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Development of New Natural Antioxidants for Cosmeceuticals (천연물 유래 항산화 기능성 화장품 신소재 개발)

  • Yoo, Ick-Dong;Kim, Jong-Pyung;Kim, Won-Gon;Yun, Bong-Sik;Ryoo, In-Ja
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.31 no.4 s.54
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    • pp.349-357
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    • 2005
  • New antioxidative substances for cosmeceuticals were screened from natural resources such as microbial metabolites, mushrooms, and medicinal plants. Four antioxidants were isolated from the fungal metabolite of Eupenicillium shearii and their structures were determined to be new phenolic compounds. The compounds were designated as melanocins A, B, C, and D. Melanocins $A{\sim}D$ exhibited free radical scavenging activity on DPPH and superoxide with $EC_{50}$ values of $21{\sim}94\;and\;7{\sim}84{\mu}M$, respectively, which were stronger activity than those of ${\alpha}-tocopherol$ and BHA. Melanocin A showed anti-wrinkle effects on the UV-irrated hairless mouse skin. A novel hispidin antioxidative compound designated as inoscavin A was isolated from the fruiting body of the mushroom, Inonotus xeranticus. Inoscavin A scavenged superoxide radical with $EC_{50}$ values of $0.03{\mu}g/mL$, and inhibited rat liver microsomal lipid peroxidation with $EC_{50}$ values of $0.3{\mu}g/mL$. Benzastatins $A{\sim}G$, the novel antioxidants isolated from the culture of Streptomyces nitrosporeus showed potent lipid peroxidation inhibitory activity with $EC_{50}$ values of $3{\sim}30{\mu}M$. A cyclopentene compound with strong hypopigmentary effect was isolated from the fungal metabolite of Penicillium sp. and identifed as terrein. Terrein significantly reduced melanin levels in a melanomacyte cell line, Mel-Ab. It showed 10 times stronger activity than kojic acid, but exhibited no cytotoxic effect even in $100{\mu}M$. It was suggested that terrein reduced melanin synthesis by reducing tyrosinase production by MITF down-regulation.

Effects of Drain Bias on Memory-Compensated Analog Predistortion Power Amplifier for WCDMA Repeater Applications

  • Lee, Yong-Sub;Lee, Mun-Woo;Kam, Sang-Ho;Jeong, Yoon-Ha
    • Journal of electromagnetic engineering and science
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    • v.9 no.2
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    • pp.78-84
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    • 2009
  • This paper represents the effects of drain bias on the linearity and efficiency of an analog pre-distortion power amplifier(PA) for wideband code division multiple access(WCDMA) repeater applications. For verification, an analog predistorter(APD) with three-branch nonlinear paths for memory-effect compensation is implemented and a class-AB PA is fabricated using a 30-W Si LOMaS. From the measured results, at an average output power of 33 dBm(lO-dB back-off power), the PA with APD shows the adjacent channel leakage ratio(ACLR, ${\pm}$5 MHz offset) of below -45.1 dBc, with a drain efficiency of 24 % at the drain bias voltage($V_{DD}$) of 18 V. This compared an ACLR of -36.7 dEc and drain efficiency of 14.1 % at the $V_{DD}$ of 28 V for a PA without APD.

Characteristics of Soil Electrical Conductivity in Plastic Film House Located in Southern Part of Korea (남부지방(南部地方) 시설재배지(施設栽培地) 토양(土壤)의 염농도(鹽濃度) 특성(特性))

