• Korean Journal of Environmental Agriculture
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• v.11 no.2
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• pp.125-132
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• 1992

This study was conducted to know degradation products of the synthetic pyrethroid insecticide bifenthrin under soil, aqueous solution and UV-light irradation, and know its movement by leaching in soil. The major degradation product of bifenthrin was identified with 2-methylbiphenyl -3-y1 methanol by HPLC, UV, Mass and NMR under soil, aqueous solution and UV-light irradiation, The main degradation route was hydrolysis of the ester linkage. On exposure to UV-light, bifenthrin was decomposed almost completely in concentrations of 10 and 100 ppm in 24 hr but decomposed about 80% in 1,000 ppm. Bifenthrin was immobile in soil column system and on soil thin-layer chromatography system. Mostly bifenthrin remained in the 0-2.0㎝ layer of soil column and soil TLC.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2018.10a
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• pp.186-186
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• 2018

• Applied Chemistry for Engineering
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• v.17 no.6
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• pp.638-643
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• 2006

Pyrolytic reaction study of dichloromethane ($CH_{2}Cl_{2}$) in excess hydrogen was performed to investigate pyrolytic reaction pathways at a pressure of 1 atm with residence times of 0.3~2.0 sec in the temperature range of $525{\sim}900^{\circ}C$. A constant feed molar ratio $CH_{2}Cl_{2}$:$H_{2}$ of 4:96 was maintained through the experiment. Reagent loss and product formation were monitored by using an on-line gas chromatograph, where batch samples were analyzed by GC/MS. Complete destruction(99%) of the parent reagent was observed at temperature near $780^{\circ}C$ with residence time over 1 sec. Major products observed were $CH_{3}Cl$, $CH_{4}$, $C_{2}H_{4}$, $C_{2}H_{6}$, and HCl. Minor products included $CHClCCl_{2}$, CHClCHCl, $CH_{2}CHCl$, and $C_{2}H_{2}$. The pyrolytic reaction pathways to describe the important features of intermediate product distributions and reagent loss, based upon thermodynamic and kinetic principles, were suggested. The results of this work provided a better understanding of pyrolytic decomposition processes which occur during the pyrolysis of $CH_{2}Cl_{2}$ and similar chlorinated methanes.

• Journal of the Korean Chemical Society
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• v.62 no.5
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• pp.344-351
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• 2018

The IR spectra of gaseous phenanthrene, phenathrenols, phenanthrenyl radicals, and hydroxylphenanthrene radicals have been obtained using the BLYP/6-311++G(d,p) method. A comparison of these spectra shows that the measurements of IR spectra can be valuable to identify the reaction pathway(s) of the phenanthrene decomposition reaction by ${\cdot}OH$. We have found that the H atom abstraction reaction process can be easily identifiable from the $650-850cm^{-1}$ (CH out-of-plane bending) region and the ${\cdot}OH$ addition reaction process from the CH stretching and bending modes region of IR spectra. In addition, the calculated IR spectra of all five phenanthren-n-ols (n = 1, 2, 3, 4, 9) have also given in this work.

• Korean Journal of Microbiology
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• v.55 no.1
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• pp.83-85
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• 2019

Pseudomonas sp. PAMC 29040 was isolated from a maritime tundra soil in Antarctica for its ability to degrade lignin and subsequently confirmed to be able to depolymerize heterogeneous humic substance (HS), a main component of soil organic matter. The draft genome sequences of PAMC 29040 were analyzed to discover the putative genes for depolymerization of polymeric HS (e.g., dye-decolorizing peroxidase) and catabolic degradation of HS-derived small aromatics (e.g., vanillate O-demethylase). The information on degradative genes will be used to finally propose the HS degradation pathway(s) of soil bacteria inhabiting cold environments.

