• Analytical Science and Technology
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• v.21 no.4
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• pp.304-315
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• 2008

The total suspended particles (TSP) collected at the 1100 site of Mt. Halla have shown higher compositions for the anthropogenic components followed by marine and soil originated ones. The concentrations of the soil originated nss-$Ca^{2+}$, Al, Fe, Ca components have been increased in spring, and the anthropogenic $NH{_4}^+$, $K^+$, nss-$SO{_4}^{2-}$ components showed high concentrations in June. Meanwhile, the concentration of $NO{_3}^-$ as same as nss-$Ca^{2+}$ was higher in spring. It's likely due to the influence of its long-range transport from China. Compared to the non-Asian Dust periods, the concentrations of nss-$Ca^{2+}$, Al, Ca, and Fe have been increased 7.2~9.5 times in Asian Dust storm periods, and those of nss-$SO{_4}^{2-}$ and $NO{_3}^-$ were 1.3 and 3.8 times, respectively. From the factor analysis, the TSP compositions were influenced mainly by anthropogenic emission sources, followed by oceanic and soil sources. The backward trajectory analysis has shown that the concentrations of the anthropogenic and soil components were increased when the air parcels had been moved into Jeju island via China in a northwesterly wind.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.3
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• pp.329-336
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• 2006

Iron manufacturing process involves production of various by-product including slag, sludge, sintering and EAF(Electric Arc furnace dust). Some of the by-products such as EAF and sintering dust are disposed of as waste due to their high heavy metal contents. It has been notice for many years that the EAF dust also contain about 65% of Fe(0) and Fe(II) and then the possible utilization of the iron. One possibility is to apply the EAF as a lining material in conjunction with clay or HDPE liners, in waste landfill. The probable reaction between the leachate containing toxic elements such as TCE, PCE dioxine and $Cr^{6+}$ is reduction of the toxic materials in corresponding to the oxidation of the reduced iron and therefore diminishing the toxicity of the leachate. It is, however, prerequisite to evaluate the leaching characteristics of the EAF dust before application. Amelioration of the leachate would be archived only when the level of toxic elements in the treated leachate is less than that of in the untreated leachate. Several leaching techniques were selected to cover different conditions and variable environments including time, pH and contact method. The testing methods include availability test, pH-stat test and continuous column test. Cr and Zn are potentially leachable elements among the trace metals. The pH of the EAF dust is highly alkaline, recording around 12 and Zn is unlikely to be leached under the condition. On the contrary Cr is more leachable under alkaline environment. However, the released Cr should be reduced to $Cr^{3+}$ and then removed as $Cr(OH)_3$. Removal of the Cr is observed in the column test and further study on the specific reaction of Cr and EAF dust is underway.

• Fire Science and Engineering
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• v.12 no.4
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• pp.13-19
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• 1998

We investigated the weight loss according to temperature using Thermal Gravimetric Analysis(TGA) in order to find the thermal hazard of carbon black(Hi-Black 10, Hi-Black 50L) dusts, and the properties of dust explosion in variation of the surface functional groups and specific surface area of their dust with the same particle size. Using Hartman's dust explosion apparatus which estimate dust explosion by electric ignition after making dust disperse by compressed air, dust explosion experiments have been conducted by varying concentration and size of carbon black dust. The explosion pressure of both carbon black increased as the specific surface area increased. The results indicated that Hi-Block 50L of which specific surface area was larger three to four times than that of Hi-Black 10 was much easier of dust explosion.

• Resources Recycling
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• v.24 no.3
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• pp.27-33
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• 2015

EAFD (Electric Arc Furnace Dust) is considered as pernicious pollutant, assigned hazardous waste. Since this dust is a by-product of industry, it contains valuable metals such as Fe, Zn, Ni, Cu which can be turned into resources by recycling process. In this study, hydrometallurgical process was applied to recover Zn from Electric Arc Furnace Dusts. The result showed 95% Zn recovery at 3M $H_2SO_4$, Solids/Liquid ratio 1:2 and aeration of 1.8L/min for 2hr. However there was 80% Zn recovery at lower $H_2SO_4$ concentration apply for pilot scale plant.

• Applied Chemistry for Engineering
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• v.18 no.2
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• pp.126-129
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• 2007

In order to ruduce traffic-jam, it is requested to extend road. As a result, the construction of tunnels is inevitable considering our mountatinous topography. In tunnel construction work, major contamination materials occur from rock drilling, blasting rock, rock transporting, and short-creat. After rock blasting, a very high concentration of particles over $5000{\mu}g/m^3$ is maintained for 4 h when air is supplied by pans, by which the construction work has to be delayed at least 30 min. Although dry dust collectors are used, the effective operation time span is limited to 3 h. In this work, the behavior of particles in air and use of particle removal instruments are investigated. As a result, it was important to compare efficiencies of dry and hydro dust collectors.

• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.229-236
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• 2022

An experimental investigation was conducted on the influences of median size, dust concentration, dust condition (cloud and layer) for the fire and explosion hazard assessment of dusts with the same powder property. For this purpose, tests have been performed in accordance with 20 L explosion sphere, thermogravi- metric analyze, combustion rate tester (UN method). We investigated the explosion characteristics and flame propagation velocity (FPV) in dust cloud and the flame spread velocity(FSV) over dust layer on 8 dust samples with different particle sizes of 4 types of dusts (Sugar, Mg, Al, Zr). An explosion hazard increased with decreasing particle size in Mg and Al dust clouds, but sugar did not show the effect of explosion hazard due to particle size change in dust clouds. The flame propagation velocity (FPV) of suspended dusts increased significantly when the particle size decreased from micro to nano than the variation of particle size in micro range. The flame spread velocity (FSV) over dust layer showed a tendency to increase over the inclined dust layers (30° slope) rather than the horizontal dust layers (0° slope). The flame spread rate (FSV) over dust layers increased on the inclined dust layer (30° slope) rather than the horizontal dust layer (0° slope) and was higher upward flame than the downward flame in condition of inclined dust layers(30° slope).

