• Title/Summary/Keyword: 생지화학

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Vertical distributions of dissolved eu and Ni in the central East Sea (동해 중앙 해역의 용존 Cu와 Ni의 수직적 분포)

  • Yang, Jae-Sam
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.2 no.2
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    • pp.117-124
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    • 1997
  • Vertical profiles of dissolved Cu and Ni at the upper 400 m water layer have been determined at two stations in the central East Sea in October 1995. This is the first report on the vertical distribution of trace metals in Korea. Copper concentrations are in the range of 2.1~5.8 nmol/kg and 1.6~2.4 nmol/kg for stations S and N, respectively. The vertical profile of Cu at S is found a scavenging type (i.e., drastic decrease with increasing depth). Concentrations of Ni range from 4.3 to 7.1 nmol/kg and from 3.4 to 5.4 nmol/kg for stations Sand N, respectively. At station S, Ni is best correlated with phosphate, but not at stations N. Such difference between two stations are probably due to their different vertical distribution of water masses. Station S has a strongly stratified water column with 6 distinct water masses, but station N with a well-mixed subsurface water layer extending from 50 to 300 m depth. Extremely low salinity (31.87~31.96 psu) found at the surface water of station S was interpreted as a result of the Yangtze River effluents which were probably fed into the East Sea through the Korea Strait during the late summer. Such seasonal appearance of low salinity in southern part of the East Sea was reported previously. The concentrations of Cu and Ni at two sites are comparable to those reported in the North Pacific. It was found that Ni mostly exist as dissolved phase.

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Significance of Estuarine Mixing in Distribution of Bacterial Abundance and Production in the Estuarine System of the Mankyung river and Dongjin River, Korea (만경강 및 동진강 하구의 박테리아 개체수와 생산량 분포에 있어서의 하구 혼합 (estuarine mixing)의 중요성)

  • CHO, BYUNG CHEOL;SHIM, JAE HYUNG
    • 한국해양학회지
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    • v.27 no.2
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    • pp.154-163
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    • 1992
  • Bacterial abundance, production, and environmental parameters were investigated three times to study distribution of bacterial variables and to examine how estuarine mixing would influence the distribution of bacterial variables in the euphotic zone of the estuarine system of the Mankyung river and Dongjin river during a period of October, 1990-August, 1991. Although a limited number of investigations were made, bacterial abundance and production showed large variations from 0.4 to 5.8${\times}$10/SUP 9/ 1/SUP -1/ and from 0.1 to 22.2 ug C 1/SUP -1/ d/SUP -1/, respectively. The wide ranges of bacterial variables indicated very dynamic changes in conditions of bacterial growth in the estuary. Interestingly, bacterial abundance substantially increased with depth in most stations f shallow depth. but bacterial production remarkably decreased with depth. We propose that the observed distribution of bacterial abundance and production would be explained by estuarine mixing in the estuary. Analyses of mixing diagrams showed that estuarine mixing would mix conservatively bacteria and bacterial production. Further, estuarine mixing often seemed to cause an increase in bacterial abundance and reduction of bacterial production presumably due to resuspension of sediment. This suggests that roles of estuarine mixing would be significant in the distribution of bacterial abundance and production, and thus in biogeochemical cycles in the estuary.

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Processes and Fluxes of Uranium Removal Across the Sediment-Water Interface: A Biogeochemical Approach (해수-퇴적물 경계면을 지나는 우라늄 제거 과정과 플럭스 연구: 생지화학적 접근)

