• Title/Summary/Keyword: 석탄층

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A Study on Optimization of Perovskite Solar Cell Light Absorption Layer Thin Film Based on Machine Learning (머신러닝 기반 페로브스카이트 태양전지 광흡수층 박막 최적화를 위한 연구)

  • Ha, Jae-jun;Lee, Jun-hyuk;Oh, Ju-young;Lee, Dong-geun
    • The Journal of the Korea Contents Association
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    • v.22 no.7
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    • pp.55-62
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    • 2022
  • The perovskite solar cell is an active part of research in renewable energy fields such as solar energy, wind, hydroelectric power, marine energy, bioenergy, and hydrogen energy to replace fossil fuels such as oil, coal, and natural gas, which will gradually disappear as power demand increases due to the increase in use of the Internet of Things and Virtual environments due to the 4th industrial revolution. The perovskite solar cell is a solar cell device using an organic-inorganic hybrid material having a perovskite structure, and has advantages of replacing existing silicon solar cells with high efficiency, low cost solutions, and low temperature processes. In order to optimize the light absorption layer thin film predicted by the existing empirical method, reliability must be verified through device characteristics evaluation. However, since it costs a lot to evaluate the characteristics of the light-absorbing layer thin film device, the number of tests is limited. In order to solve this problem, the development and applicability of a clear and valid model using machine learning or artificial intelligence model as an auxiliary means for optimizing the light absorption layer thin film are considered infinite. In this study, to estimate the light absorption layer thin-film optimization of perovskite solar cells, the regression models of the support vector machine's linear kernel, R.B.F kernel, polynomial kernel, and sigmoid kernel were compared to verify the accuracy difference for each kernel function.

Geology and Metallic Mineral Resources of Sinaola State in Mexico (멕시코 시나올라주의 지질 및 금속광물자원)

  • Nam, Hyeong-Tae;Heo, Chul-Ho
    • Economic and Environmental Geology
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    • v.46 no.3
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    • pp.257-266
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    • 2013
  • The geology of Sinaola state consists of Precambrian metamorphic rocks(Sonobari Complex), two Paleozoic units(lower non-differentiated metamorphic rocks and upper Carboniferous sedimentary rocks), five Mesozoic units(metavolcanic, clastic, and calcareous rocks), Cenozoic volcanic rocks, and Quaternary clastic sediments and volcanic flows. The Sinaola state is potentially rich in metallic mineral resources with lower degree of non-metallic mineral resources. They are related to a variety of geological environments and are mainly physiographically located on the Sierra Madre Occidental. Mainly known mineral deposits are of gold and silver followed by zinc, lead, copper and some iron. The state also has deposits of molybdenum, tungsten and bismuth that have been occasionally exploited. There is a reference of nickel and cobalt mineralization, but these deposits have been exploited only at a small scale.

Properties of Ground Solidification Materials using Vietnam CFBC Fly Ash (베트남 CFBC 플라이애시를 사용한 지반고화재의 특성)

  • Kim, Keeseok;Lee, Jaewon;Lee, Dongwon;Yu, Jihyung;Hoang, Truong Xuan;Minh, Ha;Min, Kyongnam
    • Resources Recycling
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    • v.27 no.3
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    • pp.39-47
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    • 2018
  • According to Vietnam government establishes additional coal-fired power plants to secure generation capacity, emission of ashes is accelerating and processing them is urgent issue. This study targeted utilize fly ashes that occurred in circulating fluidized bed combusion (CFBC) power plant to use ground solidification materials. CFBC fly ashes are used to make solidification with ground granulated blast furnace slag (GGBFS), gypsum and cement. Then produced specimens by mixing with soft ground soil to confirm mixing effect of fly ash in solidification. As a result it was possible to find mixture design that is satisfied 3 MPa compressive strength in age 28 days and reduce weight loss rate over 50% in acid immersion test than plain specimens that using only ordinary portland cement.

