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Experimental Study on the Properties of Solid Material Made by Autoclave Curing according to CaO/SiO2 Ratio and W/B (CaO/SiO2비 및 W/B 변화에 따른 오토클레이브 양생 경화체의 특성에 관한 실험적 연구)

  • Kang, Cheol;Kang, Ki-Woong;Kim, Jin-Man
    • Journal of the Korea Concrete Institute
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    • v.21 no.5
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    • pp.557-563
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    • 2009
  • This study is on the properties of inorganic porous calcium silicate material made from silica powder through the autoclaving curing, the results of this study should be utilized fundamental data for the development of noise reduction porous solid material using siliceous byproduct generated by various manufacture process. For the manufacture of autoclave curing specimen, various calcareous materials used and siliceous materials used silica powder. In this study, properties in density and compressive strength according to the change of W/B and C/S ratio, microscopy for the shape of pore, SEM and XRD for the examination of hydrate after autoclave curing are carried out respectively. The test results shown that the more slurry density decrease, the more W/B increase at the fresh state, this tendency shown similar to in hardened state. Among the specimens of C/S ratio, the compressive strength of C/S ratio of 0.85 gave the highest the compressive strength. In the results of XRD, tobermorite generated by autoclaving curing was created all of specimens regardless of C/S ratio. To ascertain pore structure, we compared with existing porous calcium silicate product(ALC, organic sound absorbing porous material). The results of microscope observation, pore structure of specimen of this study was similar to that of existing inorganic sound absorbing foam concrete. therefore, we could conformed a possibility of sound absorbing porous solid material on the basis of the results.

Influence of Natural Salt Treatments on Soil Chemical Properties and Inorganic Contents of Garlic (천일염 살포가 토양 화학성과 마늘(Allium sativum L.)의 무기성분 함량에 미치는 영향)

  • Kim, Myung-Sook;Kim, Yoo-Hak;Kang, Seong-Soo;Yun, Hong-Bae;Gong, Hyo-Young;Lee, Sang-Beom
    • Korean Journal of Organic Agriculture
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    • v.20 no.2
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    • pp.231-241
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    • 2012
  • Farming using natural salts for supply of nutrients to crops is increasing recently. It is necessary to evaluate the salt accumulation in soil and the effects on crop growth by treatment of natural salt. This study was conducted at the organic cultivation fields which garlics were planted. The treatments were no natural salts (control) and plots applied 100~600 $kg\;ha^{-1}$ with natural salts. Soil samples were taken from the 0 to 25 cm depth at 12 and 107 day (harvest time) after natural salts application. The results showed that electrical conductivity (EC), exchangeable Na (Exch.$-Na^+$) and Cl- were increased by application of natural salts. But, pH and exchangeable cations ($K^+$, $Ca^{2+}$ and $Mg^{2+}$) had not significantly differences among treatments. In 300 $kg\;ha^{-1}$ plots of natural salt, the level of EC, Exch.$-Na^+$ and $Cl^-$ in top soil (0-5 cm) was were increased more 0.3, 3.7, and 12.7 times than control plot, respectively. EC, Exch.$-Na^+$, and $Cl^-$ were highest in the top 5 cm of soil and decreased with depth at 12 days after natural salts application, but were decreased in the plower layer (0-15cm) at the harvest time because they were leached with natural rain. An increasing the application level of natural salt resulted in increasing of sodium adsorption ratio, exchangeable sodium percentage, and percentage of soil dispersion. The concentration of nutrient uptake such as total nitrogen (T-N), chloride (Cl) in garlic had significant difference between control and plots applied with natural salts The content of T-N of garlic in plots with natural salt application was lower than control plot, but Cl is higher than control plot.