  • Kim, Kee-Hyun;Cho, Jin-Hyung;Lee, Jae-Seong
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.4 no.3
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    • pp.188-197
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    • 1999
  • In order to estimate the uranium flux from seawater to sediments, we took pore water samples and deployed benthic chambers on seafloor of Chonsu Bay, Korea. The uranium flux across the sediment-water interface was estimated from the pore water to be 0.112-0.566 mg/$m^2yr$, corresponding to a removal flux of $4.3-21.5{\times}10^7$ gU/yr for the entire Yellow Sea. Nutrient fluxes from sediment to bottom water were estimated to be 135.6 mmol/$m^2yr$ for ammonia, 228.2 mmol/$m^2yr$ for nitrate, 36.8 mmol/$m^2yr$ for phosphate and 23.9 mmol/$m^2yr$ for silicate. The redox boundary, based on the distribution of pore water nitrate and solid phase manganese, was located at 3-5 cm below the sediment surface. Phosphate flux obtained by benthic chambers was 28.S mmol/$m^2yr$. On the other hand, estimates of uranium and silicate fluxes were orders of magnitude greater than those based on pore water profiles. Flux estimates on the basis of pore water concentration is believed to have greater reliability than those obtained from benthic chamber data.

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Status and Prospect of Unmanned, Global Ocean Observations Network (글로벌 무인해양관측 네트워크 현황과 전망)

  • Nam, Sunghyun;Kim, Yun-Bae;Park, Jong Jin;Chang, Kyung-Il
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.19 no.3
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    • pp.202-214
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    • 2014
  • We introduce status and prospect of increasingly utilizing, unmanned, global ocean observing systems, and the global network to integrate, coordinate, and manage the systems. Platforms of the ocean observing system are diversified in order to resolve/monitor the variability occurring at multiple scales in both three-dimensional space and time. Here purpose, development history, and current status of the systems in two kinds - mobile (surface drifter, subsurface float, underwater glider) and fixed platforms (surface and subsurface moorings, bottom mounts), are examined and the increased future uses to produce synergies are envisioned. Simultaneous use of various mobile and fixed platforms is suggested to more effectively design the observing system, with an example of the NSF-funded OOI (Ocean Observations Initiative) program. Efforts are suggested 1) to fill the data gap existing in the deep sea and the Southern Ocean, and toward 2) new global network for oceanic boundary currents, 3) new technologies for existing and new sensors including biogeochemical, acoustic, and optical sensors, 3) data standardization, and 4) sensor calibration and data quality control.

Contribution of Nutrient Flux through the Korea Strait to a Primary Production in the Warm Region of the East Sea (동해 난수역의 일차생산에 대한 대한해협 유입 영양염의 기여)

  • Lee, Tongsup;Rho, Taekeun
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.18 no.2
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    • pp.65-69
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    • 2013
  • In situ measurement of a primary production in East Sea, a marginal sea with a fair accessibility, is nonetheless an arduous task because of dynamic variability. In this study, we estimated the mean value of background (gross) primary production over the warm region of the East Sea based on a biogeochemical hypothesis. We propose an immiscible-shoaling hypothesis for the estimation of primary production, which assumes that primary production in the warm region occurred only by the nutrient supply through the Korea Strait. Annual primary production thus estimated is $209\;gC\;m^{-2}\;y^{-1}$, which is comparable to the satellite-based estimates of net primary production in the region. However, since this hypothesis assumes that primary production is based on only the new nutrients supplied to the system, primary production would increase by 40% if we release the assumption, and assume f = 0.6. This suggests that nutrient influx through the Korea Strait alone is more than enough to support primary production previously reported. Primary production may increase as much as two times if we considered other external perturbations excluded intentionally to estimate the background level of primary production, such as coastal upwelling, submerged ground water discharge, aeolian input, ocean dumping, and mixing by typhoons as well as the contribution of cyanobacteria that has not been quantified in the region. This implies the primary production in the warm region of the East Sea would be comparable to that of the Peru upwelling region with f = 0.6.

