• Title/Summary/Keyword: 산화마모

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C0$_{2}$ 레이저를 이용한 스테인리스강의 절단특성

  • 이준호;김규태;나일;김재도
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1993.04b
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    • pp.23-27
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    • 1993
  • 스테인리스강은 내식성, 내열성, 내산화성이 좋으므로 화학산업, 의학용기, 고정밀 산업 등에서 많이 사용되고 있다. 스테인리스강은 열전도율이 낮고 용융물의 점성이 크고 가공경화가 심하기 때문에 인코넬 티탄합금 등과 함께 난삭재로 알려져 있다. 스테인리스강의 고합금강을 사용한 기계가공은 공구의 마모가 심하게 일어나므로 가 공이 어렵다. 화염절단(Flame dutting)도 합금물의 버닝(burning)현상을 막는 성질 때문에 잘쓰이지 않고 플라 즈마-아크(plasma-arc) 절단은 수중에서 이루어질 경우 절단끝이 산화되지 않는 좋은 절단면을 얻을 수 있으나 수중에서 사용해야 하는 어려움이 있다. 레이저를 이용한 가공은 절단폭이 작아 재료의 손실이 적으며 복잡한 형상의 절단도쉽고 공구의손실이 없는등 많은 장점이 있어서 사용이 증가하고 있다. 본 연구에서는 스테인리스 강의 절단메커니즘에대한 이해를 돕기 위해 절단가공에 큰 영향을 끼치는 레이저 출력, 절단속도, 절단가스의 압력, 재질, 절단두께를 절단변수로채택하여 절단을 수행하였다. 절단결과를 비교 검토하여 절단변수가 절단에 미치는 영향을 분석하였고 최적의 절단을 얻는 가공조건을 제시하였다.

내연기관용 윤활유 첨가제의 국산화에 대한 연구

  • 김종호
    • Tribology and Lubricants
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    • v.3 no.2
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    • pp.15-22
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    • 1987
  • 윤활유는 일반적으로 윤활기유의 물성을 개량하기 위해 여러종류의 윤활유 첨가제를 포함하고 있는데 이 첨가제는 윤활기유가 가지고 있는 물성을 강화시키기 위해 첨가하는 것과 윤활기유에는 없는 물성을 얻기 위해 첨가하는 두가지로 나눌수 있다. 윤활기유의 산화분해, 열분해, 마찰이나 마모의 감소등을 위해 첨가흔 넉승 전자에 속하는 경우이고 기유 분해분의 침적을 막아주거나 부식을 방지하며 온도에 따른 점도변화를 극소화시키기 위한 첨가제는 후자에 해당한다. 즉 윤활유 첨가제는 윤활기유의 물리적, 화학적 성질을 보완 또는 강화시키므로서 윤활유로서의 소기의 목적을 달성하도록 첨가하는 화학물질을 말한다. 본 보에서는 위에서 열거한 여러종류의 첨가제 중 사용물량이 많아 수입대체 효과가 뚜렷한 6종의 첨가제의 국산화에 대한 연구결과를 간략하게 기술하였으며 앞으로 2회에 걸쳐 나누어 설명코자 한다.

Influence of External Air Velocity for Tribological Characteristics between Sintered Friction Material and Disk (외부 공기속도 변화에 따른 소결마찰재와 디스크간 마찰특성)

  • Lee, Jong Seong;Lee, Hi Sung
    • Tribology and Lubricants
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    • v.29 no.1
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    • pp.19-26
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    • 2013
  • Cu-matrix sintered brake pads and low-alloy heat-resistant steel are commonly applied to basic brake systems in high-energy moving machines. In this research, we analyzed the tribological characteristics to determine the influence of the air velocity between the disk and pad. At a low brake pressure with airflow, the friction stability was decreased as a result of the lack of tribofilm formation at the disk surface. However, there were no significant changes in the friction coefficient under any of the test conditions. The wear rates of the friction materials were decreased with an increase in the airflow velocity. As a result, the airflow velocity influenced the friction stability, as well as the wear rate of the friction materials and disk, but not the friction coefficient.

