• Title/Summary/Keyword: 석탄층

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Adsorption Characteristics of Reactive Red 120 by Coal-based Granular Activated Carbon : Isotherm, Kinetic and Thermodynamic Parameters (석탄계 입상활성탄에 의한 Reactive Red 120의 흡착 특성 : 등온선, 동력학 및 열역학 파라미터)

  • Lee, Jong Jib
    • Applied Chemistry for Engineering
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    • v.31 no.2
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    • pp.164-171
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    • 2020
  • Adsorption characteristics of reactive red 120 (RR 120) dye by a coal-based granular activated carbon (CGAC) from an aqueous solution were investigated using the amount of activated carbon, pH, initial concentration, contact time and temperature as adsorption variables. Isotherm equilibrium relationship showed that Langmuir's equation fits better than that of Freundlich's equation. The adsorption mechanism was considered to be superior to the adsorption of monolayer with uniform energy distribution. From the evaluated Langmuir separation coefficients (RL = 0.181~0.644), it was found that this adsorption process belongs to an effective treatment area (RL = 0~1). The adsorption energy determined by Temkin's equation and Dubinin-Radushkevich's equation was E = 15.31~7.12 J/mol and B = 0.223~0.365 kJ/mol, respectively. The adsorption process showed the physical adsorption (E < 20 J/mol and B < 8 kJ/mol). The adsorption kinetics followed the pseudo first order model. The adsorption reaction of RR 120 dye on CGAC was found to increase spontaneously with increasing the temperature because the free energy change decreased with increasing the temperature. The enthalpy change (12.747 kJ/mol) indicated an endothermic reaction. The isosteric heat of adsorption (△Hx = 9.78~24.21 kJ/mol) for the adsorption reaction of RR 120 by CGAC was revealed to be the physical adsorption (△Hx < 80 kJ/mol).

Characteristics and Parameters for Adsorption of Carbol Fuchsin Dye by Coal-based Activated Carbon: Kinetic and Thermodynamic (석탄계 활성탄에 의한 Carbol Fuchsin의 흡착 특성과 파라미터: 동력학 및 열역학)

  • Lee, Jong Jib
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.283-289
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    • 2021
  • Adsorption characteristics of carbol fuchsin (CF) dye by coal-based activated carbon (CAC) were investigated using pH, initial concentration, temperature and contact time as adsorption variables. CF dissociates in water to have a cation, NH2+, which is bonded to the negatively charged surface of the activated carbon in the basic region by electrostatic attraction. Under the optimum condition of pH 11, 96.6% of the initial concentration was adsorbed. Isothermal adsorption behavior was analyzed using Langmuir, Freundlich, Temkin and Dubinin-Radushkevich models. Langmuir's equation was the best fit for the experimental results. Therefore, the adsorption mechanism was expected to be adsorbed as a monolayer on the surface of activated carbon with a uniform energy distribution. From the evaluated Langmuir's dimensionless separation coefficients (RL = 0.503~0.672), it was found that CF can be effectively treated by activated carbon. The adsorption energies determined by Temkin and Dubinin-Radushkevich models were E = 15.31~7.12 J/mol and B = 0.223~0.365 kJ/mol, respectively. Therefore, the adsorption process was physical (E < 20 J/mol, B < 8 kJ/mol). The experimental result of adsorption kinetics fit better the pseudo second order model. In the adsorption reaction of CF dye to CAC, the negative free energy change increased as the temperature increased. It was found that the spontaneity also increased with increasing temperature. The positive enthalpy change (40.09 kJ/mol) indicated an endothermic reaction.