• Korean Chemical Engineering Research
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• v.57 no.6
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• pp.790-803
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• 2019

The dioctyl terephthalic acid (DOTP) process produces plastic plasticizers by esterification of terephthalic acid with powder in the form of octanol. In this study, the dust explosion characteristics of terephthalic acid directly injected into the manhole in the form of powder in the presence of flammable solvent or vapor in the reactor of this process were investigated. Dust particle size and particle size distribution dust characteristics were investigated, and pyrolysis characteristics of dust were investigated to estimate fire and explosion characteristics and ignition temperature. Also, the minimum ignition energy experiment was performed to evaluate the explosion sensitivity. As a result, the average particle size of terephthalic acid powder was $143.433{\mu}m$. From the thermal analysis carried out under these particle size and particle size distribution conditions, the ignition temperature of the dust was about $253^{\circ}C$. The lower explosive limit (LEL) of the terephthalic acid was determined to be $50g/m^3$. The minimum ignition energy (MIE) for explosion sensitivity is (10 < MIE < 300) mJ, and the estimated minimum ignition energy (Es) based on the ignition probability is 210 mJ. The maximum explosion pressure ($P_{max}$) and the maximum explosion pressure rise rate $({\frac{dP}{dt}})_{max}$ of terephthalic acid dust were 7.1 bar and 511 bar/s, respectively. The dust explosion index (Kst) was 139 mbar/s, corresponding to the dust explosion grade St 1.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.246-249
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• 2008

IGCC (석탄가스화 복합발전) 시스템 공정 중 가스화기에서 발생되는 합성가스 내에는 높은 농도의 분진들이 함유되어 있기 때문에 하부 공정들을 보호하기 위해서는 가스화기 후단에 집진장치가 필히 설치되어야 한다. 집진장치의 설계 제작 운전에 있어서 점착성 분진층 부착,분진 브리징, 필터 파손 현상 등과 같은 다양한 문제점들로 인하여 고온의 합성가스를 처리하는 데는 아직 기술적 한계들이 산재해 있는 상황이다. 이와 같은 문제점들은 필터에 부착된 분진층의 탈진성능을 향상시키거나, 필터의 열피로를 줄일 수 있도록 필터 재생을 위한 탈진의 횟수를 줄이는 방법을 통하여 해결될 수 있다. 본 연구에서는 파일롯 규모의 IGCC용 세라믹캔들필터 집진장치에서의 가스 유입 및 탈진 조건에 따른 집진장치의 차압 특성 변화를 수치해석과 실험을 통하여 분석함으로써 탈진성능을 향상시킬 수 있는 조건과 탈진 횟수를 최소화시킬 수 있는 방안을 도출하고자 하였다.

• Tuberculosis and Respiratory Diseases
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• v.58 no.2
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• pp.167-173
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• 2005

Background : Airborne particles during Yellow Sand phenomena are known to be associated with the respiratory disease. The purpose of this study was to evaluate the concentration and metal component properties of Yellow Sand particles and compare with airborne microbial concentration and species in non Yellow Sand and Yellow Sand phenomena. Methods : Samplings were carried out in 2002 in Seosan, during non Yellow Sand and Yellow Sand phenomena. Samples were taken using the 8-stage Cascade impactor and metallic elements were analyzed by XRF. Those were culture on the media for bacterial and fungal culture and celline for virus. Results : The concentration of total suspended particulate matter were respectively $80.2{\mu}g/m^3$, $40.3{\mu}g/m^3$ in non Yellow Sand and Yellow Sand phenomena. The concentration of metallic elements such as Ca, Fe, Cu and Zn in Yellow Sand phenomena were higher than its in non Yellow Sand. Two bacteria, Bacillus species and Staphylococcus were grown in two periods. In both periods, several fungal spores(Mucor species, Cladosporum, Alternaria, Aspergillus, Penicillium, and Alternaria species) were identified. The differences of bacteria and fungus species not observed in Yellow Sand and non Yellow Sand. Any viruses were not isolated in between both periods. Conclusions : The concentration of total suspended particulate matter and some metallic elements in Yellow Sand phenomena were higher than its in non Yellow Sand. The difference of bacteria and fungus species was not observed in non Yellow Sand and Yellow Sand phenomena.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.6
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• pp.449-453
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• 2009

This study focused on the content characteristics of regulated hazardous substances in specific wastes. Regulated heavy metal such as Cu, Pb, Cd analyzed the 108 waste samples that it choice from the representative facilities. Analytical method used content test method, suggested on the basis of analytical method of developing country, and the results as compared with limited standard in Austria Petroleum, primary metalworking and electronic industry had high content of Cu more than 100 mg/kg of Austria limited standard. Pb detected high level concentration the sample that dust producted at Primary metalworking industry. In case of total Cr was show that high content at KSIC 18, 19, 23 etc but result analyzed Cr(VI), it was shown that high level at dust producted from sewing clothes and fur industry.