• Title/Summary/Keyword: 비극

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Synthesis of Resin Derivatives and Purification of Protein - Synthesis of Benzoyl-AH-Sepharose 4B and Purification in Pleurotus cornucopiae(mushroom) - (친화성 고분자 유도체의 합성 및 단백질의 분리정제에 관한 연구 - Benzoyl-AH-Sepharose 4B의 합성 및 흰느타리버섯중 단백질의 분리정제 -)

  • Min, Tae-Jin;Chang, Hung-Bae;Choi, Won-Ki
    • The Korean Journal of Mycology
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    • v.16 no.3
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    • pp.121-127
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    • 1988
  • For selective purification of protein in Pleurotus cornucopiae (Per.) Rolland, affinity chromatography was performed by benzoyl-AH-Sepharose 4B gel synthesized using AH-Sepharose 4B with starting materials. Ligand capacity of benzoyl group was 9.3 micromole per milliliter of gel. Total apparent molecular weight of affinity protein was 255KD, which were protein complex of 29.5, 31.5 34.0, 71.0 and 89.0KD, respectively. The contents of nonpolar, polar, positively charged, and negatively charged amino acid were 45.68%, 26.93%, 11.81% and 15.58%, respectively. The nonpolar protein was selectively purified by hydrophobic ligand of benzoyl group of gel.

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Effect of Polar Components on Phase Inversion Temperatures in Systems Containing Nonionic Surfactants and Nonpolar Oils (비이온성 계면활성제, 비극성 오일을 포함한 계에서의 극성 성분의 Phase Inversion Temperature에 대한 영향)

  • Lim, Jong-Choo;Mori, Fuyuhiko
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.274-284
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    • 1994
  • Phase Inversion Temperature (PIT) measurements showed that the addition of polar components such as oleyl alcohol and oleic acid to the system comprising n-dodecylpentaoxyethylene monoether ($C_{12}E_5$), nonpolar oil (n-hexadecane) and water produced large reductions in the PIT. The PIT was lowered as the additive-to-surfactant ratio in the surfactant films in the microemulsion phase was increased. Another dramatic effect of additive was the manner in which it affects the volume of the microemulsion phase at the PIT of the oil and water solubilization characteristics. Microemulsion phase volume was increased rapidly with decreasing PIT, i.e., with increasing amounts of additive in the system. Also with a decrease in PIT, the solubilization parameters of both oil and water in the microemulsion phase were strikingly increased. Even though soil removal data were not available for the conditions where our results obtained, PIT measurement seems a useful starting point for estimating conditions when middle-phase microemulsion formation and its associated high solubilization of oil can be expected.

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Filler-Elastomer Interactions 5. Effect of Silane Surface Treatment on Interfacial Adhesion of Silica/Rubber Composites (충전재-탄성체 상호작용 5. 실란 표면처리가 실리카/고무 복합재료의 계면 특성에 미치는 영향)

  • 박수진;조기숙
    • Polymer(Korea)
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    • v.26 no.4
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    • pp.445-451
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    • 2002
  • In this work, the adsorption characteristics and mechanical interfacial properties of treated silicas by silane coupling agents, such as, ${\gamma}$-methacryloxy propyl trimethoxy silane (MPS), ${\gamma}$-glycidoxy propyl trimethoxy silane (GPS), and ${\gamma}$-mercapto propyl trimethoxy silane (MCPS), were investigated. The equilibrium spreading pressure ($pi_e$), surface free energy ($gamma_s$ s/), and specific surface area ($S_{BET}$) were studied by the BET method with $N_2$/77 K adsorption. The developments of nonpolar functional groups of the silica surfaces treated by silane coupling agents led to the increase in the $S_{BET}$, $pi_e$, and $gamma_s$, resulting in the improved tearing energy ($G_{mc}$)of the silica/rubber composites. The composites treated by MPS showed the superior mechanical interfacial properties in these systems. These results explained by changing of crystalline size, dispersion, agglomerate, and surface functional group of silica/rubber composites.