An Analysis of the Nutritional Quality of Spreadable Liver Product (Spreadable 돼지 간제품의 영양학적 품질)

  • Kim, Young-Boong;Jeon, Ki-Hong;Lee, Nam-Hyuk;Lee, Hyun-Jung
    • Food Science of Animal Resources
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    • v.28 no.1
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    • pp.21-26
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    • 2008
  • This study was carried out to evaluate the nutritional properties of spreadable liver product. The composition of fresh hog liver used as raw material was 70.5% moisture, 5.2% fat, 20.3% protein and 1.2% ash. The composition of the spreadable liver product was 55.3% moisture, 19.4% protein, 21.6% fat and 3.7% ash. The total amino acid content of fresh liver was 18.69 g/100 g with glutamic acid at the highest level of 2.57 g/100 g. The total amino acid content of liver product was 18.03 g/100 g with glutamic acid at 2.28 g/100 g. The essential amino acid content was found to be 42% of total amino acids. The fatty acid analysis of fresh liver revealed oleic acid to be present at the highest level of 28% in the unsaturated fatty acid portion, and palmitic acid to be highest at 20.7% in the saturated fatty acid portion. The oleic acid content of the liver product was 40%, and the palmitic acid content was 20.4%. The level of cholesterol in fresh liver was 178.0 mg/100 g compared to 118.0 mg/100 g in the liver product. Regarding mineral analysis, the K and P contents of fresh liver were 362.2 mg/100 g and 339.1 mg/100 g, respectively, and 336.1 mg/100 g and 213.3 mg/100 g in the liver product, respectively. Many other minerals including Na, Mg, Ca and Fe were present in the product. Based on these results, the spreadable liver product made with hog liver was found to be a quality food with nutritional benefits and that is easy to consume.

A Study on the Quantitative Recovery of Dissolved Inorganic Carbonates in Ground Water for Radiocarbon Measurement (방사성탄소 측정을 위한 지하수 중에 용존된 무기탄소 화합물의 정량적 회수 연구)

  • Chun, Sang-Ki;Woo, Hyung-Joo;Cho, Soo-Young;Kim, Nak-Bae;Lee, Jong-Dae
    • Analytical Science and Technology
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    • v.12 no.4
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    • pp.284-289
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    • 1999
  • Dissolved inorganic carbonates in ground water were quantitatively recovered by using gas evolution method. Gas evolution method was found to be less time-consuming, less susceptible to the contamination fromatmospheric $CO_2$ and little affected by the sulfate ions in comparison to the direct precipitation method. Extraction efficiency of nearly 99% could be achieved by gas evolution method in two hours using recirculated gas at a sweeping rate of 4 liter per minute. Samples for carbon isotope fractionation study were collected in three fractions with collection times. The evolution time for the first fraction was one hours, and then second and third fractions were collected at intervals of 30 minutes, respectively. A small portion of each fraction was analyzed to evaluate ${\delta}^{13}C$ values, which were measured to be -7.9‰, -3.0‰ and +0,4‰ for the each fraction. The result clearly indicated that gas evolution method generates isotopically lighter carbon at the beginning of the purging process and heavier isotopes at the end. However, this isotope fractionation effect could be neglected by the almost complete recovery of carbonates.

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Properties of a Hexane-Degrading Consortium (Hexane 분해 혼합균의 특성)

  • Lee Eun-Hee;Kim Jaisoo;Cho Kyung-Suk
    • Microbiology and Biotechnology Letters
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    • v.33 no.3
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    • pp.215-221
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    • 2005
  • It was characterized the hexane biodegradation and mineralization using a hexane-degrading consortium, and analyzed its bacterial community structure by 16S rDNA PCR-DGGE (denaturing gradient gel electrophoresis). The specific growth rate (${\mu}_{max}$) of the hexane-degrading consortium was 0.2 $h^{-1}$ in mineral salt medium supplemented with hexane as a sole carbon source. The maximum degradation rate ($V_{max}$) and saturation constant ($K_{s}$) of hexane of the consortium are 460 ${\mu}mol{\cdot}g-DCW^{-1}{\cdot}h^{-1}$ and 25.87 mM, respectively. In addition, this consortium could mineralize $49.1{\%}$ of $^{14}C$-hexane to $^{14}CO_2$, and $43.6{\%}$ of $^{14}C$-hexane) was used for the growth of biomass. The clones isolated from the DGGE bands were closely related to the bacteria which were capable of degrading pollutants such as oil, biphenyl, PCE, and waste gases. The hexane-degrading consortium obtained in this study can be applied for the biological treatment of hexane.

