• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.109-109
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• 2018

Cr-Mo 합금강은 고온 환경 하에서 높은 크리이프 강도와 우수한 내식성 때문에 발전설비, 석유 화학, 그리고 해양산업과 같은 여러 산업분야에서 널리 사용되고 있다. 특히, Cr-Mo 강의 내식성은 합금 내 Cr 함량에 크게 의존한다. 이는 고온에서 Cr과 O가 화학적 반응을 일으킴에 따라 보호성의 Cr 산화스케일을 형성하기 때문이다. 그러나 화석연료를 사용하는 발전설비의 경우, $SO_2$가 포함된 강한 부식성의 연소 가스가 배출되며, 이에 노출된 금속의 표면에서는 산화와 황화가 동시에 발생한다. 황화스케일은 산화스케일에 비해 매우 빠르게 성장하며, 그 특성이 매우 취약하기 때문에 황화 환경에서 금속의 내식성 및 기계적 물성치는 보다 크게 저하된다. 따라서 본 연구에서는 화력 발전소의 증기발생용 튜브 재료인 9Cr-1MoVNb 강을 선정하였으며, $SO_2$ 가스 환경 하에서의 부식 및 기계적 물성치 저하 특성을 평가하고자 하였다. 본 연구에서 사용된 9Cr-1MoVNb강의 화학 성분 조성은 0.1 C, 0.38 Si, 0.46 Mn, 0.25 Ni, 8.38 Cr, 0.93 Mo, 0.18 V, 0.09 Nb, 그리고 나머지는 Fe이다. 부식시험은 가공된 미소시험편과 인장시험편을 전기열처리로에 장입한 후, $650^{\circ}C$에서 $N_2+O_2+O_2+SO_2$ 조성의 가스를 분당 50 CC로 흘려주었다. 제작된 시험편에 대한 부식거동은 무게 증가량, optical microscope, scanning electron microsope, 그리고 energy dispersive x-ray spectrum을 통해 평가하였다. 그리고 기계적 물성치 평가를 위한 인장시험은 분당 2mm 변위제어를 통해 실시하였다. 그 결과, 9Cr-1MoVNb 강은 $SO_2$ 가스 환경 하에서 비 보호적인 Fe-풍부상의 산화 스케일층이 두껍게 형성됨에 따라 열악한 내식성을 나타냈다. 그에 따라 기계적 물성치는 저하되는 경향을 나타내었다.

• Applied Chemistry for Engineering
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• v.16 no.6
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• pp.794-799
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• 2005

With the quantitative growth of the petroleum industry, the pipe facilities that connect each process increased significantly and the corresponding maintenance and repair costs of the pipe facilities increased as well. The diagnosis techniques to check a pipe efficiency while in operation are few in Korea, but in the advanced countries the pipe diagnosis using gramma-ray source was on-going research since 1960's. In this study, field experiments were performed to analyze the reasons for abnormal operation of the pipe connected to a distillation tower, and the degree of abnormality was estimated using a sealed gamma-ray source ($^{137}Cs$). Gamma radiation counts were measured by a detector (NaI) positioned outside the pipe-wall diametrically opposite to the gamma source. The results showed that a gas zone section's distribution pattern was different from the pattern of nearby fluid in a pipe. Th diagnosis technique using a gamma radiation source was proved to be an effective and reliable method, offering the information on the fluid distribution in pipe.

• Journal of the Korean Institute of Gas
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• v.27 no.4
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• pp.27-33
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• 2023

In a petrochemical plant, various mechanical equipments and structures are interconnected to ensure operability. Since the production activities of petrochemical plants have a great impact on the national economy, it is very important to maintain not only structural safety but also the operability of the facilities. However, the current seismic design standards present the design requirements of facilities mainly aimed at preventing collapse, and do not provide the requirements for securing operability of facilities. Depending on the behavioral characteristics of the facility, operability of the facility can be secured by seismic performance levels other than the collapse prevention level, so it is necessary to present seismic design methods that can apply various seismic performance levels. Spherical (ball) storage tanks are supported by columns and braces and exhibit complex nonlinear behavior because of buckling and yielding of support members. In this study, nonlinear seismic behavior characteristics were statistically analyzed and a new performance-based seismic design method was proposed based on them.

