• Journal of the Korean Chemical Society
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• v.43 no.3
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• pp.251-256
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• 1999

Viscosities of toluene were experimentally determined by the falling-ball method at several temperatures and pressures to investigate the pressure and temperature dependence of the viscosity of toluene. With the shear stress of the viscous flow of toluene, the shear free energy, the shear entropy, and the shear enthalpy were defined to discuss the variations of the shear thermodynamic properties with pressure. The effect of temperature and pressure on the shear thermodynamic properties obtained experimentally can be explained by means of the molecular thermal agitation due to temperature incleasing and the steric effect of the closed molecules of to Iuene due to pressure elevation.

• Journal of Advanced Marine Engineering and Technology
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• v.20 no.3
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• pp.11-18
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• 1996

Liquid droplets of water and argon surrounded by their vapor have been simulated by the milecular dynamics method. To explore the surface phenomena of clusters, each molecule is classified into 'liquid', 'surface', or 'vapor' with respect to the number of neighbor molecules. The contribution of a 'surface' molecule of the water cluster to the far infrared spectrum is almist the same as that of the 'liquid' molecule. Hence, the liquid-vapor interface is viewed as geometrically and temporally varying boundary of 'liquid' molecules with only a single layer of 'surface' molecules that might have different characteristics from the 'liquid' molecules. The time scale of the 'phase change' of each molecule is estimated for the argon cluster by observing the instantancous kinetic and potential energies of each molecule. To compare the feature of clusters with macroscopic droplets, the temperature dependence of the surface tension of the argon cluster is estimated.

• Journal of Advanced Navigation Technology
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• v.16 no.4
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• pp.657-664
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• 2012

One of the methods to transmit solute through solvent is diffusion. Various particles or molecules including several charged ions in the body diffuse from high density region to low density due to density difference or external electric field. This kind of mechanism is due to thermal motion of each solute molecules. These situations can be deployed using Fick's first and second laws that govern diffusion phenomena in the body. I analysis these diffusion status of material in the body using above mentioned Fick's laws and then implement them through illustration.

• Applied Chemistry for Engineering
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• v.10 no.5
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• pp.743-747
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• 1999

The component polymer was modified to enable the formation of intermolecular hydrogen bonding in the immiscibile polystyrene(PS)/polymethacrylate(PMA) blends. The mole percentages of hydroxystyrene of the poly(styrene-co-4-hydroxystyrene) copolymer(modified polystyrene, MPS) were controlled to 7%, 10% and 18%, respectively. MPS was used with PMA to study the variation of the miscibility in blends. PMA which had such different length of side chain as methyl, butyl, hexyl and ethylhexyl, respectively, was selected to study the effect of side chain length on the formation of intermolecular hydrogen bonding. As the hydroxyl content of MPS increased, the formation of intermolecular hydrogen bonding increased. The length of side chain of PMA had enormous effect on the miscibility of blend as confirmed from the result of cloud point measurement. As the length of side chain increased, the formation and the strength of intermolecular hydrogen bonding decreased severely due to the steric effect and the increased chain mobility.

• Membrane Journal
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• v.30 no.4
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• pp.242-251
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• 2020

Computer simulation tools mainly used for polymer materials and polymeric membranes are divided into various fields depending on the size of the object to be simulated and the time to be simulated. The computer simulations introduced in this review are classified into three categories: Quantum mechanics (QM), molecular dynamics (MD), and mesoscale modeling, which are mainly used in computational material chemistry. The computer simulation used in polymer research has different research target for each kind of computational simulation. Quantum mechanics deals with microscopic phenomena such as molecules, atoms, and electrons to study small-sized phenomena, molecular dynamics calculates the movement of atoms and molecules calculated by Newton's equation of motion when a potential or force of is given, and mesoscale simulation is a study to determine macroscopically by reducing the computation time with large molecules by forming beads by grouping atoms together. In this review, various computer simulation programs mainly used for polymers and polymeric membranes divided into the three types classified above will be introduced according to each feature and field of use.

• Journal of the Korean Chemical Society
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• v.53 no.6
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• pp.784-792
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• 2009

In this study, we investigated the unsuitable cases for the hierarchy of the curriculum in science 'teaching-learning lesson plan' which is on the web site of the each city's support center for teaching and learning and Seoul Science Park with a purpose of giving helpful data for science teachers at lessons. The investigation is limited to 'Three states of matter' unit for the 7th grade and the content elements used at analysis was the "state changes of matter", "molecule" and "molecular model". The case found for unsuitable case for the hierarchy of the curriculum was phase equilibrium, ice crystal theory, peculiar property of water, classification of solid, thermal energy and physical change at the "state changes of matter". While the "molecular model" showed molecular motion and density. On the other hand, no case was found at "molecule".