  • Ha, Ho-Sung;Lee, Yong-Bok;Sohn, Bo-Kyoon;Kang, Ui-Gum
    • Korean Journal of Soil Science and Fertilizer
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    • v.30 no.4
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    • pp.345-350
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    • 1997
  • Characteristics of electrical conductivity(EC) of seventy one-greenhouse soil located in southern part of Korea were surveyed to obtain the basic information for sustainable management of plastic film house soils. The averaged soil EC were 5.84 and 2.49dS/m for top-and sub-soil, respectively, showing distribution of 11.3% for top-soils and 50.7% for sub-soils within the optimum level of 2.0 dS/m. On the whole, the soils with flowering plants revealed higher EC than those with fruiting vegetables showing 2.75~6.34dS/m for the former and 2.29(sub-soils)~5.13dS/m(top-soils) for the latter. In a view of soil sampling time, the soils at Feb., 1996 marked 4.3~37.7% and 10.3(top-soils)~11.3%(sub-soils) higher EC compared with the soils at Sept. and Dec., 1995, respectively. The linear regression correlation coefficients of soil minerals to EC were in oder of $Mg^{2+}$ > $NO_3{^-}$ > $Cl^-$ > $Ca^{2+}$ > $SO_4{^{2-}}$ > $K^+$ for top-soils and were $Cl^-$ > $SO_4{^{2-}}$ > $NO_3{^-}$ > $Ca^{2+}$ > $Mg^{2+}$ > $K^+$ for sub-soils. In especial, the concentration of soil EC accompanied the increasing population ratio of soil fungi to bacteria and/or actinomycetes.

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The Effect of Calcination Temperature on the Layered Li1.05Ni0.9Co0.05Ti0.05O2 for Lithium-ion Battery (리튬이온전지용 층상 Li1.05Ni0.9Co0.05Ti0.05O2에 대한 소성 온도의 영향)

  • Ko, Hyoung Shin;Park, Hyun Woo;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.718-724
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    • 2018
  • In this study, the $Ni_{0.9}Co_{0.05}Ti_{0.05}(OH)_2$ precursor was prepared by the concentration gradient co-precipitation method. In order to overcome the structural change due to oxygen desorption in the cathode active material with high nickel content, the physical and electrochemical analysis of the cathode active material according to the calcination temperature were investigated. Physical properties of $Li_{1.05}Ni_{0.9}Co_{0.05}Ti_{0.05}O_2$ were analyzed by FE-SEM, XRD and TGA. The electrochemical performance of the coin cell using a cathode active material and $LiPF_6$(EC:EMC=1:2 vol%) electrolyte was evaluated by the initial charge/discharge efficiency, cycle retention, and rate capabilities. As a result, the initial capacity and initial efficiency of cathode materials were excellent with 244.5~247.9 mAh/g and 84.2~85.8% at the calcination temperature range of $750{\sim}760^{\circ}C$. Also, the capacity retention exhibited high stability of 97.8~99.1% after 50cycles.

Chemical Characteristics of Ground Water for Hydroponics and Waste Nutrient Solution after Hydroponics in Chungbuk Area (충북지역 양액 재배용 지하수 및 폐양액의 화학적 특징)