• Fire Science and Engineering
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• v.17 no.2
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• pp.6-9
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• 2003

Recently, forced ventilating air conditioning system has been widely used in modern buildings. However, It is obvious that this kind of system may affect on the response of fire detectors at real fire incidents, especially, on the ionization smoke detector, which is critically influenced by air stream. Therefore we studied to verify the response characteristics of air stream by ionization smoke detector for the design of facilities in practice. In this study, experiments were executed to examine the correlation between air velocity and the ionization detector's responses with var-ious air velocity and smoke densities in the simulated test room. As a result of experiments, ionization detector's operating time is in reverse proportion to air velocity. And the detector shows more sensitive reaction when the velocity of smoke stream increase over 60 cm/s. In addition, it was shown that ionization smoke detector is more sensitive to smoldering fires in paper than that in petro-chemicals.

• Proceedings of the KIEE Conference
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• 2008.09a
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• pp.58-60
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• 2008

발전소에서 만들어진 전력을 소비자까지 수송하는 송변전변 및 배전설비를 주 대상으로 하는 전력계통 설비의 운영에는 전력의 수송과 이를 위해 설치되는 각종 기자재로부터 인체 및 재산의 안전을 확보하기 위해 많은 종류의 절연재를 사용하고 있다. 지금까지 전력분야에서 사용되어 온 절연재는 자기재(porcelain)가 주종을 이루어 왔으나 재료기술의 발달과 함께 폴리머 절연재료들이 속속 개발되면서 자기재에 비해 가격 및 시공성 등에서 이점이 많은 폴리머 절연재가 자기재를 대체하고 있다. 그러나 폴리머 절연재료는 기들의 재질 및 사용 환경 등에 따라 일정 수명을 가지는 것으로 나타나 수명종기에 이르면 폐기물로 배출되게 된다. 전력산업 중 배전분야에서는 2007년 구매한 기자재를 기준으로 연간 13만연 톤의 전력폐기물이 발생될것으로 예측되었으며 이들은 PE, XLPE, FRP, PVC, EPDM, Silicone 등 유기성분이 약 40%, Cu, Al, 철 등 금속과 무기성분이 약 60% 인 것으로 조사되었다. 그러나 전선 및 케이블류를 제외한 기자재를 대상으로 한 분석에서는 유기성분의 함량이 90%에 이르며 이들은 석유화학공업의 원료로부터 만들어지는 특성상 높은 에너지를 함유하는 것으로 나타난 바, 이들을 적정하게 처리하는 방안의 확보는 폐기물의 처리 외에 폐기물로부터 에너지를 회수하여 자원화하는 것이 가능한 것으로 보여진다.

• Journal of the Korean Society of Safety
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• v.22 no.6
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• pp.35-40
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• 2007

As a way of improving the safety of the chemical facilities, the risk based-inspection(RBI) was executed for the facilities of the applied petrochemical plant using KS-RBI Ver. 3.0 program developed based on the API-581 based resource document(BRD). From an evaluation result of KS-RBI program, we could find the evaluation of the process safety management(PSM) for the applied plant, risk of the applied process, risk of static facilities and pipes, and the demage mechanism of the facilities. Also, we could suggest a proper inspection plan(frequency and method of inspection) using the calculated risk and the status of the facilities. Therefore, the applied plant could be achieved a reduced inspection cost by an extension of inspection frequency, improved productivity, improved reliability of the facilities, and a computerized history management.

