• Title/Summary/Keyword: 비등온

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Adsorption Dynamics of H2/CO2, H2/CO, H2/CH4 Mixtures in Li-X Zeolite Bed (Li-X 제올라이트 흡착탑에서 H2/CO2, H2/CO, H2/CH4 혼합기체의 흡착 동특성)

  • Park, Ju-Yong;Yang, Se-Il;Choi, Do-Young;Jang, Seong-Cheol;Lee, Chang-Ha;Choi, Dae-Ki
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.783-791
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    • 2008
  • The dynamic characteristics of adsorption using an adsorption bed packed with Li-X zeolite (UOP) were studied through the breakthrough experiments of $H_2/CH_4$ (90:10 vol%), $H_2/CO$ (90:10 vol%) and $H_2/CO_2$ (80:20 vol%) mixtures. Effects of feed flow rate (6.24~10.24 LPM) and adsorption pressure (6.1 bar~10.1 bar) in the Li-X zeolite bed with 2.7 cm of inside diameter and 80 cm of bed length were observed. The smaller feed rate or the higher operating pressure, resulted in the longer of the breakthrough time and the breakthrough curve have tailing due to temperature variance in the bed. The adsorption dynamics of the Li-X zeolite bed were predicted by using LDF model with feed flow and pressure dependent diffusivity. The prediction and experimental data were analyzed with a nonisothermal, nonadiabatic model, dual-site langmuir (DSL) isotherm

Lead-Zinc-Tin-Silver Mineralization of Tangguanpu Mine, Hunan Province, China: Fluid Inclusion and Sulfur Isotope Studies (중국 호남성 당관포 광산의 연-아연-주석-은 광화작용: 유체포유물 및 황동위원소 연구)

  • 허철호;윤성택;소칠섭
    • Economic and Environmental Geology
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    • v.34 no.2
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    • pp.157-166
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    • 2001
  • Numerous base-metal bearing hydrothermal quartz vein deposits occur in the Hunan province of southern China. The Tangguanpu lead-zinc-tin-silver mine is the major producer among these deposits. Lead-zinc-tin-silver mineralization occurs in a single stage of massive quartz veins which filled fractures in fault zones within Paleozoic metasedimentary rocks. Sphalerite, chalcopyrite, galena, pyrite, arsenopyrite and pyrrhotite are the principal sulphide minerals in the Tangguanpu lead-zinc ores with minor amounts of tin- and antimony-bearing sulphides (stannite, teallite, boulangerite and tetrahedrite). Based on the iron and zinc partitioning between coexisting stannite and sphalerite, the formation temperature for this mineral assemblage range from 300$^{\circ}$ to 330$^{\circ}$C, which relatively agree with the upper part of homogenization temperature of fluid inclusion in quartz (20T-358$^{\circ}$C). Fluid inclusion data show that main lead-zine-tin-silver mineralization occurred from $H_{2}O$-NaCl fluids with relatively low salinities (11.2-7.3 wl.% eg. NaCI) at temperatures between 207$^{\circ}$ and 358$^{\circ}$C. The relationship between homogenization temperature and salinity suggests a history of cooling and dilution followed by initial boiling. Evidence of initial fluid boiling may indicate the fluid trapping pressures of 180 bars. The ${\delta}^{34}S{{\Sigma}S}$ values of -5.0 to 1.1 %, indicate an igneous source of sulfur in the Tangguanpu lead-zinc-tin-silver hydrothermal fluids.

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Effect of Styrene and Maleic Anhydride Content on Properties of PP/Pulp Composites and Reactive Extrusion of Random PP (랜덤 PP의 반응압출 및 PP/Pulp 복합체 특성에 대한 스티렌과 무수말레인산 함량의 영향)

  • Lee, Jong Won;Kim, Ji Hyun;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.25 no.3
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    • pp.318-323
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    • 2014
  • In order to analyze the effect of maleic anhydride (MAH) content and styrene monomer (SM)/MAH mole ratio on reactive extrusion of maleic anhydride grafted random polypropylenes (MAH-g-rPP), MAH-g-rPPs were prepared by using a twin screw extruder. MAH contents were 0.5, 1.0, 3.0, and 5.0 phr and SM/initiator mole ratio was 0.0, 1.0, and 2.0. Dicumyl peroxide (DCP) was used as an initiator. The graft degree of MAH was confirmed by the existence of carbonyl group (C = O) stretching peak at $1700cm^{-1}$ from FT-IR spectrum. The degree of graft reaction increased up to 3.0 phr MAH and showed the optimum value at 1.0 SM/MAH mole ratio from the area ratio of C = O and C-H stretching peak. Thermal and crystallization properties of MAH-g-rPP and PP/MAH-g-rPP/pulp composites were investigated by DSC, TGA, XRD, and POM. There was a decrease in non-isothermal crystallization temperature of PP/MAH-g-PP/pulp composites. Based on tensile properties and SEM pictures for the fractured surface of PP/MAH-g-PP/pulp composites, MAH content of 1.0 wt% and SM/MAH mole ratio of 1.0 were the optimum formulation as the compatibilizer. The rheological properties of the composites were measured by dynamic Rheometer to compare the processability of the composites with and without compatibilizer. The power law index showed slightly low value at the composites with compatibilizer.

