• Title/Summary/Keyword: 삼투압처리

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MXene Based Composite Membrane for Water Purification and Power Generation: A Review (정수 및 발전을 위한 맥신(MXene) 복합막에 관한 고찰)

  • Seohyun Kim;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.4
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    • pp.181-190
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    • 2023
  • Wastewater purification is one of the most important techniques for controlling environmental pollution and fulfilling the demand for freshwater supply. Various technologies, such as different types of distillations and reverse osmosis processes, need higher energy input. Capacitive deionization (CDI) is an alternative method in which power consumption is deficient and works on the supercapacitor principle. Research is going on to improve the electrode materials to improve the efficiency of the process. A reverse electrodialysis (RED) is the most commonly used desalination technology and osmotic power generator. Among many studies conducted to enhance the efficiency of RED, MXene, as an ion exchange membrane (IEM) and 2D nanofluidic channels in IEM, is rising as a promising way to improve the physical and electrochemical properties of RED. It is used alone and other polymeric materials are mixed with MXene to enhance the performance of the membrane further. The maximum desalination performances of MXene with preconditioning, Ti3C2Tx, Nafion, and hetero-structures were respectively measured, proving the potential of MXene for a promising material in the desalination industry. In terms of osmotic power generating via RED, adopting MXene as asymmetric nanofluidic ion channels in IEM significantly improved the maximum osmotic output power density, most of them surpassing the commercialization benchmark, 5 Wm-2. By connecting the number of unit cells, the output voltage reaches the point where it can directly power the electronic devices without any intermediate aid. The studies around MXene have significantly increased in recent years, yet there is more to be revealed about the application of MXene in the membrane and osmotic power-generating industry. This review discusses the electrodialysis process based on MXene composite membrane.

A Study on the Treatment of Wastewater from Ion Removal Process for Purifying Electrocoat Paint in the Bath by Use of Reverse Osmosis (역삼투압을 이용한 전착도료 정제공정폐수처리에 관한 연구)

  • 김진성
    • Membrane Journal
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    • v.8 no.2
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    • pp.77-85
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    • 1998
  • To treat effectively EDIR (electrodeposition ion removal) wastewater in terms of CO$_{Mn}$ 1,500~2,000 ppm generated from aluminum painting process, a RO (reverse osmosis) process was designed and installed to recover and reuse the concentrated solvent sent back to the electrocodeposition tank while the permeate reused as rinse water. A RO system in which three polyamide-spiral wound modules ($102\Phi \times 1,016L$ mm) connnected in series had been running to treat 20 m$^3$ in waste volume in 3 days batch operation at the condition of system recovery of 30 %, applied pressure 11.5 $kg_f/cm^2$ and room temperature. During 42 hours continuous operation leading to 5-fold decrease in waste volume, nearly constant permeation flux of 390 l/m$^2$-hr was maintained and the permeate with average CO$_{Mn}$, 300 ppm was obtained which could be used for washing the remaining paint solution in ion-exchange tower instead of demineralized water. Also COD$_{Mn}$ rejection as a function of running time was observed to be in the range of 78~87 % and the observed solvent rejections for ethyl cellusolve, buthyl cellusolve and n-butanol were 79 %, 87 % and 70 %, respectively.

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Effects of 2-Mercaptoethanol on the Protoplast Formation and Osmotic Stabilizers on the Protoplast Reversion of Pyricularia oryzae Cavara (벼 도열병균(稻熱病菌)의 원형질체(原形質體) 생성(生成)에 미치는 2-Mercaptoethanol과 복귀(復歸)에 미치는 삼투압 안정제(安定劑)의 영향(影響))

  • Kim, Heung-Tae;Chung, Hoo-Sup
    • The Korean Journal of Mycology
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    • v.17 no.1
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    • pp.1-6
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    • 1989
  • The mycelia of Pyricularia oryzae were treated with enzyme solution mixture consisting of Driselase, ${\beta}-Glucuronidase$, Cellulase, and Macerozyme R-10 for the production of protoplasts. More protoplasts were formed from mycelia of race KJ 101 of P. oryzae than that of race KI 315a in the enzyme mixtures. The number of protoplasts was decreased in the untreated control three hrs after the enzyme treatment, whereas the number was increased in the treatments with 10, 50 and 100 mM 2-mercaptoethanol, respectively. The number of protoplasts increased to reach maximum at five hrs after treatment of 10 mM 2-mercaptoethanol, but the least was found in 200 mM. The protoplasts of P. oryzae in a liquid medium containing 2.5% yeast extract, and 2% dextrose reverted to the mycelia after five hrs shaking incubation at $27^{\circ}C$. Some protoplasts produced yeast like buds and the buds were developed to irregularly shaped chains of cell protruded a germ tube like hypha from the distal cell. Once in a while a germ tube like hypha protruded directly from the protoplasts. Except in the first type of reversion, other protoplasts reverted to the normal mycelia. The reversion frequency was highest on PDA with stabilizer of 0.6 M KCl. No reversion of protoplasts occurred on water agar regaardless oftreaatments.

