• Title/Summary/Keyword: 산화소성

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Electrochemical Characterization of Cobalt Oxide Xerogel Electrode for Supercapacitor (수퍼커패시터용 산화코발트 건조겔전극의 전기화학적 특성)

  • Kim Han-Joo;Shin Dal-Woo;Kim Yong-Chul;Kim Seong-Ho;Park Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.3 no.3
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    • pp.146-151
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    • 2000
  • So fine cobalt oxide xerogel powders were prepared by using a unique solution chemistry associated with the sol-gel process. The effect of thermal treatment on the crystalinity, particle structure, and corresponding electrochemical properties of the resulting xerogel remained amorphous as $Co(OH)_2$ up to $160^{\circ}C$ With an increase in the temperature above $200^{\circ}C$, both the surface area and pore volume decreased sharply, because the amorphous $Co(OH)_2$ decomposed to form CoO that was subsequently oxidized to form crystalline Co304. In addition, the changes in the crystallinity, and particle structure all had significant but coupled effects on the electrochemical properties of the xerogels. A maximum capacitance of 192F1g was obtained for an electrode prepared with the $CoO_x$ Xerogel calcined at$150^{\circ}C$, which was consistent with the maxima exhibited in both the surface area and pore volume. This capacitance was attributed solely to a surface redox mechanism.

Efficacy of antibacterial treatments of fresh ginseng (Panax ginseng C.A. Meyer) (항균제 처리에 따른 수삼의 미생물 저감화 효과)

  • Choi, Jun-Bong;Cho, Won-Il
    • Korean Journal of Food Science and Technology
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    • v.54 no.1
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    • pp.75-79
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    • 2022
  • Fresh, washed ginseng can be contaminated with microorganism loads as high as 6.5 log CFU/g for total bacteria and 4.3 log CFU/g for mold. The goal of this study was to test eight antibacterial agents on ginseng. Immersing fresh ginseng washed in 1% (w/w) sodium citrate, sodium diacetate, sodium acetate, citric acid, and sodium lactate solution for 1 h resulted in a bactericidal effect of 31.0-97.5% for total bacteria. Among the organic acids, sodium citrate had the best antibacterial effect, with total bacteria reduced from 6.5 log to 4.9 log CFU/g. A 1% (w/w) vitamin B1 lauryl sulfate solution with surfactant function by hydrophilic and hydrophobic sites can reduce 2.7 log CFU/g (99.8% inactivation) on total bacteria. In the 1% (w/w) calcium oxide solution, total bacteria were reduced by 3 log, showing an excellent inactivation effect of 99.9%. Calcium oxide is a highly useful material for inactivation of microorganisms in fresh ginseng.

A Study on Reaction Characteristics of H2 SCR using Pt/TiO2 Catalyst (Pt/TiO2 촉매의 H2 SCR 반응 특성에 관한 연구)

  • Kim, Sung Su;Choi, Hyun Jin;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.18-23
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    • 2010
  • This work investigated the catalytic reaction characteristics of $H_2$ SCR applied at low temperature ($80{\sim}150^{\circ}C$) using Pt catalyst supported on $TiO_2$. The experiments were performed in terms of $H_2O$, $O_2$ in reaction gas, calcination temperature of the Pt catalyst, $H_2$/NOx mole ratio, space velocity. $H_2O$ was an inhibitor of reaction on $H_2$ SCR using Pt catalyst, catalytic performance increased as $O_2$ concentration decreased. Nevertheless, $NH_3$ slip generated by the reaction between NOx and $H_2$ in the absence of $O_2$. While it was effective to calcine less than $600^{\circ}C$ by phase transition and the catalytic performance increased as $H_2$/NOx mole ratio increased. However, $H_2$ slip was not observed at that increase mole ratio by $H_2$ oxidation to $H_2O$.

Properties of $Fe_2O_3$-doped $SnO_2$ Oxides for CO Sensor (CO 센서용 $Fe_2O_3$를 첨가한 $SnO_2$ 산화물의 특성)

  • Bae, In-Soo;Lee, Hyun-Kyu;Hong, Kwang-Joon;Lee, Woo-Sun;Park, Jin-Seoung
    • Journal of Sensor Science and Technology
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    • v.10 no.4
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    • pp.222-231
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    • 2001
  • The material properties of $SnO_2$ were investigated as a function of the amount of $Fe_2O_3$, the partial pressure of oxygen, the concentration of CO gas, and temperature. $Fe_2O_3$-doped $SnO_2$ thick films were prepared by the screen printing technique on alumina substrate. The specimens sintered at $700^{\circ}C$ for 6 hours showed little difference of the grain size and narrow distribution with the content of $Fe_2O_3$. The electrical conductance of undoped $SnO_2$ is high at low firing temperature and at low partial pressure of oxygen. The electrical conductance of $Fe_2O_3-$-doped $SnO_2$ is increased with measurement temperature, but decreased with the content of $Fe_2O_3$. The dependence of oxygen partial pressure is decreased with dopant addition. The highest sensitivity and the good properties of response speed and repeatability for CO gas were observed on the specimen with 0.1 mol% $Fe_2O_3$ at $350^{\circ}C$.