• Korean Journal of Microbiology
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• v.55 no.2
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• pp.177-179
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• 2019

Pseudomonas kribbensis CHA-19 was isolated from a temperate forest soil (mid latitude) in New Jersey, USA, for its ability to degrade humic acids, a main component of humic substances (HS), and subsequently confirmed to be able to decolorize lignin (a surrogate for HS) and catabolize lignin-derived ferulic and vanillic acids. The draft genome sequence of CHA-19 was analyzed to discover the putative genes for depolymerization of polymeric HS (e.g., dye-decolorizing peroxidases and laccase-like multicopper oxidases) and catabolic degradation of HS-derived small aromatics (e.g., vanillate O-demethylase and biphenyl 2,3-dioxygenase). The genes for degradative activity were used to propose a HS degradation pathway of soil bacteria.

• Proceedings of the KSEG Conference
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• 2004.03a
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• pp.12001-12049
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• 2004

암석의 풍화과정은 화학적인 변질, 물리적인 분해 및 생물학적인 작용으로 나뉘어 진다. 풍화에 영향을 주는 요소는 기후, 조성광물의 종류 및 구조, 절리와 단층, 열수변질작용과 광화작용, 염기성 및 산성암맥과 지형 등이다. 또한 암석의 풍화는 성인에 따라 다양한 양상으로 진행되는데 이는 암석을 이루고 있는 각각 광물들이 열역학적인 반응경로가 서로 다르고, 이에 수반되는 물리적인 풍화진행속도가 차이가 있으며, 암석의 균질성, 투수성 등이 암종별로 다양하기 때문이다. 현장에서 암석의 풍화정도는 조성광물의 변질과 분해정도를 육안 등으로 정성적으로 판단하고 분류하는 것이 일반적이다. (중략)

• Journal of Korean Society of Industrial and Systems Engineering
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• v.21 no.48
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• pp.153-164
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• 1998

본 논문은 2-상태 시스템의 신뢰도 계산을 위하여 Heidtmann[3]이 제시한 가역 알고리즘을 부울 대수를 사용하여 경로집합으로부터 절단집합을 유도하거나, 역으로 절단집합으로부터 경로집합을 유도함으로서 효율성을 입증하였으며, 포함-불포함 공식(inclusion-exclusion formula)과 추축 분해법칙(pivotal decomposition rule)을 이용하여 직·병렬구조 및 복합구조의 신뢰도를 계산할 수 있는 알고리즘을 개발, 분석하였다.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.25 no.11A
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• pp.1613-1619
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• 2000

이 논문에서는 전파재널 측정 시스템을 이용하여 건물내 무선 채널의 전파특성인 실효 시간지연 확산과 경로손실을 측정하고 분석한 결과를 제시한다. 구성된 측정 시스템은 미끄럼 상관기를 이용한 대역확산 채널 측정 시스템에서 2 GHz에서 동작하며 3 m 의 분해능을 갖는다. 건물내 무선 채널 특성의 측정환경은 송신 안테나와 수신 안테나가 같은 층에 있을때, 서로 다른 층에 있을때, 그리고 사무실 안에 같이 위치할 때의환경으로구분하여 실험한다.

• Proceedings of the Acoustical Society of Korea Conference
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• autumn
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• pp.353-356
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• 2001

본 논문은 수중 음향을 이용하여 다중경로(Multipath) 환경에서의 해저면 설치 수신기의 3차원 위치 추정 알고리즘을 제안한다. 해저면 설치 수신기의 위치 추정을 위해 기준 음원의 위치와 음원과 수신기 사이의 수평거리를 사용하며, 수평거리 산출 시 다중경로의 영향을 고려하기 위해 음선 이론 모델을 사용하여 음원과 수신기 사이의 수평거리를 추정한다. 또한 특이치 분해법(Singular Value Decomposition estimator; SVD)을 사용하여 설정된 3차원 위치 추정 문제의 최적해를 추정하며, 이를 사용하여 동해 해상 실험 자료를 분석한다. 논문의 연구 결과 제안된 해저면 설치 3원 위치 추정 알고리즘은 다중경로 환경에서도 좋은 성능을 나타냄을 알 수 있다.