Anaerobic Mineralization of Organic Matter and Sulfate Reduction in Summer at Ganghwa Intertidal Flat, Korea (하계 강화도 갯벌의 혐기성 유기물 분해능 및 황산염 환원력)

  • Hyun, Jung-Ho;Mok, Jin Sook;Cho, Hye Youn;Cho, Byung Cheol;Choi, Joong Ki
    • Journal of Wetlands Research
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    • v.6 no.1
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    • pp.117-132
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    • 2004
  • Despite its significance in understanding ecological structure and biogeochemical element cycles, there have been few studies on the microbial mineralization of organic matter and mineralization pathway in the intertidal flat of Korea. We measured anaerobic mineralization of organic matter and sulfate reduction rate, and evaluated the significance of sulfate reduction in total anaerobic carbon respiration at the southern part of Ganghwa Island. Depth-integrated carbon mineralization rate down to 6 cm depth ranged from 41.9 to $89.4mmol\;m^{-2}d^{-1}$, which accounted for approximately 216 tons of organic matter mineralization in entire intertidal flat area of Ganghwa($300km^2$). The results indicated that capacity for the organic matter mineralization in the Ganghwa tidal flat is comparable to highly productive salt marsh environments. Mineralization rates in the sediment amended with acetate were 2~5 times higher than in unamended sediment. The results implied that microbial mineralization was limited by the availability of organic substrates, and the organic matter mineralization capacity seems to be higher than estimated at ambient organic substrate level. Depth-integrated sulfate reduction rates within 6 cm depth of the sediment ranged from 20.7 to $45.1mmol\;SO{_4}^{2-}m^{-2}d^{-1}$, and sulfate reduction was mostly responsible for organic matter remineralization. It should be noticed that the increase of $H_2S$ in the sulfate reduction dominated tidal flat may result in the decrease of biological diversity.

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Development of Reference Material Using Natural Seawater for Nutrient Analysis in Seawater (자연해수를 이용한 해수 중 영양염 분석용 표준물질 개발)

  • Rho, Taekeun;Kang, Dong-Jin;Kim, Eun-Soo;Kahng, Sung-Hyun;Cho, Sung Rok;Lee, Jung Moo;Park, Eun Ju;Moon, Cho-Rong
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.20 no.1
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    • pp.29-35
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    • 2015
  • Dissolved nutrients in seawater are recognized as an essential biogeochemical factor for detecting global environmental changes. The importance of nutrient reference material for seawater has been increased greatly for the comparison of nutrient data, measured in different time and space in global ocean by various researchers with different levels in nutrient analysis skill. In this study, we described the homogeneity and stability of nutrient reference material for seawater using natural seawater, collected at a station of Shihwa Lake, at a coastal station near Uljin (surface water), and at a station over the Ulleung Basin (surface water and 1500 m depth water) and sterilized. Based on the homogeneity data, the nutrient reference materials has similar homogeneity compared to other nutrient reference materials. During 3-13 month period, there was no unidirectional trend of increase or decrease in nutrient concentration of newly developed nutrient reference material for seawater. However, a sustained measurement is required to check stability for longer period.

Comparison of Crop Growth and Evapotranspiration Simulations between Noah Multi Physics Model and CERES-Rice Model (Noah Multi Physics 모델과 CERES-Rice 모델의 작물 생육 및 증발산 모의 비교)

  • Kim, Kwangsoo;kang, Minseok;Jeong, Haneul;Kim, Joon
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.15 no.4
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    • pp.282-290
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    • 2013
  • Biophysical and biochemical processes through which crops interact with the atmosphere have been simulated using land surface models and crop growth models. The Noah Multi Physics (MP) model and the CERES-Rice model, which are a land surface model, and a crop growth model, respectively, were used to simulate and compare rice growth and evapotranspiration (ET) in the areas near Haenam flux tower in Korea. Simulations using these models were performed from 2003 to 2012 during which flux measurements were obtained at the Haenam site. The Noah MP model failed to simulate the pattern of temporal change in leaf area index (LAI) after heading. The simulated aboveground biomass with the Noah MP model was underestimated by about 10% of the actual biomass. The ET simulated with the Noah MP model was as low as 21% of those with the CERES-Rice model. In comparison with actual ET measured at Haenam flux site, the root mean square error (RMSE) of the Noah MP model was 1.8 times larger than that of the CERES-Rice model. The Noah MP model seems to show less reliable simulation of crop growth and ET due to simplified phenology processes and assimilates partitioning compared with the CERES-Rice model. When ET was adjusted by the ratio between leaf biomass simulated using CERES-Rice model and Noah MP model, however, the RMSE of ET was reduced by 30%. This suggests that an improvement of the Noah MP model in representing rice growth in paddy fields would allow more reliable simulation of matter and energy fluxes.