Preparation and Characterization of Polymer Coated BaTiO3 and Polyimide Nanocomposite Films (고분자로 표면 코팅된 BaTiO3와 이를 이용한 폴리이미드 나노복합필름의 제조 및 특성)

  • Han, Seung San;Han, Ji Yun;Choi, Kil-Yeong;Im, Seung Soon;Kim, Yong Seok
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.527-531
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    • 2006
  • We have prepared organophilic inorganic particles and polyimide (PI) nanocomposite having excellent thermal stability and high dielectric constant that can be used for electronic application such as capacitor. We have chosen barium titanate (BT), a high dielectric constantmaterial and its surface was coated with nylon 6 to improve the affinity with PI. The FT-IR and TEM studies showed that the organophilic inorganic particle (BTN) has a polymer shell with thickness of 5 nm. We have suggested that it is possible to control the thickness of coating surface and also indicated the relationship between the ratio of inside and outside radius of BTN and the weight fraction of BT. The PI nanocomposite films based on poly(amic acid) and BTN were prepared by cyclodehydration reaction. The homogeneous dispersion of BTN in PI matrix was identified by using SEM. We have investigated the effect of BTN content on the coefficient of thermal stability, integral procedural decomposition temperature (IPDT), and dielectric constant of PI nanocomposite films.

A Study on the Durability Improvement by Controlling the Deterioration of Underground Concrete Structures (지하 콘크리트구조물의 열화 억제에 의한 내구성 증진에 관한 연구)

  • 천병식;최춘식;정원우
    • Journal of the Korean Geotechnical Society
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    • v.20 no.3
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    • pp.23-31
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    • 2004
  • Normally, coating is used for protecting reinforced concrete. For this purpose, both organic and inorganic coatings are used. The advantages of inorganic coatings are lower absorption of UV, non-burning etc. On the other hand, organic coatings have the advantage of low permeability of $CO_2, SO_2$ and water. Organic coatings provide better protection for reinforced concrete. However, organic coatings such as epoxy, urethane and acryl reduce long-term adhesive strength by the difference of their thermal expansion coefficients and elastic modules from those of concrete, and the formed coating cover of these is blistered by poor breathing. Also, when organic coatings are applied to the wet surface of concrete, they have a problem with adhesion. In this study, a new coating material for protecting concrete was hybridized with polymer and ceramics. And tests were carried out on its physical and durable characteristics, and safety characteristic on elution. All results were compared with organic coating materials and epoxies and showed that the performance of the developed coating material was not inferior to that of other organic coatings in protecting concrete. On the other hand, safety characteristic on elution was superior to epoxies which were used in this study. So, the developed coating material was considered as a suitable protecting coating material which have advantages of inorganic and organic coatings for protecting underground concrete structures, especially in contact with water.

Changes in physicochemical properties of Peucedanum japonicum Thunb. after blanching (Blanching에 따른 갯기름 나물의 이화학적 특성 변화)