Stratigraphic response to tectonic evolution of sedimentary basins in the Yellow Sea and adjacent areas (황해 및 인접 지역 퇴적분지들의 구조적 진화에 따른 층서)

  • Ryo In Chang;Kim Boo Yang;Kwak won Jun;Kim Gi Hyoun;Park Se Jin
    • The Korean Journal of Petroleum Geology
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    • v.8 no.1_2 s.9
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    • pp.1-43
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    • 2000
  • A comparison study for understanding a stratigraphic response to tectonic evolution of sedimentary basins in the Yellow Sea and adjacent areas was carried out by using an integrated stratigraphic technology. As an interim result, we propose a stratigraphic framework that allows temporal and spatial correlation of the sedimentary successions in the basins. This stratigraphic framework will use as a new stratigraphic paradigm for hydrocarbon exploration in the Yellow Sea and adjacent areas. Integrated stratigraphic analysis in conjunction with sequence-keyed biostratigraphy allows us to define nine stratigraphic units in the basins: Cambro-Ordovician, Carboniferous-Triassic, early to middle Jurassic, late Jurassic-early Cretaceous, late Cretaceous, Paleocene-Eocene, Oligocene, early Miocene, and middle Miocene-Pliocene. They are tectono-stratigraphic units that provide time-sliced information on basin-forming tectonics, sedimentation, and basin-modifying tectonics of sedimentary basins in the Yellow Sea and adjacent area. In the Paleozoic, the South Yellow Sea basin was initiated as a marginal sag basin in the northern margin of the South China Block. Siliciclastic and carbonate sediments were deposited in the basin, showing cyclic fashions due to relative sea-level fluctuations. During the Devonian, however, the basin was once uplifted and deformed due to the Caledonian Orogeny, which resulted in an unconformity between the Cambro-Ordovician and the Carboniferous-Triassic units. The second orogenic event, Indosinian Orogeny, occurred in the late Permian-late Triassic, when the North China block began to collide with the South China block. Collision of the North and South China blocks produced the Qinling-Dabie-Sulu-Imjin foldbelts and led to the uplift and deformation of the Paleozoic strata. Subsequent rapid subsidence of the foreland parallel to the foldbelts formed the Bohai and the West Korean Bay basins where infilled with the early to middle Jurassic molasse sediments. Also Piggyback basins locally developed along the thrust. The later intensive Yanshanian (first) Orogeny modified these foreland and Piggyback basins in the late Jurassic. The South Yellow Sea basin, however, was likely to be a continental interior sag basin during the early to middle Jurassic. The early to middle Jurassic unit in the South Yellow Sea basin is characterized by fluvial to lacustrine sandstone and shale with a thick basal quartz conglomerate that contains well-sorted and well-rounded gravels. Meanwhile, the Tan-Lu fault system underwent a sinistrai strike-slip wrench movement in the late Triassic and continued into the Jurassic and Cretaceous until the early Tertiary. In the late Jurassic, development of second- or third-order wrench faults along the Tan-Lu fault system probably initiated a series of small-scale strike-slip extensional basins. Continued sinistral movement of the Tan-Lu fault until the late Eocene caused a megashear in the South Yellow Sea basin, forming a large-scale pull-apart basin. However, the Bohai basin was uplifted and severely modified during this period. h pronounced Yanshanian Orogeny (second and third) was marked by the unconformity between the early Cretaceous and late Eocene in the Bohai basin. In the late Eocene, the Indian Plate began to collide with the Eurasian Plate, forming a megasuture zone. This orogenic event, namely the Himalayan Orogeny, was probably responsible for the change of motion of the Tan-Lu fault system from left-lateral to right-lateral. The right-lateral strike-slip movement of the Tan-Lu fault caused the tectonic inversion of the South Yellow Sea basin and the pull-apart opening of the Bohai basin. Thus, the Oligocene was the main period of sedimentation in the Bohai basin as well as severe tectonic modification of the South Yellow Sea basin. After the Oligocene, the Yellow Sea and Bohai basins have maintained thermal subsidence up to the present with short periods of marine transgressions extending into the land part of the present basins.

