• Title/Summary/Keyword: 산분해

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Degradation of Humic Acids by Ozone/high pH, Ozone/Hydrogen Peroxide and Ozone/Hydrogen Carbonate System ($O_3$/high pH, $O_3/H_2O_2$$O_3/{HCO_3}^-$ 시스템에서의 부식산의 분해 반응 특성)

  • Shin, Hyun Sang;Kim, Kei Woul;Rhee, Dong Seok
    • Analytical Science and Technology
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    • v.13 no.5
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    • pp.652-658
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    • 2000
  • Chemical degradation of aqueous humic acid by ozonation was studied with respect to the direct reactions of ozone and the indirect reactions due to its preliminary decomposition to secondary oxidant, OH radical. This was characterized by analyzing TOC, $UV_{254}$ and ozone consumption measured in different experimental conditions in which ozone reacted in the presence of various concentrations of $H_2O_2$ and $HCO_3{^-}$ concentrations ranging from 20 to 100 mg/L. and different pH (5-9). The results suggest that the TOC removal is mainly dependent on indirect reactions of OH radical whereas $UV_{254}$ reduction is mainly dependent on direct reactions of ozone with humic acid molecules. It has been also found that ozone consumption was most likely to be affected by pH and alkalinity in the solution.

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Organic Acid and Enzyme Pretreatment of Laminaria japonica for Bio-ethanol Production (유기산 및 효소적 전처리를 이용한 다시마에서 바이오 에탄올 생산)

  • Lee, Sung-Mok;Lee, Jae-Hwa
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.164-168
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    • 2012
  • We investigated for the production of biological bio-ethanol from Laminaria japonica using the hydrolysis reaction of enzymes and organic acids and the polysaccharide content was also analyzed. The composition of the polysaccharide was characterized as 65.99% alginate, 6.24% laminaran and 27.77% mannitol. The optimum concentration for reducing the sugar conversion by Laminaria japonica was found to be 1.874 g/L at an acetic acid concentration of 1.5%, $121^{\circ}C$ for 60 min, and for an ascorbic acid of 2.0%, 4.291 g/L was produced in the same condition. The enzyme hydrolysis such as alginate lyase and laminarinase contained the maximum 2.219 g/L reducing sugar. In the result of ethanol fermentation using hydrolysate of Laminaria japonica, the organic acid treatment showed a high of reducing sugar yield, but decreased the ethanol yield, and then the maximum ethanol production obtained was 1.26 g/L using the mixed treated of enzyme.

Change in Fructan Content and Antioxidant Activity of Garlic Treated Acid and Heat (산과 열처리에 따른 마늘 Fructan과 항산화활성 변화)

  • Hwang, In-Guk;Kim, Ki-Chan;Choi, Sung-Gil;Lee, Jun-Soo;Jeong, Heon-Sang
    • Journal of agriculture & life science
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    • v.44 no.1
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    • pp.61-67
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    • 2010
  • This study was to investigate the fructose, total fructan, polyphenol contents, and antioxidant activity of garlic treated acid and heat($100{\sim}140^{\circ}C$ for 2 hr). Optimum condition of acid hydrolysis of fructan was 0.3N $H_2SO_4$ and 5 min. As increasing heating temperature, fructose content was significantly increased from 17.1 to 189.9 mg/g whereas total fructan content was decreased from 248.1 to 2.0 mg/g. The fructan was mostly hydrolyzed by heating at $130^{\circ}C$ for 2 hr. The polyphenol contents was increased from 0.85 to 13.74 mg/g increasing heating temperature and also antioxidant activity was significantly increased. The polyphenol contents and antioxidant activity on acid hydrolysate after heating was slightly increased.

A Decomposition of the Gap between the Capital and Non-Capital Regions in the Inequality of Wealth (수도권과 비수도권 간 자산 격차의 요인분해)

  • Jeong, Jun Ho
    • Journal of the Economic Geographical Society of Korea
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    • v.22 no.2
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    • pp.196-213
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    • 2019
  • This paper attempts to analyze the contribution of different socioeconomic factors such as income, age, gender, household composition, education and employment status etc. to the difference between the Capital and Non-Capital Regions in the net wealth inequality of household in Korea. To this end, a two-stage Oaxaca-Blinder type decomposition is employed regarding the regional gap in the inequality of net wealth based upon the Recentered Influence Function of the Gini index for 'the 2018 Household Finance and Living Conditions Survey.' Despite the shortcomings of the survey data on wealth, the findings reveal that regional differences in income, marriage status (divorce), job type (agriculture, forestry and fishery related, and technical and assembly), family type (multi-cultural) variables deepen the regional gap in the net-wealth inequality, but employment status (full-time), job type (administrative and specialized, and service sales), household size variables mitigate the gap, and that regional differences in life cycles play an offsetting role.

