• Clean Technology
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• v.19 no.2
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• pp.184-188
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• 2013

To increase flash point which is related to flammability, seven unprecedented new cleaning agents containing fluoride atoms have been invented. These newly synthesized cleaning agents's physical properties which were conducted by Korea Institute of Petroleum Management by using a standard method showed excellent values. Particularly, flash point of newly synthetic cleaning agents is more higher than that of fluoride free compound. A specimen for cleaning ability was prepared by cutting in $60mm{\times}40mm$ size of stainless steel plate. The surface of the above specimens was applied with four kinds of contaminants, such as paraffin based drawing oil, flux abietic acid, water-insoluble cutting oil, and lubricating oil. Contaminated specimens were immersed in new compounds (1-7) for 1 to 5 minutes to dissolve oil in the cleaning agent. Although the data indicate that all compounds (1-7) exhibit lower cleaning ability toward cutting oil, it is observed that in the case of the present study more than 80% of pollutants on the surface were almost removed within 5 minutes.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.677-677
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• 2013

최근 석유에너지의 고갈과 휴대용 전자기기의 사용의 증가로 고효율의 배터리의 개발이 요구되고 있다. 생체칩에서 부터 전기자동차, 에너지 저장체까지 광범위한 산업군에 걸처 배터리의 개발이 되고 있어 시장규모의 계속적인 성장이 있을 것으로 전망하고 있다. 현재 상용되고 있는 음극 재료는 카본재료(이론 용량 372 mAh/g)이다. 이 카본재료의 특징은 값이 싸고, 표준 환원전위가 낮아 비교적 높은 전압을 낼 수 있다. 그러나 낮은 에너지밀도를 갖으므로 높은 에너지를 필요로 하는 차세대 산업군인 전기자동차 등에는 적합하지 않은 것으로 평가되고 있다. 그래서 더 높은 에너지 밀도를 갖는 다른 재료들에 대한 연구들이 활발히 이루어지고 있다. 본 연구에서는 음극 재료로서 주석을 선택해서 연구를 하였다. 카본계열의 음극재료의 질량당 이론 에너지 밀도는 372 mAh/g임에 반해 주석같은 경우는 약 991 mAh/g 정도의 비교적 큰 이론용량을 갖고 있다. 하지만, 주석 등 금속, 혹은 금속 합금을 음극재료로 사용할 경우 많은 양의 리튬이 삽입/탈착되면서 약 300% 이상의 부피변화가 있게 된다. 그러한 과정에서 주석이 분쇄되어 떨어지거나 전자를 제공받는 집전체로부터 떨어지게 되고, 이 과정에서 심각한 에너지 밀도의 손실이 일어나게 된다. 이러한 문제점들을 극복하기 위해 다음과 같은 구조들을 고안하여 도금 공정을 사용하여 음극재료를 제작하여 실험을 진행하게 되었다. 도금법은 대면적을 싼 가격으로 할 수 있으며 원하는 두께 및 모폴로지까지 쉽게 조절할 수 있다. 부피팽창에 의한 스트레스를 최소화하기 위해 도금법을 사용하여 나노구조를 만들어 그에 따른 전기화학적 특성 변화를 측정하였다. 다공성 필름인 AAO 디스크의 한 면에 구리를 sputtering 공정을 사용하여 0.5 um 두께의 seed layer 구리 박막을 형성하고 형성된 구리 박막 위에 도금공정을 이용하여 두껍게 구리를 증착함으로 구리 음극 집전체를 형성한다. 그 후 AAO 구조 안에 주석을 도금하면 AAO의 구조를 따라 주석 나노와이어가 형성이 된다. 마지막으로 NaOH로 AAO를 제거해주면 직경 200 nm, 길이 2 um 정도의 주석 나노와이어를 구리 집전체위에 만들 수 있었다. 배터리의 용량을 측정한 결과 안정한 싸이클 특성과 약 400 mAh/g의 에너지 밀도를 갖는 것으로 나타났다.

