• Title/Summary/Keyword: 산소확산

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Effect of ${Gd_2}{O_3}$ Addition on the Sintered Density and Resintered Density in <${UO_2}-{Gd_2}{O_3}$ Pellets (${UO_2}-{Gd_2}{O_3}$소결체에서 ${Gd_2}{O_3}$첨가가 소결 및 재소결밀도에 미치는 영향)

  • Baek, Jong-Hyeok
    • Korean Journal of Materials Research
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    • v.5 no.3
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    • pp.364-370
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    • 1995
  • ex-AUC U$O_{2}$ 분말과 $Gd_{2}$O_{3}$ 분말을 기계적으로 혼합하여 소결한 U$O_{2}$-$Gd_{2}$O_{3}$ 소결체의 밀도 변화와 재소결 후 밀도변화를 기공크기 및 분포의 변화로 서술하였다. 수소분위기에서 175$0^{\circ}C$, 4시간 동안 소결하였을 때, 순수 U$O_{2}$의 소결밀도는 97.2% T.D.였으나 6wt% $Gd_{2}$O_{3}$ 첨가까지는 U$O_{2}$-$Gd_{2}$O_{3}$의 소결밀도는 $U^{+4}$와 $Gd^{+4}$의 상호확산 때문에 약 90% T.D.로 급격히 감소하였다. 그러나 6wt% 이상의 $Gd_{2}$O_{3}$가 첨가되면 우라늄이온 산화아와 산소침입으로 인하여 소결밀도는 오히려 증가하였다. 1$700^{\circ}C$에서 재소결시킬 때 순수 U$O_{2}$ 소결체에서는 재소결 시간에 따라 밀도증가가 발생하였다. U$O_{2}$-$Gd_{2}$O_{3}$ 소결체 경우에는 재소결시 밀도가 감소하였으나 재소결 시간이 증가함에 따라 다시 밀도는 증가하였고, 6wt%$Gd_{2}$O_{3}$가 첨가된 U$O_{2}$-$Gd_{2}$O_{3}$ 소결체에서 밀도가 가장 많이 감소하였다.

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Low Splicing Loss Technique between Standard Single Mode Fiber and High Δ Fiber (표준 단일모드 광섬유와 하이델타 광섬유사이의 저 손실 접속 기법)

  • Kim, Kwang-Taek;Yang, Byoung-Cheoul
    • Korean Journal of Optics and Photonics
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    • v.19 no.3
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    • pp.169-174
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    • 2008
  • In this paper, we have presented techniques to reduce the splicing loss between standard single mode fiber and high ${\Delta}$ single mode fiber based on the mode expanding and mode evolution induced by thermal treatment of the fibers. The experimental results show that mechanical splicing loss can be reduced from 2.3 dB to 0.1 dB through proper thermal treatment of the high ${\Delta}$ fiber. Meanwhile, we achieved $0.2{\sim}0.4dB$ of low splicing loss between two fibers by heating the splicing region using electric arcing or an oxygen flame.

Pt/Ti/Si 기판에서의 후속열처리에 따른 PZT 박막의 형성 및 특성

  • 백상훈;백수현;황유상;마재평;최진석;조현춘
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1993.05a
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    • pp.64-65
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    • 1993
  • MPB 조성영역인 Zr/Ti=52/48의 composite ceramic target을 사용하여 RF magnetron sputtering 방법으로 기판온도 약 30$0^{\circ}C$에서 RZT 박막을 Pt/Ti/Si 기판위에 증착시켰다. 안정상인 perovskite 구조를 형성시키기 위하여 PbO분위기에서 furnace annealing 과 Repid thermal annealing을 실시하여 열처리 방법에 따른 상형성 및 계면반응과 그에 따른 전기적 특성을 고찰 하였다. Pt 의 두께가 250$\AA$인 경우 furnace annealing 시 $650^{\circ}C$에서 perouskite 상이 형성되었으나 Pt층이 산소의 확산을 방지하지 못하여 상부의 Ti 층이 TiOx로 변태하였으며 하부의 Ti는 Si 과 반응하여 Ti-silicide 롤 변태하였다. 또한 75$0^{\circ}C$,60sec 인 경우 Pt 층의 응집화가 관찰되어 하부전극으로서 적용이 적절하지 못하다. 급속열처리를 실시한 경우에도 마찬가지로 Ti 층이 TiOx 와 silicide 층으로 변태되었다. Pt의 두께가 1000$\AA$인 경우에도 250$\AA$와는 달리 RTA 시 (III)방향으로 Furace annealing 시(001)방향으로 우선 성장하였다. 이는 Ti(001), P(111),PZT(111)면의 lattic mismatch 가 매우 작은데다 RTA 시 계면반응이 거의발생하지 않아 PZT 박막이 (111) 방향으로 우선 성장한 것으로 보인다. Furnace annealing 경우는 심한 계면반응이 발생하여 Pt층에 어느 정도 영향을 주었기 때문에 우선성장 방향이 바뀌었다구 생각한다.

