• Applied Chemistry for Engineering
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• v.17 no.6
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• pp.565-574
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• 2006

The trend towards the application of single enantiomers of chiral compounds is undoubtedly increasing. Among the various methods to obtain one single enantio-riched compound selectively, enantioselective catalysis is the most attractive method. Especially, it is important to increase the activity, selectivity and lifetime of usually expensive chiral catalysts with a minute quantity in the enantioselective synthesis. Immobilization of active homogeneous catalysts is a fashionable topic in asymmetric catalysis, providing the inherent advantage of easy separation and better handling properties. Many different ways have been investigated to improve the enantioselectivity of products and to recycle the catalysts. This review mainly focused on the present scope and limitations of different types of enantioselective heterogeneous catalysts.

• The Journal of the Korea Contents Association
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• v.16 no.8
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• pp.387-394
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• 2016

The volatility in the stock market responds differently to information types. That is, the asymmetric volatility exists in the stock market which responds more to unexpected negative returns due to bad news than unexpected positive returns due to good news. This paper examines the asymmetric response of the volatility of KOSPI, large-cap, middle-cap, and small-cap indices returns which is announced in Korea exchange (KRX) by using the MA-GJR model and the MA-EGARCH model. According to empirical analyses, it shows that the asymmetric response of volatility exists in all indices regardless of volatility estimation models and the degree of the asymmetric volatility response of the small-cap index returns is greater than that of the large-cap index returns. Moreover, this results also observed robustly during the period of both before and after the global financial crisis.

• Management & Information Systems Review
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• v.28 no.4
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• pp.93-108
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• 2009

This study examines the asymmetric volatility in the Korean bond market and stock market by using the KTB Prime Index and KOSPI. Because accurate estimation and forecasting of volatility is essential before investing assets, it is important to understand the asymmetric response of volatility in bond market. Therefore I investigate the existence of asymmetric volatility in Korean bond market unlike the previous studies which mainly focused on stock returns. The main results of the empirical analysis with GARCH and GJR-GARCH model are as follow. At first, it exists the asymmetric volatility on KOSPI returns like the previous studies. Also, I find that the GJR-GARCH is more suitable one than GARCH model for forecasting volatility. Second, it does not exist the asymmetric volatility on KTB Prime Index returns. This result is showed by that using the GARCH model for forecasting volatility in bond market is sufficient.

• Korean Chemical Engineering Research
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• v.46 no.4
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• pp.752-755
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• 2008

Mesoporous SBA-15 silica-supported TsCHDA and TsDPEN ligands have been prepared by reaction of SBA-15 silica with (1R,2R)-N-(trimethoxysilylpropyl-N-sulfonyl)-1,2-cyclohaxanediamine or (1R,2R)-N-(trimethoxysilylpropyl-N-sulfonyl)-1,2-diphenylethylenediamine-1,2-diphenylethylenediamine, respectively. The Ru complexes exhibited excellent catalytic activity and satisfactory enantioselectivity in the asymmetric hydrogen transfer of ketones under microwave conditions. The heterogeneous Ru catalyst was reusable as well as air-stable to allow easy use. Microwave-assisted efficient procedure has been developed for asymmetric hydrogen transfer.

• Journal of the Korean Chemical Society
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• v.52 no.6
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• pp.727-733
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• 2008

• Applied Chemistry for Engineering
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• v.10 no.5
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• pp.804-807
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• 1999

New copper complexes with a ligand, L(L=N,N'-cyclohexane bis(ferrocenylmethylene)amine) which was obtained from ferrocene carboxaldehyde and 1,2-diaminocyclohexane with a mole ratio of 2:1, were prepared and characterized. Those were adapted to asymmetric catalysis. The copper(II) complexes do not work in cyclopropanation of styrene and ethyl diazoacetate but copper(I) complex catalyzes. The Cu(I)LOTf (OTf=trifluorometanesulfonate) shows a good regioselectivity giving high trans to cis ratio of up to 80:20.