  • Son, Hee-Kyoung;Kang, Su-Tae;Jung, Hae-Ok;Lee, Jae-Joon
    • Food Science and Preservation
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    • v.20 no.5
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    • pp.628-635
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    • 2013
  • This study was conducted to investigate the changes in the physicochemical properties of Peucedanum japonicum Thunb. after blanching. After blanching treatment, the crude protein content decreased but did not affect the crude fat, crude ash and carbohydrate contents of P. japonicum. All the detected free sugar contents decreased after blanching, but the total free sugar content decreased by 14.8% from that of the raw P. japonicum after blanching. The total amino acid and essential amino acid contents of the blanched P. japonicum. decreased by 10.75% and 15.22% from those of the raw P. japonicum. There were no differences in the contents of the total fatty acid between the raw and blanched P. japonicum. The total organic acid content decreased by 37.03% from that of the raw P. japonicum. after the blanching, and the reduction of the acetic acid was largest in the organic acid. The vitamin A, C and E contents decreased by 20.20%, 8.23% and 35.59% after the blanching. The total mineral content of the blanched P. japonicum. decreased by 21.84% after the blanching. The nutrients in the P. japonicum were essential amino acid, vitamin C, minerals, but these were reduced after the blanching. Therefore, the blanching conditions that can reduce nutrient loss of P. japonicum must be established.

Nitrogen Transformation in Soil Cooperated with Organic Composts and Bio-char During Corn (Zea mays) Cultivation (옥수수 재배 시 퇴비 및 바이오차 시용 토양에서 질소 이동 동태)

  • Shin, JoungDu
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.3
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    • pp.33-40
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    • 2014
  • This study were conducted to evaluate the N mineralization and nitrification rates and to estimate the losses of total carbon and nitrogen by runoff water in soils cooperated with organic composts and bio-char during corn cultivation. For the experiment, the soil texture used in this study was clay loam, and application rates of chemical fertilizer and bio-char were $230-107-190kg\;ha^{-1}$($N-P_2O_5-K_2O$) as recommended amount after soil test and 0.2% to soil weight. The soil samples were periodically taken at every 15 day intervals during the experimental periods. The treatments were consisted of cow compost, pig compost, swine digestate from aerobic digestion system, and their bio-char cooperation. For N mineralization and nitrification rates, it was shown that there were generally low in the soil cooperated with bio-char as compared to the only application plots of different organic composts except for 47 days after sowing. Also, they were observed to be highest in the application plot of swine digestate from aerobic digestion system. For loss of total carbon by run-off water, it was ranged from 1.5 to $3.0kg\;ha^{-1}$ in the different organic compost treatment plots. However, Loss of total carbon with bio-char could be reduced at $0.4kg\;ha^{-1}$ in PC treatment plot. Also, with application of bio-char, total nitrogen was estimated to be reduced at 4.2 (15.1%) and $3.8(11.8%)kg\;ha^{-1}$ in application plots of pig compost and swine aerobic digestate, respectively.

Chemical Properties of Barley Leaf Using Different Drying Methods (건조방법을 달리한 보리 잎의 이화학적 특성)

  • Park, Soo-Jin;Joung, Yong-Myeon;Choi, Mi-Kyeong;Kim, Yang-Kil;Kim, Jung-Gon;Kim, Kyong-Ho;Kang, Myung-Hwa
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.1
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    • pp.60-65
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    • 2008
  • Chemical properties of barley leaf were investigated using different drying methods. Moisture contents of barley leaf were 75.22%, 7.54%, 2.57%, 6.74% and 8.91% for samples dried using raw, hot-air dryer, freeze dryer, shade dryer, vacuum freeze dryer and microwave dryer, respectively. Mineral contents were high Ca, Mg, Na, P, and K in barley leaf regardless of drying methods. Organic acid contents were oxalic acid, acetic acid, citric acid and fumaric acid with no differences between drying methods. Contents of vitamin C were 142.56 mg%, 629.23 mg%, 598.48 mg%, 657.62 mg% and 724.34 mg% for samples using raw, hot-air dryer, freeze dryer, shade dryer, vacuum freeze dryer and microwave dryer, respectively. Chlorophyll contents of barley leaf dried by hot-air dryer and shade dryer were higher than in that of freeze dryer and microwaves dryer. b-values were lower in freeze dryer than in that of other dried methods.