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Effect of combined endurance and weight training on muscle morphology and oxidative enzyme activities in human skeletal muscle (복합 운동 훈련이 인간 골격근의 형태학적 변화와 유산소 대사관련 효소 활성에 미치는 영향)

  • Lee, Kil-Woo;Lee, Jong-Sam;Lee, Jang-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.1
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    • pp.367-376
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    • 2014
  • The purpose of this study was to investigate the effect of either endurance training only or endurance and weight training on muscle morphology and oxidative enzyme activities in human skeletal muscles. Fourteen healthy males were randomly divided into one of two experimental training groups, either swim exercise training (n=7, ST) or combined exercise training (swim and resistance exercise training; n=7, SWT). The change of muscle fiber type was not significantly different between ST and SWT following 6 weeks of exercise training. Mean cross sectional areas as well as the numbers of capillary of different types of muscle fiber were not also significantly different from baseline for both exercise training groups (p>.05) although the tendency of increase were more notable in SWT. All oxidative enzyme activities (i.e., ${\beta}$-hydroxyl acyl dehydrogenase, citrate synthase, and carnitine palmitoyl transferase) were marginally higher in SWT compared to ST even though statistical power did not reach the level of significance. Based on these results, it was concluded that performing of combined (swimming and weight) exercise training could be the better modality for improving muscle morphological changes and oxidative enzyme activities than performing of only single aerobic exercise intervention in young healthy human skeletal muscles.

Isolation and Characterization of Oxygen-tolerant Mutant of Bifidobacterium longum. (Bifidobacterium longum 산소변이주의 분리와 변이주의 산소내성)

  • 안준배;김광엽;박종현
    • Microbiology and Biotechnology Letters
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    • v.26 no.6
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    • pp.476-482
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    • 1998
  • Growth sensitivity of bifidobacteria on oxygen hindered their industrial applications so that it was necessary to select oxygen-tolerant strains. Studies on their responses to oxygen might facilitate the effective utilization of bifidobacteria in industry. Oxygen-tolerant strain of Bifidobacterium longum JI-1 was able to remove 3% dissolved oxygen within 10 min whilst oxygen-sensitive strain of B. adolescentis, slime non-former, was not. The ability to remove environmental oxygen seemed to be related to the oxygen-tolerance of bifidobacteria. Mutant B. longum ADJ-1 was induced from the B. longum JI-1 under microaerobic atmosphere. There were no differences in sugar utilization pattern, NADH oxidative enzymes and cellular fatty acid compositions between them. The maximal cell density of the mutant was a little bit reduced to 81% of that of the mother strain. However, the mutant formed thick slime layer around its cell. The layer visualized with confocal scanning laser microscopy from the mutant was 6 ${\mu}{\textrm}{m}$ in diameter but that from the mother strain was only 3 ${\mu}{\textrm}{m}$. Therefore, the improved tolerances of the mutant might come from the slime layer, indicating the increase of the layer might be one of oxygen tolerance mechanisms for bifidobacteria.

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Density and Water Absorption Characteristics of Artificial Lightweight Aggregates containing Stone-Dust and Bottom Ash Using Different Flux (폐석분 및 바텀애시를 사용한 인공경량골재의 융제(Flux) 종류에 따른 밀도 및 흡수율 특성)

  • Han, Min-Cheol;Shin, Jae-Kyung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.49-55
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    • 2012
  • In this paper, the physical properties of lightweight aggregate such as density and water absorption according to addition ratio and type of flux were investigated. When using $Na_2CO_3$ as flux of lightweight aggregate, burnability was available at low burning temperature and water absorption increased. And as increasing addition ratio of $CaCO_3$, NaOH, $Fe_2O_3$, absorption decreased and $CaCO_3$, NaOH, $Fe_2O_3$ were considered improper to use flux of lightweight aggregate because of high dried density. $Na_2SO_4$ was proper to use flux of lightweight aggregate due to dried density $1.35{\sim}1.50g/cm^3$ and lower absorption. When using glass abrasive sludge as flux of lightweight aggregate, dried density and water absorption were in the range of $1.45{\sim}1.55g/cm^3$ and 9~12% respectively. It was indicated that as increasing addition ratio of blast furnace slag powder, density increased whereas absorption decreased. In use of oxidizing slag as flux, artificial lightweight aggregate which have dried density $1.46g/cm^3$, water absorption 8,5 % can be manufactured at 10 % of addition ratio.