  • Lee, Gyeong-Ja;Kang, Bo-Goo;Lee, Ki-Yeol;Yun, Tae;Park, Seong-Gyu;Lee, Cheol-Hee
    • Korean Journal of Environmental Agriculture
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    • v.26 no.1
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    • pp.42-48
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    • 2007
  • This survey has been conducted to obtain basic data of the quality of ground water for hydroponics and waste nutrient solution after hydroponics in hydroponic farms in Chungbuk area. Ground water samples were collected and analyzed at 19 sites of hydroponic farms. Waste nutrient solution samples were analyzed at 15 sites selected of them. The values of several components in ground water for hydroponics were as follows. pH range was shown from 6.2 to 7.7 and the average was 6.8. EC range was shown from 0.10 to 0.45 dS $m^{-1}$ and the average 0.23 dS $m^{-1}$. $NO_3-N$ concentrations was ranged from 0.12 to 13.77 mg $L^{-1}$, $SO_4^{2-}$ concentrations was ranged from 1.84 to 63.01 mg $L^{-1}$ and $Cl^-$ concentrations were ranged from 10.46 to 72.09 mg $L^{-1}$. Average values of $NO_3-N$, $SO_4^{2-}$ and $Cl^-$ were 4.00 mg $L^{-1}$, 12.70 mg $L^{-1}$ and 27.57 mg $L^{-1}$, respectively. $Ca^{2+}$, $Mg^{2+}$ and $Na^+$ concentrations were ranged from 3.24 to 36.99 mg $L^{-1}$, 1.44 to 14.93 mg $L^{-1}$ and 6.12 to 25.25 mg $L^{-1}$, respectively. Average concentrations were 13.06 mg $L^{-1}$ in $Ca^{2+}$, 6.02 mg $L^{-1}$ $Mg^{2+}$ and 12.08 mg $L^{-1}$ in $Na^+$. In waste nutrient solution after hydroponics, pH range was shown from 4.3 to 8.8 and the average was 6.7. EC range was shown from 0.44 to 2.37 dS $m^{-1}$ and the average 1.15 dS $m^{-1}$. Range of $NO_3-N$, $PO_4-P$, $K^+$, $Ca^{2+}$, $Mg^{2+}$ and $Na^+$ in waste nutrient solution were $10{\sim}212$, $0.56{\sim}26.1$, $10{\sim}295$, $16{\sim}215$, $9{\sim}54$ and $10{\sim}53$ mg $L^{-1}$ respectively. Average concentration were 100 mg $L^{-1}$ in $NO_3-N$, 12.15 mg $L^{-1}$ in $PO_4-P$, 99 mg $L^{-1}$ in $K^+$, 78 mg $L^{-1}$ in $Ca^{2+}$, 26 mg $L^{-1}$ in $Mg^{2+}$ and 26 mg $L^{-1}$ in $Na^+$. Inorganic matters in waste nutrient solution after hydroponics was higher than that of ground water for hydroponics.

Evaluation of Soil in Planting Ground at Seashore Reclaimed Land in Incheon (인천지역 해안매립지 식재기반 평가 연구)

  • Kim, Won-Tae;Yoon, Yong-Han;Kim, Jeong-Ho
    • Journal of Environmental Science International
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    • v.20 no.11
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    • pp.1447-1455
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    • 2011
  • The purpose of this study was to analyze physicochmical characteristics of oil within planting base of Incheon coastal reclamation cities where 10 years have passed since reclamation, and to provide basic data to promote growth and development of plants by conducting evaluation based on the planting degree standard. Study targets were Cheongra, Sondo, and Yeongjong districts within Incheon Free Economic Zone, the coastal reclamation city. The analysis results of average soil characteristics of 3 districts. Soil acidity(pH) was shown in orders of Cheongra district(8.85) > Songdo district(8.70) > Yeongjong district(7.97) and electric conductivity(EC) was shown in orders of Cheongra district(4.80 dS/m) > Songdo district(1.30dS/m) > and Yeongjong district(0.07 dS/m). Organic matter content(OMC) was shown in orders of Cheongra district(5.72%) > Songdo district(2.60%) > Yeongjong district(0.59%) and available phosphate was shown in orders of Cheongra district(70.70 mg/kg) > Songdo district(23.07 mg/kg) > Yeongjong district(2.49 mg/kg). $K^+$ was shown in orders of Songdo district(0.84 cmol/kg) > Cheongra district(0.74 cmol/kg) > Yeongjong district(0.22 cmol/kg), $Ca^{++}$ was shown in orders of Cheongra district(22.08 cmol/kg) > Songdo district(9.87 cmol/kg) > Yeongjong district(4.04 cmol/kg), and $Mg^{++}$ was shown in orders of Cheongra district(1.98 cmol/kg) > Songdo district(1.22 cmol/kg) > Yeongjong district(1.12 cmol/kg). Planting base level of coastal reclaimed land can be applied with above intermediate level, soil acidity and available phosphate were all more than intermediate in 3 districts, and electric conductivity was low level in Cheongra district and more than intermediate level in Songdo and Yeongjong districts. Organic matters content was more than intermediate level in Cheongra district and low level in Songdo and Yeongjong district. $K^+$ among exchangeable ions was intermediate level in Cheongra and Songdo districut and low in Yeongjong district. $Ca^{++}$ and $Mg^{++}$ both were more than imtermidiate levels in 3 districts.