Influence of Inertial Mass on Tribological Characteristics between Sintered Friction Material and Disk (관성에 따른 소결마찰재와 제동디스크간 마찰특성 연구)

  • Lee, Jong Seong;Kang, Bu Byoung;Lee, Hi Sung
    • Tribology and Lubricants
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    • v.29 no.2
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    • pp.98-104
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    • 2013
  • Cu-matrix-sintered brake pads and heat-resistant low-alloy steel are commonly applied to basic brake systems in high-energy moving machines. We analyzed how the tribological characteristics are influenced by the inertial mass. A high inertial mass decreased the friction coefficient by about 15% compared to a low inertial mass under all velocity conditions. The wear rates of the friction materials increased with the inertial mass. Thus, the inertial mass influences the friction coefficient and wear rate of the friction materials and disk but not the friction stability.

Grease from Korean Bentonites (국산 벤토나이트 그리이스 제조)

  • Tak Jin Moon;Oh Kwan Kwon
    • Journal of the Korean Chemical Society
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    • v.16 no.3
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    • pp.193-199
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    • 1972
  • Bentones from Korean bentonites were first prepared by reacting bentonites with high molecular weight imidazolines. The cation exchange capacity of bentonites was found more than 100meq/100g sample. Greases were then prepared by dispersing bentones into a lubricating oil and milling through a three-roll dispersion mill. Consistency in microscale, oxidation stability (static), water resistance, and wear property of the greases were tested by the ASTM methods, and good experimental results were obtained.

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A study on friction and wear properties of plasma-sprayed $Cr_2O_3/Mo$ composite coatings (산화크롬/몰리브덴 복합 플라즈마 용사 코팅의 마찰, 마모 특성 연구)

  • 여인웅;안효석
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.10a
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    • pp.17-24
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    • 1998
  • Plasma-sprayed coatings were obtained by spray-dried $Cr_2O_3$ powder with and without Mo addition. A reciprocal type tribo-tester was employed to examine friction and wear behavior of the specimens at room temperature. The composition and the worn surface of coated specimens were observed by XRD and SEM. The results showed that friction Coefficient of the Mo added specimens were lower than one of $Cr_2O_3$ specimen. But $Cr_2O_3$ specimen had a lower wear loss. Protecting layer were observed at the worn surface of coated specimens with Mo addition.

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A Study on the Relationship between Oxidation and Sliding Wear Behavior of Ordered Fe-Al Intermetallic Alloys (규칙화된 Fe-Al 계 금속간 화합물의 산화특성과 미끄럼 마모거동과의 관계에 대한 연구)

  • 김용석
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.03b
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    • pp.144-148
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    • 1999
  • The relationship between oxidation and sliding wear behavior of Fe-28 at%. Al alloys with B2 ordered structure has been investigated. Sliding wear tests of the alloys have been carried out under various environmental conditions using a pin-on-disk wear tester. The wear rate of the ordered alloys in an oxygen atmoshpere was found to be much lower than in an oxygen atmosphere showed that Fe2O oxides formed on the wearing surface. The oxide layer prevented direct contact of the two mating materials and therefore improved wear resistance of the Fe-Al intermetallic alloy. It was found that the surface Al2O3 oxide layer which provides good oxidation resistance and improved mechanical properties broke down easily and didnot function properly as an oxidation barrier.

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Synthesis, Dispersion, and Tribological Characteristics of Alkyl Functionalized Graphene Oxide Nanosheets for Oil-based Lubricant Additives (액체 윤활제 첨가제용 알킬 기능화된 산화 그래핀의 합성/분산 및 트라이볼로지적 특성)

  • Choe, Jin-Yeong;Kim, Yong-Jae;Lee, Chang-Seop
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.533-540
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    • 2018
  • Graphene has been reported to be an excellent lubricant additive that reduces friction and wear when coated on the surface of various materials or when dispersed in lubricants as an atomic thin material with the low surface energy. In this study, alkyl functionalized graphene oxide (FGO) nanosheets for oil-based lubricant additives were prepared by using three types of alkyl chloride chemicals (butyl chloride, octyl chloride, and tetradecyl chloride). The chemical and structural properties of the synthesized FGOs were analyzed by Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscope (SEM), and transmission electron microscope (TEM). The synthesized FGOs were dispersed at 0.02 wt% in PAO-0W40 oil and its tribological characteristics were investigated using a high frequency friction/wear tester. The friction coefficient and the wear track width of poly alpha olefin (PAO) oil added with FGO-14 were tested by a ball-on-disk method, and the measured results were reduced by ~5.88 and ~3.8%, respectively compared with those of the conventional PAO oil. Thus, it was found that the wear resistance of PAO oil was improved. In this study, we demonstrated the successful functionalization of GO as well as the improvement of dispersion stability and tribological characteristics of FGOs based on various alkyl chain lengths.