Preparation of Polyolefin Based Segmented Copolymers Through Controlled Radical Polymerization Technique (조절 라디칼 중합법에 의한 폴리올레핀 기반 분절 공중합체의 제조)

  • Hong, Sung-Chul;Lee, Seong-Hoon;Cho, Hyun-Chul
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.209-221
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    • 2009
  • Polyolefins are important commodity polymers with the largest volume of business owing to their outstanding combination of cost performance and excellent physical properties. However, the lack of functional groups often has limited their end uses, such as compatibilizer, modifier and adhesive, where the interaction with other materials is especially important. The incorporation of functional groups as polymer segments to afford block or graft polyolefin copolymers has been extensively investigated in the context of the functional polyolefin hybrids. Living polymerization processes have been considered to be an efficient method to prepare the polyolefin hybrids with precisely controlled architecture and compositions. Among the living polymerization techniques, controlled/"living" radical polymerization (CRP) methods are very effective not only because of the controllability of polymerization but also because of the versatility of monomers and polymerization conditions. In this review paper, progresses on the preparations of polyolefin graft or block copolymers through CRP techniques are summarized. The commodity polymers such as polyisobutylene, polyethylene and polypropylene are combined with polar segments such as polyacrylate, polymethacrylate, polystyrene to yield functionalized polyolefins.

Vulcanization Efficiency of Non-polar Rubber Compounds by Microwave (마이크로파를 이용한 비극성 고무컴파운드의 가황 효율)

  • Jung, U-Sun;Lee, Won-Ki;Lim, Kwon-Tack
    • Polymer(Korea)
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    • v.35 no.3
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    • pp.228-231
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    • 2011
  • The rate of vulcanization of nonpolar ethylene-propylene-diene terpolymer(EPDM)/carbon black compounds was investigated by using hot air and microwave as a heating source. The present study parameters such as heating source, sample thickness, and loading of an additive. The compound thickness was the main factor in the hot air vulcanization. It was due to the poor thermal conductivity of EPDM; that is, the thicker thickness, the lower vulcanization rate. For 100% vulcanization, the compound with 3 mm thickness required 7 min at $250^{\circ}C$ in the hot air system. However, the vulcanization of EPDM compounds by microwave system was not affected by the thickness while strongly dependent on the amount of a polar additive, carbon black. A compound with 80 phr of carbon black was perfectly vulcanized within 30 sec. These results suggest that the use of microwave as a heating source is an effective method for the vulcanization of compounds including a polar component.

The Romance and Tragedy in Lee Chan's Poetry (이찬 시의 낭만성과 비극성)

  • Yoo, Sung Ho
    • Cross-Cultural Studies
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    • v.19
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    • pp.127-147
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    • 2010
  • Lee Chan's early poems were defined as the world of romance. His second-term poems were defined as proletarian poetry and poems written in prison when he made the romance as the core point through longing and desire for lost world. Maximizing the romance was proletarian poetry. His third-term poems were feelings of the northern countries called the spirit of Lee Chan's poems. He recognized the emotion of diaspora as the tragedy in these poems. It was remarkable time that the poet's tragedy observing and expressing the reality of colony. Afterward he wrote poems related inside withdrawal and war cooperation, finally he wrote poem after defecting to North Korea. Lee Chan showed the romance of desire in early poems and proletarian poems. Then he indicated acute scenery of the tragedy in the late 1930s' poems. In heavy situation, he moved from pro-Japanese literature to North Korean literature. However he didn't throw introspected self-reflection language to himself each his changing. But through several form of garden, he clearly showed consistent of maximizing his utopia sense. The time Lee Chan experienced was an icon which intensively indicated several features of deformed modern Korean poetic history. He was a unique poet who expressed various traces of modern Korean poetry in short time step by step. His path informed that he was a special poet who stepped the trace of many modern Korean poetry's extremes such as romantic poetry, proletarian poetry, prison poetry, pro-Japanese poetry and North Korean poetry. Likewise we can call his life as a grudge return. Because he left hometown, experienced the light and darkness of modern times and returned his hometown.