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Characterization of Transparent TiO2 Power and Thin Films through Sol-Gel Process (졸-겔법을 이용한 투과성 TiO2 분말 및 박막의 특성 연구)

  • Jung, Mie-Won;Lee, Zee-Young;Son, Hyun-Jin
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.252-258
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    • 2002
  • Transparent $TiO_2$ thin films prepared by sol-gel process using the modification of titanium(IV) alkoxide showed improved thermal stability and high refraction index. Compared to the pure $TiO_2$ film, the modified $TiO_2$ films show the increased index of refraction under proper condition at pH 2.5. Transparency of these $TiO_2$ thin films were more than 80% in the visible region. It has been demonstrated that the reaction occurs in the amorphous phase: an exchange of phase results in anatase before and after 400$^{\circ}C$, in rutile over 700$^{\circ}$C form the XRD results. The particle sizes, shapes and structures of these nanoclusters in the $TiO_2$ films have been identified through a SEM and XRD. The physical properties and structures of their powders have also been studied through a SEM, XRD, TGA and DSC. The thickness and index of refraction have been determined by the analysis of ellipsometric spectra.

The Effects of Aerobic Training Intensity Difference on Cardiovascular Disease Pathophysiological Pathways Linking Oxidative Tissue Damage in Obese Children (유산소 훈련 강도 차이가 비만 어린이의 산화적 조직 손상에 의한 심혈관질환 병태생리적 경로에 미치는 영향)

  • Woo, Jin-Hee;Shin, Ki-Ok;Kim, Keun-Soo;Kim, Young-Il;Kang, Sung-Hwun
    • Journal of Life Science
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    • v.20 no.9
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    • pp.1394-1401
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    • 2010
  • The purpose of this study was to examine the effect of 12 wk of aerobic exercise on lipid profiles, antioxidant enzyme activities, oxidative products, and autonomic nervous activity (ANA) in children with obesity. We studied 16 children with obesity and 19 age-matched normal weight controls over a period of 12 wk, during which time moderate intense running exercise was performed. Measurements included peak oxygen uptake, body composition, blood lipid profiles, ox-LDL, 8-OHdG, SOD, GPx activities, total mRNA, and ANA. There were no differences in body weight between periods in the OW group, but body weight increased after 12 wk in OR and CO groups. There were no differences in WHR between periods in the OR and CO groups, but the WHR values decreased after 12 weeks in the OW group. In the obese group, the baseline TG was higher than in the controls (p<0.05), while the ANA level was lower. There were differences in antioxidant enzyme gene expressions between periods in all groups. In conclusion, oxidative damage and antioxidant enzyme activities in obese children were found to be similar to those of normal weight children. However, TG was higher and ANA was lower in obese children than in normal weight children. These results indicated that increased TG and decreased ANA levels begins in childhood in obese patients. Also, regular aerobic exercise may modify the antioxidant enzyme gene expression in early life.

Analyses on the Physical and Electrochemical Properties of Al2O3 Coated LiCoO2 (리튬이차전지용 양극 활물질(LiCoC2)의 표면처리의 특성 분석 및 전기화학적 특성 고찰)

  • Chang, Youn-Han;Choi, Sei-Young
    • Journal of the Korean Electrochemical Society
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    • v.10 no.3
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    • pp.184-189
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    • 2007
  • The importance of secondary battery industry is getting excited according to the development of battery industry as a high efficiency energy supplier of electronic machine of mobile information such as mobile phone, lap-top computer, PDA. It is rasing the interest about security of safety and high efficiency of cathode material for main part of secondary lithium battery. The cathode material which has been used like $LiCoO_2,\;LiMn_2O_4,\;LiNi_xCo_yMn_zO_2,\;LiNi_xCo_yM_zO_2$ (M=Al, Zr, Mg etc.,) the most typical material is $LiCoO_2$. But it is studying the development of substitute such as efficiency amelioration of $LiCoO_2$, thetiary element, olivine element because of the capacity of $LiCoO_2$, the matter of security; especially the betterment of efficiency, security research of safety has been actively processed in domestic and overseas about surface coating treatment of active cathode which is using oxide ($M_xO_3$). This study analyses side effect of battery according to increase of surface treatment, formation of precipitation for reagent condensation, non-reagent residue of oxide ($M_xO_3$) which is remains during the surface treatment of $LiCoO_2$; conducts study of new process, the consideration of the electrochemical property to improve oxide solution of mixing rate, mixture of surface treatment, dryness, calcinations conditionetc.