Morphological Behavior of Oxy-PAN Fiber upon pH Variation (Oxy-PAN 섬유의 산도 변화에 대한 형태학적 거동 특성)

  • 남재도;김재철;김현주;유동국;정창조
    • Polymer(Korea)
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    • v.26 no.4
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    • pp.492-500
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    • 2002
  • Oxidized-polyacrylonitrile (oxy-PAN) was prepared by oxidation of PAN fiber at $240^{\circ}C$, followed by base catalyzed hydrolysis reaction. The chemical structure of PAN fiber in various pH conditions was characterized by $^{13}C-NMR$ spectroscopy. The characteristic contraction and expansion behavior of oxy -PAN fiber was observed in acidic and basic medium, respectively. In basic condition, water molecules might be absorbed into the fiber with the movement of charge balancing $Na^+$ ion, on the other hand, the water molecules seemed to be expelled in acidic condition to result in contraction. It was also observed that the facile chemical modification occurred due to free diffusion of aqueous reagent into the hydrophilic PAN fiber, and the morphology was affected by pH condition.

Studies on the Primary Structure of the Alkaline Protease in Neungee [Sarcodon aspratus (Berk.) S. Ito] I. Amino Acid Composition, Chemical Modification and Sequence of the N-terminal Amino Acid (능이[Sarcodon aspratus(Berk.) S. Ito]중 알카리성 단백질가수분해효소의 1차구조에 관한 연구 I. 아미노산 조성, 활성부위 아미노산 및 N-말단 부위의 아미노산 배열)

  • 이태규
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.22 no.6
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    • pp.811-814
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    • 1993
  • Properties of a protease purified from Sarcodon asparatus(Berk.) S. Ito have been investigated. The enzyme displays as a glycosylated serine protease. The sequence for the 21 amino acids of the N-terminal side in the enzyme was determined by automated sequence analysis. The sequence was V-T-T-K-Q-T-N-A-P-W-G-L-G-N-I-S-T-T-N-K-L-.

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Physicochemical Properties and Characteristics on Lintnerization of Sweet Potato Starches from Three Cultivars (세품종 고구마 전분의 이화학적 특성 및 산처리(lintnerization)에 의한 비교)

  • Lim, Seo-Young;Shin, Mal-Shick;Ahn, Seung-Yo
    • Applied Biological Chemistry
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    • v.28 no.3
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    • pp.156-161
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    • 1985
  • Physicochemical properties and characteristics on lintnerization of sweet potato starches from Wouki(the dry type), Shinmi(the intermediate type) ana Chunmi(the moist type) were investigated. Swelling and gelatinization curves of these starches showed a two-stage process. Swelling powers of starches were higher in order of Shinmi, Chunmi and Wonki over a range of temperatures. Amylose content of Wonki was higher than those of other two. Hydrolytic patterns of three starches with 2.2 N HCI at $35^{\circ}C$ showed two distinct stages. Hydrolysis extents of Wonki starch were lower than those of Shinmi and Chunmi starches. X-ray diffraction patterns of native and lintnerized starches were the Ca crystalline type. The relative crystallinities of these starches were higher in order of Worki, Chunmi and Shinmi.

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Production and Characteristics of Protein Hydrolysate from Sharp Toothed Eel (Muraenesox cinereus) (갯장어 효소 가수분해물의 제조 및 특성)

  • Cho Hye Young;Ahn Chang Bum
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.1
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    • pp.97-104
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    • 2002
  • Protein hydrolysate was prepared as a natural flavor stock from the sharp toothed eel (Muraenesox cinereus) mince using com-mercially available proteolytic enzymes, Alcalase, Neutrase, Protamex, and Flavourzyme. A 6 hr hydrolysis of mince, to which water of the equal weight of the mince was added, with $2\%$ (w/w, protein weight) Elavourzyme at $50^{\circ}$ yielded a hydrolysate of the highest acceptability. Removing the access lipid in liquified hydrolysate (not dehydrated) after enzyme hydrolysis, five times repetitive extraction using n-hexane (liquified hydrolysate : n-hexane=4 : 1, v/v) was effective, resulting in less than $1\%$ lipid content of the dehydrated-hydrolysate. The amino acid composition of the hydrolysate (prepared with Flavourzyme) was similar to that of the starting material. Hydrolysis led to an increase in concentration of not only total free amino acid but also free amino acid such as serine, glutamic acid, alanine, and methionine responsible for umami taste, especially up to about 40 times for methionine. Major free amino acids in amount were leucine, phenylalanine, valine, alanine, and isoleucine and they comprised about half of the total free amino acids, Moisture adsorption, fat adsorption, emulsifying capacity, and foaming capacity of the hydrolysate were 870.1 $\pm$ $7.9\%$, 352.0$\pm$ $5.3\%$, 50.3 $\pm$ $1.2\%$, and $87.5\pm$ $2.5\%$, respectively, and solubility was 83$\~$$84\%$ at acid pH range of 2$\~$4.