• Title/Summary/Keyword: 산소확산

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The Effect of Thermal Treatments on the Peel Adhesion Strength of Pt/Ti Thin Film for a Bottom Electrode of Ferroelectric Materials (강유전체의 하부전극용 Pt/Ti 박막의 필 접착력에 미치는 열처리의 영향)

  • Lee, Tae-Gon;Kim, Yeong-Ho;Choe, Deok-Gyun;Gwon, O-Gyeong
    • Korean Journal of Materials Research
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    • v.6 no.6
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    • pp.610-617
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    • 1996
  • 강유전체 재료의 하부전극으로 사용되고 있는 Pt/Ti 박막의 접착력에 대한 열처리 분위기의 영향을 연구하였다. 시편의 접착력은 90$^{\circ}$ 필 테스트 방법을 사용하여 정량적으로 측정하였다. 열처리 후 사용된 분이기에 관계없이 모두 접착력이 감소하였는데 특히 산소분위기에서 열처리 한 시편의 접착력이 매우 크게 감소하였다. AES depth profile과 단면 TEM을 이용하여 계면반응을 관찰한 결과 산소열처리시에는 Ti가 외부에서 확산해 온 산소와 반응하여 rutile TiO2상이 형성됨을 알 수 있었다. 그러므로 산소열처리 후에 일어나는 접착력의 급격한 감소 원인은 열처리시 취약한 TiO2상이 형성되며 이로 인해 Ti 접착층이 고갈되기 때문임을 알 수 있었다.

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Effects of Bioturbation of the Amphipod Monocorophium uenoi on the Vertical Distribution of Sulphides and Oxygen within Sulphides-Rich Sediments of Lake Sihwa (세가시육질꼬리옆새우(단각류)의 생물교란이 시화호 퇴적물 내 황화합물과 산소 농도의 수직적 분포에 미치는 영향)

  • Koo, Bon Joo;Kwon, Kae Kyeong;Shin, Sang-Ho;Je, Jong-Geel
    • Journal of Wetlands Research
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    • v.8 no.3
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    • pp.79-89
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    • 2006
  • The survival rate and tube number of Monocorophium uenoi, one of the dominant species in Lake Sihwa, was investigated under laboratory condition with salinity gradients (1, 5, 10, 15, 20, 25, 30, 35, 40‰). Another laboratory experiments were conducted to investigate the survival rate of Monocorophium uenoi in sulphide-rich sediment with oxic overlying water, and the effect of amphipod bioturbation on sulphide and oxygen profiles. The survival rate and tube-forming number of the amphipod were high in salinity range of 20 to 30‰. The amphipod survival rate was also high in sulphidic sediment when the water column was oxic. The amphipod bioturbation affected the oxygen and sulphide content in the sediment; oxygen conditions in the upper sediment layers were improved, and simultaneously the concentrations of sulphide were reduced. And their depth was clearly dependent on amphipod density. In Lake Sihwa, previously anoxic bottoms with sulphidic sediment during summer turn oxic with pycnocline disappearance during autumn. Amphipods seem to have the capability to quickly invade such areas, and their tubing of the sediment may play an important role in preparing the sediment for further recolonisation of other macrobenthos.

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Wave Field Analysis around Permeable Breakwaters (투과성 방파제 주변의 파랑장 해석)

  • 곽문수;이기상;편종근
    • Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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    • 2002.08a
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    • pp.49-55
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    • 2002
  • 항만을 계획함에 있어서 방파제는 가장 대표적인 계획요소로서 주된 목적은 외해로부터 내습하는 파랑을 차단하여 항내의 정온수역을 확보하는 것이다. 그러나 불투과성 방파제의 경우는 페쇄성이라는 특성 때문에 연안에서의 물질순환 체계가 구조물 건설전의 환경과는 근본적으로 달라져 심각한 환경부작용이 초래되어 왔다. 육상으로부터 유입된 유기물질이 외해로 확산되지 못하고 항내에서 누적됨으로서 부영양화가 일어나며 항외에서의 산소를 포함하고 있는 해수의 유입이 차단됨으로서 항내는 만성적인 산소부족현상이 발생하게 된다. (중략)

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Real-Time Observation of Water Diffusion under Graphene

  • Lee, Dae-Eung;Ryu, Sun-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.211-211
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    • 2013
  • 나노 크기의 공간에서의 물질의 이동은 표면의 환경에 의해 영향을 받을 수 있다. 소수성그래핀과 친수성 실리콘 기판 사이의 계면에서의 물의 확산은 호기심을 자극할 뿐만 아니라 그래핀 소자의 특성을 좌우하는 전하도핑(charge doping) 현상을 이해하는데 중요한 모델이 된다. 본 연구에서는 라만 분광법과 원자 힘 현미경을 사용하여 그래핀/SiO2 계면 사이의 물의 확산 현상과 그에 따른 정공 밀도 변화를 탐구하였다. 열처리 된 그래핀은 기판과의 상호 작용에 의해 높은 밀도의 정공(electron hole)으로 도핑 되어 있으며, 이를 물에 담지 하였다. 본 실험에서는 이차원 라만 분광법을 통해 물 속에 담겨진 그래핀의 정공 밀도의 공간적인 분포를 확산 시간에 따라 조사하였다. 물의 확산은 시료에 따라 수 시간에서 수 일의 시간대에 걸쳐 그래핀 가장자리에서 중앙으로 이루어진다는 사실을 확인하였다. 또한 물의 계면 확산으로 인하여 전하 밀도가 감소한다는 사실은 열처리 된 그래핀의 정공 도핑을 유발하는 산소가 계면에 존재한다는 것을 증명한다.