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Limit-current type zirconia oxygen sensor with porous diffusion layer (다공성 확산층을 이용한 한계전류형 지르코니아 산소센서)

  • Oh, Young-Jei;Lee, Chil-Hyoung
    • Journal of Sensor Science and Technology
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    • v.17 no.5
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    • pp.329-337
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    • 2008
  • Simple, small and portable oxygen sensors were fabricated by tape casting technique. Yttria stabilized zirconia containing cordierite ceramics (YSZC) were used as a porous diffused layer of oxygen in pumping cell. Yttria stabilized zirconia (YSZ) solid electrolyte, YSZC porous diffusion layer and heater-patterned ceramic sheets were prepared by co- firing method. Limit current characteristics and the linear relationship of current to oxygen concentration were observed. Viscosity variation of the slurries both YSZ and YSZC showed a similar behavior, but micro pores in the fired sheet were increased with increasing of the cordierite amount. Molecular diffusion was dominated due to the formation of large pores in porous diffusion layer. The plateau range of limit current in porous-type oxygen sensor was narrow than the one of aperture-type oxygen sensor. However limit current curve was appeared in porous-type oxygen sensor even at the lower applied voltage. The plateau range of limit-current was widen as increasing the thickness of porous diffusion layer of the YSZ containing cordierite. Measuring temperature of $600{\sim}650^{\circ}C$ was recommended for limit-current oxygen sensor. Porous diffusion layer-type oxygen sensor showed faster response than the aperture-type one and was stable up to 30 days running without any crack at interface between the layers.

Basic Study on the Production of Nd-Fe-B System Rare Earth Anisotropic bonded Magnet Materials by the R-D & HDDR Process(I) (R-D & HDDR Process에 의한 Nd-Fe-B계 희토류 이방성 본드자석재료의 제조에 관한 기초연구 (I))

  • Jo, Seon-Mi;Son, Chang-Bin;Jo, Tong-Rae
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.609-614
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    • 2001
  • This study was carried out to obtain a basic data on the production of the Nd-Fe-B system rare earth anisotropic bonded magnet by R-D & HDDR process. The reduction reaction of Nd$_2$O$_3$by metallic Ca and the diffusion reaction of Nd into Fe-B alloy powder were investigated for the production the Nd-Fe-B alloy powder. We concluded that a proper quantity of metallic Ca was about 1.3 times of theoretical equivalent from the yields of Nd and B after the R-D reaction at 100$0^{\circ}C$ for 1h. In the XRD analysis the diffusion reaction of Nd into the center of Fe-B alloy powder for the completed homogenization was required through about 45min at 110$0^{\circ}C$ for the R-D reaction, and also the maximum efficiency on the yield of Nd was obtained with such a condition. Residual Ca and oxygen contents of the final powder sample after washing were detected in 0.17wt% and 0.42wt% by ICP and oxygen analyzer, respectively.

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Transport Coefficients and Effect of Corrosion Resistance for SFRC (강섬유 보강 콘크리트의 수송계수 및 부식저항효과)

  • Kim, Byoung-Il
    • Journal of the Korea Concrete Institute
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    • v.22 no.6
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    • pp.867-873
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    • 2010
  • This study investigated the corrosion properties of reinforced concrete with the addition of steel fibers. The transport properties of steel fiber-reinforced concrete such as permeable void, absorption by capillary action, water permeability and chloride diffusion were first measured to evaluate the relationship with the corrosion of steel rebar. Test results showed a slight increase on the compressive strength with the addition of steel fibers as well as considerable improvement of penetration resistance to mass transport of harmful materials into concrete. The addition of steel fibers in reinforced concrete accelerated the initiation of steel corrosion contrary to the expected results based on the measured transport properties. The NaCl ponding surface showed the spalling failure due to the corrosion expansion of steel fibers and the cut-surface around the steel rebar showed the localized steel fiber's corrosion. The wet-dry cycling with high chloride ions as well as high temperature seems to induce the increase of salt crystallization on the pores continually and the increased pressure with the steel fiber's corrosion on the pores caused the spalling failure on the exposed surface. The microcracking on the surface therefore accelerated the movement of water, chloride ions and oxygen into the embedded steel rebar. The mechanism affecting corrosion of embedded steel reinforcement with steel fibers in this study are not yet fully understood and require further study comprising of accurate experimental design to isolate the effect of steel fiber's potential mechanism on the corrosion process.