Characteristics of surface damage with applied current density and cavitation time variables for 431 stainless steel in seawater (431 스테인리스강의 해수 내 적용 전류밀도 및 캐비테이션 시간 변수에 따른 표면손상 특성)

  • Kim, Seong-Jong;Chong, Sang-Ok
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.7
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    • pp.883-889
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    • 2014
  • It is generated for cavitation erosion due to the local static boiling by pressure differentials in high speed rotating fluid environment. The cavitation is influenced by various elements such as pressure, velocity, temperature, pH of fluid and medium. In particular, the damage of material is accelerated due to the electrochemical corrosion by $C1^-$ and cavitation erosion due to cavities in seawater. In this paper, hence, it investigated for martensite stainless steel the damage behavior with applied current density and cavitation time in natural seawater solution. Less damage depth at the cavitation condition was observed than static condition as a result of galvanostatic experiment. Furthermore, it was shown that dramatic increase of weightloss, damage rate and damage depth after 3 hour of cavitation test.

Ultrasonic Engancement of Flow in Clayey Sands (점토질 모래에서의 Ultrasonic을 이용한 투수성의 증진)

  • 이광열
    • Water for future
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    • v.26 no.1
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    • pp.63-69
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    • 1993
  • Remediation technology becomes an issue in environmental engineering. The vibro-recovery technique is one of popular means to remove pollutants from contaminated soils and groundwater. Using Ultrasonic excitation in soil-fluid medium, it was found that removal efficiency in a mechanical effects was significant. In this paper, therefore, laboratory experiments were conducted on clayey sand soil columns using a probe-type ultrasonic processor. Ultrasonic treatment with simultaneous pumping enhances dislodgement of clay particles, and ultrasonic excitation reduced the proportions of finer particles and thus result in increased hydraulic conductivity significantly. Also, the results provided the changes in grain size distribution curve of the soil due to ultrasonic excitation. The results indicated that the maximum size of particles mobilized by Ultrasonic is about 0.004mm and particles in the size range from 0.04mm to 1.0mm were subjected to fracturing. The economic feasibility of Ultrasonic implementation is considered in power requirement of the generator and maintenance of the horn. At a specified amplitude of vibrations, the power requirement of the generator depends on overburden pressure of the horn, temperature and viscosity of fluid in the soil medium. For comparisons, the requirement of a one inch and two inch diameter horn sonicators are compared with the power required for pumping water from different depths.

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Feasibility of Artificial Neural Network Model Application for Evaluation of Undrained Shear Strength from Piezocone Measurements (피에조콘을 이용한 점토의 비배수전단강도 추정에의 인공신경망 이론 적용)

  • 김영상
    • Journal of the Korean Geotechnical Society
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    • v.19 no.4
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    • pp.287-298
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    • 2003
  • The feasibility of using neural networks to model the complex relationship between piezocone measurements and the undrained shear strength of clays has been investigated. A three layered back propagation neural network model was developed based on actual undrained shear strengths, which were obtained from the isotrpoically and anisotrpoically consolidated triaxial compression test(CIUC and CAUC), and piezocone measurements compiled from various locations around the world. It was validated by comparing model predictions with measured values about new piezocone data, which were not previously employed during development of model. Performance of the neural network model was compared with conventional empirical method, direct correlation method, and theoretical method. It was found that the neural network model is not only capable of inferring a complex relationship between piezocone measurements and the undrained shear strength of clays but also gives a more precise and reliable undrained shear strength than theoretical and empirical approaches. Furthermore, neural network model has a possibility to be a generalized relationship between piezocone measurements and undrained shear strength over the various places and countries, while the present empirical correlations present the site specific relationship.