Adsorption Analysis of VOCs of Zeolite Synthesized by Coal Fly Ash in a Fixed-bed Adsorber (고정층 흡착탑에서 석탄비산재로부터 합성한 Zeolite의 VOCs 흡착 해석)

  • Kim, Seong-Soo;Lee, Chang-Han;Park, Sang-Wook
    • Korean Chemical Engineering Research
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    • v.48 no.6
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    • pp.784-790
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    • 2010
  • VOCs such as acetone, benzene, toluene, ethylbenzene were adsorbed in a fixed-bed adsorber using zeolite synthesized from coal fly ash and 4 kinds of activated carbon at 101.3 kPa. The adsorber was operated batchwise with the charge of 5 g adsorbent to obtain the breakthrough curve of VOCs. Experiments were carried out at $40^{\circ}C$, nitrogen flow rate of $70cm^3/min$ and sparger temperature of $30^{\circ}C$. The deactivation model was tested for these curves by combining the adsorption of VOCs and the deactivation of adsorbent particles. The observed values of the adsorption rate constant and the deactivation rate constant were evaluated through analysis of the experimental breakthrough data using a nonlinear least square technique. The experimental breakthrough data were fitted very well to the deactivation model than the adsorption isotherm models in the literature. Also, adsorption capacities of adsorbents were obtained from the breakthrough curve to observe the correlation between adsorption capacity and the physical properties of VOCs.

Modeling of Solid Particle-Slag Interactions in Entrained Gasification Reactor (분류층 가스화기에서의 고체 입자-슬래그 간 상호 작용에 대한 모델링)

  • Chi, Jun-Hwa;Kim, Ki-Tae;Kim, Sung-Chul;Chung, Jae-Hwa;Ju, Ji-Sun;Kim, Ui-Sik
    • Journal of Hydrogen and New Energy
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    • v.22 no.5
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    • pp.686-698
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    • 2011
  • Mathematical models for char-slag interaction and near-wall particle segregation developed by Montagnaro et. al. were applied to predict various aspects of coal gasification in an up-flow entrained gasifier of commercial scale. For this purpose, some computer simulations were performed using gPROMS as the numerical solver. Typical design parameters and operating conditions of the commercial gasifiers were used as input values for the simulation. Development of a densely dispersed phase of solid carbon was found to have a critical effect on both carbon conversion and ash flow behavior. In general, such a slow-moving phase was turned out to enhance carbon conversion by lengthening the residence time of char or soot particles. Furthermore, it was also found that guiding the transfer of char or soot into the closer part of the wall to coal burner is favorable in terms of gasification efficiency and vitrified ash collection. Finally, to a certain degree densely dispersed phase of carbon showed an yield-enhancing effect of syngas.

Effect of Flow Distribution on the Combustion Efficiency In an Entrained-Bed Coal Reactor (분류층 석탄반응로에서 유동분포가 연소성능에 미치는 영향)

  • CHO, Han Chang;SHIN, Hyun Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.8
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    • pp.1022-1030
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    • 1999
  • A numerical study was carried out to analyze the effect of flow distribution of stirred part and plug flow part on combustion efficiency at the coal gasification process in an entrained bed coal reactor. The model of computation was based on gas phase eulerian balance equations of mass and momentum. The solid phase was described by lagrangian equations of motion. The $k-{\varepsilon}$ model was used to calculate the turbulence flow and eddy dissipation model was used to describe the gas phase reaction rate. The radiation was solved using a Monte-Carlo method. One-step parallel two reaction model was employed for the devolatilization process of a high volatile bituminous Kideco coal. The computations agreed well with the experiments, but the flame front was closer to the burner than the measured one. The flow distribution of a stirred part and a plug flow part in a reactor was a function of the magnitude of recirculation zone resulted from the swirl. The combustion efficiency was enhanced with decreasing stirred part and the maximum value was found around S=1.2, having the minimum stirred part. The combustion efficiency resulted from not only the flow distribution but also the particle residence time through the hot reaction zone of the stirred part, in particular for the weak swirl without IRZ(internal recirculation zone) and the long lifted flame.

Pre-feasibility Study in Mongolia Tavan Tolgoi Coal Bed Methane (Tavan Tolgoi Coal Bed Methane에 대한 몽골에서의 타당성 조사)

  • CHO, WONJUN;YU, HYEJIN;LEE, JESEOL;LEE, HYUN CHAN;JU, WOO SUNG;LIM, OCKTAEK
    • Journal of Hydrogen and New Energy
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    • v.29 no.1
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    • pp.124-129
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    • 2018
  • Methane is the cleanest fuel and supplies by many distributed type: liquefaction natural gas (LNG), compressed natural gas (CNG), and pipeline natural gas (PNG). Natural gas is mainly composed by methane and has been discovered in the oil and gas fields. Coal bed methane (CBM) is also one of them which reserved in coalbed. This significant new energy sources has emerge to convert an energy source, hydrogen and hydrogen-driven chemicals. For this CBM, this paper was written to analyze the geological analysis and reserves in Mongolian Tavan Tolgoi CBM coal mine and to examine the application field. This paper is mainly a preliminary feasibility report analyzing the business of Tavan Tolgoi CBM and its exploitable gas.