Effects of Carburizing Process on Sliding wear Behavior of Carburized SCM420H Steel (침탄처리한 SCM420H의 미끄럼 마모 특성에 미치는 침탄 조건의 영향)

  • Lee, Han-Young;Lee, Kyu-Hyun
    • Tribology and Lubricants
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    • v.36 no.1
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    • pp.18-26
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    • 2020
  • The effects of the carburizing process on the sliding wear behavior of SCM420H steel have been investigated. In particular, the effects of grain boundary corrosion observed in the surface layer after gas carburizing and the effects of hardness of the carburized cases after heat-treatment on the sliding wear properties were examined. Pin specimens carburized by two methods (gas carburizing and vacuum carburizing) were tempered at two temperatures of 180℃ and 400℃ after oil-quenching, respectively. Sliding wear tests were carried out against heattreated SKH51 steel at several sliding speeds using a pin-on-disc type test machine. As results, it can be found that there is no difference in the wear behavior between the pins carburized using two methods. This implies that the grain boundary corrosion that formed in the surface layer after gas carburizing has no effect on the sliding wear behavior of carburized SCM420H steels. Additionally, there is no significant difference in the wear behavior between carburized pins tempered at 400℃ and at 180℃ after oil-quenching, regardless of the carburizing method. This is because carburized pins tempered at 400℃ have a troostite structure, which exhibits higher tribochemical reactivity even though its hardness is lower than that of martensite structure. In this respect, it can be considered that good wear resistance of carburized cases is maintained at least until the effective case depth.

합금화된 단일타겟을 마그네트론 스퍼터를 이용하여 합성된 나노복합구조 Al-Ti-X-N (X=Si,Cu,Cr) 코팅의 기계적 특성

  • Jeong, Deok-Hyeong;Lee, Han-Chan;Sin, Seung-Yong;Mun, Gyeong-Il
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.281-281
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    • 2011
  • 산업 환경에서 친환경 및 에너지효율성을 중요한 조건이 되면서 고효율성 및 다기능을 가진 재료에 대한 연구가 활발히 진행 되고 있다. 특히 Al-Ti-N 코팅은 이미 경도 측면에서 우수 하여 고속 공구 부품에 널리 사용되고 있고 최근에 Al-TiN에서 Si 첨가는 40GPa이상의 고경도와 1000도 이상의 산화온도를 지닌 나노 혼합물 코팅을 형성 시키는 것으로 알려져 있다. 본 연구에서 Al-Ti에 Si, Cu, Cr 을 첨가하였을 때 코팅을 형성하였을 때 바뀌는 물성 변화을 확인하였다. 이러한 연구를 위해 Al-Ti 합금 조성 중 가장 우수한 것으로 알려진 60:40으로 타겟을 만들어 스퍼터 장비를 이용해 코팅을 형성하여 기초 실험을 진행하였다. 그 근거로 하여 3원계인 Si, Cu, Cr 을 첨가하여 각각의 단일 타겟으로 만들고 코팅을 형성하였다. 타겟과 코팅의 성분이 동일한지 확인하기 위해 EPMA분석을 하였고 그 결과 오차 범위 내에 동일한 것으로 확인하였다. 또 내산화성 테스트를 위해 400도에서 1000도로 가열된 대기 중에 코팅 층을 1시간씩 노출시키는 공정을 통해 확인하였고 내식성 테스트는 SUS 304계열 위에 코팅을 하여 Potentiodynamic polarization scan 장비로 비교해 보았다. 표면경도는 3원계 코팅인 경우 질소비율이 증가할수록 30GPa ~ 35GPa까지 증가하였고 XRD 분석 결과와 비교 시 (111), (200) peak가 명확할수록 경도 값이 높은 것으로 확인하였다. 마모테스트 결과 3원계인 코팅 층이 dry상태에서 감소하는 경향을 보였다. 특히 0,26까지 감소한 Si 을 첨가한 코팅 층은 H/E지수도 좋아 마모트랙의 길이도 짧아 우수한 것으로 알 수 있었다. 이런 결과에서 보듯 3원소 이상 첨가 시 특성변화가 차이가 있다는 것을 알 수 있었다.

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