• Membrane Journal
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• v.26 no.4
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• pp.291-300
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• 2016

Techniques for selectively separating molecules of gas and liquid states using various separation membranes have been widely used in variety of applications such as chemical, biological, pharmaceutical, and petrochemical industries. As the nanochannel diameter, inter-channel distance and length of the nanochannel of the anodic aluminum oxide (AAO) membranes can be precisely controlled, various studies to effectively separate mixture of various molecules using AAO membrane have been widely carried out. In this study, we fabricated AAO membranes of cylindrical nanochannels of various diameter sizes and of through-hole structure, that is, nanochannels of which both ends of each nanochannel are open. Using those AAO membranes of through-hole nanochannel structure, we studied the selective permeation polymer chains dissolved in a solvent based on hydraulic volume of the polymer chains. We found a precise, quantitative relationship between the radius of gyration of polymer chains that permeated through nanochannels inside AAO membrane and the diameter of nanochannels. In addition, we demonstrate that the behavior of the polymer solution flowing through nanochannel of the AAO membrane can be successfully described with the Hagen-Poiseuille relationship. It is, therefore, possible to theoretically interpret the nanoflow of the solution flowing inside the cylindrical nanochannel.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.109-109
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• 2018

Cr-Mo 합금강은 고온 환경 하에서 높은 크리이프 강도와 우수한 내식성 때문에 발전설비, 석유 화학, 그리고 해양산업과 같은 여러 산업분야에서 널리 사용되고 있다. 특히, Cr-Mo 강의 내식성은 합금 내 Cr 함량에 크게 의존한다. 이는 고온에서 Cr과 O가 화학적 반응을 일으킴에 따라 보호성의 Cr 산화스케일을 형성하기 때문이다. 그러나 화석연료를 사용하는 발전설비의 경우, $SO_2$가 포함된 강한 부식성의 연소 가스가 배출되며, 이에 노출된 금속의 표면에서는 산화와 황화가 동시에 발생한다. 황화스케일은 산화스케일에 비해 매우 빠르게 성장하며, 그 특성이 매우 취약하기 때문에 황화 환경에서 금속의 내식성 및 기계적 물성치는 보다 크게 저하된다. 따라서 본 연구에서는 화력 발전소의 증기발생용 튜브 재료인 9Cr-1MoVNb 강을 선정하였으며, $SO_2$ 가스 환경 하에서의 부식 및 기계적 물성치 저하 특성을 평가하고자 하였다. 본 연구에서 사용된 9Cr-1MoVNb강의 화학 성분 조성은 0.1 C, 0.38 Si, 0.46 Mn, 0.25 Ni, 8.38 Cr, 0.93 Mo, 0.18 V, 0.09 Nb, 그리고 나머지는 Fe이다. 부식시험은 가공된 미소시험편과 인장시험편을 전기열처리로에 장입한 후, $650^{\circ}C$에서 $N_2+O_2+O_2+SO_2$ 조성의 가스를 분당 50 CC로 흘려주었다. 제작된 시험편에 대한 부식거동은 무게 증가량, optical microscope, scanning electron microsope, 그리고 energy dispersive x-ray spectrum을 통해 평가하였다. 그리고 기계적 물성치 평가를 위한 인장시험은 분당 2mm 변위제어를 통해 실시하였다. 그 결과, 9Cr-1MoVNb 강은 $SO_2$ 가스 환경 하에서 비 보호적인 Fe-풍부상의 산화 스케일층이 두껍게 형성됨에 따라 열악한 내식성을 나타냈다. 그에 따라 기계적 물성치는 저하되는 경향을 나타내었다.

• Journal of the Korean Geosynthetics Society
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• v.11 no.2
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• pp.21-30
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• 2012

This paper analyzes the map of soil contamination in years of 2009 by actual survey in Incheon. South-east national industrial complex and the US Army base in Bu-Pyung are turned out to be high polluted area because spilling of oil storage facilities, vehicle and glass industries. So, the soil contamination in Incheon Metropolitan area will be getting more attention. To solve this problem, the soil contamination has been predicted by using the visual Sufer and visual Modflow which are analysis program in geotechnique and water flow. The result of analysis is that F and TPH will be retarded after 5 years. However, the contamination diffusion will be increased if there is no proper management of soil contamination.