Effect of Nb, V and Cr on the High Temperature Oxidation of Ti-(42, 44)% Al Alloys (Ti-(42, 44)%Al 합금의 고온내산화성에 미치는 Nb, V 및 Cr의 영향)

  • Lee, Yeong-Chan;Kim, Mi-Hyeon;Kim, Seong-Hun;Lee, Won-Uk;Baek, Jong-Hyeon;Lee, Dong-Bok
    • Korean Journal of Materials Research
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    • v.9 no.10
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    • pp.1025-1031
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    • 1999
  • Alloys of TiAl with six different compositions. i. e., Ti-(42, 44)Al-2Nb-4V. Ti-(42, 44)Al-4Nb-2V and Ti -(42, 44)Al-4Nb-2Cr, were manufactured by arc-melting. and their oxidation behavior was studied. Both isothermal and cyclic oxidation tests were performed at 700, 800 and $900^{\circ}C$ in air for 50hr. The oxidation resistance increased in the order of Ti-(42, 44)Al-2Nb-4V, Ti-(42, 44)Al-4Nb-ZV and Ti-(42, 44)Al-4Nb-2Cr. It was found that V was a deleterious element, while Cr was a beneficial element in terms of oxidation resistance. During oxidation, a simultaneous interdiffusion was observed. All the constituent elements in the base alloys diffused outward. whereas oxygen from the atmosphere diffused inward, to form triple oxide layers composed of an outermost $\textrm{TiO}_2$ layer. upper ($\textrm{TiO}_2+\textrm{Al}_2\textrm{O}_3$) mixed layer, and lower $\textrm{TiO}_2$-rich layer.

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Early Response of Cardiopulmonary Exercise Test in Patients with Locally Advanced Non-Small Cell Lung Cancer Treated with Systemic Chemotherapy (국소진행성 폐암환자에 대한 전신항암화학요법이 운동부하 심.폐기능에 미치는 영향 : 초기변화를 중심으로)

  • Shin, Kyeong-Cheol;Chung, Jin-Hong;Lee, Kwan-Ho
    • Tuberculosis and Respiratory Diseases
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    • v.53 no.4
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    • pp.369-378
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    • 2002
  • Background : The effects of chemotherapy on pulmonary function are mainly a reduced diffusion capacity and a restrictive ventilatory impairment. Exercise can expose cardiovascular and pulmonary abnormalities not evident at rest. Exercise related cardiopulmonary function is important in patients with malignant disease as a determinant of quality of life. We performed this study to evaluate the changes of body composition and cadiopulmonary exercise perfoemance of patients with locally advanced, non-small cell, lung cancer (NSCLC) before and after chemotherapy. Methods : We evaluated resting pulmonary function, body composition, physiologic performance status, and cardiopulmonary exercise function in 11 patients with locally advanced NSCLC, at diagnosis and prior to the fourth cycle of chemotherapy. Results : After chemotherapy, 4 patients (36.4%) showed partial response and 7 (63.4%) had stable disease. After chemotherapy, diffusion capacity of the lung for carbon monoxide was reduced ($89.7{\pm}34.1%$, vs. $71.9{\pm}20.5%$) but not significantly. There were no significant changes in body composition or the state of physiologic performance after chemotherapy. There was a significant impairment of cardiopulmonary exercise tolerance in patients with NSCLC, evidenced by a reduction of maximal oxygen uptake ($VO_2$max, ml/kg/min, $17.9{\pm}2.6$ : $12.6{\pm}6.1$, <0.05) and $O_2$pulse ($O_2$ pulse, ml/beat, $7.0{\pm}1.7$, $5.2{\pm}2.1$, <0.05). Conclusion : Systemic chemotherapy resulted in a loss of cardiopulmonary exercise function in patients with locally advanced NSCLC within the short-term period, but not a physiologic change of body composition within the same period.

Phytoplankton Response to Short-term Environmental Changes in the Vicinity of a Fish Cage Farm of Tongyeong Obi in Summer (통영 오비도 어류양식장 주변에서 하계 수계 내 단주기 환경요인의 변화에 따른 미세조류 반응)

