• Proceedings of the Korean Nuclear Society Conference
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• 1996.11b
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• pp.463-468
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• 1996

질소의 함량을 0.04%~0.15% 까지 변화시킨 316L 스테인레스 강으로 공기 중에서 저주기 피로시험을 수행하였다. 전체변형범위 1%, 변형속도 2$\times$$10^3$/sec, 삼각파로 상온 ~$600^{\circ}C$ 온도범위에서 시험을 수행하였다. 상온에서는 사이클이 진행됨에 따라서 연화가 계속해서 발생하지만 온도가 증가하면 초기에 경화가 발생한다. 피로시험 초기에 경화되는 정도와 saturation 응력은 온도가 증가하면 증가한다. 이러한 경화현상은 동적변형시효에 의해서 발생되는 것으로 판명되었다. 질소를 첨가하면 강도는 증가하지만 경화는 감소되었다. 질소에 의한 경화의 감소는 질소가 동적변형시효를 억제하기 때문이다.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.25 no.3
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• pp.203-209
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• 2012

In this paper, cross-sectional stiffnesses, static stresses, and dynamic natural frequencies are analyzed to examine the structural performance of wind turbine composite blades. The material properties of composite materials are based on room-temperature and radiation curing processes. The cross-sectional stiffnesses of composite blades are calculated by applying a beam theory with solid-profile cross sections. The wind turbine blades are modeled with a finite element program, and static analyses are carried out to check the maximum displacement and stress of the blades. In addition, dynamic analyses are performed to predict the rotating natural frequencies of the composite blades including the effects of centrifugal force. By comparing these analysis results, mainly owing to the material properties of composite materials, an improvement in the structural performance of the blades according to the curing process is investigated.

• Proceedings of the KAIS Fall Conference
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• 2000.10a
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• pp.237-240
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• 2000

본 연구에서는 비스페놀 A, 에피크로로히트린을 반응시킨 에폭시 기본주제를 중심으로 경화제, 희석제, 충진제, 촉매 등을 배합하여 토목, 건축용 반고체형 에폭시 접착제를 개발하였다. 여기서 특히 에폭시 주제와 희석제의 종류 및 배합비율에 따른 기본 물성, 접착성능 등을 측정하였다. 상온 경화 특성을 측정하기 위하여 경화시 간을 측정한 결과 희석제의 종류와 관계없이 희석제의 양이 증가할수록 경화시간이 증가하고 경화온도도 증가하는 경향을 알 수 있었으며 촉매의 양이 적을 경우가 경화시간이 빠른 것을 알 수 있었다. 또한 경화 시간은 30분 내지 40분 정도로 상온에서 사용할 수 있을 것으로 기대한다. 접착력 시험 결과는 촉매의 양이 적당한 때 가장 좋은 접착력을 나타내고 희석제 중에서 HDGE의 경우가 가장 좋은 접착력을 나타내었고 희식제의 양이 증가할수록 접착력은 증가하였다. 실리카와 철분을 섞어 반고체형 에폭시 접착제를 제조한 경우 기존의 제품보다 우수한 접착력을 나타내었다. 따라서 본 연구에서 개발한 반고체형 접착제는 제조공정 코스트 등에 대한 검토와 함께 제품화하여 토목, 건축 분야의 콘크리트 균열 접착, 볼트와 콘크리트의 접합, 목재의 접합 등에 간편하게 사용될 수 있으며, 배합물질과 비율에 따라 전기전자. 토목건축, 자동차산업 등의 산업용 접착제로서 응용될 수 있을 것으로 기대된다.

• Korean Journal of Materials Research
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• v.6 no.1
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• pp.67-78
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• 1996

제 3원소가 첨가된 금속간 화합물 TiAI 금속간 화합물 분말을 PREP법(플라즈마 회전전극법)으로 제조하여, 통.방전 강압소결법에 의해 치밀한 소결체를 만들었다. 이에 대해 첨가 원소의 종류와 열처리에 따른 고온 및 상온 압축 특성의 변화를 조사하였다. 소결체의 미세조직은 ${\gamma}$/$\alpha$2 lamella로 이루어진 완전 변태구조였고, 결정립의 크기는 140-150$\mu\textrm{m}$였으며 계단형 결정립계를 나타내었다. 소결체를 ($\alpha$+${\gamma}$)구역인 130$0^{\circ}C$에서 2시간 동안 열처리한 결과, 모든 조성의 시편이 등축점 ${\gamma}$와 lamella로 이루어진 전형적인 duplexrn조로 변태하였다. 상온 압축 시험에서 시편은 파괴될 때까지 가공경화 현상이 나타났으며, Cr을 첨가한 시편이 가장 큰 파괴응력과 변형률을 나타내었다. 한편, 고온 압축 시험의 경우 온도상승 때문에 가공경화의 속도가 감소되었고, 80$0^{\circ}C$에서는 가공경화와 회복이 균형을 이루는 소위 정상 상태의 변형을 보였다.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.38 no.7
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• pp.511-523
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• 1989