• The Korean Journal of Financial Management
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• v.17 no.1
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• pp.45-65
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• 2000

본 논문은 시장상황별 주식시장의 제 현상이 상이하다는 점을 고려하여 한국주식시장에서 시장 상승기(bull market)와 시장 하락기(bear market)에 대한 주식수익률 분포의 특성을 파악하고, 음의 수익률충격에 대한 비대칭적 변동성과 시장이상현상들 중 하나인 요일효과를 시장 상황별로 실증분석하였다. 본 논문에 사용된 자료는 1990년 1월 3일부터 1997년 3월 31일 동안의 한국종합주가지수 및 자본금 규모별로 대형주지수, 중형주지수, 소형주지수의 명목수익률로 전환된 일별자료이다. 시장상황별 분석을 위하여 시장 상승기와 하락기에 따라 3기의 하위기간으로 구분하여 분석하였다. 분석에 사용된 모형은 EGARCH모형과 수정된 GARCH모형인 GJR모형이다. 분석결과 시장하락기인 하부기간1과 하부기간3에서 음의 수익률충격에 대한 비대칭적 변동성이 강하게 나타나지만 시장상승기인 2기간에는 비대칭적 변동성반응이 나타나지 않았다. 이는 주식시장이 상승국면일 때보다는 하락국면일 때 나쁜 뉴스에 대해 훨씬 민감하게 반응하는 결과이다. 또한 한국주식시장에서 월요일의 수익률이 시장하락기에 음의 수익률을 보이지만 통계적 유의성은 없었으며, 반면에 시장이 상승기인 하부기간2에서는 월요일과 수요일에 통계적 유의성이 매우 큰 양의 값을 나타냈다.

• Annual Conference on Human and Language Technology
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• 1989.10a
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• pp.278-281
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• 1989

한글 자모 인식과정의 특성을 알아보기 위하여 Stroop 및 반구 비대칭성 효과를 검증하였다. 피보험자들에게 두가지 색으로된 10개의 한글자모를 좌시야와 우시야에 제시하고, 그중 어떤 것이 가운데에 제시된 검사지극의 색 또는 자모형태와 같은 목표자극인가를 신속하게 판단하도록 하였다. 반구 비대칭성 및 Stroop 효과를 선택 반응시간을 측정하여 비교하였다. 자모 처리와 색깔 처리에서는 반구간 차이가 나타나지 않았다. 자모 처리에서 반구간 차이가 나타나지 않은 것은 한글 자모의 시각적 특성과 실험 절차의 특수성애 결부되어 해석되었다. Stroop 효과는 좌반구 보다는 우반구에서 의미있게 큰 것으로 나타났다. 따라서 대뇌 반구간의 비대칭성이 확인되었고 대뇌의 좌반구는 분석적 처리에, 우반구는 전체적인 처리에 전문화 되어 있다는 것을 확인하였다.

• Applied Microscopy
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• v.27 no.1
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• pp.57-70
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• 1997

The distribution of glutamatergic synaptic structures in the dog basilar pons was investigated at the ultrastructural level using monoclonal antibodies against fixative-modified glutamate. Electron-dense reaction product was densely localized at the perinuclear region in the neurenal somata and often observed along the microtubules located within the dendritic processes. One or more unlabelled axon terminals made asymmetric synaptic contacts with glutamate-immunoreactive dendritic profiles. In audition, reaction product was observed either within axonal processes surrounded by myelin sheath or axon terminals. Immunoreactive axon terminals made asymmetric synaptic contact either with unlabelled or labelled dendritic profiles. These observations provided an anatomic evidence of how this excitatory neural element might perform its function in a multisynaptic pathway involving glutamatergic afferents to the basilar pons, glutamate-immunoreactive pontocerebellar projection neurons, and the glutamate-positive granule cells of the cerebellar cortex.

• Applied Chemistry for Engineering
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• v.18 no.6
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• pp.630-635
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• 2007

New chiral Co-salen complexes with one $C_3-^tBu$ group in the structure have been synthesized and applied as a chiral catalyst. A dimeric chiral salen having aluminum group metal salts such as $AlCl_3$ displayed very high catalytic reactivity and enantioselectivity for the asymmetric ring opening of epoxides to synthesize optically pure ${\alpha}$-aryloxy alcohols via phenolic kinetic resolution. The salen complexes immobilized on the inorganic support were also used as effective catalysts in that reaction. The identity of metal salts in the new chiral salen complex has proved to be important in the enantioselective reactions.