• Membrane Journal
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• v.29 no.1
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• pp.37-43
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• 2019

In this study, we investigated how the force-field, which is the most important factor to define atomic motion in molecular dynamics (MD), affects the motion of the polymer and gas molecules. The repeat units and the polymer structure were well simulated in all five force-fields, and the distribution of the polymer linear chain in the final polymer 3D model did not show any significant difference. However, the movement of actual gas molecules showed a very different tendency, which was also observed in COMPASS and pcff using the same functional form. Therefore, even if the same structure is used, it can be seen that the motion of the gas molecule moves under the influence of the force-field continuously over time, so that the effect is much larger than that of macromolecules such as a polymer linear chain. Accordingly, in case of using different force-fields, it is necessary to be very careful in comparison of those results.

• Journal of The Korean Association For Science Education
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• v.22 no.3
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• pp.560-570
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• 2002

This study was focused on whether secondary science teachers have consistent, integrative scheme on the definition of atmospheric pressure and phenomena caused by air pressure. We had made questionnaire and let 94 science teachers answer. We sorted the responses according to their major, school and compared them with the description in textbooks. The result can be summarized into three findings. First of all, teachers whose major is chemistry have strong tendency to understand that atmospheric pressure is caused by molecular motion though it, in textbooks, is defined as the pressure by weight of air mass. The half of respondents believed that decreasing of atmospheric pressure in high altitude is due to molecular motions, while most textbook says decrease in the weight of air mass. Secondly, many science textbooks show that air mass expands, rises, becomes less dense and the pressure of atmosphere becomes low when it receives heat. So, most of respondents explained low pressure is formed by lower density. Thirdly, they answered that they just teach the phenomena of air pressure by using the textbooks which mainly deal with the present state rather than a principle. In conclusion, the science textbooks should present the exact description and consolidated structures of those concepts to prevent students from having misconceptions on air pressure. In addition, training program for science teachers would be necessary to reconsider and explore the natural phenomena in various viewpoints.

• The Bulletin of The Korean Astronomical Society
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• v.38 no.2
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• pp.77.1-77.1
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• 2013

산개성단은 은하계 내에서 그 일생을 보내며 자체적인 역학적 진화를 한다. 또한, 거대 성간 분자운, 은하의 회전 그리고 은하의 중력 등에 영향을 받아 성단의 헤일로 영역에 조석꼬리와 같은 구조로 나타날 수 있다. 이러한 현상을 관측하기는 어려운데 그 이유는 넓은 영역에 걸쳐 있는 성단의 흐린 구성원에 대한 고유운동 자료가 없어 낱별과 성단의 구성원을 구별하는 것이 어렵기 때문이다. 우리는 이 문제를 통계적으로 해결하기 위하여 "4차원 구성원 확률" 이라는 새로운 방법을 개발하였다. 이 방법은 별의 공간 좌표와 색-등급도 상에서 위치를 동시에 고려하여 구성원 확률을 구하는 독창적인 방법이다. 본 발표에서는 이 방법을 적용한 결과를 고유운동으로 얻은 구성원확률과 비교하고, 몬테칼로 시뮬레이션으로 검증한 결과를 소개하고자 한다. 우리의 방법을 통하여, 은하면에 있는 다양하고 많은 산개성단에 대하여 관측연구를 수행한다면, 다양한 조석꼬리의 가능성 검증을 할 수 있고, 은하와 성단의 상호 작용과 역학적 진화에 대한 이해의 폭을 넓힐 수 있을 것으로 기대한다.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.108.2-108.2
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• 2014

잔류가스측정 질량분석기(RGA)는 진공챔버 내부의 진공상태 이상유무, 공정상태 확인 및 주입가스 농도제어 등 여러 종류의 작업에 응용되고 있다. 반도체용 박막 제조공정(PVD, CVD)에서 챔버 내의 수분 혹은 불순물 가스의 정확한 모니터링은 반도체 품질향상에 매우 중요하다. 1 Pascal 진공도의 증착용 챔버에 RGA를 직접 장착하여 작동시키기 위해서는 저진공용 RGA가 사용되어야 한다. 10-3 Pascal에서 6m 자유운동거리를 갖는 질소분자는 1 Pascal에서는 6 mm로 짧은 자유운동거리를 갖는다. 따라서 1 Pascal 저진공영역에서 이온을 생성시키고 mass filter를 사용하여 질량분석을 하기 위해서는 이온원과 mass filter 길이가 자유운동거리 수준으로 작아져야한다. 저 진공영역에서는 검출기와 전자방출용 필라멘트가 저진공에서 작동되도록 일반고진공용 RGA와는 완전히 다르게 소형으로 설계 제작되어야 한다. 10-7 Pascal 이상의 초고진공에서 사용되는 RGA는 이온원이 작동할 때 발생하는 outgassing을 낮추도록 설계가 되어야 초고진공의 유지가 가능하다. 한국표준과학연구원에서 현재 개발 중인 일반고진공용 RGA를 소개하고 저진공용과 초고진공용 RGA의 설계특성을 발표한다.