This paper investigates physical properties, the electrical and mechanical characteristics of the epoxy resin with different curing methods and postcuring conditions at room temperature or cryogenic temperature (LN2). According to the results in this paper, first, it is found that the physical properties, electrical and mechanical characteristics of the epoxy resin are largely affected by the interior reaction temperature on the curing. Thus, in the fabrication of the sample, several excellent characteristics of the sample are obtained by controlling the interior reaction temperature of the epoxy resin. Second, the sample having optimal electrical and mechanical characteristics is obtained for the repetitive post-curing method at 100c in view point of the post-curing conditions of the epoxy resin. Third, it appears that tan and characteristics at LN2 temperature are about half of those at room temperature. Fourth, it appears that the dielectric strength of the epoxy resin at LN2 temperature is higher by about 0.6-1.0 MV/cm than that at room temperature. The heat-aging of the epoxy resin due to the micro-defect and excess fever-movement have been noticed to affect dielectric strength at LN2 temperature more significantly than at room temperature.

• Elastomers and Composites
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• v.42 no.1
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• pp.47-54
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• 2007

Reaction kinetics of polyurethane elastomers (PU) were studied using dynamic DSC and TGA for three PU samples of general purpose (Sample A), high temperature cross-likable CASE purpose with MOCA (Sample B), and RT cross-likable CASE purpose grade (Sample C). From DSC results, sample with MOCA(Sample B) showed lower shift of peak temperature, while showing broader thermograms than those of general purpose grade (Sample A). On the other hand, RT cross-linkable PU grade (Sample C) showed an interesting double mode reaction patterns, i.e., a lower temperature reaction at about $70\;^{\circ}C$, and a higher temperature reaction in the range of $140{\sim}170\;^{\circ}C$, indicating that it requires 2-step reaction process in order to complete the reaction. Once the cross-linking reaction completed, however, TGA results showed that all the samples would be considered to have similar chemical structures, showing similar decomposition processes. Sample C, especially, had showed decomposition properties of both Sample A and Sample B. Formation activation energies calculated from Kissinger method showed 10.39, 65.85, 36.52(Low $T_p$) and 18.21(High $T_p$) kcal/mol, while decomposition activation energies were 31.94, 30.84, 24.16 kcal/mol, respectively.

• Journal of the Microelectronics and Packaging Society
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• v.17 no.4
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• pp.41-48
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• 2010

To improve the pot life of one-part in-house anisotropic conductive paste (ACP) formulations, 2-methyl imidazole curing accelerator powders were encapsulated with five agents. Through measuring the melting point of the five agents using DSC, it was confirmed that a encapsulation process with liquid-state agents is possible. Viscosity of ACP formulations containing the encapsulated imidazole powders was measured as a function of storage time from viscosity measurements. As a result, pot life of the formulations containing imidazole powders encapsulated with stearic acid and carnauba wax was improved, and these formulations indicated similar curing behaviors to a basic formulation containing rare imidazole. However, the bondlines made of these formulations exhibited low average shear strength values of about 37% level in comparison with the basic formulation.

• Journal of the Korean Institute of Gas
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• v.3 no.3 s.8
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• pp.1-8
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• 1999

Three-point bending fatigue properties of austenitic 304 stainless steel sheets were investigated at room temperature and LNG temperature($-162^{\circ}C$) in the strain range from 0.43 to $1.7\%$. The fatigue properties at $-162^{\circ}C$ were superior to those at room temperature due to the higher volume fractions of deformation-induced martensite. The cyclic hardening behavior owing to the deformation- induced martensite transformation was detected in both specimens. In room temperature testing, the mean load amplitude increased steadily with cycles, meaning that cumulative plastic incubation strain was required for martensite transformation. On the contrary, in $-162^{\circ}C$ tested specimen, the mean load amplitude increased rapidly within a few cycles due to the rapid transformation of martensite, and slightly decreased after the maximum is reached probably due to dynamic recovery.

• Proceedings of the Korean Vacuum Society Conference
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• 2008.08a
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• pp.239-239
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• 2008

• Elastomers and Composites
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• v.40 no.3
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• pp.196-203
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• 2005

In this work, the engine oil resistant evaluation and breakdown analysis of room temperature vulcanizing silicone adhesives were performed through the surface properties, thermal stabilities, adhesive strength, and morphology measurements. As a result, the permeation of engine oil into adhesive specimens was carried out from surface to center in the specimens. And the oil content in the adhesive specimens was increased and the Si-O-Si bond of the adhesives was decomposed with increasing the aging time. The TGA results indicated that the thermal degradation was mainly occurred at under and surfaces of the specimens. The tensile strength, elongation, and adhesive strength of the adhesives were significantly decreased after the engine oil resistant tests, which could be attributed to the initial lose of adhesive properties resulting from the engine oil absorption and thermal aging. And the failure mode of the adhesive specimens was changed from cohesive failure to interfacial failure.