A Study on Performance of Initial Blowoff Flow for a Fuel Pump with Various Temperature and Composition Condition in LPG Engine (자동차용 LPG 펌프의 온도 및 연료조성에 따른 초기토출성능에 관한 연구)

  • Park, Cheol-Woong;Kim, Chang-Up;Choi, Kyo-Nam
    • Journal of the Korean Institute of Gas
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    • v.12 no.2
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    • pp.12-17
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    • 2008
  • The In recent years, the need for more fuel-efficient and lower-emission vehicles has driven the technical development of alternative fuels such as LPG (Liquefied Petroleum Gas) which is able to meet the limits of better emission levels without many modifications to current engine design. LPG has a high vapor pressure and lower viscosity and surface tension than diesel and gasoline fuels. These different fuel characteristics make it difficult to directly apply the conventional gasoline or diesel fuel pump. In this study, experiments are performed to get initial performance and efficiency of the fuel pump under different condition of the temperature and composition of fuel. The characteristics of vane type fuel pump were investigated to access the applicability on LPLi engine.

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Thermal Decomposition Behavior of Boron-Potassium Nitrate (BKNO3) by TGA (열중량분석법에 의한 Boron-Potassium Nitrate(BKNO3)의 열분해 특성 연구)

  • Go, Cheongah;Kim, Junhyung;Park, Youngchul;Moon, Youngtaek;Seo, Taeseok;Ryu, Byungtae
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.2
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    • pp.104-110
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    • 2019
  • The thermal decomposition characteristics of boron-potassium nitrate ($BKNO_3$) were investigated by non-isothermal thermal gravimetric analysis (TGA). Two steps of mass loss were observed in the temperature range between room temperature and $600^{\circ}C$. Kinetic parameters of the thermal decompositions were evaluated from the measured TGA curves using the AKTS Thermokinetics Software. For the first step of mass loss ($220-360^{\circ}C$) corresponding to the thermal decomposition process of the binder (Laminac/Lupersol), the activation energy is in the range of approximately 120-270 kJ/mol when evaluated by Friedman's iso-conversional method, while the value of activation energy varies in the range of approximately 150-400 kJ/mol during the second step process ($360-550^{\circ}C$).

Thermo-Fluid Simulation for Flow Channel Design of 7kW High-Voltage Heater for Electric Vehicles (전기차용 7kW급 고전압 히터 유로 형상 설계를 위한 열유동 시뮬레이션)

  • Son, Kwon Joong
    • Journal of the Korea Convergence Society
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    • v.13 no.3
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    • pp.191-196
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    • 2022
  • Unlike an international combustion engine car, a battery-powered electric vehicle requires an additional heat source for its heating system. A high-voltage coolant heater has the advantages of high efficiency and a wide operating temperature range. In its development, the geometry design of the coolant flow path is essential. This paper presents the thermal flow simulations of a 7kW high-voltage heater with symmetric serpentine flow channels arranged parallelly. The heater performance was evaluated from the simulation results in terms of the pressure and temperature differences and the flow uniformity. The proposed design showed a greater flow resistance and similar heat exchanging capability than the existing parallel serpentine design. It has the advantage of a relatively wide low-temperature surface area, where the control circuit board susceptible to high temperatures can be located.

Measurement of Condensation and Boiling Heat Transfer Coefficients of Non-flammable Mixed Refrigerant for Design of Cryogenic Cooling System for Semiconductor Etching Process (반도체 식각 공정용 초저온 냉각 시스템 설계를 위한 비가연성 혼합냉매 응축 및 비등 열전달 계수 측정)

  • Cheonkyu Lee;Jung-Gil Lee
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.3
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    • pp.119-124
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    • 2023
  • In this study, experimental approach of the measurement of condensation and evaporation heat transfer coefficients is discussed for mixed refrigerants using in the ultra low-temperature cooling system for semiconductor etching process. An experimental apparatus was described performing the condensation and evaporation heat transfer measurements for mixed refrigerants. The mixed refrigerant used in this study was composed of the optimal mixture determined in previous research, with a composition of Ar:R14:R23:R218 = 0.15:0.4:0.15:0.3. The experiments were conducted over a temperature range from -82℃ to 15℃ and at pressures ranging from 18.5 bar to 5 bar. The convection heat transfer coefficients of the mixed refrigerant were measured at flow rates corresponding to actual operating conditions. The condensation heat transfer coefficient ranged from approximately 0.7 to 0.9 kW/m2K, while the evaporation heat transfer coefficient ranged from 1.0 to 1.7 kW/m2K. The detailed discussion of the experimental methods, procedures, and results were described in this paper.

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