Growth responses of New Zealand Spinach [Tetragonia tetragonoides (Pall.) Kuntze] to different soil texture and salinity (신규 채소작물용 번행초의 토성 및 염도에 대한 생육 반응)

  • Kim, Sung-Ki;Kim, In-Kyung;Lee, Geung-Joo
    • Korean Journal of Agricultural Science
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    • v.38 no.4
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    • pp.631-639
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    • 2011
  • This research was conducted to investigate potential use of New Zealand spinach (Tetragonia tetragonoides) as a new vegetable crop which will be cultivating in salt-affected soils including reclaimed land. Traditionally New Zealand spinach has been studied to explore functional compound or salt removing potential. To cultivate the crop species in the salt-affected soil widely, it is essential to obtain salt and soil texture responses under the controlled environment. Fifty nine New Zealand spinach ecotypes native to Korean peninsula first collected over seashore areas, and primitive habitat soil environment was evaluated by analyzing soil chemical properties from 32 locations. Different textures of sandy, silt loam, and sandy loam soils were prepared from nearby sources of sea shore, upland and paddy soils, respectively. Target salinity levels of 16.0 dS/m, 27.5 dS/m, 39.9 dS/m, and 52.4 dS/m in electrical conductivity (ECw) were achieved by diluting of 25, 50, 75, 100% (v/v) sea water to tap water (control, 0.6 dS/m), respectively. Various measurements responding to soil texture and irrigation salinity included plant height, root length, fresh weight (FW), dry weight (DW), leaf parameters (leaf number, leaf length, leaf width), lateral branching, and inorganic ion content. was found to adapt to diverse habitats ranging various soil chemical properties including soil pH, organic matter, exchangeable bases, EC, and cation exchange capacity (CEC) in Korea. Responding to soil texture, New Zealand spinach grew better in silt loam and sandy loam soil than in sandy soil. Higher yield (FW and DW) seemed to be associated with branch number (r=0.99 and 0.99, respectively), followed by plant height (r=0.94 and 0.97, respectively) and leaf number (r=0.89 and 0.84, respectively). Plant height, FW, and DW of the New Zealand spinach accessions were decreased with increasing irrigation salinity, while root length was not significantly different compared to control. Based on previous report, more narrow spectrum of salinity range (up to 16 dS/m) needs to be further studied in order to obtain more accurate salinity responses of the plant. As expected, leaf Na content was increased significantly with increasing salinity, while K and Ca contents decreased. Growth responses to soil texture and irrigation salinity implied the potential use of New Zealand spinach as a leafy vegetable in salt-affected soil constructed with silt loam or sandy loam soils.

Comparison of Growth and Essential Oil Composition in Two Hydroponically Grown Species of Thymes at Different Nutrient Solution Strength (수경재배시 배양액 내 이온농도에 따른 두 종의 백리향 생육 및 정유 성분 비교)

  • 김예희;이문정;박권우
    • Journal of Bio-Environment Control
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    • v.9 no.2
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    • pp.79-84
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    • 2000
  • The growth and quality differences between common thyme(Thymus vulgaris L.) and lemon thym (Thymus$\times$citriodorus) were investigated. They were grown in a hydroponics culture system (DFT) with a nutrient solution developed by the European Vegetable R&D Center in Belgium. Nutrient solution ionic strength used were 1.2, 2.4, 4.8 and 7.2 mS.cm-1. The dry matter of two thymes were increased with increasing ionic strength, while shoot length, root length and fresh weight were decreased. Chlorophyll content was higher in lemon thyme, while vitamin C content and essential oil content were higher in common thyme. The essential oil content showed a similar trend as those of growth. The main compostion of essential oil were thymol and carvacrol in common thyme, and geraniol and $\alpha$-citral in lemon thyme. The highest content of these compounds was obtained in 1.2mS.cm-1 treatment. Consequently, the ionic strength of 1.2mS.cm-1 was suitable for the production of quality thymes.

