• Title/Summary/Keyword: 상전하

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Synthesis and Properties of $Al_2$$O_3$-$TiO_2$Composites by Wet Method -1. Synthesis of $Al_2$$O_3$-$TiO_2$Composite Powders- (습식법에 의한 $Al_2$$O_3$-$TiO_2$복합체의 합성 및 특성연구 -1. $Al_2$$O_3$-$TiO_2$계 복합분체의 합성(1)-)

  • 류수착;엄지영
    • Journal of the Korean Ceramic Society
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    • v.38 no.5
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    • pp.412-417
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    • 2001
  • 본 연구는 습식법으로 수산화 알루미늄과 티타니아를 출발물질로 하여 $Al_2$O$_3$-TiO$_2$복합분체를 제조하였으며, 2 mol의 Al(OH)$_3$분말에 대하여 TiO$_2$분말량을 1, 3, 5, 7, 9, 11 wt%로 첨가하여 $Al_2$O$_3$-TiO$_2$복합분체의 특성을 조사하였다. 제조된 $Al_2$O$_3$-TiO$_2$계 복합분체는 $700^{\circ}C$~140$0^{\circ}C$까지 하소하여 XRD 분석을 한 결과 100$0^{\circ}C$까지는 TiO$_2$(rutile)상과 η-Al$_2$O$_3$상이 공존하다가 110$0^{\circ}C$부터 130$0^{\circ}C$까지는 η-Al$_2$O$_3$에서 $\alpha$-Al$_2$O$_3$로의 상전이가 일어나서 $\alpha$-Al$_2$O$_3$상과 TiO$_2$(rutile)상이 나타났으며 하소온도 140$0^{\circ}C$, TiO$_2$첨가량이 5 wt%일 때부터 $Al_2$TiO$_{5}$가 생성되기 시작하였다. TiO$_2$첨가량에 따른 비표면적값은 첨가량이 7 wt%까지는 감소하였으나 그 이상 첨가시 증가하였다. 입도분석 결과 평균입경은 15.74~23.21$mu extrm{m}$로서 TiO$_2$첨가량이 3 wt%일 때 가장 작은 값을 가졌으며 TiO$_2$첨가량은 5 wt% 이상부터 점차 감소하였다.

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Effects of Metal Mg on Replacement Reaction of Molten Al for Fabrication of $Al_2$O$_3$//Al Composites (Al$_2$O$_3$/Al 복합체 제조시 용융 알루미늄의 치환반응에 미치는 금속 마그네슘의 영향)

  • 정두화;배원태
    • Journal of the Korean Ceramic Society
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    • v.35 no.1
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    • pp.23-32
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    • 1998
  • Al2O3/Al composites were produced by immersing the sintered silica preform in molten aluminum which contained magnesium as impurity. Three distinct regions existed in the penetration behavior of molten me-tal with changing the reaction temperature. These regions are denoted as low temperature regime(75$0^{\circ}C$-85$0^{\circ}C$) intermediate regime(90$0^{\circ}C$-95$0^{\circ}C$) and high temperature regime(100$0^{\circ}C$$\leq$) In the low temperature regime the penetration speed of molten aluminum increased with increasing reaction temperature whereas it decreased in the intermediate regime due to the phase transition of alumina formed by displacement reac-tion. In the high temperature regime the penetration speed of molten aluminum was the highest at 100$0^{\circ}C$ which was 3.6 mm/hr But above 105$0^{\circ}C$ molten aluminum did not penetrate into the silica preform because of the formation of a dense spinel layer at the preform surface by magnesium in molten Al.

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Electrical properties of La-doped BaTiO3 synthesized by homogeneous precipitation (균일침전법으로 제조된 란탄이 혼입된 $BaTiO_3$의 전기적 특성)

  • Huh, Woo-Young;Ryu, Kyoung-Youl;Kim, Seung-Won;Lee, Chul
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.5
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    • pp.498-503
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    • 1999
  • La-doped $BaTiO_3$ ceramics were prepared from BaTiO(C_2O_4)_2\;{\cdot}\;XH_2O(BTO)$, which was synthesized by homogeneous precipitation using dimethyl oxalate. The electrical properties of La-doped $BaTiO_3$ were investigated with variation of La-contents and particle size. It was found that a large PTCR (positive temperature coefficient of resistivity) effect was appeared in the conditions at the 0.6 mol% of La-content and at small particle size of BTO as 1.0$\mu\textrm{m}$. The plot of temperature vs. 1/$\varepsilon_m$(T) above Curie temperature $(T_c)$ was agreed with Curie-Weiss law. The potential barrier calculated from measured resistance and capacitance of specimen, also gave higher value at small particle size of BTO as 1.0 $\mu\textrm{m}$ and at La-content of 0.6 mol%.