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The Changes of Aroma in Wine Treated with Reverse Osmosis System (역삼투압 시스템으로 처리한 포도주의 향기성분 변화)

  • Lee, Seung-Ryong;Lee, Kyu-Hee;Chang, Kyu-Seob;Lee, Suk-Kun
    • Korean Journal of Food Science and Technology
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    • v.32 no.1
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    • pp.17-24
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    • 2000
  • Reverse osmosis (RO) system was applied to improve wine quality. General wine (GEN) and wines containing different sugar levels $24^{\circ}Brix$ (RO-24) and $24^{\circ}Brix$ (RO-28) by removing pure water using RO system without sugar addition on brewing method. And they were compared by wine aroma analysis. The preparing method of analysis was LLCE (liquid-liquid continuous extraction). And volatile aroma compounds of different wines were prepared for raw, and diluted materials in same proportion. The wine aromas were described by trained twelve panelists for QDA (quantitative descriptive analysis) and showed for FD (flavor dilution)-chromatogram. Consequently, overall acceptability of RO-28 showed better than that of other treatments. Aromas of RO-28 also were represented the high contents of positive aroma compounds such as ethanol and ethyl acetate, which were identified by GC-O and GC-MS.

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Characteristics of Flux Decline in Forward Osmosis Process for Asymmetric Cellulose Membrane (정삼투 공정에 있어 비대칭 셀룰로오즈 막의 투과유속 감소특성)

  • Lee, Keun-Woo;Han, Myeong-Jin;Nam, Suk-Tae
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.328-334
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    • 2014
  • This study examined the effect of concentration polarization on permeate flux in forward osmosis (FO) membrane process for saline and sucrose solution. The reduction in permeate flux during the FO membrane process is largely due to the formation of concentration polarization on membrane surfaces. The flux reduction due to internal concentration polarization formed on the porous support layer was larger than that due to the external concentration polarization on the active membrane surface. Water permeate flux through the FO membrane increased nonlinearly with the increase in osmotic pressure. The water permeability coefficient was $1.8081{\times}10^{-7}m/s{\cdot}atm$ for draw solution on active layer (DS-AL) mode and $1.0957{\times}10^{-7}m/s{\cdot}atm$ for draw solution on support layer (DS-SL) mode in NaCl solution system. The corresponding membrane resistance was $5.5306{\times}10^6$ and $9.1266{\times}10^6s{\cdot}atm/m$, respectively. With respect to the sucrose solution, the permeate flux for DS-AL mode was 1.33~1.90 times higher than that for DS-SL mode. The corresponding variation in the permeation flux (J) due to osmotic pressure (${\pi}$) would be expressed as $J=-0.0177+0.4506{\pi}-0.0032{\pi}^2$ for the forward and $J=0.0948+0.3292{\pi}-0.0037{\pi}^2$ for the latter.

Technical Feasibility for Hollow-Fiber Ultrafiltration Water Treatment System and its Economic Aspects (중공사형 한외여과막 수처리 공정의 기능성과 막을 사용한 수처리공정의 경제성에 관한 연구)

  • Wang, Jin-Soo;Kim, Byung-Jick;Choi, Soo Hyoung
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.12-18
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    • 1999
  • This research was undertaken to do the technical and economical feasibility study of membrane water treatment system. For the technical feasibility study, batch water treatment system using UF(ultrafiltration) was set up and several experiments were carried out. The performance of the UF membrane was tested in terms of turbidity. The experimental results showed that the UF membrane process produced less than 1 NTU water regardless of input water turbidity. For the economical feasibility study, the cost model was analyzed and programmed for simulation. Also costs of the membrane water treatment and the conventional treatment were evaluated. The simulation results showed that the unit production cost increased when design flow or permeate flow decreased. The production cost of membrane water treatment system was lower than that of the conventional system. Both technical and economical feasibility study showed that the UF membrane water purification system was a very competitive water purification process.

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Properties of Semen and Sperm Motility in Black Seabream, Acanthopagrus schlegeli (감성돔, Acanthopagrus schlegeli 정액의 특성과 정자의 운동성)