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Combustion Characteristics of Methane-Oxygen Diffusion Flame Formed by Swirl-coaxial Injector (스월 동축형 인젝터에 의해 형성되는 메탄-산소 확산화염의 연소특성)

  • Bae, Seong Hun;Hong, Joon Yeol;Kim, Heuy Dong;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.2
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    • pp.1-8
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    • 2017
  • In order to analyze combustion characteristics of methane-oxygen diffusion flame in a model combustor, combustion experiments were carried out under various spray conditions of propellant scrutinizing combustion stability limit and flame shapes. As the propellant approached the theoretical equivalence ratio condition, a stable detached flame was observed even under high oxygen Reynolds number. And the length of the visible flame increased and the lift-off distance of the flame exhibited a tendency toward decrease. Due to the swirl effect of the propellant by the swirl-coaxial injector, a wide and short flame was produced. Thus, it may be appropriate to employ the swirl-coaxial injector in thrusters having a limited physical dimension.

Experimental Investigations of the Characteristics of the Length Variation of Kerosene-Oxygen Laminar Diffusion Flames (등유-산소 층류 확산화염의 길이 변화 특성에 관한 실험적 연구)

  • Lee, Soo-Han;Lee, Jong won;Park, Seul Hyun
    • Fire Science and Engineering
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    • v.32 no.6
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    • pp.22-27
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    • 2018
  • The flame length in coaxial diffusion flame configurations was investigated when the kerosene fuel flow rate, temperature of the oxidizer stream, and inert gas concentrations in the oxidizer stream were varied. The diffusion flame was photographed using a Schlieren camera under each of the experimental conditions and the obtained images were then digitized to measure the flame length. The measured flame lengths were proportional to the kerosene fuel flow rate and increased with increasing temperature of the oxidizer stream. In addition, increases in the inert gas concentration in the oxidizer stream resulted in stretching of the flame. In particular, the flame was further elongated in the oxidizer steam diluted with helium gas. Inert substitutions in the oxidizer stream that can adjust the viscous drag are believed to be one of the important mechanisms that affect the length of the coaxial diffusion flames.

Mass Transfer Characteristics of Vertical Two-Phase Flows with Orifice Nozzle (오리피스 노즐 수직 2 상 유동의 물질전달 특성)

  • Kim, Dong Jun;Yang, Hei Cheon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.10
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    • pp.817-824
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    • 2015
  • Experiments were carried out to investigate the flow and mass transfer characteristics of an orifice nozzle. Measurements of primary and suction flow rates, dissolved oxygen concentration, and electric power were obtained. Vertically injected mixed-jet images were captured by a direct visualization technique with a high speed camera unit. The mass ratio, volumetric mass transfer coefficient, and mass transfer performance were calculated using the measured data. As the primary flow pressure increases, the mass ratio decreases slightly, while the volumetric mass transfer coefficient and electric power increase. As the primary flow pressure increases and the mass ratio decreases, the mass transfer rate increases because of the fine bubbles and wider distribution of the bubbles.

Investigation of Spherical LiMn2O4 Cathode Materials by Spray-drying with Different Electrochemical Behaviors at High Rate (분무건조법으로 제조한 구형 스피넬계 LiMn2O4 양극소재의 합성 조건에 따른 고출력 거동에 대한 연구)

  • Song, Jun Ho;Cho, Woosuk;Kim, Young Jun
    • Journal of the Korean Electrochemical Society
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    • v.19 no.2
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    • pp.50-56
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    • 2016
  • Spherical lithium manganese oxide spinel, $Li_{1.10}Mn_{1.86}Al_{0.02}Mg_{0.02}O_4$ was prepared by wet-milling, spray-drying, and sintering process. In the spray-drying process, solid content in slurry was varied from 20 to 30 wt%. In the sintering process, the precursors have been sintered under air or $O_2$ atmosphere. While the as-prepared samples exhibit excellent electrochemical properties at room temperature, the discharge voltage profiles at 5.0C are very different one from another. The origin for the difference especially at initial state of discharge is oxygen defect. The sample prepared in air has larger capacity related to the plateau at 3.3 V (vs. $Li/Li^+$) which is caused by the oxygen defects than the one prepared in $O_2$. The difference of discharge voltage profiles especially at the final state of discharge comes from different diffusion rate of $Li^+$ ions. The sample prepared from 30 wt% solid content of slurry shows twice higher diffusion rate than the samples prepared from 20 wt% solid content, which is attributed to better compactness between primary particles for the sample prepared from 30wt % solid content than the one prepared by 20 wt%.