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Fundamental Properties of Mortar and Concrete Using High Calcium Fly Ash (고칼슘 플라이애시를 활용한 모르타르 및 콘크리트의 기초적 물성)

  • Lee, Min-Hi
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.284-291
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    • 2016
  • To evaluate the properties of inorganic composites using a great quantity of high-calcium fly ash generated in combined heat and power plants, high-calcium fly ash and F-class fly ash commonly used as concrete admixtures were substituted with binding materials to examine changes of fluidity and compressive strength depending on the substitution ratio for each curing temperature. According to the experimental result, CFA-mixed mortar showed a tendency to reduce its flow unlike FFA-mixed mortar as the substitution ratio was increased, but its flow loss showed smaller than FFA as time passed. As a result of examining compressive strength depending on mixing FA, FFA-mixed mortar had an optimum range within 50% when curing at ambient temperature, but it was found that the compressive strength is reduced when mixing CFA. When curing at high temperature, FFA did not relatively have a great effect on the substitution ratio, but CFA could expect a strength enhancement effect compared with 100% of OPC when using within 25% of binding materials.

A Study on Reaction Characteristics of Fe$_2$O$_3$High-Temperature Desulfurization Sorbents (Fe$_2$O$_3$계 고온건식탈황제의 반응특성 연구)

  • Kang, Suk-Hwan;Rhee, Young-Woo;Kang, Yong;Han, Keun-Hee;Yi, Chang-Keun;Jin, Gyoung-Tae;Son, Jae-Ek;Park, Yeong-Seong
    • Journal of Energy Engineering
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    • v.5 no.2
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    • pp.123-130
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    • 1996
  • Reduction, sulfidation, and regeneration reactions were performed using domestic and Australian iron ore in order to develop a desulfurizing sorbent for the high temperature desulfurization process that is one of major processes in the integrated coal gasification combined cycle (IGCC) system. A TGA (Thermogravimetric Analysis) reactor and a fixed-bed reactor were used. Some basic kinetic information was obtained from BET surface area measurements, SEM photos, cyclic reactions, reaction temperature changes and TGA curves of the sorbents. The rates of both desulfurization and regeneration increased with increasing reaction temperature in the range of 500-700$^{\circ}C$.

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A Study of Regeneration Reaction for Desulfurization Sorbents using Natural Manganese Ore (천연 망간 광석 탈황제의 재생 반응 특성 연구)

  • 윤여일;윤용승;김성현
    • Journal of Energy Engineering
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    • v.11 no.3
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    • pp.247-253
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    • 2002
  • Natural manganese ore was selected as main active component for a non-zinc desulfurization sorbent used in the gas clean-up process of the integrated gasification combined cycle (IGCC) because of excellent H$_2$S removal efficiency and economical aspect . In this study, the regeneration characteristics of sorbent after desulfurization reaction were determined in a thermobalance reactor and a fixed bed reactor in the temperature range of 350~55$0^{\circ}C$. The mixed gases of oxygen and nitrogen are used as the regeneration reaction gases for manganese sorbent. According to Mn-S-O phase diagram, the manganese sorbent has a low regeneration efficiency in medium temperature due to formation of MnSO$_4$ and the regeneration temperature must be over 85$0^{\circ}C$. To improve that problem, ammonia and steam was added in regeneration mixed gases. Effect of new regeneration method was determined by XRD and difference of desulfurization through multicycle tests.

Major Industrial Minerals in Korea : Geological Occurrence and Current Status of Demand/Supply (국내 산업소재광물의 수급 및 부존 특성)

  • Lee, Dong-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.7 no.1
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    • pp.1-13
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    • 1994
  • The industrial minerals play an important role in mining sector. More than 70 % of total mineral production come from industrial mineral sector. This paper reviews geological occurrence of kaolin, pyrophyllite and limestone, and current demand-supply status of major industrial minerals in the Republic of Korea. The kaolin is mainly distributed in the Kyeongsang province, formed by deep weathering of Precambrian anorthosite on mountainside of gentle slope. The pyrophyllite mainly occurs in the Kyeongsang and Chulla provinces, formed by hydrothermal alteration of late Cretaceous andesitic and rhyolitic rocks. Pyrophyllite comprises massive and lenticular bodies and contains minor amounts of kaolin, alunite and pyrite, in some places andalusite and illite. The limestone(Great Limestone Series of Cambrian age) is distributed widely in the Kwangwon and Chungcheong provinces. The limestone bodies are approzimately 70 km long and 3 km wide, elongated NE-ward, and show high grade of CaO content. In 1992, the self-sufficiency ratio of 44 nonfuel (metallic and non-metallic) minerals was no more than 30 percent. However, the ratio of 27 industrial minerals (non-metallic) represents high value of about 72 percent. The export/productjon ratio of the industrial minerals shows decreasing patterns from 12.2 % in 1983 to 4.2 % in 1992. Also the import/production ratio shows rapidly decreasing pattern from 84 % in 1983 to 38.2 % in 1992.

