• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.6
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• pp.1745-1753
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• 2008

We analyzed the physical and chemical properties such as proximate analysis, ultimate analysis, heating values, thermogravimetric analysis, and combustion test for the organic sludge discharged from chemical and petrochemical product manufacturing industries in the industrial complex. The average combustible and ash content of organic sludges from chemical and petrochemical product manufacturing industries were 17.42%, 7.45%, and 18.25%, 4.22%, respectively. The C, H, O, N, and S compositions for chemical and petrochemical product manufacturing industries were 33.06, 4.34, 24.81, 5.18, and 0.72%. And those compositions for petrochemical product manufacturing industries were 36.58, 4.74, 26.79, 5.09, and 0.49%, respectively. From the TGA test, the minimum temperature for combustion of the sludge discharged from B company was $700^{\circ}C$ for direct use for energy and 2 sludges(F and N companies) were about $600^{\circ}C$. According to the basic combustion test, high concentration of CO was formed because oxidation and pyrolysis reaction take place in the batch type reactor at the same time. From this phenomena we could obtain the significant data for the overheating and breakage of furnace.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.4
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• pp.301-306
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• 2016

During the initial stage of propulsion shaft design, the shaft alignment process includes a thorough consideration of lateral vibration to verify the operational safety of the shaft. However, a theoretical method for analyzing forced lateral vibrations has not been clearly established. The methods currently used in classification societies and international standards can only ensure a sufficient margin to avoid the blade-passing frequency resonance speed outside the range of ${\pm}20%$ of the maximum continuous rating (MCR) for the engine. Typically, in shaft alignment analyses, longer center distances between the support bearings promote affirmative results, but the blade order resonance speed can approach the lower limit for lateral vibration. Therefore, this matter requires careful attention by engineers, and a verification of the theoretical analysis by experimental measurements is highly desirable. In this study, both theoretical and experimental analyses were conducted using strain gauges under two draught conditions of vessels used as 50,000-DWT oil/chemical tankers, introduced recently as eco-friendly ships. Based on the analyses, the influence of the lateral vibration on the shafting system and the system's reliability was reviewed.

• The Korean Journal of Petroleum Geology
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• v.5 no.1_2 s.6
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• pp.48-58
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• 1997

Core samples from the B, E, F, H wells in the Tertiary Pohang Basin were analysed for total organic carbon (TOC) content and subject to Rock-Eval pyrolysis in order to assess petroleum geochemical characteristics of organic matter. Following geochemical screening, we selected samples from each well for the study of bitumen and kerogens such as optical observation, infra-red spectroscopy and biomarker analyses. Sediments of the Tertiary Yonil Group contain total organic carbon ranging from $0.55{\%} to 3.74{\%}$ with S1+S2 values higher than 2mgHC/g Rock in B, E and F wells, which indicates fair hydrocarbon generation potential. Most organic matter in the B, E, F wells is compared to type II based on the Rock-Eval pyrolysis, infra-red spectroscopy and optical observation. However, organic matter in the H well is compared to type III because the well is located at the margin of the basin where the preservation of terrestrial material is dominant. Geochemical analyses show that organic matter in the Yonil Group is thermally immature although thermal maturity slightly increases with depth. Maturity levels of the extracted kerogens are similar to those of bulk samples ($Tmax<435^{\circ}C$. Petroleum geochemical charateristics of the sediments in the Tertairy Yonil Group is fair in terms of the organic richness and hydrocarbon genetic potential, but organic matter is thermally immature due to the shallow burial depth. Optical observation of the kerogens and biomarker analysis show that organic matter in the Yonil Group is both marine and terrestrial origin, although it was deposited in marine environment. Pristane/phytane ratio suggests rather anoxic depositional environment. Transitional characteristics of organic matter indicate that the marine Yonil Group was deposited near the terrestrial environments. Input of terrestrial organic matter is more prevalent in the samples recovered from the lowermost horizon in the wells due to the terrestrial environment at the time of basin formation.

• Fire Science and Engineering
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• v.29 no.1
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• pp.7-11
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• 2015

In Korea, The protective action distance based on Canada's ERG has been adopted for safety of residents in case of hazardous chemicals leakage accident. However, it couldn't respond properly on the accidents because of geographical and meteorological differences between two nations. In this study, It was found that the protective action distance varies depending on season and terrain, Through AERMOD modeling analysis for the petrochemical complex reflected local geographical data and meteorological conditions.