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Estimation of Spatial Distribution of Soil Moisture at Yongdam Dam Watershed Using Artificial Neural Networks (인공신경망을 이용한 용담댐 유역 공간 토양수분 분포도 산정)

  • Park, Jung-A;Kim, Gwang-Seob
    • Journal of the Korean Geographical Society
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    • v.46 no.3
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    • pp.319-330
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    • 2011
  • In this study, a soil moisture estimation model was proposed using the ground observation data of soil moisture, precipitation, surface temperature, MODIS NDVI and artificial neural networks. The model was calibrated and verified on the Yongdam dam watershed which has reliable ground soil moisture networks. The test statistics of calibration sites, Jucheon, Bugui, Sangjeon, showed that the correlation coefficients between observations and estimations are about 0.9353 and RMSE is about 1.4957%. Also that of the verification site, Cheoncheon2, showed that the correlation coefficient is about 0.8215 and RMSE is about 4.2077%. The soil moisture estimation model was applied to estimate the spatial distribution of soil moisture in the Yongdam dam watershed and results showed improved spatial soil moisture distribution since the model used satellite information of NDVI and artificial neural networks which can represent the nonlinear relationships between data well. The model should be useful to estimate wide range soil moisture information.

A Fault Diagnosis Technique of an Inverter-fed PMSM under Winding Shorted Turn and Inverter Switch Open Fault (권선 단락 및 스위치 개방 고장 시의 인버터 구동 영구자석 동기전동기의 고장 진단 기법)

  • Kim, Kyeong-Hwa
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.5
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    • pp.94-105
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    • 2010
  • To detect faults in an inverter-fed permanent magnet synchronous motor (PMSM) drive under the circumstance having faults in a stator winding and inverter switch, an on-line basis fault detecting scheme during operation is presented. The proposed scheme is achieved by monitoring the second-order harmonic component in q-axis current and the fault is detected by comparing these components with those in normal conditions. The linear interpolation method is employed to determine the harmonic data in normal operating conditions. As soon as the fault is detected, the operating mode is changed to identify a fault type using the phase current waveform. To verify the effectiveness of the proposed fault detecting scheme, a test motor to allow inter-turn short in the stator winding has been built. The entire control algorithm is implemented using DSP TMS320F28335. Without requiring an additional hardware, the fault can be effectively detected by the proposed scheme during operation so long as the steady-state condition is satisfied.

Phase Transitional Behavior and Piezoelectric Properties of 0.94(Na0.5K0.5NbO3-0.06Ba(Ti0.9Sn0.1)O3 Lead-free Ceramics (무연계 0.94(Na0.5K0.5NbO3-0.06Ba(Ti0.9Sn0.1)O3 세라믹의 상전이 거동과 압전 특성)

  • Cha, Yu-Joung;Nahm, Sahn;Jeong, Young-Hun;Lee, Young-Jin;Paik, Jong-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.9
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    • pp.766-771
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    • 2009
  • Lead-free $0.94(Na_{0.5}K_{0.5})NbO_3$-0.06Ba$(Ti_{0.9}Sn_{0.1})O_3$ [0.94NKN-0.06BTS] ceramics doped with 1 mol% $MnO_2$ were synthesized by a conventional solid state method. The phase transitional behavior and piezoelectric properties of the ceramics sintered at various temperatures were investigated. The 0.94NKN-0.06BTS ceramics sintered at $1050^{\circ}C$, having morphotropic phase boundary of orthorhombic and tetragonal phases, exhibited a microstructure with abnormal grain growth. A diffused phase transition behavior for all the specimens was verified as high degree of diffuseness (${\gamma}$) values from 1.45 to 1.79. A high piezoelectric constant of $d_{33}=256$ pC/N and a satisfactory electromechanical coupling factor of $k_p=42%$ were obtained for the relatively dense 0.94NKN-0.06BTS ceramics sintered at $1050^{\circ}C$.