• Journal of Korean Society of societal Security
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• v.1 no.1
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• pp.63-67
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• 2008

This study focuses on assessing the security ri sk or the terrorism in chemical process industries. This research modifies conventional method for assessing the terrorism risk. The risk assessment method is developed and it is implemented as software to analyze the possibility of terrorism and sabotage. This program includes five steps; asset characterization, threat assessment, vulnerability analysis, risk assessment and new countermeasures. It is a systematic, risk based approach in which risk is a function of the severity of consequences of an undesired event, the likelihood of adversary attack, and the likelihood of adversary success in causing the undesired event. The reliability of the program is verified using a dock zone case. The case dock zone includes a storage farm, a manufacturing plant, an electrical supply utility, a hydrotreater unit, many containers, and administration buildings. This study represents chemical terrorism response technology, the prevention plan, and new countermeasure to mitigate by using risk assessment methods in the chemical industry and public sector. This study suggests an effective approach to the chemical terrorism response management.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.43 no.3
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• pp.77-86
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• 2020

In this study, to improve the logistics flow of existing given chemical logistics warehouse, four logistics flow alternatives were proposed to minimize truck interference by building simulation model. The simulation model for chemical storage warehouse was built to evaluate system performance. Among the four new improved alternatives based on the basic model, the model with the same truck's pathways and locations of facilities identified an increase in the number of interferences but a decrease in daily working hours as the number of resources in a particular facility increases. Therefore, the three groups were classified as 'efficiency', 'complementary', and 'safety' based on the daily working hours, and the ratio of trucks entering two types of logistics warehouse was set in consideration of future market fluctuations. For each of the six types, the optimal number of resources was selected as the number of resources in the facilities with the least number of interferences in the basic model and the evaluation measures and characteristics set in this study were compared and analyzed. As a result, the Alternative 4 model operating the underground roadway produced interference between 17.0% and 36.4% of the basic model, with 113.3% of the interior loadspace.

• Journal of the Institute of Electronics and Information Engineers
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• v.51 no.7
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• pp.223-229
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• 2014

The acoustic cleaning system is widely used to remove foreign materials in factories, such as thermal power plants and incinerators. However, the acoustic cleaning systems tend to be clogged by foreign materials. In this paper, we develop a wireless sensor network for the sound wave detection in order to monitor proper operations in the acoustic cleaning systems. We observe that the developed wireless sensor network for the wave detection shows a stable operation in various industrial environments of wide temperature ranges. We also develop a data gathering device, which displays the current status of the sound generator and several values detected from the wireless sensor.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.7
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• pp.3302-3309
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• 2011

This study showed the reduced greenhouse gas(GHG) emission through GHG inventory establishment and process diagnosis for a response to climatic change. Also, it presented a direction for company's response to climatic change. Ulsan from its industrial complex has many energy-intensive companies such as petrochemistry, automobile and shipbuilding, and as we judged that the systematic reduction of GHG emission would make a considerable reduction of GHG emission in national dimension we executed this study from 10 companies. It showed the high rate of direction GHG emissions by its process that 5 of 10 companies calculated GHG emission and built its inventory. Also, in order to reduce energy and GHG, it produced about 227,554 million won of its economic effect and 50,740 ton/yr of its sparing effect.

• Journal of the Korean Institute of Gas
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• v.24 no.4
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• pp.73-83
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• 2020

The problem addressed in this study is that the reduction in process accidents is less than the reduction in industrial safety, and the losses from major accidents in the oil and gas processing industry have not decreased over the years. In particular, current risk approaches in storage tanks place more emphasis on improving the safety of the design than maintaining safe operation. The Bow-Tie method can be used properly to improve process safety. The Bow-Tie method can assess compliance by focusing on operational aspects, clearly highlighting all important safety barriers, and analyzing barrier effectiveness.