• Title/Summary/Keyword: 비닐에스터

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Enhanced Interfacial Adhesion of Carbon Fibers by Poly (arylene ether phosphine oxide) Coatings (Poly(arylene ether phosphine oxide) 코팅에 의한 탄소섬유의 계면 접착성 향상 연구)

  • 김익천;강현민;육종일;윤태호
    • Composites Research
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    • v.12 no.4
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    • pp.55-61
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    • 1999
  • Interfacial shear strength (IFSS) of poly(arylene ether phosphine oxide) (PEPO) coated carbon fibers was evaluated via microdroplet test and compared with results obtained from carbon fibers coated with poly(arylene ether sulfone) (PES), Udel$^{\circledR}$ P-1700 and Ultem$^{\circledR}$ 1000. Interfacial adhesion between thermoplastics and uncoated carbon fibers was also measured in order to understand the adheion mechanism. PEPO coated carbon fibers showed the highest IFSS, followed by PES, Udel and Ultem coated fibers. A similar trend was observed for thermoplastic/uncoated fibers. SEM analysis indicated that only PEPO coated fiber exhibited cohesie failure in the vinylester resin, while others showed failure at or near the interface of polymer coating and vinylester resin. The enhanced interfacial adhesion by PEPO coating could be attributed to the strong interaction of P = 0 moiety to the fiber as well as to the vinylester resin.

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Morphology and Mechanical Properties of Waste PVC Blends (I) -Morphology and Mechanical Properties of Waste PVC/PE Blends (폐 PVC계 고분자 블렌드의 구조 및 물성 연구(I) -폐 PVC/PE고분자 블렌드의 모폴로지 및 물성)

  • 박재찬;원종찬;최길영;이재흥;조성만;김명기
    • Polymer(Korea)
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    • v.26 no.1
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    • pp.37-44
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    • 2002
  • The polymer blends of waste polyvinyl chloride (RPVC) and waste polyethylene(RPE) were prepared by melt mixing, and their morphology and tensile properties were evaluated after the copolymers having an ethylene group in backbone and ester group in side position were added as comptatibilizers. The blend compositions were varied as follows ; RPVC/RPE 85/15 wt%, where RPVC formed a continuous phase : 50/50, mid composition : 15/85, RPE a continuous phase. The blends revealed a very low compatibility between component polymers because they showed domain sizes greater than $10\mu\textrm{m}$ over all compositions, especially the worst compatibility around mid composition. The blends showed higher compatibility when ethylene vinylacetate copolymer(EVA) and ethylene ethylacrylate-graft-methyl methacrylate copolymers(EEA-MMA) were added.

Resin Optimization for Manufacturing CFRP Hydrant Tanks for Fire Trucks (소방차용 CFRP 소화전 탱크제조를 위한 수지 최적화 연구)

  • Huh, Mong Young;Choi, Moon Woo;Yun, Seok Il
    • Composites Research
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    • v.35 no.4
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    • pp.255-260
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    • 2022
  • Lightweight hydrant tanks increase the amount of water that can be carried by fire trucks, resulting in longer water spray times during the initial firefighting process, which can minimize human and property damages. In this study, the applicability of carbon-fiber-reinforced polymer (CFRP) composites as a material for lightweight hydrant tanks was investigated. In particular, the resin for manufacturing CFRP hydrant tanks must meet various requirements, such as excellent mechanical properties, formability, and dimensional stability. In order to identify a resin that satisfies these conditions, five commercially available resins, including epoxy(KFR-120V), unsaturated polyesters(G-650, HG-3689BT, LSP8020), vinyl ester(KRF-1031) were selected as candidates, and their characteristics were analyzed to investigate the suitability for manufacturing a CFRP hydrant tank. Based on the analyses, KRF-1031 exhibited the most suitable properties for hydrant tanks. Particularly, CFRP with KRF-1031 exhibited successful results for thermal stability and elution tests.

An Experimental Study on the Degradations of Material Properties of Vinylester/FRP Reinforcing Bars under Accelerated Alkaline Condition (급속 알칼리 환경하에서의 비닐에스터/FRP 보강근의 재료성능 저하 특성에 관한 실험적 연구)

  • Oh, Hongseob;Kim, Younghwan;Jang, Naksup
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.2
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    • pp.51-59
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    • 2019
  • There is increasingly more research focusing on the application of FRP reinforcing bars as an alternative material for steel reinforcing bars, but most such research look at short term behavior of FRP reinforced structures. In this study, the microscopic analysis and tensile behavior of Basalt and Glass FRP bars under freezing-thawing and alkaline conditions were experimentally evaluated. After 100 cycles of the freezing and thawing, the tensile strength and elastic modulus of FRP bars decreased by about 5%. In the case of microstructure of FRP bars during the initial 20 days, no significant damages of FRP bar sections were found under $20^{\circ}C$ alkaline solution; however, the specimens immersed in $60^{\circ}C$ alkaline solution were found to experience resin dissolution, fiber damage and the separation of the resin-fiber interface. In the alkaline environment, the strength decrease of about 10% occurred in the environment at $20^{\circ}C$ for 100 days, but the tensile strength of FRPs exposed for 500 days decreased by 50%. At temperature of $40^{\circ}C$ and $60^{\circ}C$, an abrupt decrease in the strength was observed at 50 and 100 days. Especially, the tensile strength decrease of Basalt fiber Reinforced Polymer bars showed more severe degradation due to the damage caused by dissolution of resin matrix and fiber swelling in alkaline solution. Therefore, in order to improve the long-term performance of the surface braided FRPr reinforcing bars, surface treatment is required to ensure alkali resistance.