Dielectric and Piezoelectric Properties of $Pb(Sb_{1/2}Nb_{1/2})O_3-PbTiO_3-PbZrO_3$ Ceramics ($Pb(Sb_{1/2}Nb_{1/2})O_3-PbTiO_3-PbZrO_3$ 세라믹스에서의 유전 및 압전 특성)

  • Cha, Yoo-Jeong;Kim, Chang-Il;Jeong, Young-Hun;Lee, Young-Jin;Paik, Jong-Hoo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.310-310
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    • 2008
  • 본 연구에서는 (1-x) Pb(Zr0.515Ti0.485)$O_3$ - x Pb$(Sb_{1/2}Nb_{1/2})O_3$ + 0.5wt% $MnO_2$ 조성에 Pb$(Sb_{1/2}Nb_{1/2})O_3$ (PSN) (x=0.02, 0.04, 0.06, 0.08) 변화에 따른 미세구조 및 압전, 유전특성에 관해 고찰하였다. PSN 치환량이 증가함에 따라 정방정 (tetragonal)구조에서 삼방정(rhombohedral)구조로 상전이가 일어났으며, 결정립의 크기가 작아지는 것을 확인하였다. 전기기계결합계수 (kp) 는 PSN이 4 mol % 치환됨에 따라 증가하였으며, 더 이상 치환 시 감소하였다. PSN 치환에 따른 전기적 특성은, 결정구조, 결정립의 크기 및 2 차상 등의 미세구조와 긴밀한 관계가 있는 것으로 보여진다. 상경계(Morphotropic Phase Boundary) 영역인 0.96 Pb(Zr0.515Ti0.485)$O_3$ - 0.04 Pb$(Sb_{1/2}Nb_{1/2})O_3$ + 0.5wt% $MnO_2$ 조성에서 $\varepsilon{^T}_{33}/\varepsilon_o$ = 1109, $k_p$= 70.8 (%), $d_{33}$= 325 (pC/N)의 우수한 특성을 나타내었다.

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A Study on the Permeance Through Polymer Membranes and Selectivity of $CH_4/N_2$ (폴리이미드와 폴리이써설폰 분리막을 이용한 $CH_4/N_2$의 투과선택도 특성)

  • Park, Bo-Ryoung;Kim, Dae-Hoon;Lee, Gang-Woo;Hwang, Taek-Sung;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.498-504
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    • 2011
  • In this research, hollow fiber membranes were used in order to investigate to permeation and selectivity of the $CH_4$ and $N_2$. Polyimide and polyethersulfone hollow fiber membrane were prepared by the dry-wet phase inversion method and the module was manufactured by fabricating fibers after surface coating with silicone elastomer. The scanning electron microscopy (SEM) studies showed that the produced fibers typically had an asymmetric structure. The permeance of $CH_4$ and $N_2$ were increased with pressure and temperature. However, the selectivity was decreased with increasing temperature. The permeances of $CH_4$ and $N_2$ were decreased with increasing the air gap and the effect of post-treatment on membrane showed the increase in permeance up to 3.2~7.0 times.

Fabrication of Block Copolymer Membranes via SNIPS Process (SNIPS 공정을 이용한 블록공중합체 분리막의 구조 형성에 관한 연구)

  • Woo, Sanghoon;Kim, Jinhee;Lee, Junghyun;Bang, Joona
    • Korean Chemical Engineering Research
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    • v.55 no.2
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    • pp.214-219
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    • 2017
  • In this work, we fabricated PS-b-P4VP block copolymer membranes from self-assembly and non-solvent induced phase separation (SNIPS), which combines the block copolymer self-assembly and conventional NIPS process. While previous studies mostly focused on the fabrication of well-defined structures, we systematically examined various processing parameters such as polymer concentration, solvent evaporation duration, solvent composition, and humidity, to optimized the membrane structures. As a result, the morphology of PS-b-P4VP membranes was optimized at a certain polymer concentration in solution and composition of volatile solvent at low humidity conditions, resulting in SNIPS separation membranes with well-defined nanopores on the surface, 75% of membrane porosity, and 18% of surface porosity.

Circuit Design of Parallel Power Operation Equipment for Peak Power Reduction (상전원의 피크치 전력 감소를 위한 전력병합장치 회로설계)

  • Yang, Jaesoo;Kim, Donghan;Kim, ManDo
    • KIPS Transactions on Computer and Communication Systems
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    • v.3 no.9
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    • pp.273-278
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    • 2014
  • Recent use of electricity during peak hours electricity supply-demand imbalance is inevitable that limit power use force. Therefore, in this paper, a circuit of parallel power operation equipment for peak power reduction which saves the power to electricity storage device during the non-peak power time and supply from the storage power during the expected power shortages time is designed Through this circuitry, the peak power of the commercial power supply with the parallel operation and connection of the commercial power supply and the power supply of the inverter from electricity storage that is a key feature of PRS(Peak power Reduction System) can be controlled. In addition, in order to increase the efficiency, a Transless Power Circuit DC-AC inverter is developed. Moreover, a variable impedance control is applied to the storage of electric power of an Uninterruptible Power Supply associated with a commercial power source.