A Study on Various Application Technologies Using Coal Bed Methane (Coal Bed Methane을 사용한 다양한 응용 기술에 대한 고찰)

  • CHO, WONJUN;LEE, JESEOL;YU, HYEJIN;LEE, HYUN CHAN;JU, WOO SUNG;LIM, OCKTAEK
    • Journal of Hydrogen and New Energy
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    • v.29 no.1
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    • pp.130-137
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    • 2018
  • Now discusses the potential use and applications of coal bed methane (CBM) in various industries. One of the options for gas monetization is gas to power (GTP), sometimes called gas to wire (GTW). Electric power can be an intermediate product, such as in the case of mineral refining in which electricity is used to refine bauxite into aluminum; or it can be an end product that is distributed into a large utility power grid. For stranded gas, away from the regional markets, the integration of the ammonia and urea plants makes commercial sense. These new applications, if established, could lead to a surge in demand for methanol plants.

Fabrication of SOFC cell by transcription-method (전사법을 이용한 SOFC Cell 제작 및 출력특성)

  • Koo, JaBin;Choi, ByeongHyeon;Ji, MiJeong;An, YongTae;Hwang, HaeJin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.91.1-91.1
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    • 2011
  • 고체산화물 연료전지(Solid Oxide Fuel Cell이하 SOFC)는 연료가 갖는 화학에너지를 연소과정 없이, 공기와 H2, CO, CH4와 같은 환원성 가스를 공급받아 $600{\sim}1000^{\circ}C$에서 전기화학적 반응을 통하여 직접 전기를 얻는 방식이다. SOFC는 $700^{\circ}C$ 이상의 고온에서 고체산화물이 연료와 공기가 반응하여 전기와 열을 동시에 생산하기 때문에 carnot cycle의 제한을 받지 않아 발전효율이 40% 이상으로 고효율이고, NOx 및 SOx를 배출하지 않아 무공해이며, moving parts가 없어 소음이 나지 않고, 건설과 증설이 지역이나 기후 조건에 제약 없이 용이하고, 다양한 용량이 가능하며, 고가의 백금 촉매를 사용하지 않으며, 수소, 석탄가스, 천연가스 등의 연료를 사용할 수 있는 장점이 있음, 또한 다향한 형태로 제작할 수 있으며 전해질이 고체에서 전해질 손실 및 보충에 문제가 없고 타 연료전지에 비해 개질기가 필요 없어 발전시스템이 간단하고 경량화가 가능하다. 전사법은 paste를 제작하여 전사용지에 Screen printing하여 건조 후 coating하는 방법으로 기존의 여러 coating 방법보다 제작이 용이하고 소재의 크기, 두께조절이 간편하며, 구성층의 표면조도나 굴곡에 대응이 용이한 방법이다. 본 실험에서는 paste 제조, 전사법을 이용하여 Anode, AFL, Electrolyte, CFL, Cathode전사지를 제작하고 이를 세라믹 평관형 지지체에 변수로 두께 조건별 Coating 한 후 $1400^{\circ}C$ 소결을 진행하여 SEM 분석으로 미세구조 관찰, 출력특성 및 Impedance을 확인하였다.

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Modified Mathermatical Model of S. ENDRENYI and B. PALANCZ for Fluidized Bed Coal Combustion - Effect on the Variation of Specific Surface - (석탄(石炭)의 유동층(流動層) 연소(燃燒)에 관(關)한 S. ENDRENYI와 B. PALANCZ의 수학적(數學的) 수정(修正)모델(비표면적(比表面積) 변화(變化)의 영향(影響)))

  • Kim, M.J.;Rhee, K.S.;Seo, J.Y.
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.17 no.1
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    • pp.74-82
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    • 1988
  • A numerical analysis of the mathematical model for fluidized bed coal combustion has been performed. Based on the physical nature of the specific surface variation due to the decreasing of coal particle diameter according to the combustion process, the modified model which has been added the specific surface variation to the S.ENDRENYI and B.PALANCZ's mathematical model was established in this study. From the numerical analysis of these two models, it was found that the perfect combustion time is increasing largely at least 5 seconds in the modified model in comparison with that of the S.ENDRENYI and B.PALANCZ's model, and the bed temperature and the coal particle surface temperature during the main combustion period represent constant with time in the S.ENDRENYI and B.PALANCZ's model, on the other hand, these properties are decreasing linearly with time in the modified model.

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