I/Q imbalance phenomenon, that is amplitude and phase mismatch between real and imaginary part of receiver. Accordingly, researches are being carried to improve the I/Q imbalance problem. However, the tendency of the broaden bandwidth of communication systems, low pass filter(LPF) mismatch problem affects severely in I/Q mismatch phenomenon at the DCR. To study this problem, we generated 10MHz broadband signal and shifted it ${\pm}8MHz$ from the center frequency. The signal is affected by LPF mismatch and it appears as frequency selective distortion. Thus, LPF mismatch model is added to I/Q imbalance model which conventionally dealt with amplitude and phase mismatches. In addition, we proposed the compensation method for each factors of mismatch. As the simulation results, the proposed I/Q mismatch compensator resolves the frequency selective distortion which occurred by the existing LPF mismatch.

강지진동 분석의 최적화를 위한 고려요소

  • 이석태;조봉곤;이정모;조영삼
    • Proceedings of the International Union of Geodesy And Geophysics Korea Journal of Geophysical Research Conference
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    • 2003.05a
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    • pp.17-17
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    • 2003
  • 한반도에 있어서의 지진의 영향을 분석하기 위해서는 강지진동 연구가 필수적이다. 강지진동 자료가 부족한 한반도의 특성상 모사를 통해 연구하고 있다. 강지진동 분석을 하기 위해서는 되도록 노이즈가 포함되어 있지 않은 지진파자료를 선택하여 그 지진자료의 스펙트럼 분석을 통해 감쇠상수 k, Q 등을 구한다. 이러한 감쇠상수 값을 통해 한반도의 진동 특성을 이해할 수 있다. 그러나 감쇠상수를 구하는 과정에서 감쇠상수 분석에 사용된 지진자료에 노이즈가 더해졌을 경우, 어떤 형태로 스펙트럼 영역에 영향을 미치고, 감쇠상수에는 어떤 영향을 미치는 지를 연구하여 노이즈효과를 제거할 수 있는 최적화된 분석에 관한 연구가 선행되어야 한다고 본다. 따라서 이번 연구에서는 강지진동 모사프로그램을 가지고 노이즈효과를 적용하면서 감쇠상수에 노이즈가 어떤 영향을 미치는 지에 대한 수치 해석적 연구를 실시하였다. 합성지진파에 이 합성지진파와 전혀 다른 주파수 형태를 보이는 노이즈를 강도를 달리하면서 합성해 본 결과, 노이즈효과를 고려할 수 있는 몇 가지 요소가 있음을 알 수 있었다. 감쇠상수 k값을 강지진동 모사프로그램으로부터 값을 달리하며 합성해 본 결과 노이즈효과를 보이는 것을 알 수 있었으며, 감쇠상수 k를 선형회귀를 통해 $k_{s}$$k_{q}$를 구할 때의 적용 주파수 범위를 변화시켰을 때도 일정한 양상의 노이즈 효과를 보였다. 또 지진자료와 노이즈를 중첩시킨 지진파 시계열 자료의 정부분만을 감쇠상수 k를 구하는 선형회귀에 이용했을 경우에도 노이즈 효과를 보였다. 또한 계산되어 나온 감쇠상수 값으로부터 특정지역의 지반운동의 특성을 이해할 수 있는 스펙트럼 가속도, 최대 가속도, 및 최대속도 값에 따른 감쇠식을 구하였다. 이것을 한반도와 같은 판 내부 환경인 ENA 값과 비교하였으며 기존의 연구와도 비교하였다.심으로부터 지오이드까지의 거리, 지오이드로부터 지표까지의 거리를 정의해주었으며, 각 격자점의 수직구조를 정의하기 위해 깊이에 따른 각 매질의 밀도, P파의 속도, S파의 속도, P파에 대한 Q값, S파에 대한 Q값을 정의 해주었다. S파의 속도를 구하기 위해서 지구 내부 물질을 포아송 매질이라는 가정 하에, 관계식을 $Vp{\;}={\;}SQRT(3){\;}{\times}{\;}Vs$ 이용하였다. 획득한 모델치들을 이용해 동해와 동해 인근 지역에 대한 초기모델을 구축하였다. 약 1 × 10/sup 6/ e/sup -//sec·n㎡ 의 전자선량에 해당되며 이를 기준으로 각각의 illumination angle에 대한 임계전자선량을 평가할 수 있었다. 실질적으로 Cibbsite와 같은 무기수화물의 직접가열실험 시 전자빔 조사에 의해 야기되는 상전이 영향을 배제하고 실험을 수행하려면 illumination angle 0.2mrad (Dose rate : 8000 e/sup -//sec·n㎡)이하로 관찰하고 기록되어야 함을 본 자료로부터 알 수 있었다.운동횟수에 의한 영향으로써 운동시간을 1일 6시간으로 설정하여, 운동횟수를 결정하기 위하여 오전, 오후에 각 3시간씩 운동시키는 방법과 오전부터 6시간동안 운동시키는 두 방법을 이용하여 품질을 비교하였다. 각 조건에 따라 운동시킨 참돔의 수분함량을 나타낸 것으로, 2회(오전 3시간, 오후 3시간)에 나누어서 운동시키기 위한 육의 수분함량은 73.37±2.02%를 나타냈으며, 1회(6시간 운동)운동시키기 위한 육은 71.74±1.66%을 나타내었다. 각각의 운동조건에서 양식된 참돔은 사육초기에는 큰 변화가 없었으나, 사육 5일 이후에는 수분함량이 증가하여 15일에는 76.40±0.14, 75.62±0.98%의 수분함량을 2회와 1회 운동시킨 참돔의 육에서 각각 나타났다. 운동횟수에 따른 지

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SCR Reaction Activity and SO2 Durability Enhancement in Accordance with Manufacturing Conditions of the V/TiO2 Catalysts (V/TiO2 촉매의 제조조건에 따른 SCR 반응활성 및 SO2 내구성 증진에 대한 연구)

  • Lee, Seung Hyun;Seo, Jeong Uk;Byeon, Sang Geun;Hong, Sung Chang
    • Clean Technology
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    • v.22 no.2
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    • pp.114-121
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    • 2016
  • In this studies, SCR reaction activity and SO2 durability enhancement study on manufacturing conditions of the V/TiO2 catalyst was carried out for the removal of nitrogen oxides generated in the combustion furnace. The catalysts are characterized by XPS, Raman, H2-TPR and SO2-TPD. When the vanadium was contained of 2 wt%, it showed excellent SO2 durability and catalytic activity. and When the tungsten is added as a promotor, the enhancement of reducing ability at a low temperature and reduction of SO2 adsorption capacity improved the reaction activity and SO2 durability. V/W/TiO2 are prepared by the lower pH of vanadium solution, vanadium was highly dispersed on the surface and inhibited the formation of crystalline V2O5. in addition, it was confirmed that this catalyst can be used as excellent resistance to high concentration of CO in the combustion furnace.