The Memory Sttruggle Surrounding Battle of Okinawa and 4.3 Jeju Massacre - Based on Island of the Gods Island of Oshiro Tatsuhiro and Sooni's Uncle of Hyun, Ki Young (오키나와 전투와 제주 4·3사건을 둘러싼 기억투쟁 -오시로 다쓰히로 『신의 섬』과 현기영의 「순이 삼촌」을 중심으로)

  • Son, ji-youn
    • Cross-Cultural Studies
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    • v.41
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    • pp.7-32
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    • 2015
  • This study started from an interest in the unique history and literature of Okinawa and Jeju Islands. The Battle of Okinawa at a late stage of the Asia-Pacific theatre of World War II, and the indiscriminate violence in the 4.3 Jeju Massacre directly show the shared tragedy of the two islands; furthermore, they are are both located on the frontier of a nation's authority, and thus are symbolic cases. This thesis analyzes Oshiro Tatsuhiro's Island of the Gods and Hyun, Ki Young's Sooni's Uncle, both directly deal with the tragedy of two different but analogous incidents, and question the difference in memory struggle and definitions. Thus, though both novels show a similarity in focusing on and exposing the forbidden memory of mass suicide and massacre, the methods of suggesting the course of memory struggle are different. For example, in contrast to Hyun who took a different approach from the fury, accusations, and violence of South Korea to espoused forgiveness and reconciliation, Oshiro showed the changes in the form of responding to the mainland Japan.

The Study on Conflict expression of DongraeYaroo (동래야류의 갈등표현 방식 연구)

  • Sim, SangGyo
    • (The) Research of the performance art and culture
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    • no.33
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    • pp.33-58
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    • 2016
  • This thesis studied about the expression of the conflict in DongraeYaroo. Study perspective was time and passion. Time refers to a change in the time to move to the current from the past. As in the study was the change in the phase and values of the characters occurred. Passion is an act which is scheduled departing from the spirit moves the body. And the emotions move the human heart. And it was associated with the inner values that determine the ethical life. DongraeYaroo should ever criticize feudal era and values through the conflict with the changes in time. Through conflict with the realism tendencies and passions were melodramatic tendencies. DongraeYaroo is a folk masques of realism and melodramatic nature complex. DongraeYaroo has a part that is causing the conflict with the contents of the passion associated with the character's sexual desire is elsewhere. There are also distorted passions and inde normal expression of tragic passion passions that lead to death.

Compositions of fatty acids and structural identification in human breast milk (모유 중 지방산 조성 및 구조 분석)

  • Ji-Woo, Yoo;Young-Soo, Keum;Nam Mi, Kang
    • Analytical Science and Technology
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    • v.35 no.6
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    • pp.229-236
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    • 2022
  • Lipidomic analyses of transient breast milk are far more limited than those of other dairy products. As a preliminary analysis of breast milk lipidomes, analytical methods for polar and nonpolar lipids from transient breast milk were developed, and detailed fatty acid profiles were determined in this study. The newly developed methods include solvent fractionation of phospholipids and acyl glycerol, one-pot derivatization to FAMEs and pyridylcarbinol esters, and instrumental analysis, including GC-FID and GC-MS. The results indicate that breast milk contains 16 major common fatty acids with 8-22 carbons. Additionally, 29 minor fatty acids were identified, including odd-numbered fatty acids and branched analogues with 11-23 carbons. Their detailed concentrations in different fractions were measured using the internal standard method. In addition to ordinary fatty acids, breast milk contains several branched fatty acids, including iso/anteiso acids with 15-18 carbons. Structural studies have been performed on selected minor fatty acids via chemical synthesis.

Filler-Elastomer Interactions. 9. Effect of Thermal Treatment on Mechanical Interfacial Characteristics of Silica/Polyurethane Composites (충전제-탄성체 상호작용. 9. 실리카/ 폴리우레탄 복합재료의 기계적 계면특성에 미치는 열처리의 영향)

  • Park, Soo-Jin;Cho, Ki-Sook;Zaborski, M.;Slusarski, L.
    • Elastomers and Composites
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    • v.37 no.4
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    • pp.258-264
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    • 2002
  • In this work, the influence of thermal treatment on surface properties of silicas and mechanical interfacial properties of silicas/polyurethane composites was investigated. The surface properties of thermally treated silicas were studied in the context of Fourier Transform-IR (FT-IR), solid-state 29Si NMR spectroscopy, and contact angle. And the mechanical interfacial properties of the silica/polyurethane composites were evaluated by composite tearing energy (GIIIC). As a result, it was found that the thermally treated silica surfaces became hydrophobic in nature, due to the condensation of surface hydroxyls and the formation of siloxane bonds, resulting in increasing the London dispersive component of surface free energy. From which, the increase of the London dispersive component of the silicas led to an improvement of the dispersion of silicas in a polyurethane matrix, finally resulting in improving the tearing energy (GIIIC) of the silicas/polyurethane composites.