• Annual Conference of KIPS
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• 2000.10a
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• pp.457-460
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• 2000

연안역은 산업, 가정 폐기물의 종착지이고 중기계금속산업과 석유화학산업단지가 다수 포진하고 있는 지역으로 환경에 유해한 물질들로 대기나 수질을 통해 오염되기 쉬운 여건을 가지고 있으므로, 쾌적한 환경을 위한 환경 모니터링이 불가피한 곳이다. 이에 연안역의 환경 모니터링을 위한 정확한 분석결과를 현장에서 측정할 수 있으며 사용자의 편의성을 제공하는 새로운 시스템의 도입이 시급한 실정이다. 연구개발 중인 수질 및 대기 모니터링 시스템은 전문지식이 필요 없이도 테스트의 수행, 테스트 자료, 분석결과의 관리를 위해 구축했는데 특히 사용자 인터페이스의 검량선, 정량분석을 중점으로 본 논문에서 서술하였다.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.4
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• pp.288-294
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• 2016

In modern ships, the shafting system often becomes stiff owing to the high engine power, whereas the hull structure becomes more flexible owing to optimization using high-tensile-strength thick steel plates; therefore, more sophisticated shaft alignments are required. In this study, strain gauge-based measurement was conducted under five vessel operating conditions and bearing reaction forces and hull deflections affecting shaft alignment were analyzed for a 50,000 dead weight tonnage oil/chemical tanker that has gained repute as an eco-friendly vessel in recent years. Furthermore, the analytical results from each technique-theoretical calculation, jacking ups, and strain gauges-were cross-checked against each other in order to enhance the degree of accuracy and reliability of the calculation.

• Economic and Environmental Geology
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• v.42 no.1
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• pp.55-72
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• 2009

The timing of hydrocarbon generation and expulsion from source rocks can be evaluated by reconstructing the geohistory of the basin using petroleum system modeling. The Tyee basin is generally considered having a high hydrocarbon generation potential For the southern part of the basin, the basin evolution from a structural and stratigraphic points of view, the thermal history, and the burial history were reconstructed and simulated using numerical tools of basin modeling. An evaluation of organic geochemistry for the potential source rocks and the possible petroleum systems were analysed to improve the understanding of the hydrocarbon charge of the basin. Organic geochemical data indicate that the undifferentiated Umpqua Group, mudstones of the Klamath Mountains, and coals and carbonaceous mudstones in the Remote Member and the Coquille River Member are the most potential gas-prone source rocks in the basin. The relatively high maturity of the southern Tyee basin is related to deep burial resulting from loading by the Coos bay strata. And the heating by intrusion from the western Cascade arc also affects to the high maturity of the basin. The maturation of source rocks, the hydrocarbon generation and expulsion were evaluated by means of basin modeling. The modeling results reveal that the hydrocarbon was generated in all potential source rocks and an expulsion only occurred from the Remote Member.

• Fire Science and Engineering
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• v.29 no.6
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• pp.65-70
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• 2015

This research examines the removal efficiency of benzene, toluene, xylene (BTX) and total volatile organic compounds (TVOCs) by flowing VOCs, which are generated at a petrochemical complex in the Ulsan area, in a sliding arc plasma (SAP) reactor. The SAP reactor process is composed of 5 steps and the analysis was conducted using a BTX detector and TVOC measuring instrument. The removal efficiency of BTX was better at high concentration than at low concentration and the emitted TVOC concentration increased in later steps of the reactor. In addition, the removal efficiency improved, as the flow velocity increased. The maximum permissible concentration of TVOCs in the first step was about 481 ppm and showed over 94.83% efficiency when it was operated in the 2nd step at concentrations beyond 481 ppm. Therefore, there are many factors for improving the removal efficiency of SAP reactors at low concentration and measures should be prepared according to the application method for the various types of industrial reactors.

• Fire Science and Engineering
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• v.14 no.2
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• pp.1-6
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• 2000

The radiant energy from a flaming fire of fuels containing carbonaceous material can be applied to fast growing fire. Raiant energy sensinsing technique applied detectors are ultimately effective when early detecting fire alarm system is required or the smoke and heat detectors can not be applied. This study investigated the characteristics of sun light, artificial light and flame radiation light and the foundation technique of flame detecting is established. Pyroelectric element proper for the characteristics of flame radiant energy developed and circuit stabilizing technique, electro-magnetic immunity technique, durable and reliable operating technique to circuits developed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.10
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• pp.598-602
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• 2018

This study examined the characteristics of the waste catalyst used in the petroleum refinery operations. The total pore volume, specific surface area, and average pore size of the spent catalyst used in the petroleum refinery operations were 3.96cc/g, 13.81m2/g, and 1.15A, respectively. The weight loss observed in the range from $25^{\circ}C-700^{\circ}C$ for the spent catalysts using TG and DTA was approximately 23 wt. %. EDS analysis of the waste catalyst sample showed that the five major components were vanadium, nickel, manganese, iron, and copper. The extraction system is attractive for liquid-liquid extraction. In this study, Cynex 272 was used to extract vanadium from waste catalyst. The electrochemical characteristics of the extracted vanadium solution were measured by cyclic voltammetry (CV). As a result, an oxidation / reduction peak appeared, indicating the potential of an electrolytic solution.