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Efficiency of Various Nutritional Sources to Improve Physical Properties of Saline-Sodic Soil

  • Noor-Us-Sabah, Noor-Us-Sabah;Sarwar, Ghulam;Ibrahim, Muhammad;Tahir, Mukkram Ali;Iftikhar, Yasir;Haider, Muhammad Sajjad;Han, Kyung-Hwa;Ha, Sang-Keun;Zhang, Yong-Seon
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.1
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    • pp.93-97
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    • 2012
  • This study was conducted to evaluate the efficiency of various inorganic and organic materials to improve physical properties of soil. Saline sodic soil (saturation percentage = 40.36%, $EC_e=5.15dS\;m^{-1}$, $pH_s=8.70$, $SAR=18.84(m\;mol\;L^{-1})^{1/2}$, bulk density =$1.49Mg\;m^{-3}$) was collected, brought to wire house and filled in pots after laboratory analysis for various parameters. Different sources of organic nutrients like farm manure (FM), press mud, compost, poultry manure and sesbania green manure were analyzed for their chemical composition. The experiment comprised of 12 treatments replicated thrice; $T_1$: control (recommended NPK), $T_2:{\frac{1}{2}}$ recommended NPK, $T_3$: FM at 1.5% by soil weight, $T_4$: pressmud at 1.5% by soil weight, $T_5$: compost at 1.5% by soil weight, $T_6$: poultry manure at 1.5% by soil weight, $T_7$: sesbania green manure at 1.5% by soil weight, $T_8:T_2$ + FM at 0.75% by soil weight, $T_9:T_2$ + pressmud at 0.75% by soil weight, $T_{10}:T_2$ + compost at 0.75% by soil weight, $T_{11}:T_2$ + poultry manure at 0.75% by soil weight, $T_{12}:T_2$ + sesbania green manure at 0.75% by soil weight. These treatments were applied using completely randomized (CR) design and appropriate time was given to decompose these organic nutritional sources. Seeds of wheat cultivar Sahar-2006 were sown. After harvesting the wheat, soil samples were collected from each pot and analyzed for various physical properties like bulk density, porosity and saturation percentage. An improvement in physical properties (bulk density, porosity and saturation percentage) of soil was noticed with the application of various organic nutritional sources but role of compost alone ($T_5$) remained prominent.

Influence of Ultrasonification on Extraction Yield and Chemical Property of Green Tea Infusion (초음파 처리가 녹차 침출액의 추출 수율 및 화학적 특성에 미치는 영향)

  • Kim, Byung-Chul;Kang, Sung-Won;Chung, Chang-Ho;Heo, Ho-Jin;Lee, Seung-Cheol;Cho, Sung-Hwan;Choi, Sung-Gil
    • Journal of agriculture & life science
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    • v.44 no.5
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    • pp.91-99
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    • 2010
  • The objective of this work was to investigate the influence of ultrasonification on extraction yield and chemical properties of green tea infusion. Changes in total soluble matter(TSM), vitamin C, total phenolic compounds, flavonols, catechins, caffeine, free amino acids contents in green tea infusion(GTI) influenced by ultrasonification at $60^{\circ}C$ of extraction temperature for 1, 5, 30, and 60 min were investigated. The amount of infused TSM increased about 5.3% by ultrasonification for 60min. Vitamin C contents also increased 0.21, 0.16, 0.31 mg/g from 1 to 30 min by ultrasonification. However, vitamin C decreased from 2.47 to 2.22 mg/g at 60min. Total phenol compounds contents increased about 10~13 mg/g on all extraction times by ultrasonification. Flavonols such as, myricetin, quercetin, kaempferol were increased to doubled contents as an influence of ultrasonification. Catechins such as, EGCG, EGC, ECG, EC, (+)-C and caffeine contents showed same tendency as the results of vitamin C. On the other hand, result of free amino acids showed different tendency. All amounts of free amino acids did not increase by ultrasonification. Consequently, content of bioactive compounds such as, vitamin C, total phenolic, flavonols and catechins in green tea infusion were influenced by ultrasonification.