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Physical Properties and Sulfidation Kinetics of Mn-Based Sorbent for Hydrogen Sulfide Removal (황화수소 제거를 위한 망간계 탈황제의 물리적 특성과 황화반응 속도)

  • Oh, Kwang-Joong;Shon, Byung-Hyun;Choi, Eun-Hwa;Yi, Gang Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.2067-2076
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    • 2000
  • The experiments have been made to develop manganese-based sorbent(MT, MFT) for the removal of hydrogen sulfide from simulated hot coal gases. Manganese-based sorbents were tested in an ambient-pressure fixed-bed reactor to calculate H2S removal efficiency. and a three hole jet attrition tester to characterize the sorbent physical properties. According to the experimental results of attrition test. the attrition resistance of 5% bentonite containing sorbent was higher than that of 2% bentonite. The attrition resistances of both sorbents increased with induration temperature. Effects of sulfidation temperature. space velocity. and $H_2S$ concentrations on the $H_2S$ removal efficiency were investigated. Experimental results showed that $H_2S$ could be removed from 5,100ppmv to 20ppmv at $450^{\circ}C$, and to 30~65ppmv at $550{\sim}650^{\circ}C$ for both MT/MFT sorbents. As for the change of space velocity, the breakthrough time was decreased with space velocity.

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A Study on Preparation and Reactivity of Zinc Titanate Sorbents for H2S Removal (아연-티타늄 복합산화물 탈황제의 제조 및 반응특성 연구)

  • Kim, Ki-Seok;Park, No-Kuk;Lee, Tae-Jin
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.122-131
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    • 1997
  • Zinc titanate sorbents for $H_2S$ removal were prepared and their reactivities were studied for high temperature desulfurization of coal gas. Sulfidation of zinc titanates by $H_2S$ sorption was conducted in a packed-bed tubular flow reactor at the temperature range of $550{\sim}750^{\circ}C$, and the results reveal that $650^{\circ}C$ was the optimal sulfidation temperature with respect to desulfurization efficiency and zinc loss. The structural change of sorbent particle was investigated by SEM analysis for the forbents sulfided at $650^{\circ}C$ and subsequently regenerated at $750^{\circ}C$. The stability of desulfurization capability as well as the mechanical stability of the zinc titanates was studied by means of the successive cycles of sulfidation-regeneration of sorbents, and the sorbent samples taken after the 10th cycle were characterized using BET, XRD, and SEM/EDX analyses. Zinc titanate sorbents exhibited nearly constant desulfurization capability in the successive cycle operation.

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Properties of carbonated green construction materials by changes in processing conditions (공정조건 변화에 따른 탄산화 녹색건자재의 물성)

  • Kim, Yootaek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.3
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    • pp.152-160
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    • 2013
  • The purpose of this study is to enhance the mechanical strength of specimens containing fly ash from fluidized bed type boiler, which the recycling rate will be eventually increased. Specimens containing fly ash in a certain portion were made and aged for 3, 14, and 28 days. Specimens were carbonated under the supercritical condition at $40^{\circ}C$. The carbonation process under the supercritical condition was performed to enhance the mechanical property of specimens by filling the voids and cracks existing inside cement specimen with $CaCO_3$ reactants. The additional aging effect after the supercritical carbonation process on mechanical strength of specimens was also investigated by comparing the compressive strength with and without 7 day extra aging. Under the supercritical condition and additional 7 day aging specimens were very effective for enhancement of mechanical strength and compressive strength increased by 44 %.