  • Lee, Minji;Baek, Seung Ho
    • Journal of Marine Life Science
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    • v.2 no.2
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    • pp.62-69
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    • 2017
  • In order to assess the potential environmental factors in the vicinity of a fish cage farm, we investigated the biotic and abiotic factors during a short-term period in summer 2016 in two inner stations of Tongyeong Obi. High water temperature on August 10th was apparent among the full depth of up to 29℃, which might have been related to the abnormally high temperatures of large amounts of the Changjiang River discharge along the Tongyeong coast. The concentration of nitrate+nitrite, ammonium, phosphate, and silicate ranged from 0.08 to 5.11 μM, 0.08 to 34.62 μM, 0.01 to 1.15 μM, and 1.46 to 31.79 μM, respectively. The nutrients were mainly supplied by precipitation and leaching from the bottom sediments in the fish culture farm area. It was not retained for a long duration because of the phytoplankton consumption and diffusion by water currents. The chlorophyll a concentration varied from 0.49 ㎍ l-1 to 7.39 ㎍ l-1. At that time, Chaetoceros debilis, C. pseudocurvisetus, and Pseudo-nitzschia delicatissima were rapidly proliferated and reached the level of 4.74 × 109 cells l-1. In particular, the lowest dissolved oxygen was recorded at 4.52 ㎍ l-1 at the bottom layer after bloom. Therefore, even though phytoplankton blooms in summer have frequently occurred in a fish culture farm area, the oxygen-deficient environments were not found in neither the surface nor bottom layers, which implied that the water masses might be well exchanged from the mouth of the northwest and southeast between Obi and Mireuk Island in the study area.

Treatment of dyeing wastewater using Moving Bed Bioractor (부유메디아 생물막 공정을 이용한 염색폐수처리)

  • Shin, Dong-Hoon;Lee, Sang-Hun;Ryu, Seung-Han;Park, Jun-Hyung;Jo, Seog-Jin
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.110-110
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    • 2011
  • 염색공업 폐수는 그 성분이 일반적으로 매우 복잡하며, 작업공정의 가동 사항에 따라 수질 변동이 큰것이 특징으로, 각 공정에서 배출되는 염료, 보조화학물질, PVA(Polyvinyl alchol), 전분, wax 등이 포함되어 있으며 pH가 높고, 색도로 인해 하천에 방류될 경우 확산성이 높아 미생물에 의한 자정작용을 방해하여 하천의 수중생태계를 파괴할 우려가 있다. 이러한 염색산업에서 발생하는 폐수는 일반적으로 응집침전, 부상분리법 등의 전처리한 후 활성오니공정으로 처리하는 방법이 널리 이용되고 있으나, 이들 처리공정으로는 폐수 속에 포함되어 있는 다양한화학적 구조의 색소성분 및 유해물질을 완벽하게 제거하는 것이 어려운 실정이다. 유기물 함량이 높은 염색폐수를 처리하기 위해 제안된 기술로는 산소활성슬러지법, 유동상 및 고정상 생물막법, 포괄고정화법 등이 있다. 이러한 기술들중 기존의 처리공정을 증축없이도 처리효율을 높일 수 있는 방법으로 담체를 이용한 부유메디아 생물막공정(Moving-Bed BioReactor, MBBR)이 있다. 이공정은 미생물이 부착, 성장할 수 있는 공극율과 비표면적이 큰 담체를 이용하므로 반응조내의 부유 미생물 뿐만 아니라 담체에 고농도로 부착된 부착 미생물에 의해서도 유기물을 제거하기 때문에 다른 공정들에 비해 처리효율이 뛰어나고 기존의 활성슬러지 공정에 비해 갑작스러운 부하변동 및 유독성 폐수유입에 대해서도 안정적으로 운전이 가능한 장점이 있다. 본연구에서는 부유메디아 생물반응기(Moving-Bed BioReactor, MBBR)을 이용하여 염색폐수내 $COD_{Mn}$, 색도 및 난분해성 물질인 PVA 저감에 대한 Lab-scale test 수행하였다. 실험에 사용된 염색폐수의 수질은 평균 pH 13, $COD_{Mn}$ 900 mg/L, SS 135 mg/L, 색도 1,134 [C.U.], PVA 593 mg/L였으며, 2L의 반응기를 사용하여 회분식 실험을 수행였다. 본 실험에서는 호기성 미생물에 의한 염색폐수의 생분해가 유지되는데 필요한 최적의 용존산소 농도와 이에 필요한 공기 폭기량을 결정하기 위하여 i) DO uptake rate측정과 ii) 담체의 충진율, iii) COD/N ratio, iv) Air 유량, v) 담체내 흡착제의 종류, vi) $Ca^{2+}$ 첨가가 염색폐수의 생분해에 미치는 영향을 살펴보았다. 운전시간을 7일로 하여 COD, 색도, PVA 등을 측정한 결과 담체를 첨가한 경우가 담체를 첨가하지 않은 경우 보다 제거효율이 뛰어났다. 특히 충진율 30%(C/N 3)의 경우에서 COD, 색도, PVA의 제거율이 각각 평균 65%, 70%, 60%로 가장 높은 제거효율을 나타내었다.

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