CO2 and Energy Exchange in a Rice Paddy for the Growing Season of 2002 in Hari, Korea (한국 하리 논에서의 2002년 생장기간의 CO2와 에너지의 교환)

  • Byung-Kwan Moon;Jinkyu Hong;Byoung-Ryol Lee;Jin I. Yun;Eun Woo Park;Joon Kim
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.5 no.2
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    • pp.51-60
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    • 2003
  • Rice, which occupies about 60% of the farmland in Korea, is a staple crop in Asia. It not only absorbs $CO_2$ from the atmosphere, but also emits carbon in a form of CH$_4$. It has a potential role in the global budget of greenhouse gases because of its relative contributions of carbon absorption and emission associated with changing hydrologic cycle. To better understand its current and future role, seasonal variations of energy and $CO_2$ exchange in this critical ecosystem need to be quantified. The purpose of this study was to measure, document and understand the exchange of energy and $CO_2$ in a typical rice paddy in Korea throughout the whole growing season. Since late April of 2002, we have conducted measurements of energy and $CO_2$ exchange in a rural rice paddy at Hari site, one of the Korea regional network of tower flux measurement (KoFlux). After the quality control and gap-filling, the observed fluxes were analyzed in the context of micrometeorology and biophysics. $CO_2$ and energy exchanges varied significantly with land cover changes (e.g., plant growth stages), in addition to changes in weather and climate conditions. This study, reporting first direct measurement of energy and $CO_2$ exchange over a rice paddy in Korea, would serve as a useful database as one of the reference sites in AsiaFlux and FLUXNET.

Importance of Extracellular Enzyme Activities in Northern Peatland Biogeochemistry-Possible Coupling with Trace Gas Emission and DOC Dynamics (북구 이탄습지의 생지화학적 반응에 있어서 체외효소의 중요성-미량기체 발생량 및 용존유기탄소 동태와의 연관성에 대하여)

  • Freeman, Chris;Park, Seok-Soon;Kang, Ho-Jeong
    • Korean Journal of Ecology and Environment
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    • v.39 no.4 s.118
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    • pp.435-444
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    • 2006
  • A suite of extracellular enzyme activities involved in organic carbon decomposition were determined in three northern peatlands (a bog, a fen, and a swamp) over a 12 month period along with trace gas ($CO_2$ and $N_2O$) flux and DOC dynamics in the wetlands. The activities varied $0.008-0.066\;{\mu}mole\;g^{-1}\;min^{-1}$, $0.003-0.021\;{\mu}mole\;g^{-1}\;min^{-1}$, $0.003-0.016\;{\mu}mole\;g^{-1}\;min^{-1}$, $0.004-0.047\;{\mu}mole\;g^{-1}\;min^{-1}$, for ${\beta}-glucosidase$, cellobiohydrolase, ${\beta}-xylosidase$, and N-acetylglucosaminidase, respectively. In general, the activities were highest in the forested swamp followed by the fen and the bog. When the data from three wetlands are combined, the enzyme activities exhibited significant positive correlations with trace gas emission and available carbon. Further, the average activity of 4 enzymes explained about 20-40% of the variations of trace gas emssion and available carbon. The results indicate that enzymes related to the mineralization of organic carbon may play an important role in trace gas flux and DOC dynamics in northern peatlands.