  • Chang Young Jin;Lim Han Kyu;Kho Kang Hee
    • Journal of Aquaculture
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    • v.8 no.3
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    • pp.149-157
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    • 1995
  • In order to obtain the basic knowledges concerned to the semen preservation of aquacultural fishes, studies on the physical and chemical properties of semen, and sperm motility with the different osmotic pressures making by adding $Na^+,\;K^+,\; Mg^{++},\;and\;Ca^{++}$ to artificial seawater (ASW) were conducted in black seabream, Acanthopagrus schlegeli. Average semen volume per fish in one strip was 1.97ml and sperm concentration was $2.33\pm1.30\times10^{10}$ sperm/ml. Spermatocrit and pH of semen were $90.6\pm5.0\;and\;8.3\pm0.1$, respectively, Osmotic pressures of rearing seawater, seminal fluid and plasma were $939\pm24,382\pm70\;and\;342\pm77$ mOsm/l, and $Na^+,\;K^+$ and $Cl^-$ concentrations of seminal fluid were $169.5\pm4.5,\;4.9\pm2.2,\;156.0\pm2.0\;mM/l$, respectively. When semen were diluted by using $Na^+,\;K^+,\;Mg^{++}\;and\;Ca^{++}$ free ASW, only $Na^+$ free ASW had no sperm motility. As raising osmotic pressure graduary by addition of 1M NaCl to the $Na^+$ free ASW, spermatozoa showed the high motilities in 457-1128 mOsm/l, but the low motilities in 1398-1736 mOsm/l. In the case of same treatments with 1M of KCl, $MgC1_2\;and\;CaC1_2$ to the $K^+,\;Mg^{++}\;and\;Ca^{++}$ free ASW, spermatozoa revealed the high motilities in $904\~1434,\;818\~1175\;and\;956\~1343$ mOsm/l, respectively.

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Changes in Physiological Characteristics of Barley Genotypes under Drought Stress (한발저항성 정도가 다른 보리 품종들의 한발처리에 따른 생리적 특성변화)

  • 이변우;부금동;백남천;김정곤
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.6
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    • pp.506-515
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    • 2003
  • Six barley varieties that showed different degree of drought tolerance were grown with and without drought stress treatment (control), and investigated for the temporal changes in growth and several physiological traits after drought treatment. Soil water potential was -0.05 ㎫ at the initial stage of drought treatment and dropped to -0.29 ㎫ at 19 days after withholding irrigation. Soil water potential (SWP) maintained at -0.05 ㎫ in the control. The dry weight (DW) under the drought treatment were reduced compared to the control as follows: Dicktoo-S (short awn), 69% ; Dicktoo-L (long awn), 70%; Dicktoo-T (tetra), 86%; Dongbori-1, 69%; Suwonssalbori-365, 55% and Tapgolbori, ,37%. Dicktoo lines and Dongbori-1 were more tolerant than Suwonssalbori-365 and Tapgolbori. Leaf relative water contents (RWC) and leaf water potential (LWP) decreased obviously under the drought condition, the decrease being greater especially in the less drought-tolerant barley genotypes. Dongbori-1 and Dicktoo-L in drought treatment showed net photosynthesis of 38% and 17% compared to the control, respectively, and the other four genotypes much lower photosynthesis of 1.1% to 7.0%. Stomatal conductance, mesophyll conductance, and the photochemical efficiency (Fv/Fm) of PS II were reduced by drought treatment, the reduction being greater in drought-sensitive genotypes. The drought-tolerant genotypes had greater osmotic adjustment (OA) capacity under water stress. Thus, the decrease of RWC and LWP was lower and the turgor pressure conservation capacity was higher under water stress in drought-tolerant genotypes. Drought-tolerant genotypes showed less decrease of photosynthesis because stomatal conductance, mesophyll conductance and the ratio (Fv/Fm) of the variable to maximal fluorescence of drought-resistant genotype was decreased less in the drought stress condition. In conclusion, the drought-tolerant genotypes had better water conservation capacity through efficient OA, and this led to the lower decrease of photosynthesis and growth in water stress condition.

Hyposmotic Treatment for Control of the Parasitic Copepod, Alella macrotrachelus on the Gill of Cultured Black Porgy (감성돔 아가미에 기생하는 요각류 Alella macrotrachelus 구제를 위한 저삼투압 처리 효과)

  • Min, Byung-Hwa;Jeong, Min-Hwan;Noh, Gyoung-Ane;Lim, Han-Kyu;Choi, Cheol-Young;Chang, Young-Jin
    • Journal of Aquaculture
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    • v.19 no.1
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    • pp.19-24
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    • 2006
  • The objective of this study was to develop an efficient control method for the Alella macrotrachelus parasitic cultured black porgy, Acanthopagrus schlegeli utilizing the superior osmoregulatory ability of the host fish. The average number of the parasites on a fish was 5 worms (all female), which were attached to the cartilage of gill filament by their bulla. Morphologically, the parasite was tripartite with each length of $1822.1{\pm}521.5{\mu}m$ for the trunk $1825.0{\pm}495.8{\mu}m$ for the cephalothorax, and $134.2{\pm}43.1$ for the bulla. In histological observations, it was found that the female parasite took gill lamellae. Damage and loss of gill lamellae by the parasite caused hemorrhage and anemia in the fish. All parasites died within 48 hours by osmotic shock of freshwater or $5{\sim}15\%_{\circ}$ seawater treatment. These results suggest that Alella macrotrachelus could be controled by hyposmotic treatment.