• Journal of the Korean Society for Nondestructive Testing
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• v.25 no.5
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• pp.377-383
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• 2005

Because explosive fluid is used at high temperature or under high pressure in petrochemistry and refined oil equipment, the interest about safety of equipments is intensive. Specially, the safety of high pressure reactor vessel is required among them. The material selected in this study is 2.25Cr-1Mo steel that is widely used for high pressure reactor vessel material of petrochemical plant. Eight kinds of artificially aged specimens were prepared by differing from aging periods under three different temperatures. The material was iso-thermally heat treated at higher temperatures than $391^{\circ}C$ that is the operating temperature of high pressure reactor vessel. Vickers hardness properties and electrical resistivity properties about artificially aged material as well as un-aged material were measured, and master curves were made out from the correlation with larson-Miller parameter. And electrical resistivity properties as well as Victors hardness properties measured at high pressure reactor vessel of the field were compared with master curves made out in a laboratory. Degradation evaluation possibility in the field of high pressure reactor vessel by using electrical resistivity method was examined. Electrical resistivity property measured in the field is similar with that of artificially aged material in similar aging level.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.7
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• pp.599-606
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• 2019

Most facilities that manufacture products made from the hazardous materials operate at high temperatures and pressures. Therefore, there is a risk of fire explosion. In particular, an explosion accident is a major risk factor for facilities with hazardous materials, such as oil, chemical, and gas. Propylene is often used in sites producing basic raw materials and synthetic materials by addition polymerization at petrochemical plants. To prevent an explosion in the business using propylene, the explosion range with the oxygen concentration was calculated according to the changes in temperature and pressure using an inert gas, carbon dioxide. In these measurements, the temperature was $25^{\circ}C$, $100^{\circ}C$, and $200^{\circ}C$ and the amount of carbon dioxide in the container was $1.0kgf/cm^2.G$, $1.5kgf/cm^2.G$, $2.0kgf/cm^2.G$, and $2.5kgf/cm^2.G$. The explosion limit was related to temperature, pressure, and oxygen concentration. The minimum oxygen concentration for an explosion decreased with increasing temperature and pressure. The range of explosion narrowed with decreasing oxygen concentration. In addition, no explosion occurred at concentrations below the minimum oxygen concentration, even with steam and an ignition source of propylene.

• Journal of the Korean Institute of Gas
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• v.20 no.5
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• pp.17-26
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• 2016

Chemical plants and oil gas refinery facilities are intrinsically vulnerable to industrial hazards, such as explosion or fire. Especially, the fire is extremely dangerous to facility structures and plant personnel because of direct flame, radiant heat and smoke. In addition, it has the ripple effect of destroying infra-structures and polluting the environment. In an effort to tackle these potential industrial risks, the procedure of FRA techniques in chemical plants were investigated. The main focus was put on the time variation of physical properties of the main building, i.e. control rooms, warehouses and electrical substations, from a direct flame contact and radiant heat. The deformation of a building due to fire was monitored and modeled with respect to time variable. A variety of case studies, domestic and abroad, was tested in the model to verify the FRA procedure. The developed model was proven to be highly effective to reduce the possible risks at chemical plants. An accurate accident frequency prediction and damage quantification was made by the developed model.

• Korean Chemical Engineering Research
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• v.58 no.4
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• pp.550-564
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• 2020

Distillation columns are one of the main equipment used for the separation of chemical components in petrochemical process design. However, in spite of the efficient operation in wide range, and the advantage of data collection for equipment verification, the distillation columns are inherently known for high energy consumption and capital cost. Hence, the trade-off analysis needs to be done between investment cost and operation cost to develop the most economical distillation columns. This study was conducted using Aspen Plus, a popular process simulation program, in the pursuit of broad application by as many process engineers as possible. In this paper, design variables for optimization of distillation columns were defined to improve emphatically the design quality with reducing erratic practice of many engineers. In addition, by eliminating unnecessary reviewing step and establishing systematic and efficient procedures, the amount of time for design and human resources were minimized. Aspen Process Economic Analyzers (APEA) program was introduced in order to calculate the investment cost reliably, and the efficient systematic procedure for utilization of APEA was established.